KR830004187A - 스티렌제조시 방출가스로 부터 방향족 화합물의 회수공정 - Google Patents
스티렌제조시 방출가스로 부터 방향족 화합물의 회수공정 Download PDFInfo
- Publication number
- KR830004187A KR830004187A KR1019800004337A KR800004337A KR830004187A KR 830004187 A KR830004187 A KR 830004187A KR 1019800004337 A KR1019800004337 A KR 1019800004337A KR 800004337 A KR800004337 A KR 800004337A KR 830004187 A KR830004187 A KR 830004187A
- Authority
- KR
- South Korea
- Prior art keywords
- aromatic hydrocarbons
- ethylbenzene
- offgas
- volume
- adsorbed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims 4
- 238000011084 recovery Methods 0.000 title claims 2
- 150000001491 aromatic compounds Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 9
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 8
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 8
- 239000007789 gas Substances 0.000 claims 4
- 238000004821 distillation Methods 0.000 claims 2
- 238000001179 sorption measurement Methods 0.000 claims 2
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical compound C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000003463 adsorbent Substances 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Supply & Treatment (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (8)
- 흡착오일에 의해 흡착된 방향족 탄화수소 회수와 방향족 탄화수소의 0.2%(부피) 이하의 양을 포함하는 잔류 유리방향족 탄화수소를 얻고, 방출가스에 존재하는 방향족 탄화수소 흡착을 위해 최소한 400℉의 온도에서 5%(부피) 증류한 방향족에 대해서 흡착 오일과 온도 35℉ 내지 125℉ 압력 15 내지 100psia에서 방출가스와 접촉하여 방향족 탄화수소 0.5% 내지 10%를 함유하는 방출가스를 최종처리하여, 수소 및 방향족 탄화수소를 함유하는 방출가스, 에틸벤젠으로부터 스티렌을 제조하는 공정에서 발생되는 방출가스를 처리하는 공정.
- 최종처리전에 방출가스의 방향족 탄화수소의 함량을 감소시키기 위해 방출가스를 에틸벤젠과 함께 스크럽하는 청구범위 제1항의 공정.
- 최종처리전에 방출가스를 액화하여 방향족 화합물을 흡수하기 위해 냉각하는 청구범위 제1항의 공정.
- 최종 처리전에 방출가스를 방향족화합물 함량을 감소시키기 위해 냉각하고 에틸벤젠으로 스크럽하는 청구범위 제1항의 공정.
- 흡착오일이 1000℉ 이하의 95%(부피) 증류온도를 갖는 청구범위 제1항의 공정.
- 흡착오일이 600℉ 이상의 5%(부피) 증류온도를 갖는 청구범위 제5항의 공정.
- 흡착오일이 폴리에틸벤젠과 디페닐에탄으로 된 에틸벤젠의 생성물로 부터의 중부산물인 청구범위 제6항의 공정.
- 방향족 탄화수소가 스트리핑에 의해 흡착으로부터 회수되는 청구범위 제1항에 따른 공정.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/094,672 US4288234A (en) | 1979-11-15 | 1979-11-15 | Recovery of aromatics from styrene production off-gas |
| US94672 | 1979-11-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830004187A true KR830004187A (ko) | 1983-07-06 |
| KR830001368B1 KR830001368B1 (ko) | 1983-07-19 |
Family
ID=22246486
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019800004337A Expired KR830001368B1 (ko) | 1979-11-15 | 1980-11-12 | 스티렌제조시 방출가스로부터 방향족 화합물의 회수방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4288234A (ko) |
| JP (1) | JPS6033412B2 (ko) |
| KR (1) | KR830001368B1 (ko) |
| CA (1) | CA1151847A (ko) |
| DE (1) | DE3042824A1 (ko) |
| FR (1) | FR2469390A1 (ko) |
| GB (1) | GB2063291B (ko) |
| IT (1) | IT1146997B (ko) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4479025A (en) * | 1982-11-22 | 1984-10-23 | Uop Inc. | Alkylaromatic hydrocarbon dehydrogenation process |
| US4708721A (en) * | 1984-12-03 | 1987-11-24 | General Signal Corporation | Solvent absorption and recovery system |
| US5004862A (en) * | 1988-06-27 | 1991-04-02 | Hildinger Henry W | Process for recycling and purifying condensate from a hydrocarbon or alcohol synthesis process |
| US6388155B1 (en) * | 2000-08-01 | 2002-05-14 | Abb Lummus Global Inc. | Styrene dehydrogenation reactor effluent treatment |
| RU2256641C1 (ru) * | 2004-04-19 | 2005-07-20 | Открытое акционерное общество "Салаватнефтеоргсинтез" | Способ выделения ароматических углеводородов из несконденсированных газов производства стирола |
| RU2263099C1 (ru) * | 2004-04-19 | 2005-10-27 | Открытое акционерное общество "Салаватнефтеоргсинтез" | Способ выделения ароматических углеводородов из несконденсированных газов производства стирола |
| ITMI20052514A1 (it) * | 2005-12-29 | 2007-06-30 | Polimeri Europa Spa | Procedimento migliorato per la deidrogenazione di idrocarburi alchilaeomatici finalizzata alla produzione di monomeri vinilaromatici |
| EP2067749A1 (en) | 2007-11-29 | 2009-06-10 | Total Petrochemicals France | Process for purification of an aqueous phase containing polyaromatics |
| EP2065355A1 (en) | 2007-11-29 | 2009-06-03 | Total Petrochemicals France | Process for cooling the stream leaving an ethylbenzene dehydrogenation reactor |
| US8999257B2 (en) * | 2009-09-22 | 2015-04-07 | Fina Technology, Inc. | Offgas stream direct contact condenser |
| FR2974363B1 (fr) | 2011-04-22 | 2014-12-19 | Michelin Soc Tech | Recuperation de monomeres. |
| NL2018908B1 (en) | 2017-05-12 | 2018-11-15 | Stichting Energieonderzoek Centrum Nederland | Production and isolation of monocyclic aromatic compounds from a gasification gas |
| US12281071B2 (en) * | 2022-07-22 | 2025-04-22 | T.En Process Technology, Inc. | Systems and methods for enhancing the recovery of styrene |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2729588A (en) * | 1952-02-23 | 1956-01-03 | Fluor Corp | Operating a reboiler system for fractionating absorber-stills which comprises separately introducing vapors and liquid from the reboiler into the still and mixing absorbed vapors vaporized from the still bottoms with the liquid before its introduction into the still |
| US2959626A (en) * | 1957-07-15 | 1960-11-08 | Cosden Petroleum Corp | Process for the production of styrenegrade ethyl benzene |
| US3412171A (en) * | 1966-06-27 | 1968-11-19 | Petro Tex Chem Corp | Purification of hydrocarbons |
| JPS5439385B2 (ko) * | 1972-06-20 | 1979-11-27 | ||
| JPS5637227B2 (ko) * | 1972-06-20 | 1981-08-29 | ||
| US3963575A (en) * | 1974-02-25 | 1976-06-15 | A. E. Staley Manufacturing Company | Producing pullulanase with organisms having a superior capacity to elaborate pullulanase |
| DD114251A1 (ko) * | 1974-10-16 | 1975-07-20 |
-
1979
- 1979-11-15 US US06/094,672 patent/US4288234A/en not_active Expired - Lifetime
-
1980
- 1980-10-22 CA CA000362953A patent/CA1151847A/en not_active Expired
- 1980-11-10 GB GB8036057A patent/GB2063291B/en not_active Expired
- 1980-11-12 KR KR1019800004337A patent/KR830001368B1/ko not_active Expired
- 1980-11-12 IT IT50142/80A patent/IT1146997B/it active
- 1980-11-13 JP JP55160627A patent/JPS6033412B2/ja not_active Expired
- 1980-11-13 DE DE19803042824 patent/DE3042824A1/de active Granted
- 1980-11-13 FR FR8024122A patent/FR2469390A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| IT1146997B (it) | 1986-11-19 |
| DE3042824A1 (de) | 1981-05-27 |
| FR2469390A1 (fr) | 1981-05-22 |
| JPS5690023A (en) | 1981-07-21 |
| FR2469390B1 (ko) | 1983-12-30 |
| GB2063291A (en) | 1981-06-03 |
| GB2063291B (en) | 1983-09-07 |
| US4288234A (en) | 1981-09-08 |
| JPS6033412B2 (ja) | 1985-08-02 |
| DE3042824C2 (ko) | 1988-02-04 |
| IT8050142A0 (it) | 1980-11-12 |
| KR830001368B1 (ko) | 1983-07-19 |
| CA1151847A (en) | 1983-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19801112 |
|
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 19830223 Patent event code: PE09021S01D |
|
| PG1501 | Laying open of application | ||
| PG1605 | Publication of application before grant of patent |
Comment text: Decision on Publication of Application Patent event code: PG16051S01I Patent event date: 19830617 |
|
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19830926 |
|
| PR0701 | Registration of establishment |
Comment text: Registration of Establishment Patent event date: 19830929 Patent event code: PR07011E01D |
|
| PR1002 | Payment of registration fee |
Payment date: 19830929 End annual number: 3 Start annual number: 1 |
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| PR1001 | Payment of annual fee |
Payment date: 19860703 Start annual number: 4 End annual number: 4 |
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| PR1001 | Payment of annual fee |
Payment date: 19870609 Start annual number: 5 End annual number: 5 |
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| PR1001 | Payment of annual fee |
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| PR1001 | Payment of annual fee |
Payment date: 19890705 Start annual number: 7 End annual number: 7 |
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| PR1001 | Payment of annual fee |
Payment date: 19900705 Start annual number: 8 End annual number: 8 |
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| PR1001 | Payment of annual fee |
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| PR1001 | Payment of annual fee |
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| PR1001 | Payment of annual fee |
Payment date: 19940630 Start annual number: 12 End annual number: 12 |
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| PC1801 | Expiration of term |