KR900014431A - 폴리에스테르 강화 고무 - Google Patents

폴리에스테르 강화 고무 Download PDF

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Publication number
KR900014431A
KR900014431A KR1019900004046A KR900004046A KR900014431A KR 900014431 A KR900014431 A KR 900014431A KR 1019900004046 A KR1019900004046 A KR 1019900004046A KR 900004046 A KR900004046 A KR 900004046A KR 900014431 A KR900014431 A KR 900014431A
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KR
South Korea
Prior art keywords
rubber
polyester
phr
polydiene
butadiene
Prior art date
Application number
KR1019900004046A
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English (en)
Inventor
볼톤 파이크 제임스
조지 바우에르 리챠드
제임스 불레트 도날드
Original Assignee
카알 에이취.크루코우
더 굿이어 타이어 앤드 러버 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 카알 에이취.크루코우, 더 굿이어 타이어 앤드 러버 캄파니 filed Critical 카알 에이취.크루코우
Publication of KR900014431A publication Critical patent/KR900014431A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/34—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
    • C08C19/40—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups with epoxy radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
    • C08G81/027—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyester or polycarbonate sequences

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

폴리에스테르 강화 고무
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 말레산 무수물을, 최소한 하나의 폴리디엔 고무 및 최소한 하나의 폴리에스테르와 반응시킴을 포함하는, 고 모듈러스를 갖는 고무 조성물의 제조방법.
  2. 제1항에 있어서, 상기 폴리에테르가 폴리에스테르 탄성중합체인 방법.
  3. 제2항에 있어서, 상기 폴리에스테르 탄성중합체가 약 240℃미만의 융점을 갖는 방법.
  4. 제3항에 있어서, 폴리에스테르를 말레산 무수물과 반응시켜 폴리에스테르/말레산 무수물 부가물을 생성시키고, 연이어 그 폴리에스테르/말레산 무수물 부가물을 고무와 반응시킴으로써 상기 방법을 수행하는 방법.
  5. 제4항에 있어서, 상기 폴리디엔 고무가 폴리부타디엔, 스티렌-부타디엔 고무, 합성 폴리이소프렌, 천연고무, 이소프렌-부타디엔 고무, 이소프렌-부타디엔-스티렌 고무, 및 니트릴 고무로 이루어진 그룹중에서 선택되는 방법.
  6. 제5항에 있어서, 최소한 하나의 유리 라디칼 포집용 산화 방지제의 존재하에 수행하는 방법.
  7. 제6항에 있어서, 상기 폴리디엔 고무가 고 시스-1,4-폴리부타디엔, 중 비닐 폴리부타디엔, SBR, 합성 폴리이소프렌, 천연 고무 및 이소프렌-부타디엔 고무로 이루어진 그룹중에서 선택되는 방법.
  8. 제7항에 있어서, 약 0.5phr 내지 약 3phr의 말레산 무수물을 사용하는 방법.
  9. 제8항에 있어서, 약 20phr 내지 약 100phr의 폴리에스테르 탄성중합체를 사용하는 방법.
  10. 제1항에 명시한 방법에 의해 제조된 고무 조성물.
  11. 최소한 하나의 티오산을, 최소한 하나의 폴리디엔 고무 및 최소한 하나의 폴리에스테르와 반응시킴을 포함하는 고 모듈러스를 갖는 고무 조성물의 제조방법.
  12. 제11항에 있어서, 티오산과 폴리에스테르를 반응시켜 머캡탄 그룹을 함유하는 변성 폴리에스테르를 제조하고, 연이어 머캡탄 그룹을 함유하는 변성 폴리에스테르를 폴리디엔 고무와 반응시킴으로써 수행하고, 상기 폴리에스테르가 폴리에스테르 탄성중합체인 방법.
  13. 제12항에 있어서, 상기 티오산을 약 150℃ 내지 약 300℃범위의 온도에서 폴리에스테르와 반응시키며, 머캡탄 그룹을 함유하는 변성 폴리에스테르를 약 120℃ 내지 약 250℃범위의 온도에서 폴리디엔 고무와 반응시키는 방법.
  14. 제11항에 있어서, 상기 티오산이 디티오이산인 방법.
  15. 제11항에 있어서, 상기 폴리디엔 고무가 폴리부타디엔, 스티렌-부타디엔 고무, 합성 폴리이소프렌, 천연 고무, 이소프렌-부타딘엔 고무, 이소프렐-부타딘엔-스티렌 고무, 니트릴 고무 및 EPDM고무로 이루어진 그룹중에서 선택되는 방법.
  16. 제13항에 있어서, 약 0.5phr 내지 약 3phr의 티온산을 사용하는 방법.
  17. 제16항에 있어서, 상기 티오산이 디티오이산인 방법.
  18. 제16항에 있어서, 상기티오산이 디티오 디프로피온산인 방법.
  19. 약 140℃ 내지 약 300℃범위의 온도에서 최소한 하나의 에폭시화 고무와 최소한 하나의 폴리에스테르를 반응시킴을 포함하는, 고 모듈러스를 갖는 고무 조성물의 제조방법.
  20. 제19항에 있어서, 상기 에폭시화 고무가 약 40몰%미만 에폭시화 된 것이고, 상기 폴리에스테르가 폴리에스프 탄성 중합체이고, 약 20phr 내지 약 100phr의 폴리에스테르 탄성중합체가 존재하는 방법.
  21. 제11항에 명시한 방법에 의해 제조된 고무 조성물.
  22. 제19항에 명시한 방법에 의해 제조된 고무 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900004046A 1989-03-27 1990-03-26 폴리에스테르 강화 고무 KR900014431A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/329,214 US4996262A (en) 1989-03-27 1989-03-27 Polyester reinforced rubber
US07/329214 1989-03-27

Publications (1)

Publication Number Publication Date
KR900014431A true KR900014431A (ko) 1990-10-23

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ID=23284380

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900004046A KR900014431A (ko) 1989-03-27 1990-03-26 폴리에스테르 강화 고무

Country Status (12)

Country Link
US (1) US4996262A (ko)
EP (1) EP0390722B1 (ko)
JP (1) JPH02281044A (ko)
KR (1) KR900014431A (ko)
AR (1) AR247573A1 (ko)
AU (1) AU627005B2 (ko)
BR (1) BR9001314A (ko)
CA (1) CA2007072A1 (ko)
DE (1) DE69020400D1 (ko)
ES (1) ES2075183T3 (ko)
NO (1) NO175982C (ko)
ZA (1) ZA901925B (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4937290A (en) * 1988-09-26 1990-06-26 The Goodyear Tire & Rubber Company Nylon modified rubber composition wherein either nylon or rubber or both are reacted with a thio acid
AU670061B2 (en) * 1992-02-27 1996-07-04 Composite Particles, Inc. Higher modulus compositions incorporating particulate rubber
US5693714A (en) * 1992-02-27 1997-12-02 Composite Particles, Inc. Higher modulus compositions incorporating particulate rubber
US5506283A (en) * 1992-02-27 1996-04-09 Composite Particles, Inc. Higher modulus compositions incorporating particulate rubber
US5268134A (en) * 1992-06-15 1993-12-07 The Goodyear Tire & Rubber Company Technique for manufacturing hose
US5216073A (en) * 1992-07-01 1993-06-01 Hoechst Celanese Corp. Thermoset LCP blends
US5239004A (en) * 1992-07-15 1993-08-24 The Goodyear Tire & Rubber Company Polyether ester amide-sulfur vulcanized rubber compounds
JPH1180521A (ja) * 1997-09-11 1999-03-26 Daicel Chem Ind Ltd ポリマーアロイおよびそれを含有する組成物
US6248827B1 (en) 1997-12-22 2001-06-19 Bridgestone Corporation Centipede polymers and preparation and application in rubber compositions
US6204354B1 (en) 1998-05-06 2001-03-20 Bridgestone Corporation Soft compounds derived from polypropylene grafted disubstituted ethylene- maleimide copolymers
US6248825B1 (en) 1998-05-06 2001-06-19 Bridgestone Corporation Gels derived from extending grafted centipede polymers and polypropylene
US6207763B1 (en) 1998-06-12 2001-03-27 Bridgestone Corporation Application of disubstituted ethylene-maleimide copolymers in rubber compounds
US6184292B1 (en) 1998-10-05 2001-02-06 Bridgestone Corporation Soft gel polymers for high temperature use
US6191217B1 (en) 1998-11-17 2001-02-20 Bridgestone Corporation Gels derived from polypropylene grafted alkyl vinylether-maleimide copolymers
US6133354A (en) * 1998-11-17 2000-10-17 Bridgestone Corporation Copolymers as additives in thermoplastic elastomer gels
US6220634B1 (en) * 1999-02-08 2001-04-24 The Goodyear Tire & Rubber Company Branched hose construction
AU5920699A (en) * 1999-09-09 2001-04-10 Goodyear Tire And Rubber Company, The A precured non-cord reinforced carcass
US6476117B1 (en) 2000-06-05 2002-11-05 Bridgestone Corporation Grafted near-gelation polymers having high damping properties
US6350800B1 (en) 2000-06-05 2002-02-26 Bridgestone Corporation Soft polymer gel
US6417259B1 (en) 2000-06-05 2002-07-09 Bridgestone Corporation Polyalkylene grafted centipede polymers
US6384134B1 (en) 2000-06-05 2002-05-07 Bridgestone Corporation Poly(alkenyl-co-maleimide) and maleated polyalkylene grafted with grafting agent, and epoxy polymer
US6353054B1 (en) 2000-07-31 2002-03-05 Bridgestone Corporation Alkenyl-co-maleimide/diene rubber copolymers and applications
US6359064B1 (en) 2000-09-08 2002-03-19 Bridgestone Corporation Compound of polyester and polyalkylene grafted comb polymer
US20040094252A1 (en) * 2000-12-06 2004-05-20 Maurizio Galimberti Process for manufacturing, moulding and curing tyres for vehicles wheels
KR100416108B1 (ko) * 2001-04-02 2004-01-31 세원화성 주식회사 불포화폴리에스테르 수지의 제조 방법
US6861884B1 (en) * 2003-08-04 2005-03-01 Rambus Inc. Phase synchronization for wide area integrated circuits
US7891876B2 (en) * 2005-11-15 2011-02-22 Schaeffler Kg Linear roller bearing
ES2483944T3 (es) * 2007-12-28 2014-08-08 Bridgestone Corporation Interpolímeros que contienen unidades méricas de isobutileno y dieno

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Publication number Priority date Publication date Assignee Title
US4367316A (en) * 1975-11-27 1983-01-04 Toray Industries, Inc. Vulcanized elastomeric molded article
JPS5912928A (ja) * 1982-07-14 1984-01-23 Unitika Ltd 耐熱性及びゴムとの接着性の優れたポリエステルの製造法
WO1985003718A1 (en) * 1984-02-24 1985-08-29 E. I. Du Pont De Nemours And Company Toughened thermoplastic polyester compositions
US4843124A (en) * 1987-06-03 1989-06-27 E. I. Du Pont De Neumours And Company Thermoplastic elastomeric blends
US4937290A (en) * 1988-09-26 1990-06-26 The Goodyear Tire & Rubber Company Nylon modified rubber composition wherein either nylon or rubber or both are reacted with a thio acid
US4996263A (en) * 1988-10-06 1991-02-26 The Goodyear Tire & Rubber Company High modulus rubber composition

Also Published As

Publication number Publication date
NO901388D0 (no) 1990-03-26
US4996262A (en) 1991-02-26
NO901388L (no) 1990-09-28
NO175982B (no) 1994-10-03
DE69020400D1 (de) 1995-08-03
EP0390722A3 (en) 1992-04-08
AU627005B2 (en) 1992-08-13
BR9001314A (pt) 1991-04-02
CA2007072A1 (en) 1990-09-27
ES2075183T3 (es) 1995-10-01
JPH02281044A (ja) 1990-11-16
EP0390722A2 (en) 1990-10-03
EP0390722B1 (en) 1995-06-28
AR247573A1 (es) 1995-01-31
NO175982C (no) 1995-01-11
AU5223590A (en) 1990-09-27
ZA901925B (en) 1990-12-28

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