KR870000414A - Lubricant Compositions for Spraying - Google Patents

Lubricant Compositions for Spraying Download PDF

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KR870000414A
KR870000414A KR1019860004938A KR860004938A KR870000414A KR 870000414 A KR870000414 A KR 870000414A KR 1019860004938 A KR1019860004938 A KR 1019860004938A KR 860004938 A KR860004938 A KR 860004938A KR 870000414 A KR870000414 A KR 870000414A
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ester
derived
lubricant composition
polyisobutylene
acid
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KR1019860004938A
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KR940005550B1 (en
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알. 제흘러 오이진
제이. 플레이크 클라크
제이. 바이메쉬 부루스
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내셔날 디스틸러스 앤드 케미칼 코포레이션
로버트 티. 베츠
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Priority claimed from US06/747,462 external-priority patent/US4601840A/en
Priority claimed from US06/747,463 external-priority patent/US4589990A/en
Application filed by 내셔날 디스틸러스 앤드 케미칼 코포레이션, 로버트 티. 베츠 filed Critical 내셔날 디스틸러스 앤드 케미칼 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

내용 없음No content

Description

분무용 윤활제 조성물Lubricant Compositions for Spraying

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

(1) (a) 2 내지 8개의 하이드록실 그룹 및 3 내지 12개의 탄소원자를 함유하는 지방족 폴리올 및 지방족 모노카복실산 또는 5 내지 20개의 탄소원자를 갖는 지방족 모노카복실산들의 혼합물로부터 유도된 폴리올 에스테르 :(1) (a) a polyol ester derived from a mixture of aliphatic polyols containing 2 to 8 hydroxyl groups and 3 to 12 carbon atoms and aliphatic monocarboxylic acids or aliphatic monocarboxylic acids having 5 to 20 carbon atoms: (b) 트리멜리트산 또는 트리멜리트산 무수물 및 5 내지 16개의 탄소원자를 갖는 지방족 알코올로부터 유도된 트리멜리테이트 에스테르; 및(b) trimellitate esters derived from trimellitic acid or trimellitic anhydride and aliphatic alcohols having from 5 to 16 carbon atoms; And (c) 75% 또는 그 이사의 C362량체 산을 함유하는 고분자 지방산 및 C2-131작용성 알코올로부터 유도된 고분자 지방산 에스테르로 이루어진 그룹중에서 선택된, 40℃에서 15 내지 300 센티스토우크의 점도를 갖는 합성 에스테르 45 내지 95중량부 :(c) 15 to 300 centistokes at 40 ° C. selected from the group consisting of polymeric fatty acids containing 75% or its C 36 dimeric acids and polymeric fatty acid esters derived from C 2-13 monofunctional alcohols. 45 to 95 parts by weight of synthetic ester having a viscosity: (2) 100%의 중합체 기준으로, 4,000 내지 10,000의 평균 분자량을 갖는 폴리이소부틸렌 8 내지 40 중량부 : 및(2) 8 to 40 parts by weight of polyisobutylene having an average molecular weight of 4,000 to 10,000, based on 100% of polymer: and (3) 100%의 중합체 기준으로, 25,000 내지 300,000의 평균 분자량을 갖는 폴리이소부틸렌 0.1 내지 1 중량부로 이루어지며, 40℃에서 125내지 750 센티스토우크의 점도를 갖는 분무용 윤활제 조성물.(3) A lubricant lubricant composition for spraying, comprising 0.1 to 1 parts by weight of polyisobutylene having an average molecular weight of 25,000 to 300,000, based on 100% polymer, and having a viscosity of 125 to 750 centistoke at 40 ° C. 제1항에 있어서, 폴리올 에스테르 (a)가 5 내지 8개의 탄소원자 및 2 내지 4개의 하이드록실 그룹을 함유하며 15미만의 산가 및 100미만의 하이드록실가를 갖는 지방족 폴리올로부터 유도되며 : 트리멜리테이트 에스테르(b)가 15미만의 산가 및 10미만의 하이드록실가를 가지며 : 고분자 지방산 에스테르 (c)가 100미만의 산가 및 10미만의 하이드록실가를 갖는 윤활제 조성물.The polyol ester (a) according to claim 1 is derived from an aliphatic polyol containing 5 to 8 carbon atoms and 2 to 4 hydroxyl groups and having an acid value of less than 15 and a hydroxyl value of less than 100: trimelli The tate ester (b) has an acid value of less than 15 and a hydroxyl value of less than 10: The lubricant composition in which the high molecular weight fatty acid ester (c) has an acid value of less than 100 and a hydroxyl value of less than 10. 제1항 또는 제2항에 있어서, 폴리이소부틸렌 (2)가 4,500 내지 8,500의 평균-분자량을 가지며, 폴리이소부틸렌(3)이 50,000 내지 200,000의 평균 분자량을 갖는 윤활제 조성물.The lubricant composition according to claim 1 or 2, wherein the polyisobutylene (2) has an average-molecular weight of 4,500 to 8,500, and the polyisobutylene (3) has an average molecular weight of 50,000 to 200,000. 제1항, 제2항 또는 제3항에 있어서, 175 내지 550 센티스토우크의 점도를 가지며, 55 내지 85부의 합성 에스테르 (1), 12 내지 30부의 폴리이소부틸렌(2) 및 0.25 내지 0.85부의 폴리이소부틸렌(3)을 함유하는 윤활제 조성물.4. A synthetic ester according to claim 1, 2 or 3, having a viscosity of 175 to 550 centistokes, 55 to 85 parts synthetic ester (1), 12 to 30 parts polyisobutylene (2) and 0.25 to 0.85 Lubricant composition containing negative polyisobutylene (3). 제1항, 제2항, 제3항 또는 제4항에 있어서, 폴리올에스테르 (a)가 네오펜틸 글리콜, 2,2-디메틸-3-하이드록시프로필-2,2-디메틸-3-하이드록시 프로피오네이트, 2,2,4-트리메틸-1,5-펜탄디올, 트리메틸올에탄, 트리메틸올프로판, 글리세롤, 펜타에리트리톨, 디펜타에리트리톨, 및 트리펜타에리트리톨로 이루어진 그룹중에서 선택된 폴리올 및 C12-18지방족 모노카복실산 또는 산혼합물로 부터 유도되며 : 트리멜리테이트 에스테르 (b)가 트리멜리트산 또는 트리멜리트산 무수물 및 C10-13지방족 알코올 또는 알코올 혼합물로 부터 유도되고 : 고분자 지방산 에스테르 (c)가 85% 이상의 C362량체 산을 함유하는 고분자 지방산 및 C8-10지방족 모노-알코올 또는 모노알코올 혼합물로부터 유도되는 윤활제 조성물.The polyol ester (a) according to claim 1, 2, 3 or 4, wherein the polyol ester (a) is neopentyl glycol, 2,2-dimethyl-3-hydroxypropyl-2,2-dimethyl-3-hydroxy Polyols selected from the group consisting of propionate, 2,2,4-trimethyl-1,5-pentanediol, trimethylolethane, trimethylolpropane, glycerol, pentaerythritol, dipentaerythritol, and tripentaerythritol and Derived from C 12-18 aliphatic monocarboxylic acids or acid mixtures: trimellitate esters (b) are derived from trimellitic acid or trimellitic anhydride and C 10-13 aliphatic alcohols or alcohol mixtures: polymeric fatty acid esters ( A lubricant composition in which c) is derived from a polymeric fatty acid containing at least 85% C 36 dimer acid and a C 8-10 aliphatic mono-alcohol or monoalcohol mixture. 제1항, 제2항, 제3항 또는 제4항에 있어서, 폴리올에스테르 (a)가 트리메틸올프로판 트리올리에이트 또는 트리메틸올프로판 트리이소스 테아레이트이며 : 트리멜리테이트 에스테르 (b)가 이소데실 트리멜리테이트, 이소트리데실 트리멜리테이트 또는 이소데실/이소트리데실 트리멜리테이트이고 : 고분자 지방산 에스테르 (c)가 디이소데실/다이머레이트 또는 디-2-에틸헥실 다이머레이트인 윤활제 조성물.The polyol ester (a) is trimethylolpropane trioleate or trimethylolpropane triisostearate, wherein the trimellitate ester (b) is isodecyl. Trimellitate, isotridecyl trimellitate or isodecyl / isotridecyl trimellitate: a lubricant composition wherein the polymeric fatty acid ester (c) is diisodecyl / dimerate or di-2-ethylhexyl dimerate. 제1항 내지 제6항중 어느 하나에 있어서, 8중량부 이하의 첨가제를 추가함유하는 윤활제 조성물.The lubricant composition according to any one of claims 1 to 6, further comprising up to 8 parts by weight of an additive. 제1항 내지 제7항중 어느 하나의 조성물의 연무를 약 10 내지 100psig의 압력하에 공기중에서 생성시키고, 이를 미끄럽게 할 금속 표면에 압축공기에 의해 운반하고 보다 큰 소적으로 결합시키고 상기 금속 표면에 침적시켜 금속 표면상에 윤활용 필름을 형성시키는 윤활방법.A mist of the composition of any one of claims 1 to 7 is produced in air under a pressure of about 10 to 100 psig, carried by compressed air to a metal surface to be slipped and bonded into larger droplets and deposited on the metal surface. To form a lubricating film on the metal surface. 제8항에 있어서, 기온이 125˚내지 200℉이며 기압이 20 내지 80psig인 방법.The method of claim 8 wherein the temperature is between 125 ° F. and 200 ° F. and the air pressure is between 20 and 80 psig. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860004938A 1985-06-21 1986-06-20 Improved mist lubricant compositions KR940005550B1 (en)

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US747,462 1985-06-21
US06/747,462 US4601840A (en) 1985-06-21 1985-06-21 Mist lubrication process
US747462 1985-06-21
US747,463 1985-06-21
US06/747,463 US4589990A (en) 1985-06-21 1985-06-21 Mist lubricant compositions
US747643 2000-12-22

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JP4933165B2 (en) * 2006-06-23 2012-05-16 住友軽金属工業株式会社 Drawing lubricating oil for flux-cored wire for aluminum brazing, and method for drawing flux-cored wire for aluminum brazing using the same
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