KR900003218A - 폴리에스테르 예비중합체를 축압시켜 제조한 다공성 정제의 고상중합 - Google Patents

폴리에스테르 예비중합체를 축압시켜 제조한 다공성 정제의 고상중합 Download PDF

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Publication number
KR900003218A
KR900003218A KR1019890008791A KR890008791A KR900003218A KR 900003218 A KR900003218 A KR 900003218A KR 1019890008791 A KR1019890008791 A KR 1019890008791A KR 890008791 A KR890008791 A KR 890008791A KR 900003218 A KR900003218 A KR 900003218A
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KR
South Korea
Prior art keywords
microns
polyester prepolymer
solid phase
diameter
phase polymerization
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KR1019890008791A
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English (en)
Inventor
니콜라스 스카나피에코 스티븐
Original Assignee
카알 에이취. 크루코우
더 굿이어 타이어 앤드 러버 캄파니
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Application filed by 카알 에이취. 크루코우, 더 굿이어 타이어 앤드 러버 캄파니 filed Critical 카알 에이취. 크루코우
Publication of KR900003218A publication Critical patent/KR900003218A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/80—Solid-state polycondensation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/919—Sintered product

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

내용 없음

Description

폴리에스테르 예비중합체를 축압시켜 제조한 다공성 정제의 고상중합
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 상승온도에서, 저분자량의 폴리에스테르 예비중합체를 고분자량의 폴리에스테르 수지로 고상중합하는 공정에 있어서, 약841마이크론 이하의 직경을 가지는 폴리에스테르 예비중합체의 파이버를 축압시키거나 응집시켜 제조된 다공성 정제의 형태인 폴리에스테르 예비 중합체를 사용함을 특징으로 하는 공정.
  2. 매우 빠른 속도로 고분자량의 폴리에스테르 수지로 고상중합될 수 있는 다공정 정제에 있어서, 상기 다공성 정제가, 0.4g/dl의 농도에서 30℃의 온도에서 60 : 40의 페놀 ; 테트라클로로에탄 용매계내에서 측정하였을때 적어도 약 0.2dl/g의 고유점도를 가지는 폴리에스테르 예비중합체로 구성됨을 특징으로 하고 ; 상기 다공성 정제가 이 다공성 정제를 관통하여 외부로 뚫린 상당한 부피의 격자간격을 가지며 ; 및 상기 다공성 정제가 약 841마이크론 이하의 직경을 가지는 폴리에스테르 예비 중합체의 파이버를 축압시키거나 응집시켜 제조된 다공성 정제.
  3. 제2항에 있어서, 상기 파이버가 약 50마이크론 내지 약 250마이크론의 직경을 가지고 ; 상기 폴리에스테르 예비중합체가 폴리에틸렌 테레프탈 레이트이며 ; 및 상기 폴리에틸렌 테페프탈레이트가 약 0.25dl/g내지 약 0.65dl/g 범위의 고유점도를 가지는 것을 특징으로 하는 다공성 정제.
  4. 제1항에 있어서, 상기 폴리에스테로 예비중합체가 약 0.25내지 약 0.65dl/g 범위의 고유점도를 가지고 ; 및 상기 파이버가 약 25마이크론 내지 500마이크론의 직경을 가지는 것을 특징으로 하는 공정.
  5. 제4항에 있어서, 상기 고상중합을 관상 중합 반응기내에서 수행함을 특징으로 하고 ; 상기 다공성 정제가 부분적으로 막힌 상태에서 중력에 의해서 반응기의 상부로부터 바닥으로 이동하고 ; 및 불활성 가스를 반응기를 통하여 역류시키는 공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890008791A 1988-08-03 1989-06-26 폴리에스테르 예비중합체를 축압시켜 제조한 다공성 정제의 고상중합 KR900003218A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US229,680 1988-08-03
US07/229,680 US4849497A (en) 1988-08-03 1988-08-03 Solid state polymerization of porous pills made by compacting polyester prepolymers

Publications (1)

Publication Number Publication Date
KR900003218A true KR900003218A (ko) 1990-03-26

Family

ID=22862254

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890008791A KR900003218A (ko) 1988-08-03 1989-06-26 폴리에스테르 예비중합체를 축압시켜 제조한 다공성 정제의 고상중합

Country Status (10)

Country Link
US (1) US4849497A (ko)
EP (1) EP0354159A1 (ko)
JP (1) JPH0275627A (ko)
KR (1) KR900003218A (ko)
CN (1) CN1039815A (ko)
AU (1) AU611353B2 (ko)
BR (1) BR8903074A (ko)
MX (1) MX165713B (ko)
TR (1) TR24382A (ko)
ZA (1) ZA894579B (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4963644A (en) * 1989-09-18 1990-10-16 The Goodyear Tire & Rubber Company Process for crystallization of polyethylene naphthalate
ES2070878T3 (es) * 1989-10-13 1995-06-16 Phobos Nv Procedimiento para la produccion en continuo de resina de poliester de alto peso molecular.
US5145742A (en) * 1990-08-03 1992-09-08 Eastman Kodak Company Polymer pellet configuration for solid-state polymerization
US5391694A (en) * 1993-10-15 1995-02-21 Shell Oil Company Solid state polymerization of polyesters with low diffusion resistance prepolymer granules
US5449701A (en) * 1994-12-15 1995-09-12 Shell Oil Company Solid state polymerization process for foamed poly(ethylene naphthalate)
US5750644A (en) * 1996-10-30 1998-05-12 Shell Oil Company Process for the crystallization of polyethylene naphthalate prepolymers and the solid stating of those crystallized prepolymers
KR19980061618A (ko) * 1996-12-31 1998-10-07 김준웅 고중합도 폴리트리메틸렌테레프탈레이트의 제조방법
US6048922A (en) * 1997-08-20 2000-04-11 Eastman Chemical Company Process for preparing high strength fiber reinforced composites
US6043313A (en) 1997-09-04 2000-03-28 Eastman Chemical Company Thermoplastic polyurethane additives for improved polymer matrix composites and methods of making and using therefor
US6284866B1 (en) 1999-12-07 2001-09-04 Wellman, Inc. Method of preparing modified polyester bottle resins
ITTO20020714A1 (it) * 2002-08-09 2004-02-10 Giuliano Cavaglia Procedimento per la polimerizzazione continua di
ITTO20070084A1 (it) * 2007-02-06 2008-08-07 K & E Srl Dispositivi di miscelazione radiale per reattori inclinati rotanti.
US8945588B2 (en) 2011-05-06 2015-02-03 The University Of Chicago Methods and compositions involving protective staphylococcal antigens, such as EBH polypeptides
US10038726B2 (en) * 2013-06-12 2018-07-31 Visa International Service Association Data sensitivity based authentication and authorization

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3586647A (en) * 1968-07-10 1971-06-22 Mobil Oil Corp Solid state polycondensation with porous polyester prepolymer particles
US3634356A (en) * 1969-05-02 1972-01-11 Fmc Corp Solid state polymerization of polyester filaments
UST873013I4 (en) * 1969-10-23 1970-04-21 Defensive publication
US4613664A (en) * 1984-12-28 1986-09-23 Toyo Boseki Kabushiki Kaisha Process for production of polyester
US4742151A (en) * 1986-06-26 1988-05-03 Toyo Boseki Kabushiki Kaisha Ultra-high-molecular-weight polyesters
US4876326A (en) * 1987-03-26 1989-10-24 The Goodyear Tire & Rubber Company Solid state polymerization of polyester prepolymers
US4755587A (en) * 1987-03-26 1988-07-05 The Goodyear Tire & Rubber Company Solid state polymerization of polyester prepolymers
US4792573A (en) * 1988-04-01 1988-12-20 The Goodyear Tire & Rubber Company Preparation of ultra-high molecular weight polyester

Also Published As

Publication number Publication date
BR8903074A (pt) 1990-03-06
US4849497A (en) 1989-07-18
AU3647489A (en) 1990-02-08
EP0354159A1 (en) 1990-02-07
CN1039815A (zh) 1990-02-21
AU611353B2 (en) 1991-06-06
JPH0275627A (ja) 1990-03-15
TR24382A (tr) 1991-09-23
MX165713B (es) 1992-12-01
ZA894579B (en) 1990-03-28

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