KR900018471A - Light-Dose Liquid or Gel-Dishwashing Detergent Compositions Containing Alkyl Ethoxy Carboxylate Surfactants - Google Patents

Light-Dose Liquid or Gel-Dishwashing Detergent Compositions Containing Alkyl Ethoxy Carboxylate Surfactants Download PDF

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KR900018471A
KR900018471A KR1019900007312A KR900007312A KR900018471A KR 900018471 A KR900018471 A KR 900018471A KR 1019900007312 A KR1019900007312 A KR 1019900007312A KR 900007312 A KR900007312 A KR 900007312A KR 900018471 A KR900018471 A KR 900018471A
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detergent composition
alkyl
weight percent
weight
surfactant mixture
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KR1019900007312A
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안토니 크립 토마스
말론 와이즈 로드니
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리챠드 챨스 위트
더 프록터 앤드 갬블 캄파니
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Publication of KR900018471A publication Critical patent/KR900018471A/en

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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00—Methods of beating or refining; Beaters of the Hollander type
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/521—Carboxylic amides (R1-CO-NR2R3), where R1, R2 and R3 are alkyl or alkenyl groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Abstract

A light-duty liquid or gel dishwashing detergent composition containing an alkyl ethoxy carboxylate surfactant and little or no alcohol ethoxylate and soap by-product contaminants. The compositions exhibit good grease removal while manifesting mildness to the skin. A preferred type of dishwashing detergent composition is in the liquid form. High pH and magnesium ion containing versions of the compositions increase grease removal properties while maintaining mildness.

Description

알킬 에톡시 카복실레이트 계면활성제를 포함하는 경－용량의 액체 또는 겔－식기세척용 세제 조성물Light-Dose Liquid or Gel-Dishwashing Detergent Compositions Containing Alkyl Ethoxy Carboxylate Surfactants

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (28)

(a) 일반식RO(CH2CH2O)xCH2COO-M+의 알킬 에톡시 카복실레이트 약80 내지 100중량%(여기서, R은 C12－C16알킬 그룹이고 : x는0내지 약10이며, 에톡셀레이트는 x가0인 물질이 약20중량%미만이 되고 x가 7이상인 물질이 약25중량%미만이 되도록 분포하며, R의 평균 탄소수가 13미만일 경우에 평균 x는 약 2내지 4이고, R의 평균 탄소수가 13이상일 경우에 평균 x는 약 3내지 6이며 ;M은 양이온이다), (b) 일반식RO(CH2CH2O)xH의 알콜에톡실레이트 0내지 약 10중량%(여기서, R은 C12－C16알킬 그룹이고 ; x는 0내지 약10이며, 평균x는 약6미만이다), 및 (c) 일반식 RCOO－M+의 비누 0내지 약10중량%(여기서, R은 C11－C15알킬 그룹이고, M은 양이온이다)을 함유하는 계면활성제 혼합물 약 5 내지 70중량%를 함유하며, 수용액 10중량%의 pH가 약 7 내지 11임을 특징으로 하는 경－용량의 액체 또는 겔－식기세척용 세제 조정물.(a) about 80 to 100% by weight of alkyl ethoxy carboxylate of general formula RO (CH 2 CH 2 O) x CH 2 COO - M + , wherein R is a C 12 -C 16 alkyl group: x is 0 to The ethoxylate is distributed such that less than about 20% by weight of a substance with x0 and less than about 25% by weight of a substance with x of 7 or more, and if the average carbon number of R is less than 13, the average of x is about When 2 to 4 and the average carbon number of R is 13 or more, the average x is about 3 to 6; M is a cation), (b) an alcohol ethoxylate of the general formula RO (CH 2 CH 2 O) x H 0 To about 10% by weight (wherein R is a C 12 -C 16 alkyl group; x is 0 to about 10 and the average x is less than about 6), and (c) 0 to soap of formula RCOO-M + Containing about 5 to 70% by weight of a surfactant mixture containing about 10% by weight (wherein R is a C 11 -C 15 alkyl group and M is a cation) and the pH of the aqueous solution is about 7-11 Light capacity characterized by Liquid or gel-dishwashing detergent adjustment water for washing. 제1항에 있어서, pH가 약 8 내지 10.5 인 세제조성물.The detergent composition of claim 1 wherein the pH is about 8 to 10.5. 제2항에 있어서, pH가 약 8.5 내지 10인 세제조성물.The detergent composition of claim 2 wherein the pH is about 8.5-10. 제1항에 있어서, 마그세슘 이온이 0 내지 약 1.5중량% 존재하며, pH가 약 7 내지 9.5인 세제조성물.The detergent composition of claim 1, wherein the magnesium composition is present from 0 to about 1.5% by weight and has a pH of about 7 to 9.5. 제4항에 있어서, 마그네슘 이온이 0.3 내지 0.8중량% 존재하는 세제 조성물.5. The detergent composition according to claim 4, wherein 0.3 to 0.8 wt% of magnesium ions are present. 제5항에 있어서, pH가 약 8.5 내지 9.5인 세제조성물.6. The detergent composition of claim 5 wherein the pH is about 8.5 to 9.5. 제1항에 있어서, 알킬 벤젠 설포네이트 알킬 설페이트, 파라핀 설포네이트, 올레핀 설포네이트, 알킬 에테르 설페이트, 지방산 에스테르 설포네이트, 알킬 폴리글루코사이드 및 이들의 혼합물 중에서 선택된 공－계면 활성제를 추가로 포함하는 세제 조성물.The detergent composition of claim 1 further comprising a co-surfactant selected from alkyl benzene sulfonate alkyl sulfates, paraffin sulfonates, olefin sulfonates, alkyl ether sulfates, fatty acid ester sulfonates, alkyl polyglucosides, and mixtures thereof. . 제1항에 있어서, 베타인, 에틸렌 옥사이드 축합 생성물, 지방산 아미드, 아민 옥사이드 반－극성의 비이온성물질, 양이온성 계면활성제 및 이들의 혼합물중에서 선택된 함침 부우스터(booster)를 추가로 포함하는 세제 조성물.The detergent composition of claim 1 further comprising an impregnated booster selected from betaine, ethylene oxide condensation products, fatty acid amides, amine oxide semi-polar nonionics, cationic surfactants, and mixtures thereof. . 제7항에 있어서, 베타인, 에틸렌 옥사이드 축합 생성물, 지방산 아미드, 아민 옥사이드 반－극성의 비이온성물질. 양이온성 계면활성제 및 이들의 혼합물중에서 선택된 함침 부우스터를 추가로 포함하는 세제 조성물.8. The nonionic material of claim 7, wherein the betaine, the ethylene oxide condensation product, the fatty acid amide, the amine oxide semi-polar material. A detergent composition further comprising an impregnating booster selected from cationic surfactants and mixtures thereof. 제9항에 있어서, pH가 약 8 내지 10.5인 세제 조성물.The detergent composition of claim 9 wherein the pH is about 8 to 10.5. 제9항에 있어서, 마그네슘 이온이 약 0.3 내지 0.8중량%존재하는 세제 조성물.10. The detergent composition of claim 9, wherein the magnesium ions are present in about 0.3 to 0.8 weight percent. 제9항에 있어서,pH가 약 8.5 내지 9.5 이며, 마그네슘 이온이 약 0.3 내지 0.8중량% 존재하는 세제 조성물.The detergent composition of claim 9, wherein the pH is about 8.5 to 9.5 and the magnesium ions are present in about 0.3 to 0.8 wt%. 제1항에 있어서, (a)의 R이 C12－C14알킬 그룹인 세제 조성물.The detergent composition of claim 1, wherein R in (a) is a C 12 -C 14 alkyl group. 제1항에 있어서, 계면활성제 혼합물 약 12 내지 30중량%를 함유하는 액체 세제 조성물.The liquid detergent composition of claim 1, comprising about 12-30% by weight of the surfactant mixture. 제1항에 있어서, 계면활성제 혼합물이 알킬 에톡시 카복실레이트 약 85 내지 95중량%를 함유하는 세제 조성물.The detergent composition of claim 1, wherein the surfactant mixture contains about 85-95 weight percent alkyl ethoxy carboxylate. 제15항에 있어서, 계면활성제 혼합물이 알킬 에톡시 카복실레이트 약 90 내지 95중량%를 함유하는 세제 조성물.16. The detergent composition of claim 15, wherein the surfactant mixture contains about 90 to 95 weight percent alkyl ethoxy carboxylate. 제13항에 있어서, 계면활성제 혼합물이 알킬 에톡시 카복실레이트 약 85 내지 95중량%를 함유하는 세제 조성물.The detergent composition of claim 13, wherein the surfactant mixture contains about 85-95 weight percent alkyl ethoxy carboxylate. 제17항에 있어서, 계면활성제 혼합물이 알킬 에톡시 카복실레이트 약 90 내지 95중량%를 함유하는 세제 조성물.18. The detergent composition of claim 17, wherein the surfactant mixture contains about 90 to 95 weight percent alkyl ethoxy carboxylate. 제1항에 있어서, 계면활성제 혼합물이 알콜 에톡실레이트 약 8중량%미만을 함유하는 세제 조성물.The detergent composition of claim 1, wherein the surfactant mixture contains less than about 8% by weight alcohol ethoxylate. 제19항에 있어서, 계면활성제 혼합물이 알콜 에톡실레이트 약 5중량%미만을 함유하는 세제 조성물.20. The detergent composition of claim 19, wherein the surfactant mixture contains less than about 5 weight percent alcohol ethoxylate. 제1항에 있어서, 계면활성제 혼합물이 비누 약 5중량%미만을 함유하는 세제 조성물.The detergent composition of claim 1, wherein the surfactant mixture contains less than about 5% by weight soap. 제13항에 있어서, 계면활성제 혼합물이 알킬 에톡시 카복실레이트 약90 내지 95중량%, 알콜에톡실레이트 약5중량%미만, 및 비누 5중량% 미만을 함유하는 세제 조성물.14. The detergent composition of claim 13, wherein the surfactant mixture contains about 90 to 95 weight percent alkyl ethoxy carboxylate, less than about 5 weight percent alcohol ethoxylate, and less than 5 weight percent soap. 제22항에 있어서, pH가 약 7 내지 9.5이며, 마그네슘 이온이 0내지 약 1.5중량%존재하는 세제 조성물.23. The detergent composition of claim 22, wherein the pH is from about 7 to 9.5 and the magnesium ions are from 0 to about 1.5 weight percent. 제23항에 있어서, pH가 약 8.5 내지 9.5이며, 마그네슘 이온이 약 0.3내지 약 0.8중량%존재하는 세제 조성물.24. The detergent composition of claim 23, wherein the pH is about 8.5 to 9.5 and the magnesium ions are present in about 0.3 to about 0.8 weight percent. 제22항에 있어서, 알킬 에테르 설페이트, 지방산 에스테르 설포네이트, 알킬 설페이트, 알킬 폴리글루코사이드 및 이들의 혼합물중에서 선택된 공－계면활성제를 추가로 포함하는 세제 조성물.The detergent composition of claim 22 further comprising a co-surfactant selected from alkyl ether sulfates, fatty acid ester sulfonates, alkyl sulfates, alkyl polyglucosides, and mixtures thereof. 제22항에 있어서, 베타인, 아민 옥사이드 반－극성 비이온성 물질, 지방산 아미드 및 이들의 혼합물 중에서 선택된 함침 부우스터를 추가로 포함하는 세제 조성물.23. The detergent composition of claim 22 further comprising an impregnated booster selected from betaine, amine oxide semi-polar nonionics, fatty acid amides, and mixtures thereof. 제26항에 있어서, 알킬 에테르 설페이트, 지방산 에스테르 설포네이트, 알킬 폴리클루코사이드 및 이들의 혼합물중에서 선택된 공－계면활성제를 추가로 포함하며, 마그네슘 이온이 0내지 약1.5중량% 존재하고, pH가 약 7내지 9.5인 세제 조성물.27. The method of claim 26, further comprising a co-surfactant selected from alkyl ether sulfates, fatty acid ester sulfonates, alkyl polyglucosides, and mixtures thereof, wherein the magnesium ions are present from 0 to about 1.5 weight percent and the pH is A detergent composition of about 7 to 9.5. 제1항에 있어서, 계면활성제 혼합물 약 28내지 35중량%를 함유하는 겔 세제 조성물.The gel detergent composition of claim 1, comprising about 28 to 35 weight percent of the surfactant mixture. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900007312A 1989-05-22 1990-05-22 Light-Dose Liquid or Gel-Dishwashing Detergent Compositions Containing Alkyl Ethoxy Carboxylate Surfactants KR900018471A (en)

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