KR880002786A - 비닐포스포닉 디클로라이드의 제조방법 - Google Patents
비닐포스포닉 디클로라이드의 제조방법 Download PDFInfo
- Publication number
- KR880002786A KR880002786A KR870009490A KR870009490A KR880002786A KR 880002786 A KR880002786 A KR 880002786A KR 870009490 A KR870009490 A KR 870009490A KR 870009490 A KR870009490 A KR 870009490A KR 880002786 A KR880002786 A KR 880002786A
- Authority
- KR
- South Korea
- Prior art keywords
- dichloride
- reaction
- carried out
- alkyl
- catalyst
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 7
- MLSZIADXWDYFKM-UHFFFAOYSA-N 1-dichlorophosphorylethene Chemical compound ClP(Cl)(=O)C=C MLSZIADXWDYFKM-UHFFFAOYSA-N 0.000 title claims 3
- 239000003054 catalyst Substances 0.000 claims 4
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 3
- LOUZURPQCYZSJH-UHFFFAOYSA-N 1-chloro-2-dichlorophosphorylethane Chemical compound ClCCP(Cl)(Cl)=O LOUZURPQCYZSJH-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 2
- 238000004821 distillation Methods 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- WUEAMTVQNGYLRI-UHFFFAOYSA-N 2-dichlorophosphoryl-1,3,5-tri(propan-2-yl)benzene Chemical compound CC(C)C1=CC(C(C)C)=C(P(Cl)(Cl)=O)C(C(C)C)=C1 WUEAMTVQNGYLRI-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910001508 alkali metal halide Inorganic materials 0.000 claims 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 150000004714 phosphonium salts Chemical class 0.000 claims 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims 1
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/42—Halides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 트리페닐포스핀 촉매 존재하에서, 2-클로로 에탄포스포닉 디클로라이드로부터 염화수소를 제거하여 비닐포스포닉 디클로라이드를 제조하는 방법에 있어서, 반응을 감압하의 130내지 166℃온도에서 실시하고, 생성된 비닐포스포닉 디클로라이드를 동시에 증류에 의해 제거하는 방법.
- 촉매 존재하에서 2-클로로 에탄포스포닉 디클로라이드로부터 염화수소를 제거하여, 비닐포스포닉 디클로라이드를 제조하는 방법에 있어서, 다음 물질의 적어도 1개를 함유하는 촉매의 존재하에서 반응을 실시하고, 생성된 비닐포스포닉 디클로라이드를 동시에 또는 후에 증류에 의해 제거하는 방법 :a) 다음 일반식의 3급. 포스핀(상기식에서, R1,R2및 R3은 같거나 서로 다르며, 임의로 C1내지 C4알콕시기, C1내지 C4알킬티오기 또는 C1내지 C4디알킬아미노기에 의해 치환된 직쇄 또는 측쇄의 C1내지 C10알킬, 또는 수소 C1내지 C4알킬기 또는 C1내지 C4알콕시기에 의해 치환된 페닐이다.)b) 다음 일반식의 4급 암모늄염 또는 포스포늄염(상기식에서, Z은 N또는 P이고, Y-는 R1,R2및 R3이 상기 a)항에서 같은 의미를 갖을 경우 강산의 음이온이며, R4는 직쇄 또는 측쇄의 C1내지 C10알킬 또는 수소, C1내지 C4알킬기 또는 C1내지 C4알콕시기에 의해 치환된 벤질이다.)c) 알칼리 금속 또는 알칼리 토금속 할라이드,
- 제 2항에 있어서, 반응을 130내지 220℃온도에서 실시하는 방법.
- 제 2항에 있어서, 반응을 140내지 190℃온도에서 실시하는 방법.
- 제 2항 내지 4항중 어느 하나에 있어서, 사용되는 촉매가 테트라부틸암모늄 브로마이드, 테트라부틸포스포늄 브로마이드 또는 리튬 브로마이드인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863629577 DE3629577A1 (de) | 1986-08-30 | 1986-08-30 | Verfahren zur herstellung von vinylphosphonsaeuredichlorid |
| DEP3629577.9 | 1986-08-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR880002786A true KR880002786A (ko) | 1988-05-11 |
| KR950002864B1 KR950002864B1 (ko) | 1995-03-27 |
Family
ID=6308572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019870009490A KR950002864B1 (ko) | 1986-08-30 | 1987-08-29 | 비닐포스포닉 디클로라이드의 제조방법 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4761251A (ko) |
| EP (1) | EP0262394B1 (ko) |
| JP (1) | JPS6368592A (ko) |
| KR (1) | KR950002864B1 (ko) |
| CA (1) | CA1311249C (ko) |
| DE (2) | DE3629577A1 (ko) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949238B (zh) * | 2016-05-30 | 2018-09-07 | 淮阴工学院 | 2-氯乙基膦酰二氯气相脱氯化氢合成乙烯基膦酰二氯的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1568945C3 (de) * | 1966-12-23 | 1975-10-09 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung ungesättigter Phosphonsäuredichloride |
| US3950413A (en) * | 1971-10-26 | 1976-04-13 | Hoechst Aktiengesellschaft | Process for the preparation of phosphonic acid dihalides |
| GB8603549D0 (en) * | 1986-02-13 | 1986-03-19 | Vickers Plc | Phosphonic acid derivatives |
-
1986
- 1986-08-30 DE DE19863629577 patent/DE3629577A1/de not_active Withdrawn
-
1987
- 1987-08-26 EP EP87112378A patent/EP0262394B1/de not_active Expired - Lifetime
- 1987-08-26 DE DE8787112378T patent/DE3773319D1/de not_active Expired - Fee Related
- 1987-08-27 US US07/089,964 patent/US4761251A/en not_active Expired - Fee Related
- 1987-08-28 CA CA000545596A patent/CA1311249C/en not_active Expired - Fee Related
- 1987-08-28 JP JP62213198A patent/JPS6368592A/ja active Pending
- 1987-08-29 KR KR1019870009490A patent/KR950002864B1/ko active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP0262394A3 (en) | 1988-07-20 |
| DE3773319D1 (de) | 1991-10-31 |
| EP0262394A2 (de) | 1988-04-06 |
| KR950002864B1 (ko) | 1995-03-27 |
| JPS6368592A (ja) | 1988-03-28 |
| US4761251A (en) | 1988-08-02 |
| DE3629577A1 (de) | 1988-03-03 |
| CA1311249C (en) | 1992-12-08 |
| EP0262394B1 (de) | 1991-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Maynard et al. | Organophosphorus compounds. I. 2-chloroalkylphosphonic acids as phosphorylating agents | |
| ATE41136T1 (de) | Karbonsaeure-, sulfonsaeure- und quaternaere ammoniumgruppen enthaltende polymere fuer die verhuetung von kesselstein und korrosion. | |
| ES8405417A1 (es) | Procedimiento para la produccion de arilfosfinas sulfonadas | |
| ATE1242T1 (de) | Verfahren zur herstellung von 3-amino-1-hydroxypropan-1,1-diphosphonsaeure. | |
| ES2196413T3 (es) | Nuevos derivados fosfino. | |
| KR850001143A (ko) | 올레핀계모노 첨가생성물(Monoadducts of Olefines)과 이와 반응적인 텔로겐(Telogen)의 제조방법 | |
| Mikolajczyk | Optically active trivalent phosphorus acid esters: synthesis, chirality at phosphorus and some transformations | |
| GB1189257A (en) | Process for the Preparation of 1,2-Polybutadiene | |
| Gusarova et al. | Synthesis of organic phosphines and phosphine oxides from elemental phosphorus and phosphine in the presence of strong bases | |
| EP0098034A3 (en) | A process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby | |
| ATE146478T1 (de) | Verfahren zur herstellung von lithium diarylphosphiden und alkyl -derivaten davon- | |
| GB1041938A (en) | Organic phosphine oxide derivatives | |
| KR880002786A (ko) | 비닐포스포닉 디클로라이드의 제조방법 | |
| ATE46515T1 (de) | Phosphonate. | |
| DE3772308D1 (de) | Verfahren zur herstellung von retinoylchloriden. | |
| Kasho et al. | Relationships of inosine triphosphate and bicarbonate effects on F 1 ATPase to the binding change mechanism | |
| ATE248180T1 (de) | Verfahren zur herstellung von phosphonigsäureestern | |
| ATE219086T1 (de) | Verfahren zur herstellung von organozinkreagenzien | |
| KR840001181A (ko) | 유기 3급 폴리포스핀 모노옥시사이드의 제조방법 | |
| ES8504693A1 (es) | Procedimiento para la preparacion de sales organicas de n-fosfonometilglicina | |
| KR880002787A (ko) | 비닐포스폰산 디클로라이드의 제조방법 | |
| KR880002887A (ko) | 2-클로로에탄포스폰산 디클로라이드의 제조방법 | |
| Budnikova et al. | Electrochemical functionalization of white phosphorus | |
| KR880009946A (ko) | 테트라졸 화합물의 제조방법과 중간물질 | |
| Brophy et al. | The cleavage of bisphosphonium salts by sodium hydride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| NORF | Unpaid initial registration fee |