KR850700046A - High strength high elastic carbon fiber and its manufacturing method - Google Patents

High strength high elastic carbon fiber and its manufacturing method

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Publication number
KR850700046A
KR850700046A KR1019850700019A KR850700019A KR850700046A KR 850700046 A KR850700046 A KR 850700046A KR 1019850700019 A KR1019850700019 A KR 1019850700019A KR 850700019 A KR850700019 A KR 850700019A KR 850700046 A KR850700046 A KR 850700046A
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KR
South Korea
Prior art keywords
fiber
carbon fiber
heat treatment
density
yarn
Prior art date
Application number
KR1019850700019A
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Korean (ko)
Other versions
KR870000534B1 (en
Inventor
무네쓰구 나까다니
Original Assignee
가와사끼 고오오
미쓰비시 레이욘 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 가와사끼 고오오, 미쓰비시 레이욘 가부시끼가이샤 filed Critical 가와사끼 고오오
Priority claimed from PCT/JP1984/000486 external-priority patent/WO1985001752A1/en
Publication of KR850700046A publication Critical patent/KR850700046A/en
Application granted granted Critical
Publication of KR870000534B1 publication Critical patent/KR870000534B1/en

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Abstract

내용 없음No content

Description

고강도 고탄성 탄소섬유 및 그 제조방법High strength high elastic carbon fiber and its manufacturing method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

첨부된 도면은 종래 방법에 의한 탄소섬유의 타소와 온도와 스트랜드 강도, 스트랜드 탄성율 및 밀도와의 관계를 나타낸 것이다.The accompanying drawings show the relationship between the temperature and strand strength, strand elastic modulus and density of carbon fiber by conventional methods.

Claims (8)

섬유직경이 1-6μ이고, 스트랜드 강도가 430Kg/mm2이상, 스트랜드 탄성율 28ton/mm2이상, 밀도가 1,755g/cm3이상인 고강도, 고탄성탄소섬유.And the fiber diameter of 1-6μ, the strand strength 430Kg / mm 2 or more, a strand elastic modulus 28ton / mm 2 or more, high intensity density is greater than or equal to 1,755g / cm 3, high modulus carbon fiber. 아크릴니트릴제 섬유 프리커시(precursor:)를 산화성 분위기중 200-400℃의 온도에서 섬유밀도가 1.22g/cm3이 되기까지 3%이상의 신장(伸張)을 주면서 내염화처리를 한후 다시 내염화처리를 함으로써 섬유 밀도가 1.22g/cm3를 초과하고, 1.40g/cm3이하의 범위가 되도록 하고, 잇따라 불활성분위기하에서 300-800℃의 온도로 상기 내염화섬유의 신장율을 3%이상 되도록하는 조건하에서 열처리한후 다시 불활성 분위기하에서 1300-1650℃의 온도에서, 사조을 긴장시키면서 열처리하는 것을 특징으로 하는 섬유직경이 1-6μ, 스프랜드 강도 430kg/mm2이상, 스트랜드 탄성율 28ton/mm2이상, 밀도 1,755g/cm3이상인 고강도, 고탄성 탄소섬유의 제조법.Acrylonitrile fiber precursor ), The fiber density 1.22g / cm by an oxidizing atmosphere at a temperature of 200-400 ℃ fiber while a density of 3% or more in height (伸張) until the 1.22g / cm 3 hanhu my chloride reprocessed within chloride treatment After the heat treatment under the condition of exceeding 3 and in the range of 1.40 g / cm 3 or less, and subsequently increasing the elongation of the chloride fiber to 3% or more at a temperature of 300-800 ° C. in an inert atmosphere, and then again 1300 in an inert atmosphere. At the temperature of -1650 ℃, yarn The fiber diameter, characterized in that, while the heat treatment tension 1-6 μ, soup land strength 430kg / mm 2 or more, a strand elastic modulus 28ton / mm 2 or more, a density 1,755g / cm 3 or more high-strength, high modulus carbon fiber production method. 아크릴니트릴계 섬유로써 단섬유 섬도 0.1-1.1데니어의 섬유를 사용하는 것을 특징으로 하는 청구 범위 제2항 기재의 탄소섬유의 제조법.A method for producing the carbon fiber according to claim 2, wherein a single fiber fineness of 0.1-1.1 denier is used as the acrylonitrile fiber. 섬도 변동율이 15%이하인 아크릴니트릴계 섬유 속(束)을 사용하는 것을 특징으로 하는 청구범위 제3항의 탄소섬유의 제조법.The manufacturing method of the carbon fiber of Claim 3 which uses the acrylonitrile fiber bundle whose fineness fluctuation rate is 15% or less. 입경 10μ이상의 불순물이 부착되거나 함유하지 않는 아크릴니트릴계 중합체섬유를 사용하는 것을 특징으로 하는 청구범위 제3항 또는)제4항의 탄소섬유 제조법.The carbon fiber manufacturing method according to claim 3 or 4, wherein acrylonitrile-based polymer fibers do not adhere or contain impurities having a particle size of 10 μm or more. 내염화사의 불활성분위기하 300-800℃의 열처리 공정을 300-500℃와 500-800℃의 2공정으로 분할하여 300-500℃의 열처리공정에서 실의 신장율을 3%이상되게 하고, 500-800℃의 열처리 공정에 있어서는 실질적으로 실 상태가 수축하지 않도록 긴장시키면서 열처리하는 것을 특징으로 하는 청구범위 제2항 기재의 탄소섬유의 제조방법.The heat treatment process of 300-800 ℃ is divided into two processes, 300-500 ℃ and 500-800 ℃ under the inert atmosphere of flame resistant yarn, and the elongation rate of the yarn is more than 3% in the heat treatment process of 300-500 ℃, and 500-800 In the heat treatment step of ℃, the method of producing a carbon fiber according to claim 2, characterized in that the heat treatment while being so as not to shrink substantially the yarn state. 내염화섬유의 불활성분위기 하에서 500-800℃의 열처리공정에서 섬유의 신장율을 1%이상으로 하는 것을 특징으로 하는 청구범위 제6항 기재의 탄소섬유의 제조법.The carbon fiber manufacturing method according to claim 6, wherein the fiber has an elongation of 1% or more in a heat treatment at 500-800 ° C. under an inert atmosphere of flame resistant fiber. 섬유밀도1.22g/cm3로한 내염화처리사를 1.22g/cm3을 초과하고, 1.400g/cm3이하 범위의 섬유밀도를 갖는 내염화처리사로 함에 있어서 실에 1%이상의 신장을 주도록 하는 것을 특징으로 하는 청구범위 제2항 기재의 탄소섬유의 제조법.The flame resistant yarn having a fiber density of 1.22 g / cm3 is a flame resistant yarn having a fiber density exceeding 1.22 g / cm 3 and having a fiber density in the range of 1.400 g / cm 3 or less, so that 1% or more of elongation is given to the yarn. The manufacturing method of the carbon fiber of Claim 2 to be used. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019850700019A 1983-10-13 1984-10-12 Carbon fiber and it's making method KR870000534B1 (en)

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
JP58-191292 1983-10-13
JP19129258 1983-10-13
JP19129158 1983-10-13
JP19129358 1983-10-13
JP58-191293 1983-10-13
JP???58-191291 1983-10-13
JP58-191291 1983-10-13
JP58-191294 1983-10-13
JP19129458 1983-10-13
PCT/JP1984/000486 WO1985001752A1 (en) 1983-10-13 1984-10-12 Carbon fibers with high strength and high modulus, and process for their production

Publications (2)

Publication Number Publication Date
KR850700046A true KR850700046A (en) 1985-10-21
KR870000534B1 KR870000534B1 (en) 1987-03-14

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KR1019850700019A KR870000534B1 (en) 1983-10-13 1984-10-12 Carbon fiber and it's making method

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100338280C (en) * 2002-09-30 2007-09-19 帝人株式会社 Carbon fiber and process and composition for the production of felt
KR101148708B1 (en) * 2009-12-31 2012-05-23 주식회사 효성 Preparation Method Of Polyacrylonitrile Based Precursor For Carbon Fiber

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KR870000534B1 (en) 1987-03-14

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