KR900004853B1 - Making process for steel plate for galvanization - Google Patents
Making process for steel plate for galvanization Download PDFInfo
- Publication number
- KR900004853B1 KR900004853B1 KR1019860011557A KR860011557A KR900004853B1 KR 900004853 B1 KR900004853 B1 KR 900004853B1 KR 1019860011557 A KR1019860011557 A KR 1019860011557A KR 860011557 A KR860011557 A KR 860011557A KR 900004853 B1 KR900004853 B1 KR 900004853B1
- Authority
- KR
- South Korea
- Prior art keywords
- steel sheet
- less
- temperature
- adhesion
- plating
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
Abstract
Description
제1도는 도금입욕(入浴)온도에 따른 부착성지수를 나타낸 그래프.1 is a graph showing the adhesion index according to the plating bath temperature.
제2도는 도금입욕온도에 따른 도금층내의 Al함량을 나타낸 그래프.2 is a graph showing the Al content in the plating layer according to the plating bath temperature.
본 발명은 아연도금강판의 제조방법 특히, 연주재 Al-Killed 강을 소재로 밀착성이 우수한 용융아연도금강판을 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a galvanized steel sheet, in particular, to a method for producing a hot-dip galvanized steel sheet having excellent adhesion to a material Al-Killed steel.
제강공정에서의 연주비 증가에 따라 냉연강판은 물론 아연도금강판에서도 연주재 Al-Killed 강판의 사용량이 증가되고 있다. 도금소재용을 비롯한 각종 표면처리 강판은 제조 후 가혹한 가공조건에서도 도금층이 박리되어서는 제품의 가치가 없으므로 강판소재의 재질뿐만 아니라 도금밀착성이 중요한 문제로 대두된다.As the performance ratio in the steelmaking process increases, the usage of Al-Killed steel sheet is increasing in cold rolled steel sheets and galvanized steel sheets. Various surface-treated steel sheets, including those for plating materials, are not a product value when the plating layer is peeled off even in the harsh processing conditions after manufacture, so the plating adhesion as well as the material of the steel sheet material becomes an important problem.
따라서, 연주재 Al-Killed 강을 소재로 밀착성이 우수한 용융 아연도금강판을 제조하기 위하여, 성분변화, 열간압연 후 고온권취, 용융조에서의 Al함량 조정 및 환원열처리 사이클 조정 등의 방법이 제안되었다.Therefore, in order to manufacture hot-dip galvanized steel sheet having good adhesion with Al-Killed steel as a material, methods such as component change, high temperature winding after hot rolling, adjustment of Al content in the melting tank and reduction heat treatment cycle adjustment have been proposed. .
우선, 성분을 변화시키는 방법은 Fe-Zn 반응성 증대를 위한 Si:0.02wt%(이하, %로 함), 및 Sol.Al이 0.02% 이하로 하여 밀착성을 향상시키는 방법이지만 Capped 강 수준의 밀착성을 갖지 못할 뿐만 아니라 Sol.Al이 0.02% 이하인 경우 가공용 및 고가공용 강판을 제조할 수 없는 문제점이 있다.First, the method of changing the component is a method of improving the adhesion of Si: 0.02 wt% (hereinafter referred to as%) and Sol.Al to 0.02% or less for increasing the Fe-Zn reactivity, but the adhesion of the level of Capped steel is improved. Not only does not have a Sol.Al is less than 0.02% there is a problem that can not produce a steel sheet for processing and high processing.
한편, 열간압연 후 고온권취하는 방법은 강중고용 Al(Sol.Al)과 N이 결합하여 AlN을 많이 형성시켜 용융아연도금시 Fe-Zn 반응성이 향상되고 강판표층에 Al이 농화하기 어려운 것으로 알려져 있으나, 고용 Al과 N을 효과적으로 전량 AlN으로 석출시키는 것은 불가능하므로 Capped 강 수준의 밀착성은 기대하기 어렵다. 또한, 환원열처리 사이클 조정방법은 환원열처리시 소둔온도를 상승시킴으로서 결정립 조대화에 의해 도금밀착성이 향상되나 이 또한 Capped 강 수준에는 미치지 못한다.On the other hand, the method of hot winding after hot rolling is known to improve the Fe-Zn reactivity during hot dip galvanizing due to the combination of high-strength Al (Sol.Al) and N to form a large amount of AlN. As a result, it is not possible to effectively precipitate the solid solution Al and N into the total amount of AlN. In addition, the reduction heat treatment cycle adjustment method improves the plating adhesion by grain coarsening by increasing the annealing temperature during the reduction heat treatment, but this also does not reach the level of the capped steel.
따라서, 본 발명은 연주재 Al-Killed 강을 소재로 밀착성이 우수한 아연도금강판을 제조하는 방법을 제공하고자 하는 것이다.Therefore, the present invention is to provide a method for producing a galvanized steel sheet having excellent adhesion to the material Al-Killed steel.
이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.
본 발명은 아연도금강판을 제조하는데 있어서, C:0.1wt%(이하, %로 칭함)이하, Mn:0.3% 이하, Si:0.02% 이하, P,S:0.015% 이하, 및 Sol.Al:0.03-0.07%로 조성된 강의 슬라브를 통상의 열간압연, 산세 및 냉간압연한 후 입욕온도를 480-500℃로 유지시킴을 특징으로 하는 밀착성이 우수한 아연도금강판을 제조하는 방법에 관한 것이다.In the present invention, in producing a galvanized steel sheet, C: 0.1 wt% or less (hereinafter referred to as%), Mn: 0.3% or less, Si: 0.02% or less, P, S: 0.015% or less, and Sol.Al: The present invention relates to a method for producing a galvanized steel sheet having excellent adhesion, characterized in that the slab of steel composed of 0.03-0.07% is hot rolled, pickled and cold rolled to maintain the bathing temperature at 480-500 ° C.
상기에서, C는 0.1% 이상인 경우 냉간성형성이 열화되므로, 0.1% 이하가 바람직하다. Mn은 0.3% 이상인 경우 열처리시 Mn 화합물 생성에 의해 도금밀착성이 열화되므로 0.3% 이하가 바람직하다.In the above, since C is deteriorated in cold forming when 0.1% or more, 0.1% or less is preferable. When Mn is 0.3% or more, the plating adhesion is deteriorated by Mn compound formation during heat treatment, so 0.3% or less is preferable.
Si는, 환원열처리시 강판표면에서 활성이 가장 큰 원소로서, 0.02% 이상인 경우 화합물 생성에 따른 Fe/Zn 반응성 저하로 밀착성이 급격히 열화되므로 0.02% 이하가 바람직하다.Si is the most active element on the surface of the steel sheet during the reduction heat treatment, and when it is 0.02% or more, the adhesion is rapidly deteriorated due to the decrease in Fe / Zn reactivity due to the compound formation, and therefore 0.02% or less is preferable.
Sol.Al은 고용 Al(Soluble Al) 즉, 강에 첨가된 총 Al중 Al2O3로 존재하고 Al량을 제외한 Al을 의미하는 것으로서, 탈산제로서 첨가되며, 0.03% 이하인 경우 가공용 및 고가공용 도금강판을 제조할 수 없고, 0.07% 이상인 경우 표면품질이 열화되므로, 0.03-0.07%가 바람직하다.Sol.Al means solid Al (Soluble Al), that is, Al 2 O 3 in the total Al added to the steel, and means Al except Al. Since the steel sheet cannot be manufactured and the surface quality is deteriorated when it is 0.07% or more, 0.03-0.07% is preferable.
도금입욕온도는 480℃ 이하 및 500℃ 이상인 경우 Fe-Al층의 안정화 시간(duration period)이 짧아져 단시간내 Fe-Al층이 부서지기 때문에 Zn에 의해 Fe가 직접적으로 반응하여 Fe-Zn층이 생성됨에 따라 밀착성이 열화되므로 480-50℃가 바람직하다.When the plating bath temperature is below 480 ° C and above 500 ° C, the Fe-Al layer is shortened and the Fe-Al layer breaks in a short time. Therefore, Fe reacts directly with Zn, causing the Fe-Zn layer to react. As adhesion is degraded as it is produced, 480-50 ° C. is preferred.
한편, 본 발명에 바람직하게 적용되는 통상의 열간압연은 1200℃ 이상으로 가열하고, 870-920℃의 마무리 압연온도로 열간압연하고, 580-720℃에서 권취하는 것이며, 산세방법으로는 10% 염산용액에 침적하여 산세하는 방법을 들 수 있으며, 냉간압연은 60-85%의 압하율로 냉간압연하는 것이 바람직하다.On the other hand, the usual hot rolling preferably applied to the present invention is to be heated to 1200 ° C or higher, hot rolled to a finish rolling temperature of 870-920 ° C, and wound up at 580-720 ° C, and 10% hydrochloric acid by the pickling method. The method of immersing in a solution and pickling is mentioned, It is preferable to cold-roll cold-roll at a reduction ratio of 60-85%.
상기와 같이 구성된 본 발명은, Fe-Al이 자유엔탈피가 Fe-Zn보다 커서 아연도금욕으로부터 더 많은 Al이 추출될 뿐만 아니라 Fe-Zn에 비하여 Fe-Al결합이 우선적으로 형성되어 도금층내 Al함량이 증대되고 소재표면에 직접으로, 농축된 후 Fe-Zn 반응의 확산작용에 의해 도금공정이 진행되므로, 우수한 밀착성을 갖는 아연도금강판을 제공한다.In the present invention configured as described above, Fe-Al has a larger enthalpy than Fe-Zn, so that more Al is extracted from the galvanizing bath, and Fe-Al bonds are preferentially formed in comparison with Fe-Zn, so that the Al content in the plating layer is increased. Since the plating process is increased by the diffusion action of the Fe-Zn reaction after being increased and concentrated directly on the material surface, a galvanized steel sheet having excellent adhesion is provided.
이하 실시예를 통하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail through examples.
[실시예 1]Example 1
하기표 1에 따라 조성된 강의 슬라브를 열간압연 후 통상의 산세를 한 다음 냉간압연으로 최종 두께가 0.7mm인 강판을 제조한다. 연속용융도금작업은, 표 2에 나타난 바와 같이, 예열로 온도 630℃ 환원 가열온도 700℃로 고정하고, 도금입욕전 강판온도(F/S)는 460℃에서 520℃로 변화하여 침적한다.After hot rolling the slab of the steel composition according to the following Table 1 is subjected to normal pickling, and then cold rolled to prepare a steel sheet having a final thickness of 0.7mm. Continuous melt plating operation, as shown in Table 2, is fixed to the preheating temperature 630 ℃ reduction heating temperature 700 ℃, steel plate temperature (F / S) before plating bath is deposited and changed from 460 ℃ to 520 ℃.
한편, 용융조의 온도는 460℃, Al함량은 0.18%, Fe함량은 0.097%이다.On the other hand, the temperature of the melting bath is 460 ° C, Al content is 0.18%, and Fe content is 0.097%.
[표 1]TABLE 1
[표 2]TABLE 2
상기 조건으로 제조된 아연도금강판에 대한 부착성 시험 즉, 밀착성지수 및 도금층내의 Al함량을 측정하여 그 결과치를 제1도 및 제2도에 나타내었다.(제1도 및 제2도에 나타난 결과치는 상기 표 1에 제시된 각각의 강판에 대한 평균치임) 제1도 및 제2도에서 알 수 있는 바와 같이, 도금입욕온도를 480-500℃, 용융조(pot)온도 460℃에서 제조한 경우 Capped 강과 동등한 수준의 우수한 도금밀착성을 갖는다.The adhesion test on the galvanized steel sheet manufactured under the above conditions, that is, the adhesion index and the Al content in the plating layer were measured, and the results are shown in FIGS. 1 and 2. Value is an average value for each steel sheet shown in Table 1). As can be seen in FIGS. 1 and 2, when the plating bath temperature is manufactured at 480-500 ° C. and the
따라서, 본 발명은 도금밀착성이 우수한 연주재 Al-Killed 강판을 제공한다.Accordingly, the present invention provides an Al-Killed steel sheet having excellent plating adhesion.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019860011557A KR900004853B1 (en) | 1986-12-30 | 1986-12-30 | Making process for steel plate for galvanization |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019860011557A KR900004853B1 (en) | 1986-12-30 | 1986-12-30 | Making process for steel plate for galvanization |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880007768A KR880007768A (en) | 1988-08-29 |
KR900004853B1 true KR900004853B1 (en) | 1990-07-08 |
Family
ID=19254552
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860011557A KR900004853B1 (en) | 1986-12-30 | 1986-12-30 | Making process for steel plate for galvanization |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR900004853B1 (en) |
-
1986
- 1986-12-30 KR KR1019860011557A patent/KR900004853B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR880007768A (en) | 1988-08-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2587725B2 (en) | Method for producing P-containing high tensile alloyed hot-dip galvanized steel sheet | |
CN1096060A (en) | Alloyed hot-dip galvanized steel plate | |
JP2964911B2 (en) | Alloying hot-dip galvanizing method for P-added high-strength steel | |
JP3480357B2 (en) | Method for producing high strength galvanized steel sheet containing Si and high strength galvannealed steel sheet | |
JPH07216524A (en) | Hot dipping method of high tensile strength hot rolled steel plate | |
KR900004853B1 (en) | Making process for steel plate for galvanization | |
JP3382697B2 (en) | Manufacturing method of galvannealed steel sheet | |
JPH06158254A (en) | Manufacture of hot-dip galvannealed steel sheet | |
JPH06212383A (en) | Hot dip galvanizing method for silicon-containing steel sheet | |
JP2525165B2 (en) | Method for manufacturing high strength galvanized steel sheet | |
JPH04176854A (en) | Production of aluminized steel sheet excellent in adhesive strength of plating and external appearance characteristic | |
JPH07243012A (en) | Production of galvannealed steel sheet excellent in external appearance of surface | |
JPH05106001A (en) | Hot-dip galvanizing method for silicon-containing steel sheet | |
JP2674429B2 (en) | Hot-dip galvanizing method for silicon-containing steel sheet | |
JP2000119832A (en) | Hot dip galvanized steel sheet excellent in plating adhesion | |
JP3631584B2 (en) | Method for producing alloyed hot-dip galvanized steel sheet | |
JP2001026852A (en) | Production of galvanized steel sheet and galvannealed steel sheet | |
JP3166568B2 (en) | Manufacturing method of hot-dip galvanized steel | |
JP2565054B2 (en) | Method for producing galvannealed steel sheet with excellent deep drawability and plating adhesion | |
JP2549539B2 (en) | Method for producing hot dip galvanized steel sheet for ultra deep drawing | |
JP3446002B2 (en) | Method for producing thin steel sheet for paint base with excellent surface appearance and press formability | |
JPH07197225A (en) | Hot-dip metal plating method of high tensile strength hot-rolled steel sheet | |
JPH04301060A (en) | High strength alloyed galvanized steel sheet having seizing hardenability and excellent in powdering resistance and its production | |
JPH04276055A (en) | Manufacture of differential galvannealed steel | |
JP3480348B2 (en) | Method for producing high-strength galvanized steel sheet containing P and high-strength galvannealed steel sheet |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
G160 | Decision to publish patent application | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 19990629 Year of fee payment: 10 |
|
LAPS | Lapse due to unpaid annual fee |