KR840004534A - Crystalline and porous composites of silicon and boron oxides - Google Patents

Crystalline and porous composites of silicon and boron oxides Download PDF

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Publication number
KR840004534A
KR840004534A KR1019830001960A KR830001960A KR840004534A KR 840004534 A KR840004534 A KR 840004534A KR 1019830001960 A KR1019830001960 A KR 1019830001960A KR 830001960 A KR830001960 A KR 830001960A KR 840004534 A KR840004534 A KR 840004534A
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crystalline
sio
molar ratio
synthetic material
hydroxide
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KR1019830001960A
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Korean (ko)
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페레고(외 2) 기오바니
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칼로 시오니
스남프로게티 쏘시에떼 피 아찌오니
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Publication of KR840004534A publication Critical patent/KR840004534A/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/08—Compounds containing halogen
    • C01B33/10—Compounds containing silicon, fluorine, and other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B35/00—Boron; Compounds thereof
    • C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
    • C01B35/10—Compounds containing boron and oxygen
    • C01B35/1009—Compounds containing boron and oxygen having molecular-sieve properties

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Silicon Compounds (AREA)

Abstract

내용 없음No content

Description

규소 및 붕소산화물로 된 결정질 및 다공질의 합성물질Crystalline and porous composites of silicon and boron oxides

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (10)

규소유도체 붕소유도체, 테트라메틸암모늄 수산화물과 테트라부틸암모늄 수산화물의 혼합물 또는 이것의 대체들로서 메틸부틸암모늄 수산화물이 혼합된 4차염기, 임의로 첨가된 알칼리금속의 수산화물 또는 수산화 암모늄을 열수조건하에서 반응시킴에 있어서 반응물의 SiO2: B2O3의 몰비율을 0.5-30으로 하고, H2O : SiO2의 몰비를 10-50으로 하며, R : SiO2의 몰비를 0.05-5로 하고 Me+: SiO2의 몰비를 0-0.5로 하여 합성한 다음과 같은 실험식을 가지는 무수상태의 것으로서 규소와 붕소의 산화물로 된 제올라이트의 특성을 가지는 결정질 및 다공질의 합성물질.In the reaction of silicon derivative boron derivative, tetramethylammonium hydroxide and tetrabutylammonium hydroxide or a quaternary base mixed with methylbutylammonium hydroxide as an alternative thereof, hydroxide of an optionally added alkali metal or ammonium hydroxide under hydrothermal conditions The molar ratio of SiO 2 : B 2 O 3 of the reactants is 0.5-30, the molar ratio of H 2 O: SiO 2 is 10-50, the molar ratio of R: SiO 2 is 0.05-5, and Me + : SiO A crystalline and porous synthetic material having an anhydrous state having the following empirical formula synthesized with a molar ratio of 2 to 0-0.5 and having the characteristics of a zeolite made of an oxide of silicon and boron. a. R2O. (1-a)Me2O.B2O3. xSiO2 a. R 2 O. (1-a) Me 2 OB 2 O 3 . xSiO 2 단, 위의 식에서, a = 0-1, x : 30-120, Me : H+양이온, NH4+ 양이온 또는 알칼리금속의 양이온, R : 한가지 이상의 테트라알킬암모늄 양이온.Provided that a = 0-1, x: 30-120, Me: H + cation, NH 4 + cation or a cation of an alkali metal, R: one or more tetraalkylammonium cations. 청구범위 제1항에 있어서 본 명세서의 표 1에 나온 데이터에 상응하는 H+형태의 X선 회절분식 스펙트럼을 나타내는 결정질 및 다공질의 합성물질.The crystalline and porous composite according to claim 1, which exhibits an X-ray diffraction spectrum in the form of H + corresponding to the data set forth in Table 1 herein. 청구범위 제1항에 있어서 SiO2: B2O3의 몰비율을 1-15로 하고, H2O : SiO2의 몰비를 20-40으로 하며, R : SiO2의 몰비를 0.1-0.3으로 하고 Me : SiO2의 몰비를 0.01-0.4로 하여 제조한 결정질 및 다공질의 합성물질.The molar ratio of SiO 2 : B 2 O 3 of claim 1 is 1-15, the molar ratio of H 2 O: SiO 2 is 20-40, and the molar ratio of R: SiO 2 is 0.1-0.3. And a crystalline and porous synthetic material prepared with a molar ratio of Me: SiO 2 of 0.01 to 0.4. 청구범위 제1항에 있어서 테트라메틸암모늄 양이온과 테트라부틸암모늄양이온의 비율을 0.3-3으로하여 제조한 결정질 및 다공질의 합성물질.The crystalline and porous synthetic material according to claim 1, wherein the ratio of tetramethylammonium cation and tetrabutylammonium cation is 0.3-3. 청구범위 제1항에 있어서 100℃-220℃ 및 pH 9-14에서 2-30일동안 사용한 결정질 및 다공질의 합성물질.The crystalline and porous synthetic material according to claim 1, which is used for 2-30 days at 100 ° C-220 ° C and pH 9-14. 청구범위 제1항에 있어서 규소유도체로서 테트라알킬 오르토규산염, 콜로이드 실리카, 실라카겔, 규산 나트륨 또는 에어로실을 사용한 결정질 및 다공질의 합성물질.The crystalline and porous synthetic material according to claim 1, wherein tetraalkyl orthosilicate, colloidal silica, silica gel, sodium silicate or aerosil is used as the silicon derivative. 청구범위 제1항에 있어서 붕소유도체로서 트리알킬붕산염, 테트라알킬붕산염, 붕산, 붕산나트륨 또는 붕산을 사용한 결정질 및 다공질의 합성물질.The crystalline and porous synthetic material according to claim 1, wherein trialkyl borate, tetraalkyl borate, boric acid, sodium borate or boric acid is used as the boron derivative. 청구범위 제1항에 있어서 혼합된 4차 메틸부틸 암모늄염기로서 디메틸부틸암모늄 수산화물을 사용한 결정질 및 다공질의 합성물질.A crystalline and porous synthetic material according to claim 1, wherein dimethylbutylammonium hydroxide is used as the mixed quaternary methylbutyl ammonium base. 청구범위 제1항에 있어서 혼합된 메틸부틸암모늄 염기로서 트리부틸메틸암모늄수산화물을 사용한 결정질 및 다공질의 합성물질.A crystalline and porous synthetic material according to claim 1, wherein tributylmethylammonium hydroxide is used as the mixed methylbutylammonium base. 청구범위 제1항에 있어서 혼합된 4차 메틸부틸암모늄 염기로서 트리부틸메틸암모늄 수산화물을 사용한 결정질 및 다공질의 합성물질.A crystalline and porous composite according to claim 1 using tributylmethylammonium hydroxide as the mixed quaternary methylbutylammonium base. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019830001960A 1982-05-07 1983-05-07 Crystalline and porous composites of silicon and boron oxides KR840004534A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT21132A/82 1982-05-07
IT21132/82A IT1157932B (en) 1982-05-07 1982-05-07 SYNTHETIC, CRYSTALLINE, POROUS MATERIALS CONSTITUTED BY SILICON AND BORON OXIDES, THEIR PREPARATION METHOD AND THEIR USES

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JP (1) JPS58208129A (en)
KR (1) KR840004534A (en)
AU (1) AU1383983A (en)
BE (1) BE896686A (en)
BR (1) BR8302358A (en)
DD (1) DD209795A5 (en)
DE (1) DE3316488A1 (en)
DK (1) DK195883A (en)
ES (1) ES522608A0 (en)
FR (1) FR2526414A1 (en)
GB (1) GB2120226B (en)
GR (1) GR78258B (en)
IL (1) IL68543A0 (en)
IT (1) IT1157932B (en)
LU (1) LU84790A1 (en)
NL (1) NL8301590A (en)
NO (1) NO831584L (en)
PL (1) PL241838A1 (en)
PT (1) PT76656B (en)
SE (1) SE8302576L (en)
YU (1) YU95483A (en)
ZA (1) ZA832934B (en)
ZW (1) ZW9183A1 (en)

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FR2582639B1 (en) * 1985-05-28 1987-08-28 Centre Nat Rech Scient NOVEL PROCESS FOR THE SYNTHESIS OF BOROSILICATE-TYPE ZEOLITES, PRODUCTS THUS OBTAINED AND THEIR USE
IT1213504B (en) 1986-10-22 1989-12-20 Eniricerche Spa ZEOLITI LEGATE AND PROCEDIMENYE FOR THEIR PROSUCTION.
AU634962B2 (en) * 1988-06-10 1993-03-11 Kohmix Co., Ltd. Water-Soluble, film-forming inorganic compounds

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IN146957B (en) * 1976-10-18 1979-10-20 Standard Oil Co
GR66589B (en) * 1978-06-22 1981-03-30 Snam Progetti
US4331641A (en) * 1979-11-07 1982-05-25 National Distillers & Chemical Corp. Synthetic crystalline metal silicate compositions and preparation thereof

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BE896686A (en) 1983-11-07
NL8301590A (en) 1983-12-01
LU84790A1 (en) 1984-03-07
ES8406380A1 (en) 1984-08-01
IT8221132A0 (en) 1982-05-07
ZW9183A1 (en) 1983-07-20
YU95483A (en) 1985-10-31
PL241838A1 (en) 1984-06-18
DK195883D0 (en) 1983-05-03
ES522608A0 (en) 1984-08-01
PT76656B (en) 1986-04-16
GR78258B (en) 1984-09-26
SE8302576L (en) 1983-11-08
BR8302358A (en) 1984-01-10
SE8302576D0 (en) 1983-05-05
IT1157932B (en) 1987-02-18
DE3316488A1 (en) 1983-11-10
DD209795A5 (en) 1984-05-23
DK195883A (en) 1983-11-08
IL68543A0 (en) 1983-09-30
GB2120226B (en) 1985-10-23
GB8311310D0 (en) 1983-06-02
AU1383983A (en) 1983-11-10
PT76656A (en) 1983-06-01
ZA832934B (en) 1984-04-25
JPS58208129A (en) 1983-12-03
FR2526414B1 (en) 1985-04-19
FR2526414A1 (en) 1983-11-10
GB2120226A (en) 1983-11-30
NO831584L (en) 1983-11-08

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