KR830005269A - 각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법 - Google Patents

각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법 Download PDF

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KR830005269A
KR830005269A KR1019810000286A KR810000286A KR830005269A KR 830005269 A KR830005269 A KR 830005269A KR 1019810000286 A KR1019810000286 A KR 1019810000286A KR 810000286 A KR810000286 A KR 810000286A KR 830005269 A KR830005269 A KR 830005269A
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olefins
polymerization
supported
supported catalyst
catalyst mixtures
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KR1019810000286A
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English (en)
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KR850000243B1 (ko
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쥬니어 커비 로우어리
쥬니어 프레드 리 반스
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리챠드 고든 워터맨
더 다우 케미칼 캄파니
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Priority to KR1019810000286A priority Critical patent/KR850000243B1/ko
Publication of KR830005269A publication Critical patent/KR830005269A/ko
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Publication of KR850000243B1 publication Critical patent/KR850000243B1/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/63Pretreating the metal or compound covered by group C08F4/62 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/632Pretreating with metals or metal-containing compounds
    • C08F4/633Pretreating with metals or metal-containing compounds with metals covered by group C08F4/62 or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/022Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/02Carriers therefor
    • C08F4/025Metal oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/69Chromium, molybdenum, tungsten or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. 티키늄, 바나듐 또는 이의 혼합물이 함유된 하나이상의 무기 할로겐화물로 지지된 촉매와 하나이상의 무기산화물로 지지된 크롬 함유 촉매로 구성된 2이상의 각기 지지된 전이금속 촉매 촉매적량의 혼합물 존재하에 중합시킴을 특징으로 하는 지지된 전이금속 촉매 촉매적량 존재하에 하나 또는 그 이상의 α-올레핀을 중합하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810000286A 1981-01-30 1981-01-30 각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법 KR850000243B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019810000286A KR850000243B1 (ko) 1981-01-30 1981-01-30 각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019810000286A KR850000243B1 (ko) 1981-01-30 1981-01-30 각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법

Publications (2)

Publication Number Publication Date
KR830005269A true KR830005269A (ko) 1983-08-03
KR850000243B1 KR850000243B1 (ko) 1985-03-12

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019810000286A KR850000243B1 (ko) 1981-01-30 1981-01-30 각기 지지된 촉매 혼합물을 사용한 올레핀의 중합방법

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Publication number Publication date
KR850000243B1 (ko) 1985-03-12

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