KR910004577A - 옥사졸리딘 화합물 - Google Patents
옥사졸리딘 화합물 Download PDFInfo
- Publication number
- KR910004577A KR910004577A KR1019890019898A KR890019898A KR910004577A KR 910004577 A KR910004577 A KR 910004577A KR 1019890019898 A KR1019890019898 A KR 1019890019898A KR 890019898 A KR890019898 A KR 890019898A KR 910004577 A KR910004577 A KR 910004577A
- Authority
- KR
- South Korea
- Prior art keywords
- methyloxazolidinyl
- isopropoxy
- isopropyl
- methyl
- oxazolidine
- Prior art date
Links
- -1 Oxazolidine Compound Chemical class 0.000 title claims 16
- 238000000034 method Methods 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 claims 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 239000007983 Tris buffer Substances 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims 2
- 125000000027 (C1-C10) alkoxy group Chemical class 0.000 claims 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- FUECVQJEQXXUSV-UHFFFAOYSA-N 1-(2,2,5-trimethyl-1,3-oxazolidin-3-yl)propan-2-ol Chemical compound CC(O)CN1CC(C)OC1(C)C FUECVQJEQXXUSV-UHFFFAOYSA-N 0.000 claims 1
- AOMORPLAHSIXNB-UHFFFAOYSA-N 1-(5-methyl-1,3-oxazolidin-3-yl)propan-2-ol Chemical compound CC(O)CN1COC(C)C1 AOMORPLAHSIXNB-UHFFFAOYSA-N 0.000 claims 1
- HZXYMIYUTXBUAA-UHFFFAOYSA-N 1-(5-methyl-2-phenyl-1,3-oxazolidin-3-yl)propan-2-ol Chemical compound CC(O)CN1CC(C)OC1C1=CC=CC=C1 HZXYMIYUTXBUAA-UHFFFAOYSA-N 0.000 claims 1
- QYAGJVUMXBLUBF-UHFFFAOYSA-N 1-(5-methyl-2-propan-2-yl-1,3-oxazolidin-3-yl)propan-2-ol Chemical compound CC(O)CN1CC(C)OC1C(C)C QYAGJVUMXBLUBF-UHFFFAOYSA-N 0.000 claims 1
- DZARITHRMKPIQB-UHFFFAOYSA-N 2-(2-propan-2-yl-1,3-oxazolidin-3-yl)ethanol Chemical compound CC(C)C1OCCN1CCO DZARITHRMKPIQB-UHFFFAOYSA-N 0.000 claims 1
- UHKKZQIVQFZSCT-UHFFFAOYSA-N 2-[2-methyl-2-(2-methylpropyl)-1,3-oxazolidin-3-yl]ethanol Chemical compound CC(C)CC1(C)OCCN1CCO UHKKZQIVQFZSCT-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 claims 1
- VDCSGNNYCFPWFK-UHFFFAOYSA-N diphenylsilane Chemical compound C=1C=CC=CC=1[SiH2]C1=CC=CC=C1 VDCSGNNYCFPWFK-UHFFFAOYSA-N 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000012454 non-polar solvent Substances 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 150000003609 titanium compounds Chemical class 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/04—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D263/06—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hydrocarbon radicals, substituted by oxygen atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/04—Esters of silicic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- 하기식(I)로 표시되는 옥사졸리딘 화합물.[식중, R은 수소원자, C1-C10알킬, 아릴기, 비닐기, 할로겐치환된 C1-C10알콕시기를 나타내고, M은 규소원자 또는 비탄원자를 나타내며, R1은 C2-C5알킬렌기를 나타내고, R2및 R3은 각각 수소원자, C1-C10알킬기 또는 아릴기를 나타내며, R4는 수소원자 또는 메틸기를 나타내고, n은 0내지 3의 정수이다.]
- 제1항에 있어서, R이 메틸 또는 에틸인 옥사졸리딘 화합물.
- 제1항에 있어서, M이 규소원자인 옥사졸리딘 화합물.
- 제1항에 있어서, R2및 R3이 각각 메틸, 에틸, 프로필 또는 페닐인 옥사졸리딘 화합물.
- 트리스[3-(2-이소프로필-5-메틸옥사졸리딘일)-2-이소프로폭시]메틸실란.
- 테트라키스[3-(2-이소프로필-5-메틸옥사졸리딘일)-2-이소프로폭시]실란.
- 비스[3-(2-이소프로필-5-메틸옥사졸리딘일)-2-이소프로폭시]디페닐실란.
- 비스[3-(2-이소프로필-5-메틸옥사졸리딘일-5-메틸옥사졸리딘일)-2-이소프로폭시]메틸실란.
- 비스[2-(2-이소프로필옥사졸리딘일)에톡시]디페닐실란.
- 비스[3-(2-메틸-2-이소부틸-5-메틸옥사졸리딘일)-2-이소프로폭시]디메틸실란.
- 트리스[3-(2-페닐-5-메틸옥사졸리딘일)-2-이소프로폭시]메틸실란.
- 하기식(II)로 표시되는 화합물을 하기식(III)으로 표시되는 히드록시옥사졸리딘 화합물과 반응시키는 것을 특징으로하는 제1항에 따르는 옥사졸리딘 화합물의 제조방법.[식중, R, R1∼R4, n 및 M은 상기 정의한 바와 같고, X는 할로겐원자이다.]
- 제12항에 있어서, 화합물(II)가 할로겐화된 실란화합물 또는 할로겐화된 티탄 화합물인 방법.
- 제12항에 있어서, 언급된 히드록시옥사졸리딘 화합물(III)로서 2-이소프로필-3-(2-히드록시프로필)-5-메틸옥사졸리딘, 2,2-디메틸-3-(2-히드록시프로필)-5-메틸옥사졸리딘, 2-페닐-3-(2-히드록시프로필)-5-메틸옥사졸리딘, 2-이소프로필-3-(2-히드록시에틸)옥사졸리딘, 2-메틸-2-이소부틸-3-(2-히드록시에틸)옥사졸리딘 또는 3-(2-히드록시프로필)-5-메틸옥사졸리딘을 사용하는 방법.
- 제12항에 있어서, 반응이 30℃미만의 온도에서 수행되는 방법.
- 제12항에 있어서, 반응이 비극성 용매중에서 수행되는 방법.
- 제12항에 있어서, 반응이 염산을 제거하기 위한 염기의 존재하에 수행되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP89-220604 | 1989-08-28 | ||
JP1220604A JPH0383990A (ja) | 1989-08-28 | 1989-08-28 | オキサゾリジン化合物 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR910004577A true KR910004577A (ko) | 1991-03-28 |
Family
ID=16753581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890019898A KR910004577A (ko) | 1989-08-28 | 1989-12-28 | 옥사졸리딘 화합물 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5043452A (ko) |
EP (1) | EP0414962B1 (ko) |
JP (1) | JPH0383990A (ko) |
KR (1) | KR910004577A (ko) |
AU (1) | AU620486B2 (ko) |
CA (1) | CA2006850A1 (ko) |
DE (1) | DE68913972T2 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2780407B1 (fr) * | 1998-06-30 | 2000-09-15 | Rhodia Chimie Sa | Composition silicone reticulable utilisable, notamment pour la realisation de revetement et/ou d'impregnation hydrophobe et/ou oleophobe, a faible energie de surface |
JP2003267983A (ja) * | 2002-03-15 | 2003-09-25 | Yokohama Rubber Co Ltd:The | オキサゾリジン化合物および硬化性樹脂組成物 |
DE102006060943A1 (de) * | 2006-12-20 | 2008-06-26 | Henkel Kgaa | 1-Aza-3,7-dioxabicyclo[3.3.0]octan-Verbindungen und monocyclische Oxazolidine als Pro-Fragrances |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE674475A (ko) * | 1964-12-31 | 1966-04-15 | ||
US3435046A (en) * | 1965-07-02 | 1969-03-25 | Merck & Co Inc | Trialkyl-silyl ethers of n-carboxy anhydrides of monohydroxy alpha-amino acids and processes for preparing them |
US4002637A (en) * | 1973-07-09 | 1977-01-11 | Rohm And Haas Company | Oxazolidine, oxazolidine-containing condensation and addition polymers and methods of producing them |
US3937716A (en) * | 1973-07-09 | 1976-02-10 | Rohm And Haas Company | Oxazolidine derivatives |
US4043956A (en) * | 1975-03-14 | 1977-08-23 | Rohm And Haas Company | Hydrocurable oxazolidine polyanhydride compositions |
GB8308823D0 (en) * | 1983-03-30 | 1983-05-11 | Dow Corning Ltd | Silylation process |
US4680410A (en) * | 1984-03-02 | 1987-07-14 | The Dow Chemical Company | Preparation of N- and S-1,2-ethylenically unsaturated organic compounds |
US4772716A (en) * | 1986-07-14 | 1988-09-20 | Ciba-Geigy Corporation | Oxazolidines containing silane groups |
JPH0388189A (ja) * | 1989-08-31 | 1991-04-12 | Fuji Electric Co Ltd | 磁気ディスク装置 |
-
1989
- 1989-08-28 JP JP1220604A patent/JPH0383990A/ja active Pending
- 1989-12-28 AU AU47262/89A patent/AU620486B2/en not_active Ceased
- 1989-12-28 CA CA002006850A patent/CA2006850A1/en not_active Abandoned
- 1989-12-28 KR KR1019890019898A patent/KR910004577A/ko not_active Application Discontinuation
- 1989-12-28 EP EP89124041A patent/EP0414962B1/en not_active Expired - Lifetime
- 1989-12-28 DE DE68913972T patent/DE68913972T2/de not_active Expired - Lifetime
- 1989-12-28 US US07/458,372 patent/US5043452A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH0383990A (ja) | 1991-04-09 |
AU4726289A (en) | 1991-08-01 |
CA2006850A1 (en) | 1991-02-28 |
EP0414962B1 (en) | 1994-03-16 |
AU620486B2 (en) | 1992-02-20 |
DE68913972T2 (de) | 1994-07-21 |
DE68913972D1 (de) | 1994-04-21 |
US5043452A (en) | 1991-08-27 |
EP0414962A1 (en) | 1991-03-06 |
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