KR910009823A - Thermoplastic resin composition - Google Patents

Thermoplastic resin composition Download PDF

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Publication number
KR910009823A
KR910009823A KR1019890017245A KR890017245A KR910009823A KR 910009823 A KR910009823 A KR 910009823A KR 1019890017245 A KR1019890017245 A KR 1019890017245A KR 890017245 A KR890017245 A KR 890017245A KR 910009823 A KR910009823 A KR 910009823A
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KR
South Korea
Prior art keywords
phosphate
dihydrogen phosphate
resin composition
thermoplastic resin
weight
Prior art date
Application number
KR1019890017245A
Other languages
Korean (ko)
Other versions
KR930001994B1 (en
Inventor
안태완
김재경
임기철
Original Assignee
공정곤
동양 나일론 주식회사
배도
동양 폴리에스터 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 공정곤, 동양 나일론 주식회사, 배도, 동양 폴리에스터 주식회사 filed Critical 공정곤
Priority to KR1019890017245A priority Critical patent/KR930001994B1/en
Publication of KR910009823A publication Critical patent/KR910009823A/en
Application granted granted Critical
Publication of KR930001994B1 publication Critical patent/KR930001994B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/53—Core-shell polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

Abstract

내용 없음.No content.

Description

열가소성 수지 조성물Thermoplastic resin composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (6)

아래 (A) 내지 (F)로 조성되는 것을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition, which is composed of (A) to (F) below. (A) 열가소성 폴리에스테르 수지 ; 10 내지 90중량%(A) thermoplastic polyester resin; 10 to 90 wt% (B) 폴리카보네이트 수지 : 90 내지 10중량%(B) polycarbonate resin: 90 to 10% by weight (C) 부타디엔계 코아-쉘형 공중합 수지 : (A)+(B)에 대하여 1 내지 25중량%(C) Butadiene type core-shell copolymer resin: 1-25 weight% with respect to (A) + (B) (D) 에폭시 함유 올레핀 공중합체 : (A)+(B)에 대하여 0.1 내지 15중량%(D) Epoxy-containing olefin copolymer: 0.1 to 15% by weight based on (A) + (B) (E) 다음의 일반식(1) 및/또는 일반식(2)의 인계 화합물; (A)+(B)+(C)+(D)에 대하여 0.01 내지 2중량%(E) phosphorus compounds of the following general formula (1) and / or general formula (2); 0.01 to 2% by weight relative to (A) + (B) + (C) + (D) (식중 R1, R2, R3는 서로 같거나 다른 탄소수 1 내지 30인 지방족 알킬기)Wherein R 1 , R 2 and R 3 are the same or different aliphatic alkyl groups having 1 to 30 carbon atoms (F)다관능성 화합물 : (A)+(B)+(C)+(D)에 대하여 0.01 내지 5중량%(F) polyfunctional compound: 0.01 to 5% by weight relative to (A) + (B) + (C) + (D) 제1항에 있어서, 열가소성 폴리에스테르는 폴리부틸렌테레프탈레이트로 극한점도 0.4dl/g이고, 폴리카보네이트는 폴리(비스페놀-에이 카보네이트)로 평균분자량이 10,000 내지 200,000인 것을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition of claim 1, wherein the thermoplastic polyester is polybutylene terephthalate having an intrinsic viscosity of 0.4 dl / g, and the polycarbonate is poly (bisphenol-A carbonate) having an average molecular weight of 10,000 to 200,000. 제1항에 있어서, 부타디엔계 코아-쉘형 공중합 수지는 부타디엔계 코아와 메타크릴레이트계 쉘의 구조를 갖는 것을 특징으로 하는 열가소성 수지 조성물.2. The thermoplastic resin composition according to claim 1, wherein the butadiene-based core-shell copolymer resin has a structure of a butadiene-based core and a methacrylate-based shell. 제1항에 있어서, 에폭시 함유 올레핀 공중합체는 주쇄를 폴리(에틸렌-스태트-글리시딜 메타크릴레이트)로 하고 여기에 폴리메틸메타크릴레이트가 그래프트돈 것을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition according to claim 1, wherein the epoxy-containing olefin copolymer has a main chain of poly (ethylene-stat-glycidyl methacrylate) and polymethyl methacrylate is graftdon. 제1항에 있어서, 인계 화합물은 모노에스테르 또는 디에스테르의 형태로, 메틸 디하이드로겐포스페이트, 메틸 디하이드로겐포스페이트, 부틸 디하이드로겐포스페이트, 옥틸 디하이드로겐포스페이트, 2-에틸헥실 디하이드로겐포스페이트, 데실 디하이드로겐포스페이트, 도데실 디하이드로겐포스페이트, 트리데실 디하이드로겐포스페이트, 스테아릴 디하이드로겐포스페이트, 올레일디하이드로겐포스페이트, 디메틸 하이드로겐포스페이트, 디에틸 하이드로겐포스페이트, 디부틸 하이드로겐포스페이트, 디이소 아밀포스페이트, 디옥틸 하이드로겐포스페이트, 디이소옥틸하이드로겐포스페이트, 비스(2-에틸 헥실)포스페이트, 2-에틸-헥실-3-메틸부틸 포스페이트, 디도데실 하이드로겐포스페이트, 디옥타데실 하이드로겐포스페이트 중에서 1종 이상 선택되는 것을 특징으로 하는 열가소성 수지 조성물.The method of claim 1, wherein the phosphorus compound is in the form of a monoester or diester, methyl dihydrogen phosphate, methyl dihydrogen phosphate, butyl dihydrogen phosphate, octyl dihydrogen phosphate, 2-ethylhexyl dihydrogen phosphate , Decyl dihydrogen phosphate, dodecyl dihydrogen phosphate, tridecyl dihydrogen phosphate, stearyl dihydrogen phosphate, oleyl dihydrogen phosphate, dimethyl hydrogen phosphate, diethyl hydrogen phosphate, dibutyl hydrogen phosphate , Diisoamyl phosphate, dioctyl hydrogen phosphate, diisooctylhydrogen phosphate, bis (2-ethyl hexyl) phosphate, 2-ethyl-hexyl-3-methylbutyl phosphate, didodecyl hydrogen phosphate, dioctadecyl hydro Select at least one of genphosphate The thermoplastic resin composition, characterized in that the. 제1항에 있어서, 다관능성 화합물은 에폭시 실란, 또는 에폭시기를 2개 이상 갖는 폴리에폭시 화합물, 또는 이미드기를 2개 이상 갖는 디이미드계 화합물, 또는 카르본산 무수물중에서 2종 이상 선택하는 것을 특징으로 하는 열가소성 수지 조성물.The polyfunctional compound is selected from the group consisting of at least two of epoxy silanes, polyepoxy compounds having two or more epoxy groups, diimide compounds having two or more imide groups, or carboxylic anhydrides. Thermoplastic resin composition. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019890017245A 1989-11-27 1989-11-27 Thermoplastic resin composition KR930001994B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019890017245A KR930001994B1 (en) 1989-11-27 1989-11-27 Thermoplastic resin composition

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Application Number Priority Date Filing Date Title
KR1019890017245A KR930001994B1 (en) 1989-11-27 1989-11-27 Thermoplastic resin composition

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KR910009823A true KR910009823A (en) 1991-06-28
KR930001994B1 KR930001994B1 (en) 1993-03-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100604735B1 (en) * 2004-12-20 2006-07-28 에스케이씨 주식회사 Polyester-based optical film having improved polarization

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100626503B1 (en) * 2004-12-20 2006-09-20 주식회사 삼양사 Polybutylene terephthalate resin composition having good heat resistance property

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100604735B1 (en) * 2004-12-20 2006-07-28 에스케이씨 주식회사 Polyester-based optical film having improved polarization

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Publication number Publication date
KR930001994B1 (en) 1993-03-20

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