KR900701992A - Manufacturing method of high density granular material containing zeolite - Google Patents

Manufacturing method of high density granular material containing zeolite

Info

Publication number
KR900701992A
KR900701992A KR1019900701431A KR900701431A KR900701992A KR 900701992 A KR900701992 A KR 900701992A KR 1019900701431 A KR1019900701431 A KR 1019900701431A KR 900701431 A KR900701431 A KR 900701431A KR 900701992 A KR900701992 A KR 900701992A
Authority
KR
South Korea
Prior art keywords
weight
granular material
zeolite
parts
water
Prior art date
Application number
KR1019900701431A
Other languages
Korean (ko)
Inventor
야콥스 요한
얀케 울리히
카르둑크 프란츠-요셉
Original Assignee
게오르그 차이트, 호르스트 헤를레
헨켈 코만디트 게젤샤프트 아우프 아크티엔
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 게오르그 차이트, 호르스트 헤를레, 헨켈 코만디트 게젤샤프트 아우프 아크티엔 filed Critical 게오르그 차이트, 호르스트 헤를레
Publication of KR900701992A publication Critical patent/KR900701992A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065—High-density particulate detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites

Abstract

내용 없음No content

Description

제올라이트 함유 고밀도 입상물의 제조방법Manufacturing method of high density granular material containing zeolite

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도 및 제3도는, 분무건조된 제올라이트를 혼합기내에서 25중량%의 공중합성염의 수용액으로 분무하고, 입상화하여 이어서 건조시켜 제조된 입자를 나타낸다. 제2도 및 제4도는 실시예 1의 데이타에 따라 제조된 생성물의 입자구조를 나타낸다.1 and 3 show particles prepared by spraying a spray dried zeolite with an aqueous solution of 25% by weight copolymerizable salt in a mixer, granulating and then drying. 2 and 4 show the particle structure of the product prepared according to the data of Example 1. FIG.

Claims (7)

미세결정 제올라이트, 중합성 또는 공중합성 카르복실산의 나트륨염 또는 칼륨염 및 물을 함유하는 입상물의 제조방법에 있어서, (a) 제1 혼합단계에서 제올라이트와 (공)중합성 카르복실산염의 균일한 분말상 혼합물을 제조하고, (b)제2 혼합 및 입상화 단계에서 상기 제조한 혼합물을 응집시키고, 그리고 (c) 상기 응집물을 750내지 1,000g/l의 외관밀도를 갖는 양호한 자유유동성 있는 입상물이 얻어질때까지 건조하는 것을 특징으로 하는 입상물의 제조방법.A method for producing a granular product containing sodium or potassium salts of microcrystalline zeolites, polymerizable or copolymerizable carboxylic acids, and water, comprising: (a) uniformity of zeolite and (co) polymerizable carboxylic acid salt in the first mixing step; Preparing a powdered mixture, (b) agglomerating the prepared mixture in a second mixing and granulating step, and (c) good free-flowing granular material having an agglomerate density of from 750 to 1,000 g / l. It is dried until obtained, The manufacturing method of the granular material characterized by the above-mentioned. 제1항에 있어서, 상기 입상물이, (무수물질을 기준으로 하여) 60 내지 80중량%의 제올라이트, 2 내지 15중량%의 (공)중합성 카르복실산의 나트륨 염 및 제올라이트에 결합된 것을 포함한 14 내지 25중량%물을 함유하는 것을 특징으로 하는 입상물의 제조방법.The method according to claim 1, wherein the granular material is bound to 60 to 80% by weight zeolite (based on anhydride), 2 to 15% by weight sodium salt of (co) polymerizable carboxylic acid and zeolite. A method for producing a granular material, comprising 14 to 25% by weight of water. 제1항에 있어서, 상기 입상물이, (무수물질을 기준으로 하여) 62 내지 72중량%, 보다 구체적으로는 65내지 70중량%의 제올라이트와 4 내지 12중량%, 보다 구체적으로는 5내지 10중량%의 (공) 중합성 카르복실산의 나트륨염을 함유하는 것을 특징으로 하는 입상물의 제조방법.The method of claim 1, wherein the granular material is 62 to 72% by weight (based on the anhydrous substance), more specifically 65 to 70% by weight zeolite and 4 to 12% by weight, more specifically 5 to 10 A method for producing a particulated material, comprising a sodium salt of (%) by weight (co) polymerizable carboxylic acid. 제1항 내지 제3항 어느 한항에 있어서, 구성수분을 포함한 결합수를 15내지 25중량%, 바람직하게는 18내지 22중량% 함유한 분무건조된 미세분말 제올라이트 75 내지 95중량부와, (공)중합성 산의 나트륨염 3 내지 12중량부를 균일하게 혼합하며, 상기 얻어진 혼합물을 15내지 25중량부의 물을 첨가하여 응집시키며, 그리고 다음의 건조에 의하여 상기 입상화단계 (b)에서 도입된 물을 5중량부, 바람직하게는 3중량부 이하의 잔류함량까지 되도록 제거하는 것을 특징으로 하는 입상물의 제조방법.The method according to any one of claims 1 to 3, comprising 75 to 95 parts by weight of the spray-dried fine powder zeolite containing 15 to 25% by weight, preferably 18 to 22% by weight, of the combined water containing constituent moisture, 3 to 12 parts by weight of the sodium salt of the polymerizable acid is uniformly mixed, the resulting mixture is coagulated by adding 15 to 25 parts by weight of water, and the water introduced in the granulation step (b) by the following drying. Method for producing a granular material, characterized in that to remove to 5 parts by weight, preferably 3 parts by weight or less of residual content. 적어도 하나의 액상, 페이스트(paste)상 또는 지방성 세제성분을 20중량%(흡수물을 기준으로 하여)까지 함침시킨, 제1항 내지 제4항중 어느 한항에 따라 제조된 입상물.A granule prepared according to any one of claims 1 to 4, impregnated with at least one liquid, paste or fatty detergent component by 20% by weight (based on absorbent material). 제5항에 있어서, 상기 침투제가 비이온성 계면활성제인 것을 특징으로 하는 입상물.A particulate matter according to claim 5, wherein the penetrant is a nonionic surfactant. 제1항 내지 제6항 중 어느 한 항에 따라 제조된 입상물의, 세제 또는 세척조세물 내의 분말성분으로서의 용도.Use as a powder component in detergents or washing detergents of the granules prepared according to any one of claims 1 to 6. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900701431A 1988-11-10 1989-11-02 Manufacturing method of high density granular material containing zeolite KR900701992A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP3838086.2 1988-11-10
DE3838086A DE3838086A1 (en) 1988-11-10 1988-11-10 METHOD FOR PRODUCING HIGH DENSITY GRANULES CONTAINING ZEOLITE
PCT/EP1989/001312 WO1990005175A1 (en) 1988-11-10 1989-11-02 Process for producing high-density zeolite-containing granules

Publications (1)

Publication Number Publication Date
KR900701992A true KR900701992A (en) 1990-12-05

Family

ID=6366852

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900701431A KR900701992A (en) 1988-11-10 1989-11-02 Manufacturing method of high density granular material containing zeolite

Country Status (9)

Country Link
EP (2) EP0368137B1 (en)
JP (1) JPH04501730A (en)
KR (1) KR900701992A (en)
DE (2) DE3838086A1 (en)
DK (1) DK86891A (en)
ES (1) ES2047091T3 (en)
PT (1) PT92223B (en)
TR (1) TR24018A (en)
WO (1) WO1990005175A1 (en)

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GB8922179D0 (en) * 1989-10-02 1989-11-15 Rohm & Haas Polymer-containing granulates
US5108646A (en) * 1990-10-26 1992-04-28 The Procter & Gamble Company Process for agglomerating aluminosilicate or layered silicate detergent builders
DE4038609A1 (en) * 1990-12-04 1992-06-11 Henkel Kgaa METHOD FOR PRODUCING ZEOLITE GRANULES
DE4110510A1 (en) * 1991-03-30 1992-10-01 Henkel Kgaa LOW-ALKALINE, CHLORINE AND PHOSPHATE-FREE MACHINE DISTRIBUTORS IN THE FORM OF HEAVY-DENTAL POWDERS AND GRANULES
DE4125330A1 (en) * 1991-07-31 1993-02-04 Henkel Kgaa METHOD FOR PRODUCING ZEOLITE GRANULES
DE4137470A1 (en) * 1991-11-14 1993-05-19 Henkel Kgaa METHOD FOR PRODUCING LOW-ALKALINE, ACTIVE-CHLORINE AND PHOSPHATE-FREE MACHINE DISPERSIVE AGENTS IN THE FORM OF HEAVY GRANULES
DE4216774A1 (en) * 1992-05-21 1993-11-25 Henkel Kgaa Process for the continuous production of a granular washing and / or cleaning agent
DE4228044A1 (en) * 1992-08-24 1994-03-03 Henkel Kgaa Builder for detergents
DE4229660A1 (en) * 1992-09-04 1994-03-10 Henkel Kgaa Washing and cleaning agents with builders
EP0639638A1 (en) * 1993-08-18 1995-02-22 The Procter & Gamble Company Process for making detergent compositions
DE19549411C2 (en) * 1994-02-11 1999-05-12 Degussa Zeolite granulates with good re:dispersibility and high bulk density
DE19504043C2 (en) * 1994-02-11 1998-07-09 Degussa zeolite granules
DE19515256A1 (en) * 1995-04-26 1996-10-31 Degussa Zeolite granules, process for its preparation and use
GB9820573D0 (en) * 1998-09-22 1998-11-11 Ind Zeolite Uk Ltd Water absorbing composition
DE19850100A1 (en) * 1998-10-29 2000-05-04 Henkel Kgaa Polymer granules through fluidized bed granulation
DE102005025656A1 (en) 2005-06-03 2006-12-07 IPK-Institut für Pflanzengenetik und Kulturpflanzenforschung Promoter for epidermis-specific, pathogen-inducible transgene expression in plants
JP5705525B2 (en) * 2010-12-16 2015-04-22 花王株式会社 Zeolite composite particles
EP3241889B1 (en) * 2016-05-03 2019-03-20 The Procter and Gamble Company Cleaning composition

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AT330930B (en) 1973-04-13 1976-07-26 Henkel & Cie Gmbh PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES
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Also Published As

Publication number Publication date
EP0442923A1 (en) 1991-08-28
DE58906639D1 (en) 1994-02-17
DE3838086A1 (en) 1990-05-17
PT92223A (en) 1990-05-31
EP0368137A1 (en) 1990-05-16
TR24018A (en) 1991-02-01
ES2047091T3 (en) 1994-02-16
EP0368137B1 (en) 1994-01-05
WO1990005175A1 (en) 1990-05-17
JPH04501730A (en) 1992-03-26
DK86891D0 (en) 1991-05-08
DK86891A (en) 1991-07-08
PT92223B (en) 1995-07-06

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