KR830007132A - 혼합인 자원을 사용한 유동성 바나듐인 산화물 촉매의 제조 - Google Patents
혼합인 자원을 사용한 유동성 바나듐인 산화물 촉매의 제조 Download PDFInfo
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- KR830007132A KR830007132A KR1019810005270A KR810005270A KR830007132A KR 830007132 A KR830007132 A KR 830007132A KR 1019810005270 A KR1019810005270 A KR 1019810005270A KR 810005270 A KR810005270 A KR 810005270A KR 830007132 A KR830007132 A KR 830007132A
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- Prior art keywords
- vanadium
- catalyst
- weight percent
- catalyst precursor
- microspherical
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- 239000003054 catalyst Substances 0.000 title claims 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims 6
- 229910052698 phosphorus Inorganic materials 0.000 title claims 6
- 239000011574 phosphorus Substances 0.000 title claims 6
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 title 1
- 229910001935 vanadium oxide Inorganic materials 0.000 title 1
- 238000000034 method Methods 0.000 claims 29
- 229910052720 vanadium Inorganic materials 0.000 claims 20
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 20
- 239000002245 particle Substances 0.000 claims 14
- 239000012018 catalyst precursor Substances 0.000 claims 13
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 10
- 239000007788 liquid Substances 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 7
- 239000002002 slurry Substances 0.000 claims 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 7
- 238000007254 oxidation reaction Methods 0.000 claims 6
- 238000010298 pulverizing process Methods 0.000 claims 6
- 230000003647 oxidation Effects 0.000 claims 5
- 235000011007 phosphoric acid Nutrition 0.000 claims 5
- 238000001354 calcination Methods 0.000 claims 4
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims 4
- 229940005657 pyrophosphoric acid Drugs 0.000 claims 4
- 229910052770 Uranium Inorganic materials 0.000 claims 3
- 230000009969 flowable effect Effects 0.000 claims 3
- 229910052735 hafnium Inorganic materials 0.000 claims 3
- 229910052742 iron Inorganic materials 0.000 claims 3
- 229910052750 molybdenum Inorganic materials 0.000 claims 3
- 238000001694 spray drying Methods 0.000 claims 3
- 239000001226 triphosphate Substances 0.000 claims 3
- 235000011178 triphosphate Nutrition 0.000 claims 3
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims 3
- 150000003682 vanadium compounds Chemical class 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- 229910052726 zirconium Inorganic materials 0.000 claims 3
- 150000008064 anhydrides Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 239000012530 fluid Substances 0.000 claims 2
- 239000004005 microsphere Substances 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- -1 carbon hydrocarbons Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/60—Two oxygen atoms, e.g. succinic anhydride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Furan Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (35)
- 적어도 하나의 5원자 바나듐 화합물을 적어도 바나듐의 일부를 +4의 원자가 상태로 환원시킬 수 있는 유기액체 속에 놓고 적어도 바나듐 일부를 +4의 원자가 상태로 환원시키며, 바나듐을 상기 환원전 또는 후에 약 75 내지 90중량포센트의 오르토인산 및 약 10 내지 25중량퍼센트의 피로인상으로 구성된 혼합인 성분에 접촉시켜 얻어진 촉매 전구물을 분쇄시키고 촉매 전구물을 상기 분쇄전 또는 후에 물속에 넣어 수성 슬러리를 형성시키고 상기 슬러리를 분무건조하여 미세구형 촉매입자를 형성시킴을 특징으로 하여 바나듐과 인의 혼합 산화물을 함유한 유동상 산화촉매를 제조하는 방법.
- 제1항에 있어서, 미세구형 촉매입자를 하소시키는 단계를 첨부시킴이 특징인 방법.
- 제1항에 있어서, 상기 혼합인 성분이 약 80 내지 90중량퍼센트의 오르토인산, 약 10 내지 20중량퍼센트의 피로인산 및 0 내지 3중량포센트의 트리인산으로 구성되어 있음이 특징인 방법.
- 제1항에 있어서, 상기한 유기액체가 본래 무수물임이 특징인 방법.
- 제1항에 있어서 액채매체를 함유한 바나듐을 가열시켜 상기한 바나듐의 환원을 실행함이 특징인 방법.
- 제1항에 있어서 상기한 혼합인 자원에 5중량퍼센트까지 트리인산이 부가되어 구성되어 있음이 특징인 방법.
- 제1항에 있어서, 상기 촉매가 U,Co,Mo,Fe,Zn,Hf,Zr 및 이들의 혼합물로 구성된 그룹에서부터 선택된 촉진원소를 더 함유함이 특징인 방법.
- 제1항에 있어서, 상기 촉매 전구물을 물에 넣기 전에 충분히 건조시킴이 특징인 방법.
- 제1항에 있어서 상기 촉매 전구물의 대부분을 평균 직경 약 1미크론 이하의 입자크기로 분쇄함이 특징인 방법.
- 제1항에 있어서 상기 수성 슬러리에의 고체함량은 약 25 내지 약60중량퍼센트임이 특징인 방법.
- 제1항에 있어서 상기 미세구형입자의 대부분이 300미트론 이하의 입자크기를 가짐이 특징인 방법.
- 제1항에 있어서 상기 미세구형입자의 대부분이 약 20미크론 내지 약 240미크론의 입자 크기를 가짐이 특징인 방법.
- 제1항에 있어서 혼합인 성분의 존재하에서 상기 바나듐 환원을 실행함이 특징인 방법.
- 적어도 하나의 5원자가 바나듐 화합물을 적어도 바나듐의 일부를 +4의 원자가 상태로 환원시킬 수 있는 유기액체 속에 넣고 적어도 바나듐 일부를 +4의 원자가 상태로 환원시키며 바나듐을 상기 환원전 또는 후에 약 75 내지 90중량퍼센트의 오르토인산 및 약 10 내지 25중량퍼센트의 피로인산으로 구성된 혼합인 성분에 접촉시켜 얻어진 촉매전구물을 분쇄시키고 촉매전구물을 상기 분쇄전 또는 후에 물속에 넣어 수성 슬러리를 형성시키고 상기 슬러리를 분무 건조하여 미세구형 촉매입자로 형성시켜 제조된 바나듐 및 인의 혼합 산화물을 함유한 미세구형 유동성 촉매 존재하에서 반응온도는 약 250℃ 내지 600℃로 하여 유체상 반응기에서 분자상의 산소 또는 산소함유 개스로 4-탄소 탄화수소류를 산화시켜 말레산 무수물을 생성시키는 방법.
- 제14항에 있어서, 미세구형 촉매입자를 하소시키는 단계를 첨부시킴이 특징인 방법.
- 제14항에 있어서 상기 혼합인 성분이 약 80 내지 90중량퍼센트의 오르토인산, 약 10 내지 20중량퍼센트의 피로인산 및 0 내지 3중량퍼센트의 트리인산으로 구성되어 있음이 특징인 방법.
- 제14항에 있어서 상기한 유기액체가 본래 무수물임이 특징인 방법.
- 제14항에 있어서 액체매체를 함유한 바나듐을 가열시켜 상기한 바나듐의 환원을 실행함이 특징인 방법.
- 제14항에 있어서 상기한 혼합인 자원에 5중량퍼센트까지의 트리인산이 부가되어 구성되어 있음이 특징인 방법.
- 제14항에 있어서 상기 촉매가 U,Co,Mo,Fe,Zn,Hf,Zr 및 이들의 혼합물로 구성된 그룹에서부터 선택된 촉진원소를 더 함유함이 특징인 방법.
- 제14항에 있어서, 상기 촉매 전구물을 물에 넣기전에 충분히 건조시킴이 특징인 방법.
- 제14항에 있어서 상기 촉매 전구물의 대부분을 평균 직경 약 1미크론 이하의 입자 크기로 분쇄함이 특징인 방법.
- 제14항에 있어서, 상기 수성 슬러리에 고체함량은 약 25 내지 약 60중량퍼센트임이 특징인 방법.
- 제14항에 있어서, 상기 미세구형입자의 대부분이 300미크론 이하의 입자크기를 가짐이 특징인 방법.
- 제14항에 있어서, 상기 미세구형 입자의 대부분이 약 20미크론 내지 약240미크론의 입자크기를 가짐이 특징인 방법.
- 제14항에 있어서, 혼합인 성분의 존재하에서 상기 바나듐 환원을 실행함이 특징인 방법.
- 제14항에 있어서, n-부탄을 반응시킴이 특징인 방법.
- 제14항에 있어서, 상기 산화반응이 1기압 이상의 반응기 압력하에서 일어남이 특징인 방법.
- 제14항에 있어서, 상기 반응 온도가 약 325℃ 내지 500℃임이 특징인 방법.
- 적어도 하나의 5원자가 바나듐 화합물을 적어도 바나듐의 일부를 +4의 원자가 상태로 환원시킬 수 있는 유기액체 속에 넣고 적어도 바나듐 일부를 +4의 원자가 상태로 환원시키며 바나듐을 상기 환원전 또는 후에 약 75 내지 90중량퍼센트의 오르토인산 및 약 10 내지 25중량퍼센트의 피로인산으로 구성된 혼합인성분에 접촉시켜 얻어진 촉매 전구물을 분쇄시키고 촉매 전구물을 상기 분쇄전 또는 후에 물속에 넣어 수성 슬러리를 형성시키고 상기 슬러리를 분무 건조하여 미세구형 촉매 입자 형성시켜 제조한 것으로 바나듐의 평균 원자가가 약 +3.5 내지 약 +4.6이고 인 : 바나듐의 비율이 약 0.5:1 내지 3:1임을 특징으로 하는 바나듐 및 인의 혼합 산화물로 구성된 유동성 산화촉매.
- 제30항에 있어서, 상기 촉매가 U,Co,Mo,Fe,Zn,Hf,Zr 및 그의 혼합물로 구성된 그룹중에서 선택된 촉진원소를 추가로 함유함을 특징으로하는 유동성 산화촉매.
- 제30항에 있어서, 상기 촉매 전구물질이 유기액체 슬러리 중에서 제조됨을 특징으로 하는 유동성 산화촉매.
- 제30항에 있어서, 상기 미세구형입자의 대부분이 300미크론 이하의 평균 직경을 가짐을 특징으로 하는 유동성 산화촉매.
- 제1항에 있어서, 상기 촉매전구물을 하소시키기 전에 물을 도입시킴이 특징인 방법.
- 제14항에 있어서, 상기 촉매전구물을 하소시키기 전에 물을 도입시킴이 특징인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US220624 | 1980-12-29 | ||
US06/220,624 US4317778A (en) | 1980-12-29 | 1980-12-29 | Preparation of maleic anhydride using fluidized catalysts |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830007132A true KR830007132A (ko) | 1983-10-14 |
KR880001212B1 KR880001212B1 (ko) | 1988-07-11 |
Family
ID=22824293
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019810005270A KR880001212B1 (ko) | 1980-12-29 | 1981-12-28 | 바나듐과 인의 혼합산화물을 함유하는 유동상 산화 촉매의 제조방법 |
Country Status (10)
Country | Link |
---|---|
US (1) | US4317778A (ko) |
EP (1) | EP0056901B1 (ko) |
JP (1) | JPS57132550A (ko) |
KR (1) | KR880001212B1 (ko) |
BR (1) | BR8108412A (ko) |
CA (1) | CA1172234A (ko) |
DE (1) | DE3170443D1 (ko) |
ES (2) | ES8800071A1 (ko) |
MX (1) | MX159330A (ko) |
PT (1) | PT74206B (ko) |
Families Citing this family (39)
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FR2486094B1 (ko) * | 1980-07-02 | 1985-03-22 | Catalyse Soc Prod Francais | |
US4374043A (en) * | 1980-12-29 | 1983-02-15 | The Standard Oil Company | Preparation of fluidizable vanadium phosphorus oxide catalysts using a mixed phosphorus source |
US4392986A (en) * | 1981-10-08 | 1983-07-12 | Exxon Research & Engineering Co. | Catalyst for carboxylic anhydride production |
US4517371A (en) * | 1981-12-02 | 1985-05-14 | Exxon Research & Engineering Co. | Process for the synthesis of carboxylic anhydrides using a vanadium, phosphorus oxygen containing catalyst composition |
EP0094938B1 (en) * | 1981-12-02 | 1987-09-16 | Exxon Research And Engineering Company | Catalyst carboxylic anhydride production |
ATE69396T1 (de) * | 1982-06-29 | 1991-11-15 | Ici Plc | Herstellung von katalysatoren. |
CA1197230A (en) * | 1982-06-30 | 1985-11-26 | Dennis E. Dria | Preparation of improved mixed vanadium phosphorus oxide catalysts and their use in oxidation processes |
US4569925A (en) * | 1982-07-01 | 1986-02-11 | Exxon Research & Engineering Co. | Process for preparing a vanadium phosphorus oxygen catalyst composition by an organic solution method |
CA1197229A (en) * | 1982-09-23 | 1985-11-26 | Patricia R. Blum | Attrition resistant microspheroidal fluid bed catalysts containing the mixed oxides of vanadium and phosphorus |
US4525471A (en) * | 1982-09-23 | 1985-06-25 | The Standard Oil Company | Attrition resistant microspheroidal fluid bed catalysts containing the mixed oxides of vanadium and phosphorus |
US4518523A (en) * | 1983-03-04 | 1985-05-21 | The Standard Oil Company | Method for adding make-up fluid bed oxidation catalysts for fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus |
US4510258A (en) * | 1983-08-17 | 1985-04-09 | The Lummus Company | Catalysts containing mixed oxides of vanadium and phosphorus |
US4511670A (en) * | 1983-08-17 | 1985-04-16 | The Lummus Company | Catalysts containing mixed oxides of vanadium, phosphorus, and aluminum and/or boron |
US4652543A (en) * | 1983-09-30 | 1987-03-24 | Standard Oil Company (Indiana) | Catalysts useful for the manufacture of maleic anhydride having a characteristic X-ray diffraction pattern |
US4699895A (en) * | 1983-09-30 | 1987-10-13 | Standard Oil Company (Indiana) | Process for the manufacture of catalysts for the production of maleic anhydride |
US4528280A (en) * | 1983-12-28 | 1985-07-09 | Monsanto Company | Process for preparing phosphorus-vanadium mixed oxide catalysts |
IN164007B (ko) * | 1984-09-04 | 1988-12-24 | Halcon Sd Group Inc | |
US4668802A (en) * | 1985-01-18 | 1987-05-26 | E. I. Du Pont De Nemours And Company | Improved vapor phase catalytic oxidation of butane to maleic anhydride |
US5021588A (en) * | 1985-01-18 | 1991-06-04 | E.I. Du Pont De Nemours And Company | Vapor phase catalytic oxidation of butane to maleic anhydride |
US4670415A (en) * | 1985-10-28 | 1987-06-02 | Monsanto Company | Process for the preparation of iron/lithium -promoted catalysts for the production of maleic anhydride |
US4632915A (en) * | 1985-10-28 | 1986-12-30 | Monsanto Company | Iron/lithium--promoted catalysts for the production of maleic anhydride |
US4677084A (en) * | 1985-11-27 | 1987-06-30 | E. I. Du Pont De Nemours And Company | Attrition resistant catalysts, catalyst precursors and catalyst supports and process for preparing same |
JPH0395068A (ja) * | 1989-09-04 | 1991-04-19 | Tokyo Electric Co Ltd | ラベルプリンタ |
JPH0393577A (ja) * | 1989-09-06 | 1991-04-18 | Tokyo Electric Co Ltd | プリンタ |
US5155235A (en) * | 1990-07-12 | 1992-10-13 | Mitsui Toatsu Chemicals, Inc. | Catalyst for producing maleic anhydride from butane and process for preparing same |
TW290477B (ko) * | 1992-12-18 | 1996-11-11 | Amoco Corp | |
US5348927A (en) * | 1993-03-01 | 1994-09-20 | Scientific Design Company, Inc. | Treatment for virgin phosphorous/vanadium oxidation catalysts |
US5530144A (en) * | 1993-12-22 | 1996-06-25 | Mitsubishi Chemical Corporation | Process for producing a phosphorus-vanadium oxide catalyst precursor, process for producing a phosphorus-vanadium oxide catalyst, and process for producing maleic anhydride by vapor phase oxidation using the catalyst |
US5474960A (en) | 1994-06-15 | 1995-12-12 | The Standard Oil Company | Process for reactivating a fluid bed catalyst in a reactor dipley |
BE1012101A6 (fr) * | 1998-06-23 | 2000-05-02 | Pantochim Sa | Procede de conversion a haut rendement de n-butane en anhydride maleique par recyclage des gaz uses. |
US6107238A (en) * | 1998-09-30 | 2000-08-22 | E. I. Du Pont De Nemours And Company | Process for manufacture and use of improved attrition resistant catalyst |
US6313061B1 (en) | 1998-12-22 | 2001-11-06 | W. R. Grace & Co.-Conn. | Method of making frangible spray dried agglomerated supports and olefin polymerization catalysts supported thereon |
US6878668B1 (en) * | 1999-07-14 | 2005-04-12 | E. I. Du Pont De Nemours And Company | Process for manufacture of an attrition resistant catalyst |
DE10011309A1 (de) | 2000-03-10 | 2001-09-13 | Basf Ag | Verfahren zur Herstellung von Maleinsäreanhydrid |
US7763565B2 (en) * | 2007-08-31 | 2010-07-27 | Millennium Inorganic Chemicals, Inc. | Transparent, stable titanium dioxide sols |
US8663380B2 (en) * | 2007-11-16 | 2014-03-04 | Cristal Usa Inc. | Gas phase production of coated titania |
US20090148605A1 (en) * | 2007-12-05 | 2009-06-11 | Akhtar M Kamal | Process for the production of coated titanium dioxide pigments |
US7820724B2 (en) * | 2008-02-14 | 2010-10-26 | Millennium Inorganic Chemicals, Inc. | Colloidal titanium dioxide sols |
EP2498904A2 (de) | 2009-11-10 | 2012-09-19 | Basf Se | Rohrbündelreaktor zur herstellung von maleinsäureanhydrid |
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US2773921A (en) * | 1953-09-30 | 1956-12-11 | Staudard Oil Company | Phosphoric acid-vanadium pentoxide catalyst and hydrocarbon conversions therewith |
US3238254A (en) * | 1961-02-20 | 1966-03-01 | Petro Tex Chem Corp | Oxidation of alpha, beta unsaturated aldehydes in the presence of a catalyst containing v, p, cu and o |
US3474041A (en) * | 1964-03-05 | 1969-10-21 | Petro Tex Chem Corp | Organo-phosphorus compounds in the reactivation of vanadium - phosphorus-oxygen catalysts |
US3888886A (en) * | 1972-06-08 | 1975-06-10 | Mobil Oil Corp | Oxidation of alkanes to maleic anhydride using promoted vanadium-phosphorus catalyst |
US3864280A (en) * | 1972-06-19 | 1975-02-04 | Chevron Res | Catalyst for a n-butane oxidation to maleic anhydride |
US3907707A (en) * | 1973-03-19 | 1975-09-23 | Monsanto Co | Vanadium catalysts made with a trivalent phosphorus compound |
US3905914A (en) * | 1973-07-16 | 1975-09-16 | Anthony T Jurewicz | V-P-Zr catalysts and method of preparation thereof |
US3931046A (en) * | 1974-04-17 | 1976-01-06 | Mobil Oil Corporation | V-p-zr catalysts and method of preparation thereof in the absence of hydrogen halide |
US3932305A (en) * | 1974-04-17 | 1976-01-13 | Mobil Oil Corporation | V-P-Zr Catalysts and method of preparation thereof in the absence of hydrogen halide |
US3975300A (en) * | 1974-07-01 | 1976-08-17 | Mobil Oil Corporation | One step method of preparation of vanadium-phosphorus complex in the absence of hydrogen halide |
US4043943A (en) * | 1974-11-06 | 1977-08-23 | Chevron Research Company | Process for producing a mixed oxide of vanadium and phosphorus having an improved intrinsic surface area |
CA1069875A (en) * | 1975-02-24 | 1980-01-15 | Warn D. Robinson | Method for preparing an oxidation catalyst |
US4013586A (en) * | 1975-07-24 | 1977-03-22 | Monsanto Company | Vanadium catalysts prepared with phosphonates |
JPS52140490A (en) * | 1976-05-19 | 1977-11-24 | Nitto Chem Ind Co Ltd | Production of fluid catalyst containing antimony oxide |
US4179404A (en) * | 1976-12-15 | 1979-12-18 | Denka Chemical Corporation | Catalyst preparative method |
US4219484A (en) * | 1978-10-23 | 1980-08-26 | Standard Oil Company (Ohio) | Production of maleic anhydride from four-carbon hydrocarbons using catalysts prepared by water reflux techniques |
-
1980
- 1980-12-29 US US06/220,624 patent/US4317778A/en not_active Expired - Fee Related
-
1981
- 1981-10-20 CA CA000388377A patent/CA1172234A/en not_active Expired
- 1981-11-19 ES ES507286A patent/ES8800071A1/es not_active Expired
- 1981-11-25 MX MX190271A patent/MX159330A/es unknown
- 1981-12-15 DE DE8181305882T patent/DE3170443D1/de not_active Expired
- 1981-12-15 EP EP81305882A patent/EP0056901B1/en not_active Expired
- 1981-12-16 JP JP56203326A patent/JPS57132550A/ja active Granted
- 1981-12-28 KR KR1019810005270A patent/KR880001212B1/ko active
- 1981-12-28 BR BR8108412A patent/BR8108412A/pt unknown
- 1981-12-28 PT PT74206A patent/PT74206B/pt unknown
-
1982
- 1982-09-28 ES ES515994A patent/ES515994A0/es active Granted
Also Published As
Publication number | Publication date |
---|---|
DE3170443D1 (en) | 1985-06-13 |
MX159330A (es) | 1989-05-17 |
EP0056901A3 (en) | 1982-09-08 |
ES8400740A1 (es) | 1983-11-01 |
BR8108412A (pt) | 1982-10-13 |
EP0056901B1 (en) | 1985-05-08 |
ES8800071A1 (es) | 1985-03-01 |
KR880001212B1 (ko) | 1988-07-11 |
PT74206B (en) | 1983-07-14 |
US4317778A (en) | 1982-03-02 |
JPH0297B2 (ko) | 1990-01-05 |
EP0056901A2 (en) | 1982-08-04 |
CA1172234A (en) | 1984-08-07 |
JPS57132550A (en) | 1982-08-16 |
PT74206A (en) | 1982-01-01 |
ES515994A0 (es) | 1983-11-01 |
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