KR900003217A - 폴리아릴렌술피드, 그제조방법 및 수지조성물 - Google Patents
폴리아릴렌술피드, 그제조방법 및 수지조성물 Download PDFInfo
- Publication number
- KR900003217A KR900003217A KR1019890011047A KR890011047A KR900003217A KR 900003217 A KR900003217 A KR 900003217A KR 1019890011047 A KR1019890011047 A KR 1019890011047A KR 890011047 A KR890011047 A KR 890011047A KR 900003217 A KR900003217 A KR 900003217A
- Authority
- KR
- South Korea
- Prior art keywords
- polyarylene sulfide
- viscosity
- sulfide
- weight
- filler
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/025—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0209—Polyarylenethioethers derived from monomers containing one aromatic ring
- C08G75/0213—Polyarylenethioethers derived from monomers containing one aromatic ring containing elements other than carbon, hydrogen or sulfur
- C08G75/0222—Polyarylenethioethers derived from monomers containing one aromatic ring containing elements other than carbon, hydrogen or sulfur containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/0204—Polyarylenethioethers
- C08G75/0231—Polyarylenethioethers containing chain-terminating or chain-branching agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 1에서 얻게된 폴리아릴렌술피드의 분자량분포를 표시하는 GPC 차아트도.
제2도는 실시예 5에서 얻게된 폴리아릴렌술피드의 분자량 분포를 표시한 GPC 차아트도.
제3도는 비교예 4에서 얻게된 폴리아릴렌술피드의 분자량 분포를 표시한 GPC 차아트도.
Claims (11)
- 대수점도수[ninh]가 0.1∼0,5dl/g이고, 중량평균분자량이 1×104∼2×105이며, 대수점도수 [ninh]와 계산점도 [n]calc와의 비(대수점도수[n]inh/계산점도[n]calc)가 0.4∼0.8이고, 백색도[JIS P8123]가 50이상인 것을 특징으로하는 폴리아릴렌술피드.
- 제1항에 있어서, 대수점도수[ninh]가 0.2∼0,4dl/g이고, 중량평균분자량이 2×104∼1.5×105이며, 대수점도수 [ninh]와 계산점도 [n]calc와의 비(대수점도수[n]inh/계산점도[n]calc)가 0.5∼0.8이고, 백색도[JIS P8123]가 60이상인 것을 특징으로하는 폴리아릴렌술피드.
- 제1항에 있어서, 분자량2×105이상의 성분의 전체에 대한 비율이 3중량%이상임과 동시에 분자량2×103이하의 성분의 전체에 대한 비율이 20중량%이하인 분자량분포를 가진 폴리아릴렌술피드.
- 제1항에 있어서, 유동특성 파라미터가 1.2이상인 폴리아릴렌술피드.
- 극성용매속에서, (A)알칼리금속황합물 및 알칼리금속수황화물로 이루어진군에서 선택되는 적어도 1종의 금속황화물과 (B)디할로켄 방향족화합물과 (C)관능기를 3개이상 가진 방향족화합물을 접촉해서 반응시킬때, 사용하는 상기 (A)성분에 대한 상기(B)성분의 비율을 몰비[(B)/(A)]로 1.035∼1.300의 범위내로하고, 또한, 사용하는 상기(B)성분에 대한상기(C)성분의 비율을 몰비[(C)/(B)]로 0.003∼0.05의 범위내로 할것을 특징으로하는 폴리아릴렌술피드의 제조방법.
- 제5항에 있어서, 상기 극성용매가 락탐화합물이고, (A)상기 알칼리금속황화물이 황화나트륨이고, (B)상기 디할로겐방향족화합물이 디할로벤젠류이고, (C)상기 관능기를 3개이상 가진 방향족 화합물이 디할로니트로 벤젠 및 트리할로벤젠으로 이루어진 군에서 선택된 적어도 1종인 폴리아릴렌술피드의 제조방법.
- 제5항에 있어서, 상기 극성용매가 N-알킬피롤리돈이고, (A)상기 알칼리금속황화물이 황화나트륨이며, (B)상기 디할로겐방향족화합물이 P-디클로로벤젠 또는 m-디클로로벤젠을 20몰%이하의 비율로 함유하는 P-디클로로벤젠이고, (C)상기 관능기를 3개이상 가진 방향족화합물이 디클로로니트로벤젠 및 트리클로로 벤젠으로 이루어진 군에서 선택되는 적어도 1종인 폴리아릴렌술피드의 제조방법.
- 제1항기재의 폴리아릴렌술피드와, 섬유형상충전재 및 분말입자형상충전재로 이루어진 군에서 선택되는 적어도 1종의 충전재를 함유하는 것을 특징으로 하는 폴리아릴렌술피드수지조성물.
- 제8항에 있어서, 상기 충전재에 평균섬유직경 또는 평균입자직경이20㎛인 폴리아릴렌술피드수지조성물.
- 제8항에 있어서, 상기 충전재가 유리섬유인 폴리아릴렌술피드수지조성물.
- 제8항에 있어서, 상기 충전재의 배합량이 폴리아릴렌수피드 100중량부에 대해서 5500중량부인 폴리아릴렌술피드수지조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP195845 | 1988-08-05 | ||
JP63-195845 | 1988-08-05 | ||
JP63195845A JPH0645693B2 (ja) | 1988-08-05 | 1988-08-05 | ポリアリーレンスルフィドの製造法 |
JP1-114675 | 1989-05-08 | ||
JP1114675A JP2784936B2 (ja) | 1989-05-08 | 1989-05-08 | ポリアリーレンスルフィドおよび樹脂組成物 |
JP114675 | 1989-05-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR900003217A true KR900003217A (ko) | 1990-03-26 |
KR930010565B1 KR930010565B1 (ko) | 1993-10-28 |
Family
ID=26453373
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890011047A KR930010565B1 (ko) | 1988-08-05 | 1989-08-02 | 폴리아릴렌술피드, 그 제조방법 및 수지조성물 |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0353717B1 (ko) |
KR (1) | KR930010565B1 (ko) |
DE (1) | DE68928382T2 (ko) |
MY (1) | MY109689A (ko) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4970261A (en) * | 1989-09-28 | 1990-11-13 | Phillips Petroleum Company | Fiber-reinforced poly(biphenylene sulfide) composites and methods |
JP3034335B2 (ja) * | 1991-05-31 | 2000-04-17 | 出光石油化学株式会社 | ポリアリーレンスルフィド樹脂組成物 |
CA2105211A1 (en) * | 1992-09-15 | 1994-03-16 | Lachhman H. Wadhwa | Reinforced poly(arylene sulfide) resins having reduced flash |
JP3951078B2 (ja) * | 1998-05-27 | 2007-08-01 | 大日本インキ化学工業株式会社 | ポリアリーレンスルフィド製メルトブロー不織布及びその製造方法 |
EP2546280B1 (en) * | 2010-03-10 | 2016-05-04 | SK Chemicals, Co., Ltd. | Polyarylene sulfide, and preparation method thereof |
CN105085917A (zh) * | 2015-08-05 | 2015-11-25 | 广州高八二塑料有限公司 | 薄膜级聚苯硫醚树脂及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1056227A (en) * | 1963-11-27 | 1967-01-25 | Phillips Petroleum Co | Production of aryl sulfides |
US4038261A (en) * | 1975-05-27 | 1977-07-26 | Phillips Petroleum Company | Production of branched arylene sulfide polymers |
US4071509A (en) * | 1976-08-13 | 1978-01-31 | Phillips Petroleum Company | Arylene sulfide polymer purification |
US4116947A (en) * | 1977-04-29 | 1978-09-26 | Phillips Petroleum Company | Branched arylene sulfide polymer production |
EP0075769B1 (de) * | 1981-09-25 | 1986-02-26 | Bayer Ag | Verfahren zur Herstellung von Polyarylensulfiden |
AU544880B2 (en) * | 1982-08-03 | 1985-06-20 | Phillips Petroleum Co. | Arylene sulphide terpolymers |
DE3318401A1 (de) * | 1983-05-20 | 1984-11-22 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von hochmolekularen, gegebenenfalls verzweigten polyarylensulfiden |
JPH0618877B2 (ja) * | 1987-06-30 | 1994-03-16 | 出光石油化学株式会社 | ポリアリ−レンスルフィドの製造方法 |
-
1989
- 1989-07-31 MY MYPI89001039A patent/MY109689A/en unknown
- 1989-08-01 EP EP89114210A patent/EP0353717B1/en not_active Expired - Lifetime
- 1989-08-01 DE DE68928382T patent/DE68928382T2/de not_active Expired - Fee Related
- 1989-08-02 KR KR1019890011047A patent/KR930010565B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP0353717A2 (en) | 1990-02-07 |
EP0353717B1 (en) | 1997-10-15 |
MY109689A (en) | 1997-04-30 |
DE68928382T2 (de) | 1998-05-07 |
EP0353717A3 (en) | 1992-01-08 |
DE68928382D1 (de) | 1997-11-20 |
KR930010565B1 (ko) | 1993-10-28 |
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