KR840001881B1 - Porous artificial stone - Google Patents

Porous artificial stone Download PDF

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KR840001881B1
KR840001881B1 KR8204800A KR820004800A KR840001881B1 KR 840001881 B1 KR840001881 B1 KR 840001881B1 KR 8204800 A KR8204800 A KR 8204800A KR 820004800 A KR820004800 A KR 820004800A KR 840001881 B1 KR840001881 B1 KR 840001881B1
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solution
water
concrete
foamed
added
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KR8204800A
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Korean (ko)
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KR840001937A (en
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서동우
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서동우
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/08Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/08Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/10Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam

Abstract

To mfr. porous and light weight concrete, saponin and sodium alginate (30-40 %) are put in water (60-70 %) and are allowed to rest for 5-10 hrs. 10 % Polizol (35%, 50-70 ≰C) and 2-4% Ca(OH)2 are added to the above aq. solution, which is agitated. A prepared porous solution, cement, sand, gypsum or fine-grained inorganic substance, or a porous plastic spherical body are mixed in the ratio of 0.5-1 : 1: 2-6 : 0.1-0.3 : 6-12 at 200-500 rpm. Lightweight aggregate used in porous and lightweight concrete is manufd. by mixing the above porous aq. solution 5-15%, water 5-15%, and formed plastics 70-90 %.

Description

기포경량콘크리이트의 제조법과 경량골재Manufacturing Method of Lightweight Concrete and Lightweight Aggregate

본 발명은 경량, 단열, 방음, 보온등에 이용되는 기포 경량 콘크리이트의 제조법과 이에 이용되는 경량골재에 관한 것이다. 보다 상세하게는 시포닌 및 알긴산소다등 해조류 접착제 및 동물성 단백질의 수용액에 가온 초기 반응시킨 포리졸을 주입하여 규산소다 또는 수산화칼슘을 첨가하여 제조된 접착력이 강한 기포성 액체와 물과 발포 프라스틱 구상 또는 파쇄체를 혼련하여 구성되는 기포 경량 콘크리이트용의 경량 골재와 상기 재료에 시멘트, 모래, 석고 또는 기타 무기질 세립을 혼련하여 제조하는 기포 경량 콘크리이트의 제조법에 관한 것이다.The present invention relates to a method for producing foamed lightweight concrete used for light weight, heat insulation, sound insulation, thermal insulation and the like, and a lightweight aggregate used therein. More specifically, a strong foaming liquid prepared by adding a sodium hydroxide or calcium hydroxide by injecting polyazole reacted with warm initial reaction into an aqueous solution of seaweed adhesives such as siponin and sodium alginate and animal protein, and water and foamed plastic spheres or shredders The present invention relates to a method for producing light weight aggregates for mixing light weight aggregates and kneading cement, sand, gypsum or other inorganic fine grains.

오늘날 고층아파트의 발달과 또한 대도시의 소음공해의 증대는 높은 방음 및 보온효과를 가지며 또한 경량인 건축재료의 개발을 열망하고 있는 실정이다.Today, the development of high-rise apartments and the increase of noise pollution in large cities have been eager for the development of lightweight building materials with high sound insulation and insulation effect.

본발명은 상기와 같은 요구에 효과적으로 적용될 수 있는 종래에 개발된 이 분야의 그 어느 건축재료도 충족할 수 없는 우수한 작용효과를 갖는 기포 경량 콘크리이트를 제공하는 것을 목적으로 한다.It is an object of the present invention to provide a foamed lightweight concrete having excellent working effects that cannot be met by any previously developed building material in this field that can be effectively applied to such a demand.

종래에 기포 경량 콘트리이트로서는 특허공고 번호 제 68-300호에 기재된 시멘트에 금속발포제와 포리초산비닐과 아크릴산 에스텔의 공중합물의 겔화제를 혼련하여 성형한 것이 기재되어 있으나, 이는 이와 같이 제조된 기포 콘크리이트는 비Conventionally, foam light weight concrete is formed by kneading a metal foaming agent and a gelling agent of a copolymer of vinyl polyacetate and acrylic acid ester in a cement described in Patent Publication No. 68-300. Concrete is rain

또한 특허공고번호 제73-56호에 제주산송이를 골재로한 경량콘크리이트는 발포 안정제인 아스팔트 유제와 20메슈의 제주산송이와 시멘트를 혼가후 30℃에서 방치 성형한 것이 게재되어 있으나, 이 역시 비중이 크고 또한 재료비가 고가가 되며, 또한 콘크리이트 자체에 기포 형성이 없음으로 방음, 방열, 보온효과 등이 떨어지는 결점을 가지게 된다.In addition, Patent Publication No. 73-56 discloses that lightweight concrete with aggregates from Jeju is made of asphalt emulsion, which is a foam stabilizer, and Jeju mushroom and cement of 20 mesh, which are left at 30 ° C after mixing. The specific gravity is high and the material cost is high, and since there is no bubble formation in the concrete itself, it has the disadvantage that sound insulation, heat dissipation, and heat insulation effect are inferior.

이외에 경량 골재로서 개발된 것에 탄광 폐석을 이용한 경량골재(공고번호 67-149), (80-1054) 구상 발포 프라스틱 표면에 토양을 코팅하거나, 또는 토양과 유사한 무기질 세립이나, 시멘트와 경화제를 첨가 교반하여 된 점주액을 코팅하여 성형한 경량 골재(공고번호 76-466), 석면을 이용한 경량 골재(공고번호 81-123) 발포 프라스틱 구상체와 중질유를 혼합 교반하여 건식 모르타르를 피착시켜 양생한 경량 골재(공고번호 80-1056)들이 개발되어 있으나, 이들 경량골재를 이용하여 경량 콘크리이트를 제조하게 되며는 기포 콘크리이트의 형성이 되지를 않는 관계상 비중이 1.4-0.7로 비교적 중량이 되며, 또한 발포 프라스틱구상체에 토양을 코팅한 경량골재를 골재로 사용하게 되며는 모르탈내에 이물질인 토양이 혼입되므로서, 강도가 약해지는 결점이 있고, 접착매개층인 점토질부분 때문에 탄열성과 경량성이 떨어지며, 발포 프라스틱 구상체에 중질유를 코팅한 것등은 중질유동 재료비의 고가로 인하여 생산원가가 높아질뿐 아니라, 구상체 표막에 불균형한 표막층이 도포In addition, lightweight aggregates using coal mine waste-rock (Gob No. 67-149) and (80-1054) were developed as lightweight aggregates, or the soil was coated on the surface of spherical foam plastics, or the soil-like mineral fine grains or cement and hardener were added and stirred. Light weight aggregate (column No. 76-466) formed by coating the immersion liquid, and light weight aggregate using the asbestos (Got No. 81-123). Lightweight aggregate cured by depositing dry mortar by mixing and mixing foamed plastic spheroid and heavy oil (Notice 80-1056) has been developed, but the lightweight concrete is manufactured using these lightweight aggregates, and the specific gravity is 1.4-0.7, which is relatively heavy due to the fact that foamed concrete is not formed, and also foamed. The lightweight aggregate coated with soil on the plastic spherical body is used as the aggregate. So, the soil, which is a foreign substance in the mortar, is weakened. Due to the clay layer, which is an intermediate layer, elasticity and light weight are inferior, and the coating of heavy oil on the foamed plastic spheroid not only increases the production cost due to the high cost of heavy fluid materials, but also applies an unbalanced surface layer on the globular surface.

또한 석면을 이용한 경량골재를 사용하게 되며는 콘크리이트 비중도 높아지며, 또한 콘크리이트 강도도 비교적 약해지고 생산원가도 높아지는 결점등을 가진다.In addition, the use of asbestos-based lightweight aggregates increases the specific gravity of concrete, and also has the disadvantage that the concrete strength is relatively weak and the production cost is high.

또한 이들 경량 골재를 이용하여 기포 콘크리이트를 제조하게 되며는 강도가 더욱 떨어지므로서 실용적 가치가 없어지며, 별도로 기포제를 첨가해야 하므로 공정상으로도 불편한 폐단을 가지게 된다.In addition, the foam concrete is manufactured using these lightweight aggregates, and the strength is further lowered, thus the practical value is lost, and since the foaming agent must be added separately, the process has an inconvenient closure.

본 고안은 상기와 같은 종래의 여러가지 단점을 제거하여 제조된 경량 콘크리이트와 이에 사용되는 경량골재에 관한 것이며, 경량 콘크리이트의 비중이 불과 0.6-0.4 밖에 되지 않으면서도 강도면에서도 상기 여러가지 종래 기술에 의한 경량 콘크리이트에 비하여 떨어지지 않으며, 또한 원가가 파격적으로 저렴한 기포 경량 콘크리이트를 제공하게 되며, 또한 제조공정이 매우 간편하여 시공에 있어서도 극히 편리한 기포 경량 콘크리이트를 제공하게 되고, 또한 시멘트 초결 시간이 단축되며, 방음성, 단열성, 보온성이 극히 우수한 기포 경량 콘크리이트를 제공하게되어 다층 아파트나 연립주택 기타의 온돌바닥 재료로나, 벽체 칸막이 재료로서 극히 우수한 성능을 갖는 기포 경량 콘크리이트를 제공하게 된다.The present invention relates to a lightweight concrete prepared by removing various disadvantages of the related art as described above, and a lightweight aggregate used therein, and the specific gravity of the lightweight concrete is only 0.6-0.4, but in terms of strength, Compared to lightweight concrete, it is not dropped, and the cost is exceptionally low-cost foam lightweight concrete, and the manufacturing process is very simple to provide a very convenient foam lightweight concrete for construction, and also cement cement time It is shortened, and provides excellent foam lightweight concrete with excellent sound insulation, insulation, and heat insulation, thereby providing foam lightweight concrete having extremely excellent performance as a floor partition material or a wall partition material of a multilayer apartment or a town house.

본 발명의 기포 경량콘크리이트와 경량 골재는 아래와 같이 제조된다.Foam lightweight concrete and lightweight aggregate of the present invention is prepared as follows.

먼저 알긴산소다 및 사모닌 분말등 점착성 물질 30-40%을 물 60% 내지 70% 속에 넣어 용액을 만든다. 이것을 5-10시간 이상 방치 하므로서 완전히 용해 되도록 한다.First, 30-40% of the adhesive substance such as sodium alginate and samonine powder is added to 60% to 70% of water to make a solution. Allow it to dissolve for 5-10 hours or more.

다음에 35% 포리졸을 약 50℃-70℃로 가온하여 초기 반응이 나타나게 되며는 상기 수용액속에 포리졸 약 10%를 주가하여 이를 교반하고 다시 규산소다 또는 수산화칼슘 약 2-4%를 첨가하여 잘 혼합하게 되며는 본 발명의 접착력이 뛰어난 기포성 용액이 완성된다.Next, the initial reaction occurs by heating the 35% polyazole to about 50 ° C.-70 ° C., adding about 10% of the polyazole to the aqueous solution, stirring the mixture, and adding about 2-4% of sodium silicate or calcium hydroxide. By mixing, a foamable solution having excellent adhesion of the present invention is completed.

여기에 상기 알긴산소다 대신 CMC를 사용할 수도 있다. CMC를 사용할때에는 물과 CMC의 비율을 약 90:10로 하는 것이 좋다.CMC may be used instead of the sodium alginate. When using CMC, the ratio of water and CMC should be about 90:10.

이와같이 제조된 기포성용액은 장시간 저장하여 두고 사용할 수 있게 된다.The foamed solution prepared in this way can be stored and used for a long time.

상기와 같이 제조된 기포성용액에 시멘트와 모래와 약간의 석고 또는 무기질 세립과 스치로폴 구상체 또는 스치로폴 파쇄품과 물을 소정의 비율을 믹서내에 투입하여 200-500RPm의 속도내에서 혼련하여 주형이나 기타 소요의 곳에 주입하게 되며는 본 발명의 기포성 경량 콘크리이트를 얻게 된다.Cement, sand, some gypsum or mineral fine granules, Schiropol spheroids or Schiropol crushed products and water are mixed into the foamed solution prepared as described above in a mixer and kneaded at a speed of 200-500 RPM to form a mold or other necessary materials. When injected into the to obtain a foamable lightweight concrete of the present invention.

이때 시멘트와 물의 비율은 대략 1:0.7-1.2물과 기포성 용액의 비율은 대략 1:6-10이 되는 범위로 하며, 시멘트:모래:스치로폴의 비율은 일반적으로 1:2-6:6-12로 혼합하면 된다.At this time, the ratio of cement and water is about 1: 0.7-1.2, and the ratio of water and foaming solution is about 1: 6-10, and the ratio of cement: sand: schiropol is generally 1: 2-6: 6-12. Mix with

또한 상기와 같은 기포 경량콘크리이트 제조방법에 있어서 스치로폴 구상체액 같은 발포 프라스틱 구상체와 상기 기포성 용액과 약간의 물을 믹서내에 투입하여 믹싱하므로서, 제조한 기포 경량콘크리이트용 골재를 사전에 제조하여 시멘트와 모래와 약간의 석고 또는 무기질 세립과 상기와 같이 제조된 기포 경량콘크리이트용 골재와 물의 소정량을 믹서내에 투입하여 혼련한 다음 주형이나 소정의 장소에 주입하게 되며는 본 발명의 기포 경량 콘크리이트를 얻게 된다.In addition, in the above-mentioned method for manufacturing light-weight foam concrete, foamed plastic spherical bodies such as Schiropol spheroidal liquid, the foaming solution and some water are mixed in a mixer, and the foamed lightweight concrete aggregate is manufactured in advance to prepare cement and cement. Sand and some gypsum or inorganic fine granules and the above-mentioned aggregates for foam lightweight concrete and water prepared as described above are introduced into a mixer, kneaded, and then injected into a mold or a predetermined place to obtain the foam lightweight concrete of the present invention. do.

이때 발포 프라스틱 구상체와 약간의 물을 혼합한 기포성 용액의 비율은 대략 8:0.5-1.5로 한다.At this time, the ratio of the foamed solution in which the expanded plastic sphere and some water are mixed is approximately 8: 0.5-1.5.

즉 예를들어 발포 프라스틱 구상체 또는 파쇠물 약 80ℓ에 기포성 용액 0.5ℓ와 물 0.5ℓ 정도를 혼합한 것을 믹서내에서 믹싱하게 되며는 기포 경량 콘크리이트용 골재를 얻게된다. 그리고 콘크리이트 제조시의 시멘트와 모래와 상기 기포 경량골재의 혼합비는 대략 1:2-6:6-12의 비율로 하게 된다.That is, for example, a mixture of about 0.5 liter of a foaming solution and about 0.5 liter of water in a foamed plastic spherical body or about 80 liters of crushed material is mixed in a mixer to obtain an aggregate for foaming lightweight concrete. And the mixing ratio of cement and sand and the foam light aggregate in the production of concrete is about 1: 2-6: 6-12 ratio.

이와같은 방법으로 제조된 기포경량 콘크리이트는 내부에 균일하며 미세한 기공들이 형성되며, 또한 발포 프라스틱 구상체가 균등하게 분포되므로서, 아주 양질의 기포 경량콘크리이트를 얻을 수 있을 뿐만 아니라, 아주 양호한 강도를 가지는 비중이 0.6-0.4밖에 되지 않는 초경량 기포 콘크리이트를 얻게 된다.The foamed lightweight concrete prepared in this way is uniform and fine pores are formed therein, and the foamed plastic spherical body is evenly distributed, so that it is possible to obtain very good foam and lightweight concrete, and has a very good strength. Ultra-light foam concrete with specific gravity of only 0.6-0.4 is obtained.

이로서 종래에 기포 콘크리이트내에 발포 프라스틱 구상체를 골재로 하여 콘크리이트의 제조를 시도할시에 문제가 되었던 정전기에 의한 프라스틱 구상체의 집합현상이나 가벼운 비중에 기인하여 믹서에서의 혼련시 생기는 재료 분리현상을 극복한 우수한 기포 경량 콘크리이트를 얻을 수 있게 되며, 상기한 여러가지 목적물을 달성할 수 있게 된다.As a result, the separation of materials generated during kneading in a mixer due to the aggregation phenomenon or the light specific gravity of the plastic spherical body caused by static electricity, which has been a problem when attempting to manufacture the concrete using foamed plastic spherical aggregates in aerated concrete It is possible to obtain excellent foam lightweight concrete overcoming the phenomenon, and to achieve the various objects described above.

또한 본 발명에 있어서 금속 분말 기포제인 알미늄 분말, 아연 분말, 마그네슘 분말 등을 표면 활성재인 포리초산등으로 처리하여 발포 프라스틱의 코오팅재로 사용할 수도 있다.In the present invention, aluminum powder, zinc powder, magnesium powder, etc., which are metal powder foaming agents, may be treated with polyacetic acid, which is a surface active material, and used as a coating material for foamed plastics.

Claims (2)

사포린 및 알긴산소다 30% 내지 40%를 물 60% 내지 70%에 투입하여 5-10시간 방치하여 용해시킨 수용액을 만들고 다음에 35% 포리졸을 약 50℃ 내지 70℃로 가온하여 초기 반응이 나타날때 상기 수요액속에 약 10% 정도가 되도록 주가하여 교반하고 수산화칼슘 약 2 내지 4%를 첨가하여 기포성 용액을 제조하는 단계와, 상기 제조된 기포성용액과 시멘트와 모래와 약간의 석고 또는 무기질 세립과 발포 프래스틱 구상체 또는 파쇠품과 물을 시멘트:모래:석고:발포 프라스틱 구상체:기포성용액:물의 비율이 대략 1:2-6:0.1~0.3:6-12:0.5-1:0,5 -1의 비율로 200 내지 500RPM의 속도로 믹싱하여 콘크리이트를 제조하는 단계로 구성되는 것이 특징인 기포 경량콘크리이트 제조 방법.30% to 40% of saporin and sodium alginate were added to 60% to 70% of water, and left for 5-10 hours to form an aqueous solution. Then, 35% of the polyazole was heated to about 50 ° C to 70 ° C. When appearing, the mixture was stirred to add about 10% to the demanded liquid and added about 2 to 4% of calcium hydroxide to prepare a foamed solution, and the prepared foamed solution, cement, sand, some gypsum or inorganic fine granules, and foaming. Plastic globular or crushed water and cement: sand: gypsum: foamed plastic globular: foaming solution: water ratio of about 1: 2-6: 0.1 ~ 0.3: 6-12: 0.5-1: 0,5- Method for producing light-weight concrete foam, characterized in that consisting of the step of producing concrete by mixing at a rate of 200 to 500 RPM at a ratio of 1. 사포닌 및 알긴산소다 30% 내지 40%를 물 60% 내지 70%에 투입하여 5-10시간 방치하여 용해시켜 수용액을 만들고 다음에 35% 포리졸을 약 50℃ 내지 70℃로 가온하여 초기 반응이 나타날때 상기 수용액 속에 약 10%가 되도록 주가하여 교반하고 수산화칼슘 약 2 내지 4%를 첨가하여 제조된 기포성 수용액 약 5 내지 15%와 물 약 5 내지 15%와 발포 프라스틱 구상체 또는 파쇠체 약 70-90%를 믹싱하여 제조된 기포 경량콘크리이트용 경량 골재.30% to 40% of saponin and sodium alginate were added to 60% to 70% of water, left for 5-10 hours to dissolve to form an aqueous solution. Then, 35% of the polyazole was heated to about 50 ° C to 70 ° C to give an initial reaction. When the mixture is added to the solution in an amount of about 10%, the mixture is stirred, and about 2 to 4% of calcium hydroxide is added. About 5 to 15% of the foamed aqueous solution, about 5 to 15% of water, and about 70 to 90 of foamed plastic spheres or breakers Lightweight aggregate for foam lightweight concrete manufactured by mixing%.
KR8204800A 1982-10-26 1982-10-26 Porous artificial stone KR840001881B1 (en)

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