KR830001350B1 - 중급 비닐 폴리부타디엔의 제조방법 - Google Patents

중급 비닐 폴리부타디엔의 제조방법 Download PDF

Info

Publication number
KR830001350B1
KR830001350B1 KR1019800000178A KR800000178A KR830001350B1 KR 830001350 B1 KR830001350 B1 KR 830001350B1 KR 1019800000178 A KR1019800000178 A KR 1019800000178A KR 800000178 A KR800000178 A KR 800000178A KR 830001350 B1 KR830001350 B1 KR 830001350B1
Authority
KR
South Korea
Prior art keywords
modifier
catalyst
dimethyl ether
glycol dimethyl
polybutadiene
Prior art date
Application number
KR1019800000178A
Other languages
English (en)
Korean (ko)
Other versions
KR830001985A (ko
Inventor
토마스 프르덴스 로버트
Original Assignee
더 굳이어 타이어 앤드 러버 컴페니
씨. 에취. 크루코우
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 더 굳이어 타이어 앤드 러버 컴페니, 씨. 에취. 크루코우 filed Critical 더 굳이어 타이어 앤드 러버 컴페니
Publication of KR830001985A publication Critical patent/KR830001985A/ko
Application granted granted Critical
Publication of KR830001350B1 publication Critical patent/KR830001350B1/ko

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
KR1019800000178A 1979-01-31 1980-01-18 중급 비닐 폴리부타디엔의 제조방법 KR830001350B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/007,741 US4230841A (en) 1979-01-31 1979-01-31 Process for medium vinyl polybutadiene
US7741 1979-01-31

Publications (2)

Publication Number Publication Date
KR830001985A KR830001985A (ko) 1983-05-21
KR830001350B1 true KR830001350B1 (ko) 1983-07-14

Family

ID=21727885

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019800000178A KR830001350B1 (ko) 1979-01-31 1980-01-18 중급 비닐 폴리부타디엔의 제조방법

Country Status (14)

Country Link
US (1) US4230841A (US06649357-20031118-C00005.png)
JP (1) JPS55104313A (US06649357-20031118-C00005.png)
KR (1) KR830001350B1 (US06649357-20031118-C00005.png)
AU (1) AU526516B2 (US06649357-20031118-C00005.png)
BE (1) BE881357A (US06649357-20031118-C00005.png)
BR (1) BR8000378A (US06649357-20031118-C00005.png)
CA (1) CA1136341A (US06649357-20031118-C00005.png)
DE (1) DE3003097A1 (US06649357-20031118-C00005.png)
FR (1) FR2447938A1 (US06649357-20031118-C00005.png)
GB (1) GB2040961B (US06649357-20031118-C00005.png)
IT (1) IT1127335B (US06649357-20031118-C00005.png)
NL (1) NL185081C (US06649357-20031118-C00005.png)
RO (1) RO79700A (US06649357-20031118-C00005.png)
ZA (1) ZA8013B (US06649357-20031118-C00005.png)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4230841A (en) * 1979-01-31 1980-10-28 The Goodyear Tire & Rubber Company Process for medium vinyl polybutadiene
CA1141090A (en) * 1979-04-23 1983-02-08 Teiji Tsuruta Linear polydivinylbenzene and derivative thereof
JPS56149413A (en) * 1980-04-22 1981-11-19 Japan Synthetic Rubber Co Ltd Production of styrene/butadiene copolymer
CA1196138A (en) * 1981-09-04 1985-10-29 Edward J. Haas Pneumatic tire with tread of medium vinyl polybutadiene/rubber blend
CA1229699A (en) * 1982-01-04 1987-11-24 William G. Carson Increasing the reactivity of coupling homopolymers
JPS58154703A (ja) * 1982-03-09 1983-09-14 Daicel Chem Ind Ltd 光学活性な高分子の合成方法
US4476240A (en) * 1982-07-01 1984-10-09 The Firestone Tire & Rubber Company Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier
US4473661A (en) * 1982-07-01 1984-09-25 The Firestone Tire & Rubber Company Polymerization catalyst system containing organolithium, dialkyl magnesium and/or trialkyl aluminum, and a phosphine oxide
US4483381A (en) * 1983-03-07 1984-11-20 The Goodyear Tire & Rubber Company Pneumatic tire with belt reinforcement
US4530959A (en) * 1984-03-08 1985-07-23 The Goodyear Tire & Rubber Company Pneumatic tire with tread of medium vinyl polybutadiene/rubber blend
US4808657A (en) * 1984-03-08 1989-02-28 The Goodyear Tire & Rubber Company Rubbery adhesive cements
GB8407629D0 (en) * 1984-03-23 1984-05-02 Shell Int Research Preparation of polymers
US4522970A (en) * 1984-06-25 1985-06-11 The Goodyear Tire & Rubber Company Tire with tread rubber containing medium vinyl polybutadiene with clay and carbon black
WO1989004843A1 (en) * 1987-11-16 1989-06-01 The Dow Chemical Company Amine containing initiator system for anionic polymerization
US5070150A (en) * 1990-07-02 1991-12-03 The Goodyear Tire & Rubber Company Process for the solid state (solventless) hydroxylation of vinyl-containing rubbers using a hydroxymercaptan
US5253691A (en) * 1992-01-13 1993-10-19 The Goodyear Tire & Rubber Company Tire having specified belt rubber composition
US6025450A (en) * 1992-10-02 2000-02-15 Bridgestone Corporation Amine containing polymers and products therefrom
US5329005A (en) * 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
US5674798A (en) * 1992-10-16 1997-10-07 Bridgestone Corporation Hydrocarbon soluble anionic polymerization initiators
USH2030H1 (en) * 1993-06-29 2002-06-04 Shell Oil Company Process for the preparation of random copolymers of conjugated dienes and vinyl aromatic compounds
US5728782A (en) * 1996-12-06 1998-03-17 Union Carbide Chemicals & Plastics Technology Corporation Gas phase anionic polymerization of dienes and vinyl-substituted aromatic compounds
US6160063A (en) * 1999-12-30 2000-12-12 Bridgestone Corporation Iron-based catalyst for producing binary cis-1,4-/1,2-polybutadiene
US6362282B1 (en) 2000-09-29 2002-03-26 Firestone Polymers, Llc Polymers with high vinyl end segments

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3451988A (en) * 1966-10-25 1969-06-24 Exxon Research Engineering Co Polymerization catalyst and uses thereof
US4022959A (en) * 1969-11-22 1977-05-10 Chemische Werke Huels Aktiengesellschaft Organolithium-Lewis base polymerization of 1,3-butadiene and novel polybutadienes thus produced
US3725368A (en) * 1970-01-19 1973-04-03 Lithium Corp Preparation of polymers
US3804486A (en) * 1972-07-20 1974-04-16 Bausch & Lomb Adapter stand for converting a binocular to a microscope
US4085265A (en) * 1972-08-25 1978-04-18 Nippon Oil Company, Limited Process for isomerization of lower polymers of butadiene
US3966691A (en) * 1973-07-12 1976-06-29 The Firestone Tire & Rubber Company Polymerization of conjugated dienes with starved lithium, potassium or sodium catalyst
DE2355941A1 (de) * 1973-11-09 1975-05-15 Bayer Ag Polymerisation und copolymerisation von dienen
US4230841A (en) * 1979-01-31 1980-10-28 The Goodyear Tire & Rubber Company Process for medium vinyl polybutadiene

Also Published As

Publication number Publication date
DE3003097C2 (US06649357-20031118-C00005.png) 1988-12-29
ZA8013B (en) 1980-11-26
RO79700A (ro) 1982-08-17
US4230841A (en) 1980-10-28
KR830001985A (ko) 1983-05-21
FR2447938B1 (US06649357-20031118-C00005.png) 1985-05-17
NL8000071A (nl) 1980-08-04
DE3003097A1 (de) 1980-08-07
JPS55104313A (en) 1980-08-09
AU526516B2 (en) 1983-01-13
BR8000378A (pt) 1980-10-21
NL185081B (nl) 1989-08-16
GB2040961A (en) 1980-09-03
IT1127335B (it) 1986-05-21
GB2040961B (en) 1983-05-25
NL185081C (nl) 1990-01-16
CA1136341A (en) 1982-11-23
JPH0232284B2 (US06649357-20031118-C00005.png) 1990-07-19
AU5427380A (en) 1980-08-07
IT8047615A0 (it) 1980-01-16
BE881357A (fr) 1980-05-16
FR2447938A1 (fr) 1980-08-29

Similar Documents

Publication Publication Date Title
KR830001350B1 (ko) 중급 비닐 폴리부타디엔의 제조방법
JP3162103B2 (ja) 共役ジオレフィンポリマーの選択水素化
Morton et al. Synthesis and Properties of Uniform Polyisoprene Networks. I. Synthesis and Characterization of α, ω-Dihydroxy-Polyisoprene
US3210333A (en) Fluidizing polymer solution
JPH07188341A (ja) ゲル生成の減ぜられたシス−1,4−ポリブタジエンの製造法
US3847883A (en) Method of preparing polymers utilizing as catalysts hydrocarbon-soluble complexes of an organomagnesium compound with a group i organometallic compound
JPS6133132A (ja) オレフインの水添方法
US5212249A (en) Method for preparing asymmetric radial polymers
RU2093524C1 (ru) Способ получения гидрированных блок-полимеров на основе сопряженных диенов
US3580895A (en) Production of copolymers in the presence of an organolithium compound and an orthoester
US4223116A (en) Conjugated diene polymerization process and catalyst
JPH04248815A (ja) 共役ジオレフィンポリマーの選択的水素化
EP0730611A1 (en) Capping of anionic polymers with oxetanes
US3801554A (en) Lithium alkenoxides as modifiers in organolithium initiated polymerization
US7550537B2 (en) Organo-dilithium compound and process for preparing the same
EP0998502B1 (en) Enhanced hydrogenation catalyst removal from block copolymers by reduction in polymer cement viscosity by increasing the vinyl content of the block copolymers
US3230209A (en) Cobaltous halide-aluminium-mercuric halide or hydrogen halide-aromatic solvent reaction product catalyst for the polymerization of olefins
US4314045A (en) Polymerization process for cis-1,4-polybutadiene using aliphatic solvents and an aromatic polymerization regulator
US3542716A (en) Polymerization process
JPS60155204A (ja) ジリチウム触媒を用いる単分散ポリマ−の製造方法
US3755283A (en) Novel polymers and method of preparing same
US3403141A (en) Polymerization of 1, 3-butadiene
US3479331A (en) Catalytic process for preparing a high molecular weight cis-1,4-polyisoprene
USH2030H1 (en) Process for the preparation of random copolymers of conjugated dienes and vinyl aromatic compounds
US4452952A (en) Increasing the reactivity of coupling homopolymers