KR840004193A - Tows and yarns composed of high-strength metal-clad fibers, methods for manufacturing the same, and articles made therefrom - Google Patents

Tows and yarns composed of high-strength metal-clad fibers, methods for manufacturing the same, and articles made therefrom Download PDF

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Publication number
KR840004193A
KR840004193A KR1019830001033A KR830001033A KR840004193A KR 840004193 A KR840004193 A KR 840004193A KR 1019830001033 A KR1019830001033 A KR 1019830001033A KR 830001033 A KR830001033 A KR 830001033A KR 840004193 A KR840004193 A KR 840004193A
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yarn
core
tow
metal
fiber
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KR1019830001033A
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Korean (ko)
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KR880000477B1 (en
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죠오지 모린 루이스
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죠오지 모린 루이스
일렉트로 메탈로이드 코오포레이션
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    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36—Cored or coated yarns or threads
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41J—TARGETS; TARGET RANGES; BULLET CATCHERS
    • F41J2/00—Reflecting targets, e.g. radar-reflector targets; Active targets transmitting electromagnetic or acoustic waves
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
    • D01F11/127—Metals
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties

Abstract

내용 없음No content

Description

고강도 금속 피복섬유로 구성된 토우와 얀, 그의 제조 방법 및 그로부터 제조된 물품Tows and yarns composed of high strength metal sheathed fibers, methods for making them and articles made therefrom

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

제1도는 본 발명의 금속도금 섬유의 횡단면도.1 is a cross-sectional view of a metal plated fiber of the present invention.

제1(a)도는 본 발명의 금속도금 섬유의 종단면도.Figure 1 (a) is a longitudinal cross-sectional view of the metal plated fiber of the present invention.

제2도 및 제2(a)도는 본 발명에 따른 다절코어 및 금속으로 도금된 균열코어 섬유2 and 2 (a) show crack core fibers plated with a multi-core core and metal according to the present invention.

제3도는 본 발명에 따른 급격히 휜 금속도금 섬유의 종단면도, 제3(a)도는 종래의 기술에 따라 제조된 급격히 휜 금속도금 조성물의 종단면도.Figure 3 is a longitudinal cross-sectional view of the sharply metalized fiber according to the present invention, Figure 3 (a) is a longitudinal cross-sectional view of the sharply metallized composition prepared according to the prior art.

제4도는 본 발명을 이용하여 얻은 금속도금 조성물 섬유 보강 폴리머의 부분 단면도.4 is a partial cross-sectional view of a metal plating composition fiber reinforced polymer obtained using the present invention.

제5도는 본 발명의 방법을 수행하기 위한 단면도.5 is a cross-sectional view for carrying out the method of the present invention.

Claims (38)

고강도 조성 섬유로 구성되며 그 대부분이 전기 전도 반금속 코어와 상기 코어상에 적어도 하나의 전착 금속으로된 얇고, 균일하여 견고히 부착된 적어도 하나의 전기 전도층을 가지며, 상기 코어에 대한 상기층의 결합 강도가 실질적으로 금속의 장력강도의 약 10%이하가 아닌 연속얀 또는 토우.Composed of high strength composition fibers, most of which have an electrically conductive semimetal core and at least one electrically conductive layer of at least one electrodeposited metal on the core, the at least one electrically conductive layer adhered to the core, the bonding of the layer to the core Continuous yarn or tow whose strength is not substantially less than about 10% of the tensile strength of the metal. 제1항에 있어서, 상기 섬유의 대부분에서 상기 코어에 대한 상기층의 결합강도가 적어도 조성섬유를심하게 구부려 굴곡된 신장면상의 코팅이 그의 탄성한계치가 초과되어 부서질 정도로 충분히 굴곡되었을때 구부린 압축면상의 코팅이 코어에 걀합된 채 남아 원극상으로 균열되지 않기에 충분한 강도를 가진 연속토우 또는 얀.The compressive surface of claim 1, wherein in most of the fibers the bond strength of the layer to the core is flexed at least when the coating on the elongated surface that is flexed by bending the composition fiber at least is flexed enough to break and exceed its elastic limit. Continuous tow or yarn of sufficient strength to remain coated on the core and not crack in the original. 제1항에 있어서, 상기 결합 강도가 실질적으로 상기 장력 강도의 약 25%보다 적지않은 연속 얀 또는 토우.The continuous yarn or tow of claim 1, wherein the bond strength is substantially less than about 25% of the tensile strength. 제1항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 50%보다 실질적으로 적지않은 연속 얀 또는 토우.The continuous yarn or tow of claim 1, wherein the bond strength is substantially less than about 50% of the tensile strength. 제1항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 90%보다 실질적으로 적지않은 연속 얀 또는 토우.The continuous yarn or tow of claim 1, wherein the bond strength is substantially less than about 90% of the tensile strength. 제1항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 99%보다 실질적으로 적지않은 연속 얀 또는 토우.The continuous yarn or tow of claim 1, wherein the bond strength is substantially less than about 99% of the tensile strength. 제1항에 있어서, 상기 금속이 결정성인 연속 얀 또는 토우.The continuous yarn or tow of claim 1, wherein the metal is crystalline. 제1항에 있어서, 상기 코어가 탄소, 붕소, 또는 탄화실리콘으로 구성된 섬유.The fiber of claim 1 wherein said core consists of carbon, boron, or silicon carbide. 제1항에 있어서, 상기 코어가 탄소 파리브 릴로 구성된 섬유.The fiber of claim 1 wherein said core consists of carbon parryl. 제9항에 있어서, 기계적 방법으로 코팅을 제거하여 제거된 코팅내면상에 파이브릴면이 복사되어 있는 섬유.10. The fiber of claim 9 wherein the fibril face is copied on the inner surface of the coating removed by mechanical removal of the coating. 제1항에 있어서, 상기 금속 코팅이 분리되거나 손실됨이 없이 매듭을 지을 수 있는 토우 또는 얀.The tow or yarn of claim 1, wherein the metal coating can be knotted without separation or loss. 제1항에 있어서, 얀단독으로부터 또는 다른 물질로 된 얀과 혼합하여 짜거나 뜬 직물.2. The fabric of claim 1 wherein the fabric is woven or knitted from yarn alone or in admixture with a yarn of another material. 제1항에 있어서, 얀을 단독으로 또는 다른 물질로 된 얀과 혼합하여 적층한 부직포시트..A nonwoven sheet according to claim 1, wherein the yarns are laminated alone or by mixing with yarns of different materials. 제1항에 있어서 얀단독 또는 다른 물질로 된 얀과 혼합된 얀으로 구성된 매트를 짜거나 뜨거나 적층하여 만든 입체적 제품.The three-dimensional article of claim 1 made by weaving, knitting, or laminating a mat composed of yarn alone or a yarn mixed with a yarn of other material. 제1항에 있어서, 절단된치된 얀 또는 토우로 구성된 조성물.The composition of claim 1 consisting of a cleaved yarn or tow. 제1항에 있어서, 금속 또는 유기중합물질로 구성된 매트릭스에 배치된 얀 또는 토우로 구성된 조성물.The composition of claim 1 consisting of yarns or tows disposed in a matrix of metals or organopolymers. 제1항에 있어서 상기 금속이 니켈, 은, 아연, 동, 납, 비소, 카드뮴, 주석, 코발트, 금, 인디움, 이리디움, 철, 팔라디움, 백금, 텔루리움, 텅스텐 또는 그의 혼합물로 구성된 얀 또는 토우.The yarn of claim 1, wherein the metal comprises nickel, silver, zinc, copper, lead, arsenic, cadmium, tin, cobalt, gold, indium, iridium, iron, palladium, platinum, tellurium, tungsten or mixtures thereof. Or tow. (a) 다수의 전기 전도성 반금속 코어 섬유들을 길이로 연속으로 얻은 후, (b) 상기 섬유의 기장중 적어도 일부를 적어도 하나의 금속을 전착시킬 수 있는 욕중에 연속적으로 함침시키고, (c) 섬유와 욕사이에 외부 전압을 (i) 상기 섬유의 가장 내부에 있는 특정 금속을 해리하며 (ii) 해리된 금속이 밧데리 층을 통해 상기 섬유의 표면상에 균일하게 핵을 이루기에 충분한 만큼 과량 적용시킨 다음 (d) 상기 전압 및 결과 생성 된 전류를 상기 코어 상에 얇고, 균일하며 견고히 부착된 전해 침착 금속의 전기전도층이 생성되기에 충분한 시간동안 유지시켜 주며 상기층의 코어에 대한 결합강도가 금속의 장력강도의10%보다 적지 않은 것으로구성된 고강도 조성섬유로된 연속 얀 또는 토우의 제조 방법.(a) obtaining a plurality of electrically conductive semimetal core fibers continuously in length, then (b) at least a portion of the length of the fiber is continuously impregnated in a bath capable of electrodepositing at least one metal, and (c) fibers An external voltage is applied between the bath and the bath (i) to dissociate the specific metal at the innermost of the fiber and (ii) to the extent that the dissociated metal is sufficiently nucleated on the surface of the fiber through the battery layer. (D) maintaining the voltage and the resulting current for a time sufficient to produce an electrically conductive layer of thin, uniform and firmly deposited electrolytically deposited metal on the core and the bond strength to the core of the layer A process for the production of continuous yarns or tows of high strength composition fibers composed of not less than 10% of the tensile strength of the fiber. 제18항에 있어서, 상기 섬유의 대부분에서 상기 코어에 대한 상기층의 결합강도가 적어도 조성섬유를 심하게 구부려 굴곡된 신장면상의 코팅이 그의 탄성치를 초과하여 부서질 정도 충분히 굴곡되었을 때구부린 압축면상의 코팅이 코어에 결합된 채 남아 원주상으로 균열되지 않기에 충분한 강도를 가진 방법.19. The compressive surface according to claim 18, wherein in most of the fibers the bond strength of the layer to the core is at least bent to a degree that the coating on the elongated surface that bends the composition fiber severely and flexes to exceed its elastic value is broken enough to break. A method having sufficient strength that the coating remains bonded to the core and does not crack circumferentially. 제18항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 25%보다 실질적으로 적지 않은 방법.19. The method of claim 18, wherein the bond strength is substantially less than about 25% of the tensile strength. 제18항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 50%보다 실질적으로 적지 않은 방법.19. The method of claim 18, wherein the bond strength is substantially less than about 50% of the tensile strength. 제18항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 90%보다 실질적으로 적지 않은 방법.19. The method of claim 18, wherein the bond strength is substantially less than about 90% of the tensile strength. 제18항에 있어서, 상기 결합 강도가 상기 장력 강도의 약 99%보다 실질적으로 적지 않은 방법.19. The method of claim 18, wherein the bond strength is substantially less than about 99% of the tensile strength. 제18항에 있어서, 상기 금속이 결정성인 방법.The method of claim 18, wherein the metal is crystalline. 제18항에 있어서, 상기 코어섬유가 탄소, 붕소 또는 탄화실리콘으로 구성된 방법.19. The method of claim 18, wherein the core fibers are comprised of carbon, boron, or silicon carbide. 제18항에 있어서, 상기 코어섬유가 탄소파이브릴로 구성된 방법.19. The method of claim 18, wherein the core fibers consist of carbon fibrils. 제18항에 있어서, 방법의 생성물이 코어섬유로부터 금속층 또는 그 일부를 분리함이 없이 매듭지을수 있는 조성섬유로 된 토우 또는 얀인 방법.19. The method of claim 18, wherein the product of the method is a tow or yarn of composition fibers that can be knotted without separating a metal layer or portions thereof from the core fibers. 제18항에 있어서, 본 방법에 의해서 제조된 얀을 단독으로 또는 다른물질로 돤 얀과 함께 직물로짜거나 또는 단계를 포함한 방법.19. The method according to claim 18, wherein the yarns produced by the process are woven or stepped together with the yarns, alone or in combination with other materials. 제18항에 있어서, 본 방법에 의해서 제조된 얀을 단독으로 또는 다른 물질로 된 얀과 함께 부직포시트로 적층하는 단계를 포함한 방법.19. The method of claim 18, comprising laminating the yarns produced by the method, either alone or together with yarns of other materials. 제28항 또는 제29항에 있어서 물질을 입체적 제품으로 짜거나 뜨거나 절단하는 단계를 포함한 방법.30. The method of claim 28 or 29 comprising squeezing, knitting or cutting the material into a three-dimensional product. 제18항에 있어서, 본 방법에 의해 제조된 얀을 짧은 길이로 절단하는 단계를 포함한 방법.19. The method of claim 18, comprising cutting the yarn made by the method to short lengths. 제28, 제29 또는 제30항중 어느 하나에서, 금속 또는 유기 중합물질을 상기 얀, 시트 또는 절단섬유의 최소 보강 유효량과 긴밀히 접촉시켜 보강된 조성물을 생성하는 단계를 포함한 방법.31. The method of any one of claims 28, 29 or 30, comprising contacting a metal or organic polymeric material in intimate contact with a minimum reinforcing effective amount of said yarn, sheet or chopped fiber to produce a reinforced composition. 제18항에 있어서, 욕을 재순환시켜 욕내 함침하기 직전에 얀 또는 토우와 접촉되게 하여 얀 또는 토우에 증가된 전류 전달능력을 제공하며 섬유 표면상에 전해질을 보충시키는 주도록 하는 것을 포함한 방법.19. The method of claim 18 comprising recycling the bath to bring it into contact with the yarn or tow just prior to impregnation to provide yarn or tow with increased current carrying capacity and to replenish the electrolyte on the fiber surface. 제18항의 방법에 의해 제조된 고강도 조성섬유로된 얀 또는 토우.Yarn or tow of high strength composition fibers made by the method of claim 18. 제33항의 방법에 의해 제조된 고강도 조성섬유로된 얀 또는 토우.Yarn or tow of high strength composition fibers made by the method of claim 33. 제32항의 방법에 의해 제조된 보강조성물.Reinforcement composition prepared by the method of claim 32. 제32항에 있어서, 얀, 시트 또는 절단섬유의 양이 적어도 정전차폐 보강 조성물을 제공하기에 충분한 보강된 조성물.33. The reinforced composition of claim 32, wherein the amount of yarn, sheet or cut fibers is sufficient to provide at least an electrostatic shielding composition. 제1항에서 있어서, 연속얀 또는 토우로부터 회수된 단섬유.The short fiber of claim 1 recovered from the continuous yarn or tow. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application. 전기 전도 반금속 코어와 상기 코어상에 적어도 하나의 전착 금속으로 된 얇고, 균일하여 견고히 부착된 적어도 하나의 전기 전도층을 가지며, 상기 코어에 대한 상기 금속의 결합 강도가 적어도 조성섬유를 심하게 구부려 굴곡된 신장면상의 코팅이 그의 탄성치를 초과하여 부서질 정도 충분히 굴곡되었을 때 구부린 압축면상의 코팅이 코어에 결합된채 남아 원주상으로 균열되지 않기에 충분한 강도를 가진 섬유.An electrically conductive semimetal core and at least one electrically conductive layer of at least one electrodeposited metal on the core, the thin and uniformly and firmly adhered electrically conductive layer, wherein the bond strength of the metal to the core is at least flexibly bending the composition fibers A fiber having sufficient strength not to be circumferentially cracked when the coating on the curved compression surface remains bonded to the core when the coated extension surface is bent enough to break beyond its elastic value. 전기 전도 반금속 코어와 코어상에 적어도 하나의 전착금속으로 된 얇고, 균일하여 견고히 부착된 적어도 하나의 전기 전도층을 가지며, 금속 코팅의 실질적인 분리 및 손실없이 매듭지을 수 있는 섬유.15. A fiber having an electrically conductive semimetal core and at least one electrically conductive layer of at least one electrodeposited metal on the core, the at least one electrically conductive layer being firmly attached and capable of being knotted without substantial separation and loss of the metal coating. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019830001033A 1982-03-16 1983-03-15 Yarns and tows comprising high strenght metal wated fibers,process for their production and articles made from that KR880000477B1 (en)

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US35863782A 1982-03-16 1982-03-16
US358637 1982-03-16

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IL67867A (en) * 1982-03-16 1987-10-30 Electro Metalloid Corp Yarns and tows comprising high strength metal coated fibers,process for their production and articles made therefrom
DE3482273D1 (en) * 1983-06-24 1990-06-21 American Cyanamid Co DEVICE AND METHOD FOR CONTINUOUSLY PLATING FIBERS.
DE3474841D1 (en) * 1983-06-24 1988-12-01 American Cyanamid Co Electrodes, electro-chemical cells containing said electrodes, and process for forming and utilizing such electrodes
EP0149763A3 (en) * 1983-11-29 1985-08-21 Toho Beslon Co., Ltd. Electroplating method for carbon fibers and apparatus therefor
FR2562101B1 (en) * 1984-03-27 1987-03-06 Brochier Sa MATERIAL BASED ON INORGANIC FIBERS, PARTICULARLY SILICON CARBIDE, FOR USE IN THE PRODUCTION OF COMPOSITE STRUCTURES
IL84284A (en) * 1986-10-31 1992-01-15 American Cyanamid Co Copper coated fibers
DE68900928D1 (en) * 1988-10-12 1992-04-09 Johnson Matthey Plc METAL FABRIC.
CA2125378A1 (en) * 1993-06-09 1994-12-10 James A. E. Bell Composition for lightning strike protection and improved electrical conductivity
JP2002180372A (en) * 2000-12-15 2002-06-26 Toho Tenax Co Ltd Carbon fiber coated with metal oxide and method for producing the same
JP7032348B2 (en) * 2019-03-26 2022-03-08 矢崎総業株式会社 Metal-plated carbon material and its manufacturing method

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GB1215002A (en) * 1967-02-02 1970-12-09 Courtaulds Ltd Coating carbon with metal
FR1535660A (en) * 1967-06-28 1968-08-09 Thomson Houston Comp Francaise Improvements in manufacturing processes for composite materials and products obtained
IL67867A (en) * 1982-03-16 1987-10-30 Electro Metalloid Corp Yarns and tows comprising high strength metal coated fibers,process for their production and articles made therefrom

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FI75876C (en) 1988-08-08
DK120683D0 (en) 1983-03-15
AU1245083A (en) 1983-09-22
ES8406576A1 (en) 1984-08-01
HK14491A (en) 1991-03-08
FI830854A0 (en) 1983-03-15
IL67867A (en) 1987-10-30
DK158159B (en) 1990-04-02
AU588991B2 (en) 1989-09-28
DK158159C (en) 1990-08-27
AU561667B2 (en) 1987-05-14
ES520574A0 (en) 1984-08-01
CA1256052A (en) 1989-06-20
FI830854L (en) 1983-09-17
NO830897L (en) 1983-09-19
EP0088884B1 (en) 1986-09-10
IN158302B (en) 1986-10-11
NO164996B (en) 1990-08-27
FI75876B (en) 1988-04-29
AR240342A1 (en) 1990-03-30
NO164996C (en) 1990-12-05
DK120683A (en) 1983-09-17
ATE22121T1 (en) 1986-09-15
EP0088884A1 (en) 1983-09-21
JPS58169532A (en) 1983-10-06
BR8301227A (en) 1983-11-22
DE3365941D1 (en) 1986-10-16
MX159077A (en) 1989-04-14
AU7108187A (en) 1987-07-23
IL67867A0 (en) 1983-06-15
KR880000477B1 (en) 1988-04-07

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