KR890008071A - 2-(2,2- 디플루오로시클로프로필)알킬 에스테르, 그의 제조방법 및 살충제 및 진드기 구충제로서의 용도 - Google Patents
2-(2,2- 디플루오로시클로프로필)알킬 에스테르, 그의 제조방법 및 살충제 및 진드기 구충제로서의 용도 Download PDFInfo
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- KR890008071A KR890008071A KR1019880000747A KR880000747A KR890008071A KR 890008071 A KR890008071 A KR 890008071A KR 1019880000747 A KR1019880000747 A KR 1019880000747A KR 880000747 A KR880000747 A KR 880000747A KR 890008071 A KR890008071 A KR 890008071A
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
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Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 하기 일반식(I)로 표시된 2-(2,2-디플루오로시클로프로필)알킬 에스테르상기 식중 Y는 임의로 치환된 아릴기로서, 이 아릴기는 C1-6-알킬, 할로-C1-6-알킬, 페닐-C1-6-알킬, C2-6-알케닐, 페닐-C2-6-알케닐, C2-6-일키닐, 할로-C2-6-알키닐,페닐-C2-6-알키닐, C1-16-알콕시, 할로-C1-6-알콕시, 페닐-C1-6-알콕시, C3-10-시클로알콕시, 할로-C3-10-시클로알콕시, 페닐-C3-10-시클로알콕시, C3-6-시클로알킬알콕시, 할로-C3-6-시클로알킬알콕시, 페닐-C3-6-시클로알킬알콕시, C2-6-알케닐옥시, 할로-C2-6-알케닐옥시, 페닐-C2-6-알케닐옥시, C2-6-알키닐옥시, 할로-C2-6-알키닐옥시, 페닐-C2-6-알키닐옥시, 알킬술포닐옥시, 할로알킬술포닐옥시, 아릴술포닐옥시, 페닐, 할로겐, 아미노, 시아노, 히드록시, 니트로, 아릴옥시, 할로아릴옥시, C1-6-알킬아릴옥시, 니트로아릴옥시, 아릴아미노, 할로아릴아미노, C1-6-알킬아미노, 아릴-N-C1-6-알킬아미노, C1-6-알콕시카르보닐, 할로-C1-6-알콕시카르보닐, 페닐-C1-6-알콕시카르보닐, C3-10-시클로알콕시카르보닐, 할로-C3-10-시클로알콕시카르보닐, C3-6-시클로알콕시카르보닐, 할로-C3-6-시클로알콕시카르보닐, 페닐-C3-6-시클로알콕시카르보닐, C1-2-알킬디옥시, 알킬-C3-10-시클로알콕시, C1-6-알킬 티오, 할로-C3-6-시클로알킬알킬아미노, C1-6-알킬아미노, 디-C1-6-알킬아미노, N-피롤릴, COOR8(여기에서 R8은 수소 또는 금속 원자임) 또는 N(R9)3X기(여기에서 R9는 수소 또는 C1-6-알킬기이고, X는 할로임)에 의해 임의로 1회 이상 치환되고, R1,R2,R3,R4,R5,R6및 R7은 서로 동일하거나 또는 상이한 것으로서 수소, C1-6-알킬, 할로-C1-6-알킬, 페닐 또는 할로페닐기이거나 또는 R1과 R2가 함께 알리시클릭 고리를 형성할 수도 있고, n은 0 또는 1이다.
- 제 1 항에 있어서 Y가 페닐, 푸라닐, 티로페닐, 벤조티오페닐기이거나, 또는 니트로, 플루오로, 클로로, 브로모, C1-6-알킬, C1-6-알콕시, 할로-C3-6-시클로알킬알콕시, 페닐, C2-6-알키닐옥시 또는 할로-C2-6-알케닐옥시기에 의해 1회 이상 치환된 페닐, 푸라닐, 티오페닐, 벤조티오페닐, 나프틸 또는 페닐렌기이고, R1-4가 수소이고, R5-7이 수소 또는 메틸기이고,n이 0 또는 1임을 특징으로 하는 2-(2,2-디플루오로시클로프로필)알킬 에스테르.
- 제 1 항 또는 2항에 의한 화합물과 농업적으로 허용 가능한 희석제 또는 담체로 되는 살충 및 진드기 구충 조성물
- 제 1 항 또는 2항에 의한 화합물 유효량을 곤충 또는 진드기 또는 그의 소재지에 투여하는 것으로 되는 곤충 및 진드기 박멸 방법
- A)하기 일반식(II)의 산 할로겐화물을 산 수용테의 존재하에 임의로 용매를 사용하여 하기 일반식 (III)의 알코올과 반응시키거나, 또는 B) 하기 일반식(IV)의 유리산을 임의로 용매와 촉매를 사용하여 일반식(III)의 알코올과 반응시키거나, 또는 C)일반식(IV)의 유리산을 임의로 용매와 촉매를 사용하여 하기 일반식(V)의 알코올과 반응시켜서 하기 일반식(IV)의 중간체를 얻고, 이 중간체를 불활성 용매 존재 하에 구조식[:CF₂]의 디플루오로카르벤과 반응시킴을 특징으로하는 제 1 항에 의한 화합물의 제조방법상기식중 Y,n 및 R1-7은 제 1 항에서 정의한 바와 같고, X는 염소 또는 브롬이다※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873703212 DE3703212A1 (de) | 1987-01-30 | 1987-01-30 | 2-(2,2-difluorcyclopropyl)-alkylester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide mittel |
DEP3703212.7 | 1987-01-30 |
Publications (1)
Publication Number | Publication Date |
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KR890008071A true KR890008071A (ko) | 1989-07-08 |
Family
ID=6320124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019880000747A KR890008071A (ko) | 1987-01-30 | 1988-01-29 | 2-(2,2- 디플루오로시클로프로필)알킬 에스테르, 그의 제조방법 및 살충제 및 진드기 구충제로서의 용도 |
Country Status (17)
Country | Link |
---|---|
US (1) | US4889870A (ko) |
EP (1) | EP0277908A3 (ko) |
JP (1) | JPS63218642A (ko) |
KR (1) | KR890008071A (ko) |
CN (1) | CN88100537A (ko) |
AU (1) | AU609084B2 (ko) |
BR (1) | BR8800390A (ko) |
DD (1) | DD273189A5 (ko) |
DE (1) | DE3703212A1 (ko) |
DK (1) | DK46788A (ko) |
FI (1) | FI880410A (ko) |
HU (1) | HUT47204A (ko) |
IE (1) | IE880226L (ko) |
IL (1) | IL85067A (ko) |
PH (1) | PH24948A (ko) |
SU (1) | SU1690536A3 (ko) |
ZA (1) | ZA88667B (ko) |
Families Citing this family (1)
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AU2004289152B8 (en) * | 2003-11-13 | 2010-05-27 | The New Zealand Institute For Plant And Food Research Limited | Insect behaviour modifying compounds |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3993774A (en) * | 1973-02-16 | 1976-11-23 | Shell Oil Company | Pesticidal cyclopropane derivatives |
US3995054A (en) * | 1974-04-12 | 1976-11-30 | Zoecon Corporation | Control of Acarina by esters of cyclopropane acids |
AU526817B2 (en) * | 1978-06-21 | 1983-02-03 | Ici Australia Limited | Pesticides |
US4198527A (en) * | 1978-09-15 | 1980-04-15 | Zoecon Corporation | Ether substituted cyclopropanecarboxylic acids and esters |
WO1981002892A1 (en) * | 1980-04-10 | 1981-10-15 | Dainippon Jochugiku Kk | Cyclopropanecarboxylic acid ester derivatives,process for their preparation,and insecticidal and acaricidal composition containing such as effective ingredients |
DE3417791A1 (de) * | 1984-05-14 | 1985-11-14 | Basf Ag, 6700 Ludwigshafen | Neue halogenvinylbenzylester, deren herstellung und verwendung zur schaedlingsbekaempfung |
DE3431219A1 (de) * | 1984-08-24 | 1986-03-06 | Bayer Ag, 5090 Leverkusen | Benzoylharnstoffe |
-
1987
- 1987-01-30 DE DE19873703212 patent/DE3703212A1/de not_active Withdrawn
-
1988
- 1988-01-11 IL IL85067A patent/IL85067A/xx unknown
- 1988-01-19 SU SU884355013A patent/SU1690536A3/ru active
- 1988-01-27 EP EP88730019A patent/EP0277908A3/en not_active Withdrawn
- 1988-01-28 IE IE880226A patent/IE880226L/xx unknown
- 1988-01-28 DD DD88312513A patent/DD273189A5/de unknown
- 1988-01-28 JP JP63016028A patent/JPS63218642A/ja active Pending
- 1988-01-29 HU HU88406A patent/HUT47204A/hu unknown
- 1988-01-29 FI FI880410A patent/FI880410A/fi not_active IP Right Cessation
- 1988-01-29 US US07/149,732 patent/US4889870A/en not_active Expired - Fee Related
- 1988-01-29 AU AU10958/88A patent/AU609084B2/en not_active Ceased
- 1988-01-29 DK DK046788A patent/DK46788A/da not_active Application Discontinuation
- 1988-01-29 ZA ZA880667A patent/ZA88667B/xx unknown
- 1988-01-29 KR KR1019880000747A patent/KR890008071A/ko not_active Application Discontinuation
- 1988-01-30 CN CN198888100537A patent/CN88100537A/zh active Pending
- 1988-02-01 BR BR8800390A patent/BR8800390A/pt unknown
- 1988-06-29 PH PH36432A patent/PH24948A/en unknown
Also Published As
Publication number | Publication date |
---|---|
IL85067A0 (en) | 1988-06-30 |
EP0277908A3 (en) | 1989-10-18 |
BR8800390A (pt) | 1988-09-20 |
DK46788A (da) | 1988-07-31 |
AU1095888A (en) | 1988-08-04 |
HUT47204A (en) | 1989-02-28 |
EP0277908A2 (en) | 1988-08-10 |
DK46788D0 (da) | 1988-01-29 |
AU609084B2 (en) | 1991-04-26 |
DE3703212A1 (de) | 1988-08-11 |
CN88100537A (zh) | 1988-08-24 |
IL85067A (en) | 1992-02-16 |
IE880226L (en) | 1988-07-30 |
FI880410A0 (fi) | 1988-01-29 |
DD273189A5 (de) | 1989-11-08 |
SU1690536A3 (ru) | 1991-11-07 |
ZA88667B (en) | 1988-08-03 |
JPS63218642A (ja) | 1988-09-12 |
PH24948A (en) | 1990-12-26 |
FI880410A (fi) | 1988-07-31 |
US4889870A (en) | 1989-12-26 |
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