KR910011876A - 술폰화 트리페닐포스판 화합물을 함유하는 로듐의 착화합물 - Google Patents
술폰화 트리페닐포스판 화합물을 함유하는 로듐의 착화합물 Download PDFInfo
- Publication number
- KR910011876A KR910011876A KR1019900020651A KR900020651A KR910011876A KR 910011876 A KR910011876 A KR 910011876A KR 1019900020651 A KR1019900020651 A KR 1019900020651A KR 900020651 A KR900020651 A KR 900020651A KR 910011876 A KR910011876 A KR 910011876A
- Authority
- KR
- South Korea
- Prior art keywords
- triphenylphosphane
- complexes
- compounds
- containing sulfonated
- rhodium containing
- Prior art date
Links
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 title claims 2
- 229910052703 rhodium Inorganic materials 0.000 title 1
- 239000010948 rhodium Substances 0.000 title 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical class C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 title 1
- 239000011734 sodium Substances 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims 1
- 239000005922 Phosphane Substances 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 238000005227 gel permeation chromatography Methods 0.000 claims 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910000064 phosphane Inorganic materials 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 비스{μ-히드록소)비스[트리스(소듐 m-술포네이토페닐)포스판]로듐(Ⅰ)}·도데카히드레이트.
- 수용액 중의 CIRh[P(C6H4-m-SO3Na)3]x9H20를 실온에서 또는 약간 높은 온도에서 히드라진 히드레이트로써 처리함을 특징으로 하는 제1항에 따른 화합물의 제조방법.
- HRh[P(C6H5)]4를 과량의 P(C6H4-m-SO3Na)3와 반응시킴을 특징으로 하는 제1항에 따른 화합물의 제조방법.
- 제1 또는 2항에 있어서, 반응 생성물을 겔 크로마토 그래피로 정제함을 특징으로 하는 방법.
- 촉매 또는 촉매성분으로서의 제1항에 청구된 화합물의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3942789A DE3942789A1 (de) | 1989-12-23 | 1989-12-23 | Sulfoniertes triphenylphosphan enthaltende komplexverbindung des rhodiums |
| DEP3942789.7 | 1989-12-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR910011876A true KR910011876A (ko) | 1991-08-07 |
Family
ID=6396316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900020651A KR910011876A (ko) | 1989-12-23 | 1990-12-14 | 술폰화 트리페닐포스판 화합물을 함유하는 로듐의 착화합물 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5051522A (ko) |
| EP (1) | EP0435069A3 (ko) |
| KR (1) | KR910011876A (ko) |
| AU (1) | AU625957B2 (ko) |
| BR (1) | BR9006468A (ko) |
| CA (1) | CA2032361A1 (ko) |
| DE (1) | DE3942789A1 (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1286879B1 (it) * | 1996-11-21 | 1998-07-17 | Consiglio Nazionale Ricerche | Leganti 1,3-difosfinopropanici e complessi da essi formati con metalli di transizione,loro preparazione e uso |
| EP1157740A3 (en) | 2000-05-18 | 2002-02-27 | Haldor Topsoe A/S | Rhodium containing solutions |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4748261A (en) * | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
| US4885376A (en) * | 1987-10-13 | 1989-12-05 | Iowa State University Research Foundation, Inc. | New types of organometallic reagents and catalysts for asymmetric synthesis |
| US4873213A (en) * | 1988-08-12 | 1989-10-10 | Puckette Thomas A | Low pressure rhodium catalyzed hydroformylation of olefins |
-
1989
- 1989-12-23 DE DE3942789A patent/DE3942789A1/de not_active Withdrawn
-
1990
- 1990-12-12 EP EP19900123909 patent/EP0435069A3/de not_active Withdrawn
- 1990-12-14 CA CA002032361A patent/CA2032361A1/en not_active Abandoned
- 1990-12-14 KR KR1019900020651A patent/KR910011876A/ko not_active Application Discontinuation
- 1990-12-19 BR BR909006468A patent/BR9006468A/pt unknown
- 1990-12-21 US US07/632,469 patent/US5051522A/en not_active Expired - Fee Related
- 1990-12-21 AU AU68369/90A patent/AU625957B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU625957B2 (en) | 1992-07-16 |
| CA2032361A1 (en) | 1991-06-24 |
| AU6836990A (en) | 1991-06-27 |
| DE3942789A1 (de) | 1991-06-27 |
| EP0435069A2 (de) | 1991-07-03 |
| BR9006468A (pt) | 1992-08-04 |
| US5051522A (en) | 1991-09-24 |
| EP0435069A3 (en) | 1991-12-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E601 | Decision to refuse application |