KR20240154069A - 적어도 이중모드의 분자량 분포를 갖는 설폰화 폴리아릴렌설폰 중합체(sp) - Google Patents

적어도 이중모드의 분자량 분포를 갖는 설폰화 폴리아릴렌설폰 중합체(sp) Download PDF

Info

Publication number
KR20240154069A
KR20240154069A KR1020247032549A KR20247032549A KR20240154069A KR 20240154069 A KR20240154069 A KR 20240154069A KR 1020247032549 A KR1020247032549 A KR 1020247032549A KR 20247032549 A KR20247032549 A KR 20247032549A KR 20240154069 A KR20240154069 A KR 20240154069A
Authority
KR
South Korea
Prior art keywords
component
sulfonated
polymer
aromatic
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020247032549A
Other languages
English (en)
Korean (ko)
Inventor
마틴 베버
다니엘 말코
요아힘 스트라우흐
Original Assignee
바스프 에스이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바스프 에스이 filed Critical 바스프 에스이
Publication of KR20240154069A publication Critical patent/KR20240154069A/ko
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
    • C08G65/4056—(I) or (II) containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1034—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having phosphorus, e.g. sulfonated polyphosphazenes [S-PPh]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/34—Molecular weight or degree of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06—Polysulfones; Polyethersulfones
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Dispersion Chemistry (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Polyethers (AREA)
KR1020247032549A 2022-02-28 2023-02-23 적어도 이중모드의 분자량 분포를 갖는 설폰화 폴리아릴렌설폰 중합체(sp) Pending KR20240154069A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP22159256.1 2022-02-28
EP22159256 2022-02-28
PCT/EP2023/054580 WO2023161357A1 (en) 2022-02-28 2023-02-23 Sulfonated polyarylenesulfone polymer (sp) having an at least bimodal molecular weight distribution

Publications (1)

Publication Number Publication Date
KR20240154069A true KR20240154069A (ko) 2024-10-24

Family

ID=80595228

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020247032549A Pending KR20240154069A (ko) 2022-02-28 2023-02-23 적어도 이중모드의 분자량 분포를 갖는 설폰화 폴리아릴렌설폰 중합체(sp)

Country Status (6)

Country Link
US (1) US20250163221A1 (enExample)
EP (1) EP4486820A1 (enExample)
JP (1) JP2025508945A (enExample)
KR (1) KR20240154069A (enExample)
CN (1) CN118900870A (enExample)
WO (1) WO2023161357A1 (enExample)

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3330154A1 (de) 1983-08-20 1985-03-07 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polyethern
EP0297363A3 (de) 1987-06-27 1989-09-13 BASF Aktiengesellschaft Hochtemperaturbeständige thermoplastische formmassen mit verbesserter Schmelzestabilität
JP4234422B2 (ja) * 2000-09-20 2009-03-04 バージニア テック インテレクチュアル プロパティーズ インコーポレーテッド イオン導電性スルホン化重合体材料
US7361729B2 (en) * 2000-09-20 2008-04-22 Virginia Tech Intellectual Properties, Inc. Ion-conducting sulfonated polymeric materials
DE60329518D1 (de) * 2002-10-08 2009-11-12 Toyo Boseki SULFONSuUREGRUPPENHALTIGE POLYARYLENETHER-VERBINDUNG, DIESE ENTHALTENDE ZUSAMMENSETZUNG UND VERFAHREN ZU DEREN HERSTELLUNG
WO2004086584A2 (en) * 2003-03-19 2004-10-07 Virginia Tech Intellectual Properties, Inc. Aromatic nitrile containing ion-conducting sulfonated polymeric material
KR100963409B1 (ko) * 2008-06-02 2010-06-14 광주과학기술원 술폰화된 폴리(아릴렌 에테르) 교대 공중합체와 고분자사슬 말단에 가교구조를 함유한 술폰화된 폴리(아릴렌에테르) 교대 공중합체 및 이를 이용한 고분자 전해질막
US9199205B2 (en) * 2012-04-20 2015-12-01 Basf Se Ultrafiltration membranes fabricated from sulfonated polyphenylenesulfones
US9120062B2 (en) * 2012-04-20 2015-09-01 Basf Se High performance positively charged composite membranes and their use in nanofiltration processes
WO2014095973A1 (en) * 2012-12-18 2014-06-26 Solvay Specialty Polymers Usa, Llc Mobile electronic devices made of low-chlorine aromatic polysulfones
US10569232B2 (en) * 2014-10-31 2020-02-25 Basf Se Copolymers for making membranes
WO2017220363A1 (en) * 2016-06-20 2017-12-28 Basf Se Process for removing arsenic compounds from aqueous systems
CN106279693B (zh) * 2016-08-31 2018-08-21 浙江工业大学 一种侧链含苯并咪唑聚芳醚酮/砜及其制备方法与应用
KR101756343B1 (ko) * 2016-10-26 2017-07-11 한국과학기술연구원 연료전지의 전극 바인더용 신규한 폴리아릴렌에테르계 공중합체, 이를 포함하는 막전극접합체 및 그 제조방법
KR20200034760A (ko) * 2017-07-20 2020-03-31 바스프 에스이 설폰화 폴리아릴에테르설폰 및 이의 막
JP7460549B2 (ja) * 2018-05-18 2024-04-02 ソルベイ スペシャルティ ポリマーズ ユーエスエー， エルエルシー ポリアミドを含む相溶化ポリマー組成物
CN112673052A (zh) * 2018-09-11 2021-04-16 巴斯夫欧洲公司 聚亚芳基醚砜
KR102142566B1 (ko) * 2018-11-22 2020-08-07 건국대학교 글로컬산학협력단 부분 불소화된 설폰이미드를 포함하는 신규한 중합체, 이의 제조방법 및 이를 포함하는 양성자 교환막

Also Published As

Publication number Publication date
US20250163221A1 (en) 2025-05-22
EP4486820A1 (en) 2025-01-08
JP2025508945A (ja) 2025-04-10
WO2023161357A1 (en) 2023-08-31
CN118900870A (zh) 2024-11-05

Similar Documents

Publication Publication Date Title
Harrison et al. Influence of the bisphenol structure on the direct synthesis of sulfonated poly (arylene ether) copolymers. I
US8846854B2 (en) Sulfonated poly(arylenes), polymer compounds and methods of producing the same
US20120083541A1 (en) Aromatic polyether sulfone block copolymers
KR102368334B1 (ko) 막 적용을 위한 폴리아릴렌 에테르 술폰 폴리머
EP1611182B1 (en) Aromatic nitrile containing ion-conducting sulfonated polymeric material
CN101633734B (zh) 嵌段共聚物及其用途
US20100273953A1 (en) Functionalized polyaryl ethers
US20110172317A1 (en) Sulfonated polyarylene compounds, membrane material made therefrom, method for the production thereof and use
JP4161249B2 (ja) イオン伝導性芳香族ポリエーテル
WO2017148850A1 (en) Method for the preparation of a membrane which comprises an organic polymer of intrinsic microporosity (pim) and a sulfonated polyarylenesulfone polymer
US7473714B2 (en) Materials for use as proton conducting membranes for fuel cells
EP4486822B1 (en) Process for the preparation of a membrane (m) containing a sulfonated polyarylenesulfone polymer (sp)
US20250163221A1 (en) Sulfonated polyarylenesulfone polymer (sp) having an at least bimodal molecular weight distribution
KR20170109295A (ko) 폴리에테르에테르케톤 기반의 양이온 교환막, 이의 제조방법 및 이를 포함하는 연료전지
KR20240154061A (ko) 설폰화 폴리아릴렌설폰 중합체(sp)의 제조 방법
CN100336845C (zh) 含三苯基氧膦结构单元的磺化聚芳硫醚及其制备方法
WO2026074001A1 (en) Method for the preparation of a catalyst coated membrane (ccm)
WO2023237365A1 (en) Filtration membrane with improved hydrophilicity
WO2025132101A1 (en) Use of a membrane (m) comprising a non-crosslinked sulfonated polyarylene ether sulfone polymer (sp) in an aqueous redox flow battery (arfb)
WO2013085463A1 (en) Polymeric material comprising ortho-positioned acidic groups
CN1651485A (zh) 含三苯二酮结构单元的磺化聚芳硫醚及其制备方法
KR20090087724A (ko) 술폰화 멀티 블록 공중합체 및 브랜치된 술폰화 멀티 블록공중합체의 제조방법

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20240927

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application