KR880701758A - 블록공중합체를 포함하는 겔 - Google Patents

블록공중합체를 포함하는 겔

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Publication number
KR880701758A
KR880701758A KR1019880700309A KR880700309A KR880701758A KR 880701758 A KR880701758 A KR 880701758A KR 1019880700309 A KR1019880700309 A KR 1019880700309A KR 880700309 A KR880700309 A KR 880700309A KR 880701758 A KR880701758 A KR 880701758A
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KR
South Korea
Prior art keywords
copolymer
block
composition
block copolymer
hard
Prior art date
Application number
KR1019880700309A
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English (en)
Other versions
KR960006797B1 (ko
Inventor
제인 발레리에 프랜시스
노엘 마르셀 미치엘 오버버치
잔 로데위제크 엠. 에프. 지. 반산트
Original Assignee
원본 미기재
레이캠 리미티드
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Application filed by 원본 미기재, 레이캠 리미티드 filed Critical 원본 미기재
Publication of KR880701758A publication Critical patent/KR880701758A/ko
Application granted granted Critical
Publication of KR960006797B1 publication Critical patent/KR960006797B1/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Materials For Medical Uses (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Mechanical Coupling Of Light Guides (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

블록공중합체를 포함하는 겔
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. (A)비교적 경질의 블록 및 비교적 고무상의 블록을 함유하는 대부분의 공중합체, (b) 상기한 블록 공중합체의 경질 블록에 비해 더 높은 유리전이온도, 연화온도 또는 용융온도와 함께 블록공중합체의 경질블록과의 최소한 부분적으로나마 상용성을 갖는 부가중합체 또는 공중합체물질 ; 그리고 (c) 블록 공중합체의 100 중량부에 기초하여, 블록 공중합체의 고무상 블록을 익스텐드하고, 연화시켜주는 최소한 500 중량부의 익스텐더 액체의 친밀한 혼합물을 포함하는 조성물인 것으로써, (i) 100 내지 400(10-1mm)의 범위내에서 ASTM D217 원뿔관입값, (ii) 최소한 100% 신율의 실제적인 탄성변형율과 함께 100% 이상의 ASTM D412 극한실율, (iii) 1 MPa 이내의 ASTM D412 극한 인장강도, 그리고 (iv) 230C에서 50000pa 이내의 동적 기억 모듈러스를 갖는 겔 또는 겔로이드 액전중합체 조성물.
  2. 100 내지 300(10-1mm)의 범위내에서 ASTM D217 원뿔관입값을 갖는 제1항에 따른 조성물.
  3. 제1 또는 2항에 있어서, 부가중합체 또는 공중합체는 경질 블록과의 실제적 완전한 상용성을 가짐을 특징으로 하는 조성물.
  4. 상기 항들중의 어느 한항에 있어서, 익스텐더 액체의 비등점은 블록공중합체와 부가중합체 또는 공중 합체의 혼합물의 연화온도 또는 용융온도 보다 높음을 특징으로 하는 조성물.
  5. 제4항에 있어서, 익스텐더 액체는 블록공중합체와 부가중합체 또는 공중합체물질의 혼합물의 용융온도 또는 연화온도 미만의 온도에서 블록 공중합체 및 부가중합체 또는 공중합체물질과 혼합됨을 특징으로 하는 조성물.
  6. 제5항에 잇어서, 블록 공중합체 및 부가중합체 또는 공중합체 물질은 익스텐더 액체와 혼합되기전에 일제히 배합됨을 특징으로 하는 조성물.
  7. 상기 항들중의 어느 한항에 있어서, 블록 공중합체의 고무상 블록은 수소화된 고무를 포함함을 특징으로 하는 조성물.
  8. 상기 항들중의 어느 한항에 있어서, 블록 공중합체의 경질블록은 폴리스티렌을 포함함을 특징으로 하는 조성물.
  9. 상기 항들중의 어느 한항에 있어서, 부가중합체물질은 폴리페닐렌에테르를 포함함을 특징으로 하는 조성물.
  10. 상기 항들중의 어느 한항에 있어서, 부가 중합체 또는 공중합체 물질은 부가중합체물질이 경질블록과 최소한 부분적으로나마 상용성을 갖게 만드는 최소한 하나의 상용성화제와 함께, 그 자체 만으로는 블록공중합체의 경질블록과 중요하게 상용성을 갖지 못하는 중요한 비율의 중합체 또는 공중합체를 포함함을 특징으로 하는 조성물.
  11. 상기 항들중의 어느 한항에 있어서, 블록공중합체중의 경질블록 대 고무상 블록의 중량비는 0.25 : 1의 범위내에 있음을 특징으로 하는 조성물.
  12. 상기 항들중의 어느 한항에 있어서, 부가중합체 또는 공중합체의 양은 부가중합체 또는 공중합체가 없을때의 동일조성물의 연화온도 또는 용융온도 이상으로 조성물의 연화온도 또는 용융온도를 중요하게 증가 시키기에 충분한 양임을 특징으로 하는 조성물.
  13. 블록공중합체중의 경질블록의 중량부에 기초하여, 0.15 내지 3, 바람직하게는 0.15 내지 1.2 중량부의 부가 중합체 또는 공중합체를 포함하는 제12항에 따른 조성물.
  14. 상기 항들중의 어느 한항에 있어서, 최소한 200%의 신율을 가짐을 특징으로 하는 조성물.
  15. 상기 항들중의 어느 한항에 있어서, 익스탠더 액체는 2% 이내의, 바람직하게는 실제적으로 0의 방향족 함량을 가짐을 특징으로 하는 조성물.
  16. 블랜드중의 블록공중합체의 경질블록의 유리전이온도 이내의 온도에서 블록공중합체와 부가중합체 또는 공중합체 물질의 블랜드를 익스텐더액체와 혼합함을 특징으로 하는 제1항에 따른 겔 조성물의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880700309A 1986-07-18 1987-07-17 블록 공중합체를 포함하는 겔 KR960006797B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB868617559A GB8617559D0 (en) 1986-07-18 1986-07-18 Gels
GB86175599 1986-07-18
GB8617550 1986-07-18
PCT/GB1987/000506 WO1988000603A2 (en) 1986-07-18 1987-07-17 Gels comprising block copolymers

Publications (2)

Publication Number Publication Date
KR880701758A true KR880701758A (ko) 1988-11-05
KR960006797B1 KR960006797B1 (ko) 1996-05-23

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KR1019880700309A KR960006797B1 (ko) 1986-07-18 1987-07-17 블록 공중합체를 포함하는 겔

Country Status (12)

Country Link
EP (1) EP0426658B1 (ko)
JP (1) JP2716711B2 (ko)
KR (1) KR960006797B1 (ko)
AT (1) ATE145230T1 (ko)
AU (1) AU604490B2 (ko)
BR (1) BR8707747A (ko)
CA (1) CA1317047C (ko)
DE (1) DE3751952T2 (ko)
DK (1) DK146088D0 (ko)
FI (1) FI890273A0 (ko)
GB (1) GB8617559D0 (ko)
WO (1) WO1988000603A2 (ko)

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DE3751952T2 (de) 1997-06-05
DE3751952D1 (de) 1996-12-19
KR960006797B1 (ko) 1996-05-23
JP2716711B2 (ja) 1998-02-18
GB8617559D0 (en) 1986-08-28
DK146088A (da) 1988-03-17
WO1988000603A3 (en) 1988-03-24
AU604490B2 (en) 1990-12-20
BR8707747A (pt) 1989-08-15
WO1988000603A2 (en) 1988-01-28
AU7693787A (en) 1988-02-10
CA1317047C (en) 1993-04-27
FI890273A (fi) 1989-01-18
EP0426658B1 (en) 1996-11-13
EP0426658A1 (en) 1991-05-15
JPH02502023A (ja) 1990-07-05
DK146088D0 (da) 1988-03-17
FI890273A0 (fi) 1989-01-18
ATE145230T1 (de) 1996-11-15

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