KR860000620B1 - Tansfer printing method on ceramic or metallic surface - Google Patents
Tansfer printing method on ceramic or metallic surface Download PDFInfo
- Publication number
- KR860000620B1 KR860000620B1 KR1019840003662A KR840003662A KR860000620B1 KR 860000620 B1 KR860000620 B1 KR 860000620B1 KR 1019840003662 A KR1019840003662 A KR 1019840003662A KR 840003662 A KR840003662 A KR 840003662A KR 860000620 B1 KR860000620 B1 KR 860000620B1
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- South Korea
- Prior art keywords
- transfer
- printing
- layer
- gold
- silver
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/28—Printing on other surfaces than ordinary paper on metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
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- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Thermal Sciences (AREA)
- Toxicology (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
Description
본 발명은 초자나 금속재 표면에 철분의 금, 은색 전사 인쇄하는 전사 인쇄방법에 관한 것이다. 초자나 금속재는 표면에 유막이 있고 전사 인쇄할때 필수적인 피 전사물의 표면 용융이 전사지의 접착용융 상태에 미치지 못하여 밀착 전사되지 못하였다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transfer printing method for transferring iron or gold and silver onto a surface of a candle or metal material. In the case of the glass or metal material, there was an oil film on the surface, and the surface melting of the transferred object, which was essential for the transfer printing, did not reach the adhesive melting state of the transfer paper, and thus, the transfer was not carried out.
그러므로 이러한 초자나 금속재에는 식물성 안료로 인쇄된 전사지를 유약을 도포하기 전에 전사 공정을 한후 유약을 도포하여 다시 차소성하여서 되는 전사방법에 있었고, 금, 은색의 경우 순금이나 은을 함유한 용매를 사용하므로써 제조공정이 매우 번거롭고 원가가 높을뿐 아니라 염분이나 공기중의 습기나 가스등에 쉽게 변색되는 결점이 있었다.Therefore, the transfer method printed on vegetable or metal materials was transferred by applying the glaze before applying the glaze to the transfer paper printed with the vegetable pigment and then glazing again, and in the case of gold and silver, a solvent containing pure gold or silver was used. As a result, the manufacturing process is very cumbersome and expensive, and there is a drawback of discoloration easily due to salt, moisture or gas in the air.
그리고, 금속류에슨 금, 은색의 효과를 낼수 있는 금, 은박 인쇄는 가능하나 이 또한 초자와 같이 일차 인쇄 공정을 한후 그 표면에 투명 피막층을 형성하므로써 고유의 금, 은색의 광택성 발광 효과가 없고 색상의 선명도가 저하되며 인쇄과정이 매우 복잡하여 이 또한 가격상승의 원인이 되었다.In addition, it is possible to print metal and gold, silver and silver foil which can give a silver effect, but also it has no inherent gold and silver luminescent effect by forming a transparent film layer on the surface after the first printing process like a candle. The sharpness of the colors was reduced and the printing process was very complicated, which also caused the price increase.
인쇄의 선명도에 있어 특히 금, 은색일 경우에는 철분의 금, 은 전사인쇄보다 효과가 있는 다른 인쇄가 없다는 것은 이 분야에서 공지된 바다.It is well known in the art that there are no other prints that are more effective than gold and silver transfer printing, especially in the case of gold and silver in print clarity.
그러나, 이러한 전사 인쇄는 알려진 바와같이 가소성 수지층에 적당한 온도를 가한 압형으로 가압하여 피 전사물에 전사지를 가열 가압하므로써 압형의 형태모양이 피 전사물에 용융 접합 인쇄되는 것이다. 이와같이 이러한 전사 인쇄과정에 있어서 피전사물의 선택요건 중에서 가장 중요한 것은 압형의 가온 온도가 피전사물에 전달되어서 그 표면이 용융되어 전사지의 접착제와 용융 접합되는 용융 가능한 것임은 자명한 일이다.However, such transfer printing is press-molded by applying a suitable temperature to the plastic resin layer and heat-pressing the transfer paper to the object to be transferred, whereby the shape of the mold is melt-bonded and printed on the object to be transferred. In this transfer printing process, it is obvious that the most important thing among the selection requirements of the transfer object is that the warming temperature of the mold is transferred to the transfer object, and the surface thereof is melted and melt-bonded with the adhesive of the transfer paper.
본 발명은 이러한 요건을 구비하지 않은 피전사물 즉, 금속이나 초자재 표면에 철분재의 금, 은색 전사인쇄를 하고자 하는데 그 목적이 있다.An object of the present invention is to transfer gold, silver transfer printing of iron powder on the surface of a transfer material that does not have such a requirement, that is, metal or supermaterial.
앞서도 말한바 있듯이 철분재로된 금, 은박 전사용지는 피전사물의 용융 상태가 전사용지에 첨착된 접착제가 접착되는 가열온도에 용융되는 조건에 맞지 않으면 전사되지 않는다는 것을 본 발명자가 수차에 걸쳐 실험한바 분명하여졌다.As mentioned above, the inventors experimented several times that the gold and silver foil transfer paper made of iron material is not transferred unless the molten state of the transfer object melts at the heating temperature at which the adhesive attached to the transfer paper is bonded. It became clear.
여기서 시험한 것이 용융되지 않는 피전사물에 용융되어 전사인쇄되어지는 피전사물층을 중간 개재시켜 그위에 전사하는 것이다.What is tested here is to transfer onto a transfer object layer which is melted on a transfer object which is not melted, and which is to be transferred and printed.
전사 인쇄되는 피전사물의 기판은 용융이 가능한 가소성 수지가 적당하므로 가소성수지를 매개로 하여 초자나 금속재 표면에 일차 도포하여 보았다.The substrate to be transferred is preferably a plastic resin which can be melted, so that the substrate is first applied to the surface of the glass or metal material through the plastic resin.
그러나 이러한 공정은 성공치 못하였다.However, this process was not successful.
가소성수지는 초자나 금속재등의 유막에 접착되지 않았다.The plastic resin did not adhere to the oil film such as glass or metal material.
가소성 수지는 점탄성(粘彈性)의 성질이기 때문에 이러한 착색과정에서 가열되는 고온에서 용융되거나 접착성이 상실되어 전사 인쇄하는 중간층으로는 부적당하였다.Since the plastic resin is viscoelastic, it is inadequate as an intermediate layer for transfer printing because it melts at a high temperature heated during this coloring process or loses adhesiveness.
더구나, 본 발명은 초자나 금속표면에 일정한 임의의 도형만을 전사하는데 있는 것이며, 이러한 가소성수지의 기층은 전사인쇄 과정에서 발생되는 가온 가압에 의해 용융이형되어 정교한 도형 또는 문자의 부분 전사 인쇄가 불가능하였다.In addition, the present invention is to transfer only a certain figure on the initial surface or the metal surface, the base layer of the plastic resin is melt-deformed by the heating pressure generated during the transfer printing process, the partial transfer printing of fine figures or characters was impossible. .
여기서 다시 착안한 것이 경도가 높고 열변형하지 않는 열경화성 수지를 채용하기로 하였다.It was decided again to adopt a thermosetting resin having high hardness and not thermally deforming.
시험결과 열경화성 수지중에서 도료로써 사용되는 멜라민과 포름알레히드를 반응시킨 멜라민 포름알데히드 수지(melamine formaldehyde)를 선택하고 축합할때 부탄올을 넣어서된 부탄올화 멜라민 수지를 사용하기에 이르렀다.As a result, in the thermosetting resin, butanolated melamine resin containing butanol was used when condensing melamine formaldehyde reacted with melamine used as a paint and formaldehyde.
단, 내열성, 내후성이 좋은 저중합도(低重合度)를 채용하였다.However, low polymerization degree with good heat resistance and weather resistance was adopted.
본 발명의 제조공정은 2단계로써 대별할 수 있는바 중간층의 인쇄 공정과 전사지의전사인쇄 공정이다. 즉,The manufacturing process of the present invention can be roughly divided into two stages: the intermediate layer printing process and the transfer printing process of the transfer paper. In other words,
제조공정 1.Manufacturing process 1.
멜라민포름알데히드 수지에 축합할때 부탄올을 넣어서된 저중합도의 부탄올화 멜라민수지로써 일차 도포 피막처리된 금속재 표면에 일정무늬 또는 문자를 스크린 인쇄방식을 써서 인쇄한다.Low-condensation butanolated melamine resin containing butanol when condensed with melamine formaldehyde resin, using a screen printing method to print a pattern or text on the surface of the first coating film.
제조공정 2.Manufacturing process 2.
일정무늬로 스크린 인쇄된 인쇄층에 약 100℃정도의 온도로써 약 4-5분 정도 가열하여 인세층이 완전경화되기전에 전사지를 덮고 평판의 고무패드를 열압한 다음 고온 또는 상온에서 완전 경화시킨다. 일정무늬로스크린 인쇄된 인쇄층은 기판보다 돌출형성되므로 전사지를 덮고평판의 고무패드를 열 가압하면 돌출부의 스크린 인쇄층에만 전사 인쇄되는 것이다.The printed layer screen-printed with a constant pattern is heated at a temperature of about 100 ° C. for about 4-5 minutes, and the transfer sheet is covered, and the rubber pad of the plate is hot pressed before being completely cured, and then completely cured at high temperature or room temperature. Since the printed layer screen-printed with a predetermined pattern is formed more protruding than the substrate, the transfer layer is only transferred to the screen printed layer of the protruding portion by covering the transfer sheet and thermally pressing the rubber pad of the flat plate.
여기서 중요한 것은 종래의 전사인쇄는 평면의 가소성수지 기판에 전사지를 덮고 원하는 무늬의의 금형을 열가압하여서 전사 인쇄하는 것이므로 기판이 가소성수지로도 가능하였으나 본 발명은 전사하고자 하는 부위만이 인쇄돌출되어 있으므로 점탄성(粘彈性)의 가소성수지로는 가압순간 인쇄층이 뭉개지게되어 부적당한 것이다.What is important here is that conventional transfer printing covers transfer paper on a planar plastic resin substrate, Since the substrate can be a plastic resin because the mold is thermally pressurized and transferred, the present invention can print out only the portion to be transferred, so that the printing layer is crushed at an instant with a viscoelastic plastic resin. It is.
또한, 중간 인쇄층이 경화되기전에 전사인쇄하는 이유는 경화성수지인 멜라민 수지는 일단 경화된후 변형되지 않는 성질과 경화된 후에는 전사인쇄가 불가능하기 때문이다.In addition, the transfer printing before the intermediate print layer is cured because the melamine resin, which is a curable resin, is not deformed after being cured once and transfer printing is impossible after curing.
즉, 본 발명은 경화성 수지를 선택하여 기판(초자나 금속재)에 스크린 인쇄를 하여 인쇄층을 돌출시키고 이 인쇄층에 반경화시킬 겸 적당한 온도를 가하여 전사인쇄가 가능한 조건을 만드는 공정과 이돌출된 인쇄층부위에 평판의 고무패드를 사용하여 전사지를 가압하므로써 돌출부인 인쇄층만이 전사되게 하는 공정의 결합에 요지가 있다고 할 것이다.That is, the present invention selects the curable resin and screen-prints the substrate (curve or metal material) to protrude the print layer and apply the appropriate temperature to semi-curing the print layer to create a condition that enables transfer printing. The press of the transfer sheet using the rubber pad of the flat plate on the printing layer portion will have the gist of the process of combining only the printing layer that is the projection portion.
이와같이 된 본 발명은 멜라민수지의 특성인 경도와 밀착성에 의해 전사인쇄층이 견고히 밀착 인쇄되며 약간의 돌출무늬가 형성되어 종래 금, 은색의 인쇄효과보다 입체적이고 광택성이 우수한 미려한 전사인쇄층을 구유할 수 있다.Thus, the present invention has a transfer printing layer is tightly printed by the hardness and adhesiveness of the melamine resin, and a slight protrusion pattern is formed, so that a beautiful transfer printing layer having superior three-dimensional and glossiness than the conventional gold and silver printing effect is provided. can do.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019840003662A KR860000620B1 (en) | 1984-06-27 | 1984-06-27 | Tansfer printing method on ceramic or metallic surface |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019840003662A KR860000620B1 (en) | 1984-06-27 | 1984-06-27 | Tansfer printing method on ceramic or metallic surface |
Publications (2)
Publication Number | Publication Date |
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KR860000157A KR860000157A (en) | 1986-01-25 |
KR860000620B1 true KR860000620B1 (en) | 1986-05-24 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019840003662A KR860000620B1 (en) | 1984-06-27 | 1984-06-27 | Tansfer printing method on ceramic or metallic surface |
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KR (1) | KR860000620B1 (en) |
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1984
- 1984-06-27 KR KR1019840003662A patent/KR860000620B1/en not_active IP Right Cessation
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Publication number | Publication date |
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KR860000157A (en) | 1986-01-25 |
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