KR900017967A - "옥소"화합물 또는 그 유도체의 합성 공정 및 그 공정에 사용가능한 플라즈마 반응기를 포함하는 장치 - Google Patents

"옥소"화합물 또는 그 유도체의 합성 공정 및 그 공정에 사용가능한 플라즈마 반응기를 포함하는 장치 Download PDF

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KR900017967A
KR900017967A KR1019900007546A KR900007546A KR900017967A KR 900017967 A KR900017967 A KR 900017967A KR 1019900007546 A KR1019900007546 A KR 1019900007546A KR 900007546 A KR900007546 A KR 900007546A KR 900017967 A KR900017967 A KR 900017967A
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reactor
point
plasma
mixture
substrate
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두블라 아발리
아무루 자끄
브리세 쟝-루이
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원본미기재
엘렉트리시떼 드 프랑스
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/26—Plasma torches
    • H05H1/30—Plasma torches using applied electromagnetic fields, e.g. high frequency or microwave energy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/002—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor carried out in the plasma state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/20—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxo-reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894—Processes carried out in the presence of a plasma

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  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Spectroscopy & Molecular Physics (AREA)
  • Electromagnetism (AREA)
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  • General Chemical & Material Sciences (AREA)
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Abstract

내용 없음

Description

“옥소”화합물 또는 그 유도체의 합성 공정 및 그 공정에 사용가능한 플라즈마 반응기를 포함하는 장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 이 발명에 따른 공정에 이용가능한 포인트-플레인 코로나 방전형 플라즈마 반응기를 도식적으로 설명하는 도면, 제2도는 상이한 내부전극 간격에 대해 실시한 이 발명에 따른 공정의 1-헥센의 주파수에 따른 투광도를 타나내는 적외선 스펙트럼.

Claims (12)

  1. 카보닐 및/또는 히드록실기르 포함하는 탄화수소 화합물로 구성되는 “옥소” 생성물 또는 그 유도체 합성을 위한 공정에 있어서, 알켄과 같은 불포화 탄화수소기질이 수소와 일산화탄소의 혼합물로 이루어지는 반응물과 반응하며, 기질이 플라즈마 상태로 활성화된 반응 혼합물의 중성 활성종과 접촉하도록 이동된 이후에 반응이 일어나는 것을 특징으로 하는 합성공정.
  2. 제1항에 있어서, 알켄이 알켄 이중결합에 각각 H-C=O또는 환원에 의한 H-C-OH기가 고정된 알데히드 및 알코올을 포함하는 생성혼합물 또는 이 혼합물로 부터의 분리에 의한 이들 두 성분중 하나를 얻기위하여 반응하는 것을 특징으로 하는 합성공정.
  3. 1또는 2항에 있어서, 수소/일산화탄소 혼합물의 활성화반응이 플라즈마 반응기에서 일어나며, 기질이 활성화된 혼합물과 접촉하도록 플라즈마의 활성부분 밖으로 이동되는 것을 특징으로 하는 합성공정.
  4. 제3항에 있어서, 상기 기질 및 반응체가 대기압 및 실온에 가까운 온도에서 반응기로 주입되는 것을 특징으로 하는 합성공정.
  5. 상기 항들중 어느 한항에 있어서, CO/H2부피 이동 속도비가 1이상인 것을 특징으로 하는 합성공정.
  6. 상기 항들중 어느 한항에 있어서, CO/H2부피 이동 속도비가 1/2이상인 것을 특징으로 하는 합성공정.
  7. 제3항 내지 6항에 있어서, 상기 플라즈마와 반응기가, 포인트가 플레인전극에 평행하게 배열되는 포인트-플레인 코로나 방전형이며, 상기 기질이 포인트와 플레인사이의 활성영역아래로, 포인트 축 방향으로 반응기에 주입되는 것을 특징으로 하는 합성공정.
  8. 제7항에 있어서, 상기 포인트 전극이 양하진을 띠며, 플레인전극이 어스에 연결되는 것을 특징으로 하는 합성공정.
  9. 제7또는 8항에 있어서, 일산화탄소가 포인트 전극 레벨에 주입되며, 수소가 반응기 외면에 주입되는 것을 특징으로 하는 합성공정.
  10. 제1항 내지 6항중 어느 한항에 있어서, 상기플라즈마 반응기가, CO+H2혼합물이 활성화된후, 처리되는 기질과 접촉하도록 이동되기 전에, 수소기체의 기류에 의한 입자의 유동 베드에 의해 냉각되는 열 플라즈마형인 것을 특징으로 하는 합성공정.
  11. 하나 이상의 홀로 포인트 전극을 구비하며, 포인트 전극을 통해 반응기가 인살화탄소 기체로 채워지고, 포인트 전극이 플레인전극과 평행하게 배열되며, 수소가 반응기 외면에 주입되고, 액체 탄화수소 기질이 포인트-플레인 간격보다 적은 포인트-기질 간격으로 축방향으로 포인트 아래에 위치하는 것을 특징으로 하는 포인트-플레인 코로나 방전형 플라즈마 반응기로 구성되는 제1항 내지 9항중 어느 한항에 따른 공정에 사용가능한 장치.
  12. 유동화 장치의 챔버에 측면으로 주입되는 CO+H3플라즈마 토치를 생성하는 고주파수 플라즈마 반응기와, 상기 챔버의 출구에 연결되며 기질이 활성화된 CO+H2혼합물의 이동에 대해 반대방향으로 순환하는 팩킹 컬럼형 튜브형 반응기를 구비하는 것을 특징으로 하는 제10항의 공정을 수행하기 위해 사용가능한 장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900007546A 1989-05-24 1990-05-24 "옥소"화합물 또는 그 유도체의 합성 공정 및 그 공정에 사용가능한 플라즈마 반응기를 포함하는 장치 KR900017967A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR89/06799 1989-05-24
FR8906799A FR2647442B1 (fr) 1989-05-24 1989-05-24 Procede de synthese de produits " oxo " par voie plasma et installation comprenant un reacteur a plasma utile dans le procede

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US (1) US5122245A (ko)
EP (1) EP0399913B1 (ko)
JP (1) JPH03204827A (ko)
KR (1) KR900017967A (ko)
AR (1) AR246245A1 (ko)
AT (1) ATE94863T1 (ko)
AU (1) AU632815B2 (ko)
BR (1) BR9002432A (ko)
CA (1) CA2017368A1 (ko)
DD (1) DD296070A5 (ko)
DE (1) DE69003448T2 (ko)
DK (1) DK0399913T3 (ko)
ES (1) ES2060099T3 (ko)
FR (1) FR2647442B1 (ko)
RU (1) RU1834882C (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100441851B1 (ko) * 2001-06-04 2004-07-27 안강호 코로나 방전을 이용한 입자의 제조장치 및 그 제조방법

Families Citing this family (3)

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Publication number Priority date Publication date Assignee Title
DE19581551B4 (de) * 1995-01-04 2006-08-17 Fujitsu Ltd. Gasreaktor
US6139694A (en) * 1998-05-28 2000-10-31 Science Applications International Corporation Method and apparatus utilizing ethanol in non-thermal plasma treatment of effluent gas
WO2001035479A1 (fr) * 1999-11-05 2001-05-17 Ebara Corporation Procede de purification du combustible d'une cellule a combustible

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US3248446A (en) * 1962-10-22 1966-04-26 Phillips Petroleum Co Plasma streams and method for utilizing same
US4183871A (en) * 1968-05-09 1980-01-15 Badische Anilin-& Soda-Fabrik Aktiengesellschaft Production of aldehydes and alcohols by the oxo method
US4694100A (en) * 1984-07-14 1987-09-15 Nippon Petrochemicals Company, Ltd. Method for producing α-(p-isobutylphenyl)propionic acid or its alkyl esters
FR2593493B1 (fr) * 1986-01-28 1988-04-15 British Petroleum Co Procede de production de gaz reactifs riches en hydrogene et en oxyde de carbone dans un post-arc electrique
FR2615523B1 (fr) * 1987-05-22 1990-06-01 Electricite De France Procede d'hydrocraquage d'une charge d'hydrocarbures et installation d'hydrocraquage pour la mise en oeuvre de ce procede
FR2622893B1 (fr) * 1987-11-06 1990-03-30 Bp France Procede de conversion d'hydrocarbures et residus lourds ou difficilement fusibles en hydrocarbures liquides legers,ramifies et a bas point de fusion a l'aide de melanges de gaz co+xh2 rendus reactifs par choc d'energie
US4946903A (en) * 1989-03-27 1990-08-07 The Research Foundation Of State University Of Ny Oxyfluoropolymers having chemically reactive surface functionality and increased surface energies

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100441851B1 (ko) * 2001-06-04 2004-07-27 안강호 코로나 방전을 이용한 입자의 제조장치 및 그 제조방법

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FR2647442A1 (fr) 1990-11-30
ATE94863T1 (de) 1993-10-15
EP0399913A1 (fr) 1990-11-28
DE69003448D1 (de) 1993-10-28
DE69003448T2 (de) 1994-01-20
JPH03204827A (ja) 1991-09-06
AU632815B2 (en) 1993-01-14
DK0399913T3 (da) 1993-10-25
DD296070A5 (de) 1991-11-21
CA2017368A1 (fr) 1990-11-24
BR9002432A (pt) 1991-08-06
AR246245A1 (es) 1994-07-29
ES2060099T3 (es) 1994-11-16
EP0399913B1 (fr) 1993-09-22
AU5588290A (en) 1990-11-29
FR2647442B1 (fr) 1991-09-13
US5122245A (en) 1992-06-16
RU1834882C (ru) 1993-08-15

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