KR860006535A - Metal-Processing Liquid Composition - Google Patents

Metal-Processing Liquid Composition Download PDF

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KR860006535A
KR860006535A KR1019860000705A KR860000705A KR860006535A KR 860006535 A KR860006535 A KR 860006535A KR 1019860000705 A KR1019860000705 A KR 1019860000705A KR 860000705 A KR860000705 A KR 860000705A KR 860006535 A KR860006535 A KR 860006535A
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composition
acid
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polymeric
amine
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할페른 유발
할페론 외 1 유발
체르니 리
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지이케미칼즈, 인코포레이티드
케이트 디. 슐쯔
보그-워너 케미컬스, 인코포레이티드
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Abstract

내용 없음No content

Description

금속－가공액 조성물Metal Processing Fluid Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (26)

일반식(Ⅰ)의 비교적 고분자 알콕실화아민 ; 총 6개 이하의 알콕시단위를 함유하는 일반식(Ⅱ)의 알칼올아민; 및 유기산, 무기산 및 그들의 염으로 이루어진 그룹중에서 선택한 산－유도 화합물로 이루어진 수용성 금속－가공조성물.Relatively high molecular alkoxylated amines of the general formula (I); Alkalolamines of formula (II) containing up to six alkoxy units in total; And an acid-derived compound selected from the group consisting of organic acids, inorganic acids and salts thereof. 상기식에서,In the above formula, R1은 수소, 하이드로카빌 잔기, 알콕시잔기 및 폴리알콕시잔기로 이루어진 그룹중에서 선택하고;R 1 is selected from the group consisting of hydrogen, hydrocarbyl residues, alkoxy residues and polyalkoxy residues; R2는 C7이상의 하이드로카빌잔기로 이루어진 그룹중에서 선택하며;R 2 is selected from the group consisting of C 7 or more hydrocarbyl residues; R3는 알콕시잔기 및 폴리알콕시 잔기로 이루어진 그룹중에서 선택하고;R 3 is selected from the group consisting of alkoxy residues and polyalkoxy residues; R4는 ⅰ) 수소, ⅱ) C1내지 C6하이드로카빌 잔기 및 ⅲ) 에톡시, 2－프로폭시, 2－부톡시 및 그들의 혼합기로 이루어진 그룹중에서 선택한 알콕시 단위로 주로 이루어진 모노머성 및 폴리머성 알콕시 잔기로 이루어진 그룹중에서 선택하며;R 4 is monomeric and polymeric mainly consisting of alkoxy units selected from the group consisting of iii) hydrogen, ii) C 1 to C 6 hydrocarbyl residues and iii) ethoxy, 2-propoxy, 2-butoxy and mixtures thereof Selected from the group consisting of alkoxy moieties; R5는 ⅰ) C1내지 C6하이드로카빌 잔기 및 ⅱ) 에톡시, 2－프로폭시, 2－부톡시 및 그들의 혼합기로 이루어진 그룹중에서 선택한 알콕시 단위로 주로 이루어진 모노머성 및 폴리머성 알콕시 잔기로 이루어진 그룹중에서 선택하고;R 5 consists of monomeric and polymeric alkoxy moieties mainly consisting of alkoxy units selected from the group consisting of iii) C 1 to C 6 hydrocarbyl residues and ii) ethoxy, 2-propoxy, 2-butoxy and mixtures thereof. Select from a group; R6는 에톡시, 2-프로폭시, 2－부톡시 및 그들의 혼합기로 이루어진 그룹중에서 선택한 알콕시 단위로 주로 이루어진 모노머성 및 폴리머성 알콕시 잔기로 이루어진 그룹중에서 선택한다.R 6 is selected from the group consisting of monomeric and polymeric alkoxy moieties mainly consisting of alkoxy units selected from the group consisting of ethoxy, 2-propoxy, 2-butoxy and their mixtures. 제 1 항에 있어서,The method of claim 1, R1및 R3를 다음일반식의 알콕시단위 또는 그의 혼합기로 주로 이루어진 모노머성 및 폴리머성 알콕시잔기로 이루어진 그룹중에서 서로 독립적으로 선택하는데,R 1 and R 3 are independently selected from the group consisting of monomeric and polymeric alkoxy residues composed mainly of alkoxy units or mixtures thereof of the following general formula, R1및 R3를 상기 고분자 알콕실화아민중 알콕시 단위의 총수가 2내지 약 35가 되도록 선택하는 조성물.Wherein R 1 and R 3 are selected such that the total number of alkoxy units in the polymeric alkoxylated amine is from 2 to about 35. 상기식에서,In the above formula, R7은 수소 및 C1내지 C28하이드로카빌 잔기로 이루어진 그룹중에서 선택한다.R 7 is selected from the group consisting of hydrogen and C 1 to C 28 hydrocarbyl residues. 제 2 항에 있어서, 상기 고분자 알콕실화 아민중 알콕시 단위의 총수가 5내지 약 20인 조성물.3. The composition of claim 2, wherein the total number of alkoxy units in the polymeric alkoxylated amine is from 5 to about 20. 제 2 항에 있어서, R7이 수소 또는 메틸인 조성물.The composition of claim 2, wherein R 7 is hydrogen or methyl. 제 1 항에 있어서, R2를 약 C12내지 약 C20하이드로카빌 잔기로 이루어진 그룹중에서 선택하는 조성물.The composition of claim 1, wherein R 2 is selected from the group consisting of about C 12 to about C 20 hydrocarbyl residues. 제 5 항에 있어서, R2를 스테아릴, 올레일, 코코(coco), 소야(soya) 및 탤로우(tallow)로 이루어진 그룹중에서 선택하는 조성물.6. The composition of claim 5, wherein R 2 is selected from the group consisting of stearyl, oleyl, coco, soya and tallow. 제 1 항에 있어서, R5를 메틸, 하이드록시에틸 및 하이드록시프로필 잔기로 이루어진 그룹중에서 선택하고, R4를 R5와 동일한 그룹중에서 R5와 독립적으로 선택하고 또한 R4가 수소를 나타내기도 하는 조성물.According to claim 1, selected from the group consisting of R 5 as methyl, hydroxyethyl and hydroxypropyl residues, choose the R 4 to R 5 and independently from the same group as R 5 and also R 4 a represents hydrogen prayer Composition. 제 7 항에 있어서, R6가 하이드록시 에틸인 조성물.8. The composition of claim 7, wherein R 6 is hydroxy ethyl. 제 1 항에 있어서, 상기 산－유도 화합물을 H3PO4, H2SO4및 HNO3로 이루어진 그룹중에서 선택하는 조성물.The composition of claim 1 wherein said acid-derived compound is selected from the group consisting of H 3 PO 4 , H 2 SO 4 and HNO 3 . 제 1 항에 있어서, 산－유도 화합물이 아세트산, 포름산, 프로피온산, 옥살산, 석신산, 글루타르산, 아디프산, 피멜산, 벤조산, 수베르산, 아젤라산, 파라톨루엔 설픈산, 세박산 및 아미노 산으로 이루어진 그룹중에서 선택한 유기산인 조성물.The acid-derived compound according to claim 1, wherein the acid-derived compound is acetic acid, formic acid, propionic acid, oxalic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, benzoic acid, suveric acid, azelaic acid, paratoluene sulfonic acid, sebacic acid and The composition is an organic acid selected from the group consisting of amino acids. 제 1 항에 있어서, 산－유도 화합물이 Ⅷ족 금속, 알칼리금속, 알칼리로금속, 질산염, 황산염, 인산염 및 아민염으로 이루어진 그룹중에서 선택한 염인 조성물.The composition of claim 1 wherein the acid-derived compound is a salt selected from the group consisting of Group VIII metals, alkali metals, alkali metals, nitrates, sulfates, phosphates and amine salts. 제 1 항에 있어서, 고분자 알콕실화 아민에 대한 알칸올 아민의 중량비가 약 20:1 내지 약 0.05:1인 조성물.The composition of claim 1 wherein the weight ratio of alkanol amine to polymeric alkoxylated amine is from about 20: 1 to about 0.05: 1. 제12항에 있어서, 고분자 알콕실화 아민에 대한 알칸올 아민의 중량비가 약 10:1 내지 약 0.1:1인 조성물.The composition of claim 12, wherein the weight ratio of alkanol amine to polymeric alkoxylated amine is about 10: 1 to about 0.1: 1. 제13항에 있어서, 고분자 알콕실화 아민에 대한 알칸올 아민의 중량비가 약 7:1 내지 약 0.5:1인 조성물.The composition of claim 13, wherein the weight ratio of alkanol amine to polymeric alkoxylated amine is about 7: 1 to about 0.5: 1. 제12항에 있어서, 고분자 알콕실화 아민에 대한 산－유도 화합물의 중량비가 약 3:1 내지 약 0.01:1인 조성물.The composition of claim 12 wherein the weight ratio of acid-derived compound to polymeric alkoxylated amine is from about 3: 1 to about 0.01: 1. 제15항에 있어서, 고분자 알콕실화 아민에 대한 산－유도 화합물의 중량비가 약 1.5:1 내지 약 0.1:1인 조성물.The composition of claim 15 wherein the weight ratio of acid-derived compound to polymeric alkoxylated amine is from about 1.5: 1 to about 0.1: 1. 제 1 항에 있어서, 상기 조성물이 수용액인 조성물.The composition of claim 1, wherein said composition is an aqueous solution. 제17항에 있어서, 상기 고분자 알콕실화 아민, 알칸올 아민 및 산－유도 화합물이 함께 상기 용액의 약 0.1 내지 15중량%를 구성하는 조성물.18. The composition of claim 17, wherein said polymeric alkoxylated amine, alkanol amine, and acid-derived compound together constitute about 0.1-15% by weight of the solution. 제18항에 있어서, 상기 고분자 알콕실화 아민, 알칸올 아민 및 산－유도 화합물이 함께 상기 용액의 약 0.5 내지 10중량%를 구성하는 조성물.19. The composition of claim 18, wherein said polymeric alkoxylated amine, alkanol amine and acid-derived compound together constitute about 0.5 to 10 weight percent of said solution. 제 1 항에 있어서, 상기 조성물의 pH가 약 7.5 내지 약 10.5인 조성물.The composition of claim 1 wherein the pH of the composition is from about 7.5 to about 10.5. 제20항에 있어서, 상기 조성물의 pH가 약 8내지 약 9.5인 조성물.The composition of claim 20 wherein the pH of the composition is between about 8 and about 9.5. (a) 일반식(Ⅰ)의 비교적 고분자 알콕실화 아민, (b) 트리에탄올 아민, 디에탄올 아민, N－메틸－에탄올아민 및 그들의 혼합물로 이루어진 그룹중에서 선택한 알칸올 아민 및 (c) 유기산, 무기산 및 그들의 염으로 이루어진 그룹중에서 선택한 산－유도 화합물로 이루어졌으며 ; 약 7.5 내지 약 10.5의 pH를 갖고, 상기 고분자 알콕실화 아민에 대한 알칸올 아민의 중량비가 약 10:1 내지 약 0.1:1이고, 상기 고분자 알콕실화 아민에 대한 산 유도 화합물의 중량비가 약 3:1 내지 약 0.01:1인 금속－가공 조성물.(a) an alkanol amine selected from the group consisting of relatively high molecular alkoxylated amines of general formula (I), (b) triethanol amines, diethanol amines, N-methyl-ethanolamines and mixtures thereof; and (c) organic acids, inorganic acids and Consisting of acid-derived compounds selected from the group consisting of their salts; Has a pH of about 7.5 to about 10.5, a weight ratio of alkanol amine to the polymeric alkoxylated amine is about 10: 1 to about 0.1: 1, and a weight ratio of acid derivative compound to the polymeric alkoxylated amine is about 3: A metal-working composition having from 1 to about 0.01: 1. 상기식에서In the above formula R2는 C12내지 약 C20하이드로카빌 잔기이고;R 2 is a C 12 to about C 20 hydrocarbyl residue; R1및 R3는 일반식(여기에서 R7은 수소 및 C1내지 C23하이드로카빌잔기로 이루어진 그룹중에서 선택한다)의 알콕시 단위 또는 그의 혼합기로 주로 이루어진 모노머성 및 폴리머성 알콕시 잔기로 이루어진 그룹중에서 독립적으로 선택하는데, R1및 R3는 상기 고분자 알콕실화 아민중 알콕시단위의 총수가 2내지 약 35가 되도록 선택한다.R 1 and R 3 are general formula Wherein R 7 is selected from the group consisting of hydrogen and C 1 to C 23 hydrocarbyl residues, independently selected from the group consisting of monomeric and polymeric alkoxy moieties mainly composed of alkoxy units or mixtures thereof, wherein R 1 And R 3 is selected such that the total number of alkoxy units in the polymer alkoxylated amine is from 2 to about 35. 제22항에 있어서, R2를 스테아릴, 올레일, 코코, 소야 및 탤로우로 이루어진 그룹중에서 선택하는 조성물.The composition of claim 22, wherein R 2 is selected from the group consisting of stearyl, oleyl, coco, soya and tallow. 제23항에 있어서, 고분자 알콕실화 아민중 알콕시단위의 총 수가 약 5 내지 약 15인 조성물.The composition of claim 23 wherein the total number of alkoxy units in the polymer alkoxylated amine is from about 5 to about 15. 제22항에 있어서, 알칸올아민을 트리에탄올아민, N－메틸에탄올아민 및 그들의 혼합물중에서 선택하는 조성물.The composition of claim 22, wherein the alkanolamine is selected from triethanolamine, N-methylethanolamine and mixtures thereof. 제22항에 있어서, 상기 조성물이, 고분자 알콕실화 아민, 알칸올아민 및 산－유도 화합물을 0.1 내지 15중량%로 함유하는 수용액인 조성물.The composition according to claim 22, wherein the composition is an aqueous solution containing 0.1 to 15% by weight of a polymer alkoxylated amine, alkanolamine and acid-derived compound. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860000705A 1985-02-04 1986-02-03 Metal working fluid composition KR930007896B1 (en)

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