KR930702466A - Well borhaul drilling method and composition used therein - Google Patents

Well borhaul drilling method and composition used therein

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Publication number
KR930702466A
KR930702466A KR1019930700790A KR930700790A KR930702466A KR 930702466 A KR930702466 A KR 930702466A KR 1019930700790 A KR1019930700790 A KR 1019930700790A KR 930700790 A KR930700790 A KR 930700790A KR 930702466 A KR930702466 A KR 930702466A
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South Korea
Prior art keywords
acylating agent
polyoxyalkylene
reaction product
amine
average
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KR1019930700790A
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Korean (ko)
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다불류 포오스 버어그 존
다불류 잔크 리차드
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조이지 아아르 힐
더 루우브리졸 코오포레이션
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Publication of KR930702466A publication Critical patent/KR930702466A/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02—Well-drilling compositions
    • C09K8/04—Aqueous well-drilling compositions
    • C09K8/14—Clay-containing compositions
    • C09K8/18—Clay-containing compositions characterised by the organic compounds
    • C09K8/22—Synthetic organic compounds
    • E—FIXED CONSTRUCTIONS
    • E21—EARTH DRILLING; MINING
    • E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B31/00—Fishing for or freeing objects in boreholes or wells
    • E21B31/035—Fishing for or freeing objects in boreholes or wells controlling differential pipe sticking
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02—Well-drilling compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02—Well-drilling compositions
    • C09K8/04—Aqueous well-drilling compositions
    • C09K8/06—Clay-free compositions
    • C09K8/12—Clay-free compositions containing synthetic organic macromolecular compounds or their precursors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2208/00—Aspects relating to compositions of drilling or well treatment fluids
    • C09K2208/02—Spotting, i.e. using additives for releasing a stuck drill

Abstract

본 발명은 물 및, 드릴링 토오크를 감소시키고, 드릴링 동안에 파이프의 고착 또는 비틀림을 예방하거나, 웰 브로호울 내 고착 파이프를 해제하기에 충분한 양의, (A-1)적어도 하나의 히드로카르빌-치환 카르복실아실화제 및(A-2) 수평균 분자량 약 600 내지 약 10,000을 갖는 적어도 하나의 아민-말단 폴리옥시알킬렌의 (A)적어도 하나의 반응 생성물, 또는 반응생성물의 적어도 하나의 염으로 구성된 조성물을 웰 보르호울내에 도입하고, 웰 보르호울을 드릴링하는 단계들로 구성된 방법에 관한 것이다. 드릴링 토오크, 드릴링 동안에 파이프의 비틀림 및 고착 및 웰 브로호울내 고착 파이프의 해제는 모두 본 발명의 방법 및 조성물에 의해 효과적으로 조절된다.The present invention provides (A-1) at least one hydrocarbyl-substituted in an amount sufficient to reduce water and drilling torque, to prevent seizure or twisting of the pipe during drilling, or to release the seizure pipe in the well brows. (A) at least one reaction product, or at least one salt of the reaction product, of a carboxyacylating agent and (A-2) at least one amine-terminated polyoxyalkylene having a number average molecular weight of about 600 to about 10,000 It is directed to a method consisting of introducing a composition into a well borehole and drilling the well borehole. Drilling torque, torsion and fixation of the pipe during drilling and release of the fixation pipe in the well brows are all effectively controlled by the methods and compositions of the present invention.

Description

웰 보르호울 드릴링 방법 및 이에 사용된 조성물Well borhaul drilling method and composition used therein

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (35)

물 및, 드릴링 토오크를 감소시키고, 드릴링 동안에 파이프의 고착 또는 비틀림을 예방하거나, 웰 브로호울내 고착 파이프를 해제하기에 충분한 양의(A-1)적어도 하나의 히드로카르빌-치환 카르복실 아실화제 및(A-2) 수평균 분자량 약 600 내지 약 10,000을 갖는 적어도 하나의 아민-말단 폴리옥시알킬렌의 (A)적어도 하나의 반응 생성물, 또는 반응생성물의 적어도 하나의 염으로 구성된 조성물을 웰 보르호울내에 도입하고, 웰 보르호울을 드릴링하는 단계들로 구성된 방법.(A-1) at least one hydrocarbyl-substituted carboxyl acylating agent in an amount sufficient to reduce water and drilling torque, to prevent seizure or twisting of the pipe during drilling, or to release the seizure pipe in the well brows. And (A-2) a composition comprising (A) at least one reaction product of at least one amine-terminated polyoxyalkylene having a number average molecular weight of about 600 to about 10,000, or at least one salt of the reaction product. Introducing into the hole and drilling the well borhaul. 제1항에 있어서, (A-1)의 히드로카르빌 기는 평균 약 8내지 약 40개의 탄소 원자를 함유하는 방법.The method of claim 1, wherein the hydrocarbyl group of (A-1) contains an average of about 8 to about 40 carbon atoms. 제1항에 있어서, 카르복실 아실화제는 지방산 또는 딜스-알더 모노카르복실 아실화제인 방법.The method of claim 1, wherein the carboxyl acylating agent is a fatty acid or a Diels-Alder monocarboxyl acylating agent. 제1항에 있어서, 카르복실 아실화제(A-1)는 숙신산 아실화제, 딜스-달더 이산, 이량체 아실화제, 트리카르복실 아실 화제, 또는 이들이 혼합물로 부터 선택된 디-또는 트리카르복실 아실화제인 방법.The di- or tricarboxyl acylating agent of claim 1, wherein the carboxyl acylating agent (A-1) is a succinic acylating agent, a Diels-dalder diacid, a dimer acylating agent, a tricarboxylic acylating agent, or a mixture thereof. Way to be. 제1항에 있어서, 카르복실 아실화제(A-1)는 알케닐기 내에 평균 약 12내지 약 28탄소 원자를 갖는 알케닐 숙신 산 또는 무수물인 방법.The method of claim 1, wherein the carboxyl acylating agent (A-1) is an alkenyl succinic acid or anhydride having an average of about 12 to about 28 carbon atoms in the alkenyl group. 제1항에 있어서, 카르복실 아실화제 (A-1)는 평균 약 18내지 약 44개의 탄소 원자를 갖는 이량체 산인 방법.The method of claim 1, wherein the carboxyl acylating agent (A-1) is a dimer acid having an average of about 18 to about 44 carbon atoms. 제1항에 있어서, 카르복실 아실화제 (A-1)는 평균 약 18내지 약 66개의 탄소 원자를 갖는 삼량체 산인 방법.The method of claim 1, wherein the carboxyl acylating agent (A-1) is a trimer acid having an average of about 18 to about 66 carbon atoms. 제1항에 있어서, 아민-말단 폴리옥시알킬렌(A-2)은 수평균 분자량 약 3,000 내지 약 7,000을 갖는 방법.The method of claim 1, wherein the amine-terminated polyoxyalkylene (A-2) has a number average molecular weight of about 3,000 to about 7,000. 제1항에 있어서, 아민-말단 폴리옥시알킬렌(A-2)는 하기 일반식들에 의해 나타내어지는 방법 :The method of claim 1, wherein the amine-terminated polyoxyalkylene (A-2) is represented by the following general formula: 상기 식에서 R은 1 내지 약 8개의 탄소 원자를 갖는 알킬기이고, a는 0내지 약 200 범위의 평균 수이고, b는 약 10내지 약 650 범위의 평균수이고, c는 0내지 약 200범위의 평균수이고, d는 약 1내지 약 150범위의 평균수이며, e는 적어도 약 600의 수 평균 분자량을 갖는 화합물을 제공하기에 충분한 수이다.Wherein R is an alkyl group having from 1 to about 8 carbon atoms, a is an average number ranging from 0 to about 200, b is an average number ranging from about 10 to about 650, c is an average number ranging from 0 to about 200 d is an average number ranging from about 1 to about 150, and e is a sufficient number to provide a compound having a number average molecular weight of at least about 600. 제1항에 있어서, 반응 생성물의 염을 암모니아, 적어도 하나의 아민, 적어도 하나의 금속 또는 이들의 혼합물로 부터 유래 하는 방법.The process of claim 1 wherein the salt of the reaction product is derived from ammonia, at least one amine, at least one metal or mixtures thereof. 제1항에 있어서, 반응 생성물의 염이 알칼리 또는 알칼리 토류 금속 염인 방법.The process of claim 1 wherein the salt of the reaction product is an alkali or alkaline earth metal salt. 제1항에 있어서, 반응 생성물이 나트륨 또는 칼륨 염인 방법.The method of claim 1 wherein the reaction product is a sodium or potassium salt. 제1항에 있어서, 조성물이 (B)적어도 하나의 계면 활성제를 포함하는 방법.The method of claim 1 wherein the composition comprises (B) at least one surfactant. 제13항에 있어서, 계면 활성제(B)는 적어도 하나의 폴리옥시알킬렌 아민, 폴리옥시알킬렌 아미드, 폴리옥시알킬렌 알코올, 폴리옥시알킬렌 페놀, 폴리옥시 알킬렌에테르, 폴리옥시알킬렌에스테르, 또는 이들의 지방산 또는 염인방법.The surfactant (B) according to claim 13, wherein the surfactant (B) comprises at least one polyoxyalkylene amine, polyoxyalkylene amide, polyoxyalkylene alcohol, polyoxyalkylene phenol, polyoxy alkylene ether, polyoxyalkylene ester Or fatty acids or salts thereof. 제13항에 있어서, 계면 활성제(B)는 폴리옥시알킬렌 폴리올인 방법.The method of claim 13, wherein the surfactant (B) is a polyoxyalkylene polyol. 제1항에 있어서, 조성물이 점토를 포함하는 방법.The method of claim 1 wherein the composition comprises clay. 제16항에 있어서, 점토가 벤토나이트인 방법.The method of claim 16 wherein the clay is bentonite. 제1항에 있어서, 반응 생성물(A)이 조성물의 약 0.5 내지 약 20중량% 양으로 존재하는 방법.The method of claim 1 wherein the reaction product (A) is present in an amount from about 0.5 to about 20 weight percent of the composition. 물 및, 조성물의 약 0.5 내지 약 20중량%의, (A-1) 적어도 하나의 히드로카르빌-치환 카르복실아실화제 및(A-2) 수평균 분자량 약 3000 내지 약 10,000을 갖는 적어도 하나의 아민-말단 폴리옥시알킬렌의 (A)적어도 하나의 반응 생성물 또는 반응 생성물의 적어도 하나의 염으로 구성된 조성물을 웰 보르호울 내에 도입하고, 웰 보르호울을 드릴링하는 단계들로 구성된 방법.Water and at least one having from about 0.5 to about 20 weight percent of the composition (A-1) at least one hydrocarbyl-substituted carboxyacylating agent and (A-2) number average molecular weight from about 3000 to about 10,000 A method comprising (A) introducing at least one reaction product or at least one salt of a reaction product of an amine-terminated polyoxyalkylene into a well borehole and drilling the well borehole. 제19항에 있어서, 카르복실 아실화제(A-1)는 알케닐기 내에 평균 약 12내지 약 28탄소 원자를 갖는 알케닐 숙신산 또는 무수물인 방법.20. The process of claim 19, wherein the carboxyl acylating agent (A-1) is an alkenyl succinic acid or anhydride having an average of about 12 to about 28 carbon atoms in the alkenyl group. 제19항에 있어서, 카르복실 아실화제 (A-1)는 평균 약 18내지 약 66개의 탄소 원자를 갖는 삼량체 산인 방법.The method of claim 19, wherein the carboxyl acylating agent (A-1) is a trimer acid having an average of about 18 to about 66 carbon atoms. 제19항에 있어서, 아민-말단 폴리옥시알킬렌(A-2)은 수평균 분자량 약 3000 내지 약 7000을 갖는 방법.20. The method of claim 19, wherein the amine-terminated polyoxyalkylene (A-2) has a number average molecular weight of about 3000 to about 7000. 제19항에 있어서, (A)반응 생성물은 암모니아, 적어도 하나의 아민, 적어도 하나의 금속 또는 이들의 혼합물로 부터 유래된 염인 방법.The process of claim 19, wherein the reaction product (A) is a salt derived from ammonia, at least one amine, at least one metal, or mixtures thereof. 제19항에 있어서, 반응 생성물의 염이 알칼리 또는 알칼리 토류 금속 염인 방법.The method of claim 19, wherein the salt of the reaction product is an alkali or alkaline earth metal salt. 제19항에 있어서, 반응 생성물이 나트륨 또는 칼륨염인 방법.The method of claim 19, wherein the reaction product is sodium or potassium salt. 제19항에 있어서, 조성물이 (B) 적어도 하나의 계면 활성제를 포함하는 방법.The method of claim 19, wherein the composition comprises (B) at least one surfactant. 제26항에 있어서, 계면 활성제(B)는 적어도 하나의 폴리옥시알킬렌 아민, 폴리옥시알킬렌 아미드, 폴리옥시알킬렌 알코올, 폴리옥시알킬렌 페놀, 폴리옥시 알킬렌 에테르, 폴리옥시 알킬렌 에스테르, 또는 이들의 지방산 또는 염인 방법.27. The surfactant according to claim 26, wherein the surfactant (B) is at least one polyoxyalkylene amine, polyoxyalkylene amide, polyoxyalkylene alcohol, polyoxyalkylene phenol, polyoxy alkylene ether, polyoxy alkylene ester Or fatty acids or salts thereof. 수성 드릴링 유체 및, (A-1)적어도 하나의 히드로카르빌 치환 카르복실 아실화제 및 (A-2) 평균 분자량 약 600 내지 약 10,000을 갖는 적어도 하나의 아민-말단 폴리옥시 알킬렌의 (A)적어도 하나의 반응 생성물 또는 반응생성물의 적어도 하나의 염으로 구성된 조성물.(A) of an aqueous drilling fluid and (A-1) at least one hydrocarbyl substituted carboxyl acylating agent and (A-2) at least one amine-terminated polyoxy alkylene having an average molecular weight of about 600 to about 10,000 A composition consisting of at least one reaction product or at least one salt of a reaction product. 제28항에 있어서, 카르복실 아실화제는 지방산 또는 딜스-알더 모노카르복실 아실화제인 조성물.The composition of claim 28, wherein the carboxyl acylating agent is a fatty acid or a Diels-Alder monocarboxyl acylating agent. 제28항에 있어서, 카르복실 아실화제(A-1)는 숙신산 아실화제, 딜스-알더 이산, 이량체산 아실화제, 트리카르복실, 아실 화제 또는 이들이 혼합물로 구성된 군으로부터 선택된 디-또는 트리카르복실 아실화제이며, 이때 아실화제는 평균 약 8내지 약 40개의 탄소 원자를 함유하는 조성물.29. The di- or tricarboxyl of claim 28 wherein the carboxyl acylating agent (A-1) is selected from the group consisting of succinic acylating agent, Diels-alder diacid, dimer acid acylating agent, tricarboxyl, acylating agent or mixtures thereof Acylating agent, wherein the acylating agent contains on average about 8 to about 40 carbon atoms. 제28항에 있어서, 카르복실 아실화제(A-1)는 알케닐기 내에 평균 약 12내지 약 28탄소 원자를 갖는 알케닐 숙신산 또는 무수물인 조성물.The composition of claim 28, wherein the carboxyl acylating agent (A-1) is an alkenyl succinic acid or anhydride having an average of about 12 to about 28 carbon atoms in the alkenyl group. 제28항에 있어서, 카르복실 아실화제 (A-1)는 평균 약 18내지 약 66개의 탄소 원자를 갖는 삼량체산인 조성물.The composition of claim 28, wherein the carboxyl acylating agent (A-1) is a trimeric acid having an average of about 18 to about 66 carbon atoms. 제28항에 있어서, 아민-말단 폴리옥시알킬렌(A-2)은 수평균 분자량 약 3000 내지 약 7000을 갖는 조성물.The composition of claim 28, wherein the amine-terminated polyoxyalkylene (A-2) has a number average molecular weight of about 3000 to about 7000. 제28항에 있어서, 조성물이 (B) 적어도 하나의 계면 활성제를 포함하는 조성물.The composition of claim 28, wherein the composition comprises (B) at least one surfactant. 제28항에 있어서, 계면 활성제(B)는 적어도 하나의 폴리옥시알킬렌 아민, 폴리옥시알킬렌 아미드, 폴리옥시알킬렌 알코올, 폴리옥시알킬렌 페놀, 폴리옥시알킬렌 에테르, 폴리옥시 알킬렌 에스테르, 또는 이들의 지방산 또는 염인 조성물.The surfactant according to claim 28, wherein the surfactant (B) comprises at least one polyoxyalkylene amine, polyoxyalkylene amide, polyoxyalkylene alcohol, polyoxyalkylene phenol, polyoxyalkylene ether, polyoxy alkylene ester Or fatty acids or salts thereof. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930700790A 1991-07-18 1992-07-14 Well borhaul drilling method and composition used therein KR930702466A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US73227691A 1991-07-18 1991-07-18
US07/732,276 1991-07-18
PCT/US1992/005879 WO1993002151A1 (en) 1991-07-18 1992-07-14 Methods of drilling well boreholes and compositions used therein

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CA2091402A1 (en) * 1992-03-17 1993-09-18 Richard W. Jahnke Compositions containing derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same
CA2091419A1 (en) * 1992-03-17 1993-09-18 James H. Bush Compositions containing esters of carboxy-containing interpolymers and methods of using the same
US5599777A (en) * 1993-10-06 1997-02-04 The Lubrizol Corporation Methods of using acidizing fluids in wells, and compositions used therein
US5470822A (en) * 1994-05-18 1995-11-28 Arco Chemical Technology, L.P. Low-toxicity invert emulsion fluids for well drilling
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US6484821B1 (en) * 2000-11-10 2002-11-26 M-I L.L.C. Shale hydration inhibition agent and method of use
US6831043B2 (en) 2002-01-31 2004-12-14 M-I Llc High performance water based drilling mud and method of use
CN102757773A (en) * 2011-04-26 2012-10-31 中国石油化工集团公司 High-inhibition non-solid phase alkaline completion fluid
FR2986798B1 (en) * 2012-02-14 2014-01-31 Rhodia Operations NOVEL AGENT INHIBITOR FOR SWELLING OF CLAYS, COMPOSITIONS COMPRISING SAID AGENT AND METHODS EMPLOYING SAID AGENT
CN102807850B (en) * 2012-07-30 2014-07-23 天津中海油服化学有限公司 Oil-based stuck freeing agent composition for drilling fluid and preparation method for oil-based stuck freeing agent composition
CN105441054B (en) * 2014-08-27 2018-09-14 中国石油化工股份有限公司 Surface activator composition and its preparation method and application suitable for low calcium and magnesium oil reservoir
CN105368428B (en) * 2014-08-27 2019-12-10 中国石油化工股份有限公司 Anionic-nonionic mixed oil-displacing surfactant and preparation method and application thereof
CN107043616B (en) * 2017-04-20 2020-02-07 长江大学 Deepwater white oil flat plate fluid oil base drilling fluid
CN110746955B (en) * 2019-09-26 2021-01-12 中国石油天然气股份有限公司 Gemini surfactant for oil displacement, binary composite system, preparation method and application thereof
CN111484835B (en) * 2020-04-23 2023-02-03 新疆塔里木油田建设工程有限责任公司 Water-soluble oil-based drilling fluid lubricant and preparation method thereof

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DK653488D0 (en) * 1988-11-23 1988-11-23 Esti Kemi Aps based lubricant

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PH30262A (en) 1997-02-20
ZA925310B (en) 1993-04-28
WO1993002151A1 (en) 1993-02-04
EP0549770A1 (en) 1993-07-07
CA2088480A1 (en) 1993-01-19
CN1068842A (en) 1993-02-10
MX9204198A (en) 1993-07-01
AU2324492A (en) 1993-02-23
AU647309B2 (en) 1994-03-17
TW271448B (en) 1996-03-01

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