KR880001121B1 - Method for manufacture wire rod of used arc welding - Google Patents

Method for manufacture wire rod of used arc welding Download PDF

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KR880001121B1
KR880001121B1 KR1019840008361A KR840008361A KR880001121B1 KR 880001121 B1 KR880001121 B1 KR 880001121B1 KR 1019840008361 A KR1019840008361 A KR 1019840008361A KR 840008361 A KR840008361 A KR 840008361A KR 880001121 B1 KR880001121 B1 KR 880001121B1
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wire rod
arc welding
less
sec
rolling
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KR860005041A (en
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이충복
강신왕
장경영
유선준
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포항종합제철 주식회사
고준식
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

Processing method of wire rod for CO2 gas sheilded arc welding comprises (i) heating step of a billet to 1200-1250 deg.C, (ii) rolling step of the billet at high speed of 60m/sec or more, (iii) rapid cooling step of the rolled wire rod to 800-850 deg.C, and (iv) coiling step of the wire rod with cooling slowly to 400 deg.C at the cooling rate of 2-3 deg.C/sec. The composition of the billet is 0.10-0.13 wt.% C, 0.70-1.0 wt.% Si, 1.2-1.5 wt.% Mn, up to 0.012 wt.% P, up to 0.025 wt.% S, up to 0.04 wt.% Cr, up to 0.02 wt.% Ni, up to 0.02 wt.% Cu, 0.01-0.02 wt.% Ti and the balance Fe.

Description

제어냉각에 의한 탄산가스 아크용접용 선재의 제조방법Method for manufacturing wire rod for carbon dioxide arc welding by controlled cooling

제1도는 본 발명에 이용한 제어냉각설비의 평면개략도.1 is a schematic plan view of a control cooling system used in the present invention.

본 발명은 냉간가공성이 우수한 탄산가스 아크용접용 선재 제조방법에 관한 것이다.The present invention relates to a method for producing a carbon dioxide arc welding wire rod excellent in cold workability.

탄산가스 아크용접용 선재는 철 또는 강의 용접, 연강 또는 합금원소를 소량 첨가하여 강도를 크게 한 고장력강, 마모부품의 표면을 경한 금속으로 육성하는 표면경화 육성용접의 소재에 사용되어 왔고, 이 용접에 사용되는 용접선은 0.9-1.6㎜ψ로서 성품화되기 때문에 이의 소재인 탄산가스 아크용접용 선재는 우수한 냉간가공성이 요구되어 왔다. 그러나, 탄산가스 아크용접용 선재는 일반 저탄소강으로 망간(Mn)과 규소(Si)함량이 높아 불순원소들을 규제하고 압연조건과 냉간온도를 관리하여도 저탄소 마르템사이드(Low Carbon Martensite)가 다량 포함된 훼라이트(Ferrite)조직이 형성되어 냉간가공시 이들 조직은 서로 다른 상으로 작용하여 저탄소 마르텐사이트 주위에는 응력집중점이 되어 단선발생의 요인이 되기 때문에 종래에는 통상 중간신선을 하고 소둔등의 열처리를 실시한 후 최종 신선을 하여 성품화하고 있다. 이 때문에 제조원가를 증가시킬뿐만 아니라 용접후에는 용착금속의 결정립조대화에 의해 인성을 악화시키고 있다. 따라서, 본 발명은 이러한 문제점을 해결하기 위해 일반 탄산가스 아크용접용 강재에 티타늄(Ti)를 소량 첨가시켜 탄. 질화물을 오스테나이트(Austenite)결정입계에 석출시켜 결정립성장을 억제하고 결정립 미세화에 의한 훼라이트(Ferrite)생성위치를 증가시키기 위한 제어냉각법으로 행한 탄산가스 아크용접용 선재방법으로서 특히 연강과 50 및 60㎎/㎟ 급 고정력강의 탄산가스 아크용접에 사용된다.Carbon dioxide arc welding wire has been used in the welding of iron or steel, high strength steel with high strength by adding a small amount of mild steel or alloying elements, and the surface hardening welding material that grows the surface of wear parts with hard metal. Since the welding wire used is characterized by 0.9-1.6 mm ψ, the carbon dioxide arc welding wire which is its material has been required to have excellent cold workability. However, carbon dioxide arc welding wire is a low carbon steel, which is high in manganese (Mn) and silicon (Si), and has a high amount of low carbon martensite even though it regulates impurities and controls rolling conditions and cold temperatures. In the case of embedded ferrite structure, these structures act as different phases during cold working and become stress concentration points around low-carbon martensite, causing disconnection. After the finalization, the final freshness is used for characterization. For this reason, not only increases the manufacturing cost but also deteriorates the toughness by coarsening of the weld metal after welding. Therefore, the present invention burnt by adding a small amount of titanium (Ti) to the carbon dioxide arc welding steel to solve this problem. Carbon dioxide arc welding wire rod method for carbon dioxide arc arc welding, which is performed by controlled cooling to precipitate nitride at austenite grain boundary to suppress grain growth and increase ferrite formation position by grain refinement. It is used for arc welding of carbon dioxide gas of MG / mm2 fixed steel.

본 발명의 구성을 좀더 구체적으로 설명하면 다음과 같다. 본 발명은 탄소 : 0.10-0.13%, 규소 : 0.70-1.0%, 망간 : 1.2-1.5%, 인 : 0.012%이하, 황 : 0.025이하, 크롬 : 0.04%이하, 니켈 : 0.02%이하, 구리 : 0.02%이하, 티타늄 : 0.10-0.02%를 함유한 빌레트(Billet)를 1200-1250℃로 가열한후 60m/sec 이상으로 고속압연을 한후 압연된 제품을 800-850℃의 범위내로 물분사에 의해 급속냉각하여 권취하고 400℃까지 2-3℃/sec의 냉각속도로 서냉하는 것을 특징으로 한다.The configuration of the present invention in more detail as follows. In the present invention, carbon: 0.10-0.13%, silicon: 0.70-1.0%, manganese: 1.2-1.5%, phosphorus: 0.012% or less, sulfur: 0.025 or less, chromium: 0.04% or less, nickel: 0.02% or less, copper: 0.02 % Or less, Titanium: Billet containing 0.10-0.02% is heated to 1200-1250 ℃, high-speed rolling over 60m / sec, and then the rolled product is rapidly sprayed by water spray within the range of 800-850 ℃. Cooling and winding up to 400 ℃ characterized in that the slow cooling at 2-3 ℃ / sec cooling rate.

이하 본 발명에 대하여 상세히 설명하기로 한다. 먼저, 본 발명의 성분범위에 대하여 설명하면 다음과 같다. 탄소는 강도를 증가시키나 연성및 인성을 저하시키고 특히 용접성을 저하시키기 때문에 상한성을 0.13%로 하였다. 규소는 강도증가를 위해 필요하고 많은 경우에는 연성을 저하시키지만 본 용접시 보호가스인 탄산가스의 고온아크중 분해된 일산화탄소에 의한 기포방생방지와 적합한 탈산반응을 할 수 있도록 상한선을 1.0%로 하였다. 망간은 강도 및 인성의 확보뿐만 아니라 경화능을 좋게 하지만 특히 용접성을 상실시키는 탄소량을 규제한 만틈 용접후의 용착금속의 강도보증을 위해 상한선을 1.5%로 하였다. 인은 인성을 저하시키고 냉간가공에 영향을 주므로 0.012%이하로 규제하였다. 한편, Cu는 용접성을 저하시키므로 0.02%이하로 규제하고 Cr는 용착금속의 기계적 성질향상을 위해 경화능이 큰 Cr을 미량인 0.04%이하로 첨가하였으며, Ni은 0.02%이하로 첨가하여 용체경화(solution hardening)를 꾀하였다. 티타늄은 고온가열시 오스테나이트 입계로 석출된 티타늄 질화물(TiN)에 의하여 결정입성장을 억제하고 압연후 냉각시에는 미세한 훼라이트조직의 생성을 촉진시켜 강도 및 인 성을 양호하게 한다. 특히 본 용접시에는 TiC, TiN등의 탄질화물에 의하여 결정립 미세화는 물론 열영향부까지도 인성을 향상시키고 또한 탄소, 산소, 유황, 질소와의 친화력이 크므로 유화 개재물을 구상화해서 기게적 성질의 이방성을 없애주고 있다. 이러한 목적을 위해 첨가성분 범위를 0.02%미만으로 하였다. 다음은 본 발명의 압연 및 냉각방법에 대하여 설명하기로 한다. 일반적으로 고온에서 압연을 실시하면 압연온도 및 속도변형량등의 조건에 따라 재결정이 발생한다.Hereinafter, the present invention will be described in detail. First, the component range of the present invention will be described. Carbon increased the strength but lowered the ductility and toughness, and in particular the weldability, so the upper limit was made 0.13%. Silicon is needed to increase strength and in many cases ductility is reduced, but the upper limit is 1.0% to prevent bubble generation by carbon monoxide decomposed in high-temperature arc of carbon dioxide gas, which is a protective gas during welding, and to perform proper deoxidation reaction. Manganese not only secures strength and toughness, but also improves hardenability, but the upper limit is 1.5% to ensure the strength of the weld metal after intermetallic welding, which regulates the amount of carbon that loses weldability. Phosphorus is regulated below 0.012% because it lowers toughness and affects cold working. On the other hand, Cu reduces the weldability, so it is regulated to 0.02% or less, and Cr is added to a small amount of Cr less than 0.04% to improve the mechanical properties of the weld metal, and Ni is added to 0.02% or less. hardening). Titanium suppresses grain growth by titanium nitride (TiN) precipitated at the austenite grain boundary during high temperature heating, and promotes the formation of fine ferrite structure during cooling after rolling to improve strength and toughness. In particular, during welding, the toughness of grains as well as heat affected zones are improved by carbonitrides such as TiC and TiN, and the affinity with carbon, oxygen, sulfur, and nitrogen is large. Is getting rid of. For this purpose, the additive component range was less than 0.02%. Next, a rolling and cooling method of the present invention will be described. In general, when rolling at a high temperature, recrystallization occurs depending on conditions such as rolling temperature and speed deformation.

본 발명은 이와 같은 재결정을 촉진코져 1200-1250℃로 가열된 상기한 조성의 빌레트를 60m/sec이상의 압연속도로서 고속압연을 실시한다. 한편 압연시 압연온도를 높혀 변형량을 증가시키면 재결정화가 용이하므로 가능한 결정립 미세화를 유지할 수 있도록 본 발명은 압연시에 발생하는 압연열을 이용하는 것으로서, 압연속도 60m/sec이상의 고속압연에 의해 최종 사상 압연스탠드에서 압연재의 온도가 고온 오스테나이트 단상구역인 1100-1150℃를 유지할 수 있다.The present invention accelerates such recrystallization and performs high-speed rolling of the billet of the above composition heated to 1200-1250 ° C. at a rolling speed of 60 m / sec or more. On the other hand, when the rolling temperature is increased during rolling to increase the amount of deformation, it is easy to recrystallize, so that the present invention utilizes the heat of rolling generated during rolling, so that the final finishing stand by high-speed rolling at a rolling speed of 60 m / sec or more. The temperature of the rolled material can be maintained at 1100-1150 ° C which is a high temperature austenite single phase zone.

이와 같이 하여 압연된 압연재는 오스테나이트의 결정립성장을 억제하고저 물분사에 의해 800-850℃까지 급속냉각을 실시한다. 이 온도범위는 오스테나이트 단상구역으로 오스테나이트 결정립을 가장 미세하게 유지시킬 수 있다. 한편, 급속냉각된 압연재는 코일형태로 권취한 후, 연속적으로 움직이는 콘베어(Conveyer)상에서 과냉조직인 베어나이트(Bainite)나 마르텐사이트 생성을 억제할 수 있는 냉각속도인 2-3℃/sec로 400℃부근까지 서냉한다.The rolled material thus rolled suppresses grain growth of austenite and is rapidly cooled to 800-850 ° C. by low water spray. This temperature range is the austenite single phase zone, which allows the most austenitic grains to be retained. On the other hand, the cold-cooled rolled material is wound in a coil form, and then 400 ° C. at 2-3 ° C./sec, which is a cooling rate capable of suppressing formation of bareite or martensite, which is a supercooled structure, on a continuously moving conveyor. Cool slowly to the vicinity.

제1도는 본 발명을 실시하는데 적합한 장치의 평면개략도로서, 1은 가열로, 2는 수평식 공형압연스탠드(스탠드 25개), 3은 수냉각구역, 4는 권취기, 5는 콘베어(Conveyer)이다.1 is a schematic plan view of a device suitable for carrying out the present invention, where 1 is a heating furnace, 2 is a horizontal ball rolling stand (25 stands), 3 is a water cooling zone, 4 is a winder, and 5 is a conveyor. to be.

이상과 같은 본 발명의 방법에 의해 제조된 탄산가스 아크용 선재는 훼라이트가 주조직으로 펄라이트(Pearlite)와 저탄소 마르텐사이트가 다소 포함되어 있지만 냉간시선은 0.9㎜ψ 미만까지 가능하였다.In the carbon dioxide arc wire produced by the method of the present invention as described above, the ferrite is mainly composed of pearlite (Pearlite) and low-carbon martensite as the main structure, but the cold line was possible to less than 0.9㎜ψ.

표 1은 본 발명의 방법으로 제조된 탄산가스 아크용접용 선재의 조성을 나타낸 것이고 각 조성의 제품의 특성은 표2와 같다.Table 1 shows the composition of the carbon dioxide arc welding wire produced by the method of the present invention and the characteristics of the product of each composition are shown in Table 2.

[표 1]TABLE 1

Figure kpo00001
Figure kpo00001

[표 2]TABLE 2

Figure kpo00002
Figure kpo00002

Claims (1)

탄소 : 0.10-0.13%, 규소 : 0.70-1.0%, 망간 : 1.2-1.5%, 인 : 0.012%이하, 황 : 0.025이하, 크롬 : 0.04%이하, 니켈 : 0.02%이하, 구리 : 0.02%이하, 티타늄 : 0.10-0.02%를 함유한 빌베트를 1200-1250℃로 가열한후 60m/sec 이상으로 고속압연을 한후 압연된 제품을 800-850℃의 범위내로 급속냉각하여 권취하고 400℃까지 2-3℃/sec의 냉각속도로 서냉하는 것을 특징으로 하는 탄산가스 아크용접용 선재의 제조방법.Carbon: 0.10-0.13%, Silicon: 0.70-1.0%, Manganese: 1.2-1.5%, Phosphorus: 0.012% or less, Sulfur: 0.025 or less, Chromium: 0.04% or less, Nickel: 0.02% or less, Copper: 0.02% or less, Titanium: Bilvet containing 0.10-0.02% is heated to 1200-1250 ℃, high-speed rolling at 60m / sec or more, and then the rolled product is rapidly cooled in the range of 800-850 ℃ and wound up to 400 ℃. A method for producing a carbon dioxide arc welding wire rod, characterized by slow cooling at a cooling rate of 3 ° C / sec.
KR1019840008361A 1984-12-26 1984-12-26 Method for manufacture wire rod of used arc welding KR880001121B1 (en)

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