KR890001920B1 - A process for the high caloric coal from low quality by the utilization of carbon black - Google Patents

A process for the high caloric coal from low quality by the utilization of carbon black Download PDF

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KR890001920B1
KR890001920B1 KR1019860004821A KR860004821A KR890001920B1 KR 890001920 B1 KR890001920 B1 KR 890001920B1 KR 1019860004821 A KR1019860004821 A KR 1019860004821A KR 860004821 A KR860004821 A KR 860004821A KR 890001920 B1 KR890001920 B1 KR 890001920B1
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coal
soot
low
low quality
utilization
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KR880000555A (en
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허속
정판석
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허속
정판석
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Low quality coal (1800-3100 kcal/kg) is improved by mixing with soot from Bc boiler. Thus, pulverize low-grade coal (2900kcal/kg) to 100- 120 mesh, mix powd. coal (former, 54%) and soot (46%) to give solid high caloric coal (4510kcal/kg).

Description

그을음을 이용한 저질탄의 고열화 방법High deterioration method of low quality coal using soot

본 발명은 국내 전역에 걸쳐서 매장되어 있는 1800-3100kcal/kg의 발열량을 함유하고 있는 저질탄을 산업용 유류 보일러의 집진기에서 수거한 그을음(Dust)과 혼합하여 발열량이 높은 고체 연료를 제조하는 방법에 관한 것이다. 종래에는 저질탄의 이용 방법으로 3000kcal/kg정도의 발열랑을 갖는 저질탄에 방카씨유와 소량의 조연제를 혼합하여 구멍탄을 제조토록 하였으나, 이 구멍탄은 방카씨유에 내포되어 있는 황화물의 중금속 물질이 제거되지 않아 연소시에 유독가스 발생될뿐 아니라, 고가인 방카씨유를 혼합하므로 생산비가 높아 비 경제적이었다.The present invention relates to a method of producing a solid fuel having a high calorific value by mixing low coal containing 1800-3100 kcal / kg of calorific value stored throughout the country with soot collected in a dust collector of an industrial oil boiler. . Conventionally, a method of using low-carbon coal is to make a hole coal by mixing banca seed oil and a small amount of coagulant with a low-carbon coal having a heating flow of about 3000 kcal / kg, but this hole coal removes heavy metal substances of sulfides contained in the banca oil. Not only does it generate toxic gas during combustion, but also mixes expensive banca seed oil, making it uneconomical with high production costs.

이러한 경제성을 고려하여 본 발명은 산업용 유류 보일러에서 유류(Bc)연소시에 불완전 연소되어 생기는 그을음(Dust)을 굴뚝 하부에 설치된 집진기에서 수거하여 발열량이 낮아 쓸모없이 버려져 있는 저질탄과 혼합하여 발열량이 높은 연료로 활성화시켜 자체 열량만으로 사용가치가 없는 저질탄을 산업 및 가정 연료로 사용토록 개발하여 에너지자원 확대 및 보다 경제적인 고체 연료를 보급하는데 그 목적이 있는 것이다.In consideration of such economics, the present invention collects soot (Dust) generated by incomplete combustion at the time of burning oil (Bc) in an industrial oil boiler in a dust collector installed under the chimney, and generates a low calorific value by mixing with low quality coal that has been discarded and wasted. It aims to expand energy resources and supply more economical solid fuels by developing low-carbon coal, which has no value in its own calories, to be used as industrial and household fuels.

그을음(Dust)은 산업용 유류 보일러에서 불완전 연소되어 생기는 흑분재가 굴뚝에 설치된 집진기에 축적된 것으로서 KSE 3705-82, 3706-82, 3707-82에 의한 국립공업 시험원의 분석치는 다음과 같다.Soot is a black ash produced by incomplete combustion in an industrial oil boiler and accumulated in a dust collector installed in a chimney. The analysis results of the National Institute of Industrial Testing according to KSE 3705-82, 3706-82, and 3707-82 are as follows.

Figure kpo00001
Figure kpo00001

이상과 같은 그을음의 발열량이 6400kcal/kg으로 매우 높은뿐 아니라 산업용 유류 보일러에서 사용되는 중유(BC)의 량이 연간 약 1150만톤으로 추정되는 가운데, 불완전 연소되어 생기는 그을음의 량이 2%-10%임을 감안하여 산정하여 보면 연간 23만-115만톤의 그을음이 수거되어 바람에 날리거나 매몰시킴이 적합하지 않아 환경오염만 가져올뿐 폐기처분 하기에 곤란하였던 점을 착안하여 발열량이 낮은 저질탄에 발열량이 높은 그을음을 알맞은 비율로 혼합하여 고열의 고체연료를 제공하므로 폐기처분이 곤란하였던 그을음을 유용하게 재 활용시켜 에너지 자원의 확대와 경제적인 고체 연료를 보급시킬 수 있는 것이다. 이를 실시예에 따라 상세히 설명하면 다음과 같다.The soot calorific value is 6400kcal / kg and the amount of heavy oil (BC) used in industrial oil boilers is estimated to be about 11.1 million tons per year, while the amount of soot produced by incomplete combustion is 2% -10%. It is estimated that 230,000 to 1.15 million tons of soot is collected annually, so it is not suitable to be blown or buried, so it is difficult to dispose of only environmental pollution. By mixing it at an appropriate ratio, it provides high-temperature solid fuel, so that it is useful to recycle soot, which was difficult to dispose of, to expand energy resources and to supply economical solid fuel. This will be described in detail according to an embodiment as follows.

[실시예 1]Example 1

채취된 2900kcal/kg의 저질탄을 분쇄기로 100-120매쉬가 되게 분쇄하여 저질탄 54%와 그을음 46%를 혼합하여 4510kcal/kg의 발열량을 갖는 고형 연료를 얻는다.The collected 2900 kcal / kg of low-carbon coal is pulverized to a 100-120 mesh by a pulverizer and 54% of low-carbon coal and 46% of soot are mixed to obtain a solid fuel having a calorific value of 4510 kcal / kg.

[실시예 2]Example 2

채취된 2900kcal/kg의 저질탄을 분쇄기로 100-120매쉬가 되게 분쇄하고 저질탄 68%와 그을음 32%로 혼합하여 발열량이 4020kcal/kg의 고형 연료를 얻는다.The collected 2900 kcal / kg of low quality coal is pulverized to a 100-120 mesh with a pulverizer and mixed with low carbon 68% and soot 32% to obtain a calorific value of 4020 kcal / kg of solid fuel.

[실시예 3]Example 3

2500kcal/kg의 저질탄을 100-120매쉬 분쇄하고 저질탄 74%와 그을음 26%를 혼합하여 3514kcal/kg의 고형 연료를 얻는다.2,500 kcal / kg of coal is crushed 100-120 mesh and 74% of coal and 26% of soot are mixed to obtain 3514 kcal / kg of solid fuel.

[실시예 4]Example 4

2500kcal/kg의 저질탄을 100-120매쉬 분쇄하고 저질탄 60%와 그을음 40%를 혼합하여 발열량이 4060cal/kg의 고형 연료를 얻는다.2,500 kcal / kg of low-carbon coal is crushed 100-120 mesh and 60% of low-carbon coal and 40% of soot are mixed to obtain 4060 cal / kg of solid fuel.

[실시예 5]Example 5

채취된 3100kcal/kg의 저질탄을 100-120매쉬로 분쇄하고 저질탄 82%에 그을음 18%를 혼합하여 발열량이 4310kcal/kg의 고형 연료를 얻는다.The collected 3100kcal / kg low-carbon coal is pulverized into 100-120 mesh and 82% of low-carbon coal is mixed with soot 18% to obtain a calorific value of 4310kcal / kg solid fuel.

이와같이 연료로 사용할 수 없었던 저질탄의 발열량에 따라 그을음을 실시예와 같이 혼합하여 무연탄, 갈탄등의 연료로서 각기 필요한 발열량의 고형 연료를 제공할 수 있고, 산업용 유류 보일러에서 불완전 연소되어 집진기에 축적된 그을음은 불완전연소되었기 때문에 연소성이 높으며 일차 연소되었으므로 유독가스가 적고, 저질탄의 연소를 촉진시키며, 공해로 폐기 처분이 곤란하던 그을음을 연료로 재활용하므로 환경오염을 없애주고, 쓸모없이 매장되어 있는 저질탄을 고열의 연료로 제공하므로 에너지 자원의 확대로 수입탄의 대체 효과와 경제적인 고체 연료를 보급할 수 있는 것이다.As such, the soot may be mixed according to the calorific value of the low quality coal, which could not be used as a fuel, to provide solid fuel having the calorific value required for each of the anthracite coal and lignite, and the soot accumulated in the dust collector due to incomplete combustion in an industrial oil boiler. Because it is incompletely burned, it is highly combustible and it is first-burned, so it has less toxic gas, promotes combustion of low-carbon, and recycles soot, which was difficult to dispose of due to pollution, as a fuel, eliminating environmental pollution, and high-temperature of low-purity low-carbon. As a fuel for gasoline fuels, the expansion of energy resources can replace imported coal and supply economical solid fuels.

Claims (1)

100-120매쉬로 분쇄된 저질탄과 그을음을 혼합하여 고열화시킴을 특징으로 한 그을음을 이용한 저질탄의 고열화 방법.A method of high deterioration of low carbon using soot characterized in that the deterioration of the coal and sooty pulverized coal 100-120 mesh.
KR1019860004821A 1986-06-18 1986-06-18 A process for the high caloric coal from low quality by the utilization of carbon black KR890001920B1 (en)

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