KR20230039898A - A tape-type road-line manufactured with a fluorescent whitening mixture composition - Google Patents

A tape-type road-line manufactured with a fluorescent whitening mixture composition Download PDF

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KR20230039898A
KR20230039898A KR1020210122814A KR20210122814A KR20230039898A KR 20230039898 A KR20230039898 A KR 20230039898A KR 1020210122814 A KR1020210122814 A KR 1020210122814A KR 20210122814 A KR20210122814 A KR 20210122814A KR 20230039898 A KR20230039898 A KR 20230039898A
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South Korea
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tape
weight
fluorescent whitening
parts
mixed composition
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KR1020210122814A
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Korean (ko)
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KR102515257B1 (en
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김동인
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대한로드라인 페인트 주식회사
강산안전(주)
(주)에이원이앤씨
주식회사 동주안전
동일건설(주)
(주)삼광건설
(주)오딘솔루션
(주)무량기술
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J5/00Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
    • C09J5/06Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers involving heating of the applied adhesive
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013Fillers, pigments or reinforcing additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C23/00Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces
    • E01C23/16Devices for marking-out, applying, or forming traffic or like markings on finished paving; Protecting fresh markings
    • E01C23/18Devices for marking-out, applying, or forming traffic or like markings on finished paving; Protecting fresh markings for applying prefabricated markings
    • E01C23/185Tape- or sheet-shape markers or carriers
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/576Traffic lines
    • E01F9/578Traffic lines consisting of preformed elements, e.g. tapes, block-type elements specially designed or arranged to make up a traffic line

Abstract

The present invention relates to a tape-type lane manufactured by including a fluorescent whitening mixed composition. Specifically, in a method for manufacturing a tape-type lane installed on a road surface by a fusion method using a binder, an elastic material, a filler, a glass bead, an inorganic pigment, a fluorescent whitening mixed composition, an anti-settling agent and a viscosity modifier as materials, the fluorescent whitening mixed composition is manufactured by: a step of obtaining grain rice flour; a rice flour kneading step; an optical whitening agent coating step using sedimentation; and a powder acquisition step.

Description

형광증백 혼합조성물을 포함하여 제조된 테이프형 차선{A tape-type road-line manufactured with a fluorescent whitening mixture composition}A tape-type road-line manufactured with a fluorescent whitening mixture composition}

본 발명은 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선에 관한 것이다.The present invention relates to a tape-type lane prepared including a fluorescent whitening mixed composition.

구체적으로는, 바인더, 탄성재, 충전재, 글라스비드, 무기안료, 형광증백 혼합조성물, 침강방지제 및 점도조절제를 재료로 하여, 도로 노면에 융착방식으로 설치되는 테이프형 차선의 제조방법에 있어서, 상기 형광증백 혼합조성물은 곡물 미강분 획득단계; 미강분 반죽단계; 침강을 이용한 형광증백제 코팅단계; 및 분말 획득단계;의 과정으로 이루어지는, 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선에 관한 것이다.Specifically, in the manufacturing method of a tape-type lane installed on a road surface by a fusion method using a binder, an elastic material, a filler, a glass bead, an inorganic pigment, a fluorescent whitening mixed composition, an anti-settling agent and a viscosity modifier as materials, The fluorescent whitening mixed composition includes the steps of obtaining grain rice flour; rice flour kneading step; Optical whitening agent coating step using sedimentation; And powder acquisition step; it relates to a tape-type lane manufactured by including a fluorescent whitening mixed composition consisting of a process.

도로 노면의 차선은 운전자로 하여금 도로의 구분과 차선의 식별을 가능하도록 하고, 그 외에도 해당 도로의 사용 목적, 유의 사항 등을 운전자에게 전달하는 역할을 한다.Lanes on the road surface enable drivers to classify roads and identify lanes, and in addition, serve to convey to drivers the purpose of using the road and matters to be noted.

그러나, 종래의 노면표시방법은 일반 페인트 및 융착식 페인트 등의 도료를 사용하여 도색하는 방법이 주로 사용되었고, 이러한 종래의 방법은 표면이 고르지 못한 도로의 표면에 현장도색을 하게 되므로, 일정한 두께로 도색이 쉽지 않고, 건조가 늦어짐에 따라, 교통체증을 유발하는 문제점이 있었다.However, in the conventional road surface marking method, a method of painting using paints such as general paint and fusion paint was mainly used, and since this conventional method paints the surface of an uneven road on the spot, a constant thickness It was not easy to paint, and as drying was delayed, there was a problem of causing traffic congestion.

또한, 야간에 반사효율이 좋지 못해 시야확보가 어렵고, 이러한 시야확보 문제를 해결하기 위해 도로용 페인트 혼합물을 도로에 도포한 후에, 수동식 기계를 통해 인위적으로 반사체를 도로용 페인트의 표면에 살포하게 되면, 반사체가 침강되거나, 차량 타이어와의 마찰로 인해 쉽게 이탈되어 반사효율이 저하되는 문제점이 있었다.In addition, it is difficult to secure visibility due to poor reflective efficiency at night, and after applying a paint mixture for roads to the road to solve this problem of securing visibility, if a reflector is artificially sprayed on the surface of the paint for roads through a manual machine However, there is a problem in that the reflector settles or is easily separated due to friction with the vehicle tire, reducing the reflection efficiency.

또한, 우천시 시인성이 좋지않아 운전자들로 하여금 교통사고를 미연에 방지하는 효과가 미미하다.In addition, visibility is not good in rainy weather, so the effect of preventing traffic accidents by drivers is insignificant.

이러한 문제점을 극복하기 위하여, 도로 노면의 차선을 테이프형으로 제작하여 융착시키는 방법의 기술을 제안한다.In order to overcome this problem, we propose a technique for fusing lanes on the road surface by manufacturing them in a tape form.

관련된 특허로서, 공개특허공보 제10-2019-0002015호에는 도로용 차선표시 테이프와 이를 이용한 차선표시방법이 기재되어 있다.As a related patent, Laid-Open Patent Publication No. 10-2019-0002015 describes a lane marking tape for roads and a lane marking method using the same.

상기 기술은, 도로용 차선표시 테이프와 이를 이용한 차선표시방법에 관한 것으로, 그 목적은 차선표시 테이프를 도막시트층과 차선도장층의 이중구조로 형성하여, 도막시트층의 고연화점 및 고잡착성에 의해 아스팔트에 대한 접착성을 향상시키고, 차선도장층의 우수한 시안성 및 도막시트층과의 접착성에 의해 차량에 의한 밀림현상이 발생되지 않으며, 도막시트층과 차선도장층의 저온굴곡성에 의해 표면균열없이 장기간 수명이 연장되는 도로용 차선표시 테이프 및 그 시공방법을 제공하는 것이다.The above technology relates to a lane marking tape for roads and a lane marking method using the same, and the purpose thereof is to form the lane marking tape into a dual structure of a coating sheet layer and a lane coating layer, thereby improving the high softening point and high adhesion of the coating sheet layer. Improves adhesion to asphalt, excellent cyanability of the lane coating layer and adhesion with the coating sheet layer, so that the phenomenon of rolling by vehicles does not occur, and surface cracking due to the low-temperature flexibility of the coating sheet layer and the lane painting layer It is to provide a road marking tape and its construction method that extends its lifespan for a long period of time.

이러한 상기 기술은, 고연화점 개질아스팔트로 이루어진 도막시트층; 도막시트층 상에 도포되는 차선도장액에 의해 형성되는 차선도장층;을 포함하되, 상기 도막시트층이 유리섬유메쉬 또는 글라스페이퍼에 고연화점 개질아스팔트가 소정두께로 도포함침되고, 프라이머의 도포없이도 토치의 가열에 의해 시공도로면에 손쉽게 시공할 수 있도록 되어 있다.The above technology includes a coating sheet layer made of high softening point modified asphalt; A second coating layer formed by a second coating liquid applied on the coating sheet layer; wherein the coating sheet layer is coated with a glass fiber mesh or glass paper in a predetermined thickness and impregnated with a high softening point modified asphalt, and a torch without application of a primer It is designed to be easily installed on the construction road surface by heating.

또한, 공개특허공보 제10-2006-0094246호에는 축광 역반사시트를 이용한 차선표시용 테이프가 기재되어 있다.In addition, Laid-Open Patent Publication No. 10-2006-0094246 discloses a lane marking tape using a photoluminescent retro-reflective sheet.

상기 기술은, 도로의 차선표시용 테이프에 관한 것으로, 바람직하게는 외표면으로부터 차례로 표면필름층, 축광층 또는 형광층, 플라스틱비드층, 초점수지층, 금속반사층, 접착제층, 금속호일층, 점착제층 및 이형지를 포함하는 역반사시트를 이용한 차선표시용 테이프에 관한 것이다.The technology relates to a tape for marking lanes on a road, preferably a surface film layer, a phosphorescent layer or a fluorescent layer, a plastic bead layer, a focus resin layer, a metal reflective layer, an adhesive layer, a metal foil layer, and an adhesive in order from the outer surface. It relates to a lane marking tape using a retro-reflective sheet including a layer and a release paper.

이러한 차선표시용 테이프는 재귀반사성능을 포함한 역반사시트의 기본특성을 보유하여 우수한 주야간 시인성을 확보하였고, 특히 축광안료 또는 형광안료를 사용함으로써 높은 재귀반사율로 인한 더욱 향상된 주야간 시인성을 확보하였으며, 차량의 중량에 의해 쉽게 파괴될 수 있는 유리비드 대신에 강도가 우수한 고투명 플라스틱비드를 사용함으로써 역반사시트를 차선표시용 테이프에 적용가능하게 되었으며, 또한 제품층 내부에 금속호일(foil)층을 형성함으로써 장기안착성이 탁월하여 지속적인 형상을 유지하므로 면이 고르지 않고 요철이나 굴곡이 심한 도로의 차선표시용으로 적합한 것으로 기재되어 있다.This lane marking tape has the basic characteristics of a retro-reflective sheet, including retro-reflective performance, to ensure excellent day and night visibility. In particular, by using phosphorescent pigments or fluorescent pigments, improved day and night visibility is secured due to high retro-reflectivity. By using highly transparent plastic beads with excellent strength instead of glass beads that can be easily destroyed by the weight of the product, the retroreflective sheet can be applied to the lane marking tape, and also by forming a metal foil layer inside the product layer. It has excellent long-term stability and maintains its continuous shape, so it is described as suitable for lane marking on roads with uneven surfaces and severe irregularities or curves.

또한, 공개특허공보 제10-2006-0075621호에는 도로용 차선표시 테이프가 기재되어 있다.In addition, Laid-Open Patent Publication No. 10-2006-0075621 describes a road marking tape.

상기 기술은, 차량의 안전 운행을 유도해서 교통사고를 방지할 수 있고, 짧은 시간 내에 용이하게 시공할 수 있음과 동시에, 시공 비용을 절감할 수 있을 뿐만 아니라, 장시간 사용해도 반사기능을 유지할 수 있는 도로용 차선표시 테이프에 관한 것이다.The technology can prevent traffic accidents by inducing safe operation of vehicles, can be easily constructed within a short time, can reduce construction costs, and can maintain reflective function even after long-term use. It relates to road marking tape.

또한, 등록특허공보 제10-0390852호에는 초고휘도 노면표시용 핫테이프 및 그의 시공방법이 기재되어 있다.In addition, Patent Registration No. 10-0390852 discloses a hot tape for ultra-high luminance road surface display and a method of installing the same.

상기 기술은, 초고휘도 노면표시용 핫테이프 및 그의 시공방법이 개시된다. 초고휘도 노면 표시용 핫테이프는 도로 노면표시용 핫테이프에 있어서,도로상에 소정 두께로 접착되는 접착층; 접착층 상면 일측에 소정 두께로 균일하게 도포되며, 에폭시접착제와 제강슬러거를 혼합하여 이루어지는 미끄럼방지부; 및 접착층 상면 타측에 소정 두께로 균일하게 도포되며, 에폭시 접착제와 유리알을 혼합하여 이루어지는 식별반사부를 포함하여 이루어진다.The above technology discloses a hot tape for ultra-high luminance road marking and a construction method thereof. A hot tape for ultra-high luminance road marking is a hot tape for road marking, comprising: an adhesive layer adhered to a predetermined thickness on a road; An anti-slip unit that is uniformly applied to one side of the upper surface of the adhesive layer with a predetermined thickness and is made by mixing epoxy adhesive and steelmaking slugger; And it is uniformly applied to the other side of the upper surface of the adhesive layer to a predetermined thickness, and includes an identification reflection part made by mixing epoxy adhesive and glass beads.

전술한 핫테이프는 바로 도로상에 접착층을 도포성형하는 제 1공정; 접착층 상면 일측에 에폭시접착제와 제강슬러그의 혼합물을 소정두께로 균일하게 도포하는 제2공정; 및 접착층 상면 타측에 에폭시접착제와 유리알의 혼합물을 소정두께로 균일하게 도포하는 제3공정을 통해 도로상에 설치되어 질 수 있다. 초고휘도 유리알과 에폭시접착제의 식별반사부를 다양하게 구성하여 도로상태나 주변상황에 맞춰 효과적으로 사용되게 한다.The aforementioned hot tape includes a first step of applying and molding an adhesive layer on a road; A second step of uniformly applying a mixture of epoxy adhesive and steelmaking slug to a predetermined thickness on one side of the upper surface of the adhesive layer; And it can be installed on the road through a third process of uniformly applying a mixture of epoxy adhesive and glass beads to a predetermined thickness on the other side of the upper surface of the adhesive layer. The ultra-high brightness glass bead and the epoxy adhesive's identification reflector are configured in various ways so that they can be used effectively according to the road conditions or surrounding conditions.

따라서, 모든 도로상에서 유효하며 특히, 모든 차선 및 내리막길이나 커브길에서 차량주행시 도로선형을 유도하여 야간주행에 선명함을 보여줌과 동시에 또한, 야간이나 우천시 운행에도 식별이 용이해 위험을 미리 감지하여 교통사고의 위험에서 벗어나게 한다.Therefore, it is effective on all roads, and in particular, it induces the road alignment when driving in all lanes and on downhill or curve roads to show clarity in night driving. avoid the risk of an accident.

상술된 기술들을 개선하기 위하여, 등록특허공보 제10-2261217호의 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선이 개발되었으나, 시인성 확보를 위한 추가 연구가 지속적으로 필요한 상황이다.In order to improve the above-described technologies, a tape-type lane manufactured by including the fluorescent whitening mixed composition of Patent Registration No. 10-2261217 has been developed, but additional research is continuously needed to secure visibility.

공개특허공보 제10-2019-0002015호(2019.01.08.)Publication No. 10-2019-0002015 (2019.01.08.) 공개특허공보 제10-2006-0094246호(2006.08.29.)Publication No. 10-2006-0094246 (2006.08.29.) 공개특허공보 제10-2006-0075621호(2006.07.04.)Publication No. 10-2006-0075621 (2006.07.04.) 등록특허공보 제10-0390852호(2003.07.10. 공고)Registered Patent Publication No. 10-0390852 (Announced on July 10, 2003)

본 발명의 목적은, 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선을 제공하는데 있다.An object of the present invention is to provide a tape-type lane manufactured by including a fluorescent whitening mixed composition.

상술된 목적을 달성하기 위하여 안출된 것으로 본 발명에 따른 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선은, 바인더, 탄성재, 충전재, 글라스비드, 무기안료, 형광증백 혼합조성물, 침강방지제 및 점도조절제를 재료로 하여, 도로 노면에 융착방식으로 설치되는 테이프형 차선의 제조방법에 있어서,In order to achieve the above object, the tape-type lane manufactured including the fluorescent whitening mixed composition according to the present invention is a binder, an elastic material, a filler, a glass bead, an inorganic pigment, a fluorescent whitening mixed composition, an antisettling agent, and a viscosity In the manufacturing method of a tape-type lane that is installed on a road surface in a fusion method using a regulator as a material,

상기 재료는,The material is

무게비를 기준으로 바인더 100중량부에 대하여, 탄성재 50중량부, 충전재 350중량부, 글라스비드 200중량부, 무기안료 20중량부, 형광증백 혼합조성물 50중량부, 침강방지제 10중량부 및 점도조절제 20~30중량부를 사용하는 것을 특징으로 한다.Based on the weight ratio, with respect to 100 parts by weight of binder, 50 parts by weight of elastic material, 350 parts by weight of filler, 200 parts by weight of glass beads, 20 parts by weight of inorganic pigment, 50 parts by weight of fluorescent whitening mixed composition, 10 parts by weight of anti-settling agent and viscosity modifier It is characterized by using 20 to 30 parts by weight.

이때, 상기 테이프형 차선의 제조방법은,At this time, the manufacturing method of the tape-type lane,

상기 재료를 준비하는 a단계;a step of preparing the material;

상기 a단계에서 준비된 재료 중, 바인더, 탄성재, 충전재, 무기안료, 침강방지제 및 점도조절제를 용융시켜 용융물로 금형에 투입하는 b단계;Step b of melting a binder, an elastic material, a filler, an inorganic pigment, an antisettling agent, and a viscosity control agent among the materials prepared in step a, and introducing the melt into a mold;

상기 b단계 후 수행되는 단계로서, 상기 a단계의 재료 중, 글라스비드를, As a step performed after step b, among the materials of step a, glass beads,

상기 b단계에서 투입된 용융물에 혼입하여 혼합 용융물을 획득하는 c단계;step c of obtaining a mixed melt by mixing with the melt introduced in step b;

상기 c단계 후 수행되는 단계로서, 상기 a단계의 재료 중 형광증백 혼합조성물을 혼입하여 최종 용융물을 획득하는 d단계;As a step performed after step c, step d of obtaining a final melt by incorporating the fluorescent whitening mixed composition among the materials of step a;

상기 d단계까지 종료됨에 따라 금형에 투입된 최종 용융물이 경화된기 전에 디자인을 형성하는 e단계; 및e step of forming a design before the final melt injected into the mold is hardened as the step d is completed; and

상기 e단계가 종료되면 금형 내부의 용융물을 냉각시켜 고체의 제품으로 제작하고, 금형으로부터 테이프형 차선을 분리하는 f단계;를 포함하는 것을 특징으로 한다.It is characterized in that it includes; when the step e is completed, the melt inside the mold is cooled to produce a solid product, and the step f of separating the tape-shaped lane from the mold.

본 발명에 따른 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선에 의하면, 도로 노면에 형성된 차선을 테이프형으로 구성하여 차선이 형성될 영역에 테이프형 차선을 설치하고, 열융착을 이용하여 노면에 테이프형 차선이 융착되어 형성될 수 있도록 하는, 우천시 및 야간시 시인성이 향상된 테이프형 차선을 제공함으로써, 종래 도료를 이용한 차선 표시 기술의 문제점을 극복할 수 있고,According to the tape-type lanes manufactured including the fluorescent whitening mixed composition according to the present invention, the lanes formed on the road surface are formed in a tape shape, the tape-type lanes are installed in the area where the lanes are to be formed, and the road surface is bonded to the road surface using thermal fusion. By providing a tape-type lane with improved visibility in rainy weather and at night, which allows the tape-type lane to be fused and formed, it is possible to overcome the problems of the conventional lane display technology using paint,

아울러, 테이프형 차선을 이루는 조성물에 고굴절 글라스비드를 함유시킴으로써, 시야 확보가 어려운 우천시 혹은 빛의 양이 적은 야간시에도 시인성을 향상시킬 수 있는 장점을 가진다.In addition, by including high refractive glass beads in the composition constituting the tape-type lane, visibility can be improved even in rainy weather or at night when the amount of light is low.

본 명세서 및 청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정해서 해석되어서는 안되며, 발명자는 그 자신의 발명을 가장 최선의 방법으로 설명하기 위해 용어의 개념을 적절하게 정의할 수 있다는 원칙에 입각하여 본 발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 한다.The terms or words used in this specification and claims should not be construed as being limited to their usual or dictionary meanings, and the inventors can properly define the concept of terms in order to best explain their invention. Based on the principle, it should be interpreted as a meaning and concept consistent with the technical idea of the present invention.

따라서 본 명세서에 기재된 실시 예와 도면에 도시된 구성은 본 발명의 가장 바람직한 실시 예에 불과할 뿐이고 본 발명의 기술적 사상을 모두 대변하는 것은 아니므로, 본 출원시점에 있어서 이들을 대체할 수 있는 다양한 균등물과 변형 예들이 있을 수 있음을 이해하여야 한다.Therefore, since the embodiments described in this specification and the configurations shown in the drawings are only the most preferred embodiments of the present invention and do not represent all of the technical spirit of the present invention, various equivalents that can replace them at the time of the present application It should be understood that there may be variations and examples.

이하, 도면을 참조하여 설명하기에 앞서, 본 발명의 요지를 드러내기 위해서 필요하지 않은 사항 즉 통상의 지식을 가진 당업자가 자명하게 부가할 수 있는 공지 구성에 대해서는 도시하지 않거나, 구체적으로 기술하지 않았음을 밝혀둔다.Hereinafter, prior to description with reference to the drawings, matters that are not necessary to reveal the subject matter of the present invention, that is, known configurations that can be added obviously by those skilled in the art, are not shown or specifically described. reveal the sound

본 발명은 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선에 관한 것이다.The present invention relates to a tape-type lane prepared including a fluorescent whitening mixed composition.

구체적으로는, 도로 노면에 형성된 차선을 테이프형으로 구성하여 차선이 형성될 영역에 테이프형 차선을 설치하고, 열융착을 이용하여 노면에 테이프형 차선이 융착되어 형성될 수 있도록 하는 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선에 있어서, 차선에 설치시 시인성이 향상되도록 제조된, 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선에 관한 것이다.Specifically, a fluorescent whitening mixture composition in which the lanes formed on the road surface are formed in a tape shape, the tape-shaped lanes are installed in the area where the lanes are to be formed, and the tape-shaped lanes are fused and formed on the road surface using thermal fusion. It relates to a tape-type lane manufactured including a fluorescent whitening mixture composition manufactured to improve visibility when installed on the lane.

이러한 본 발명에 따른 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선은 첨부된 도면의 도 1과 같이 이루어진다.The tape-type lane manufactured by including the fluorescent whitening mixture composition according to the present invention is made as shown in FIG. 1 of the accompanying drawings.

도 1은 본 발명에 따른 형광증백 혼합조성물을 포함하여 제조된 테이프형 차선을 블록도로 나타낸 것이다.1 is a block diagram showing a tape-type lane prepared including a fluorescent whitening mixed composition according to the present invention.

가. 재료 준비단계go. material preparation step

재료 준비단계는, 테이프형 차선의 제조에 사용되는 재료를 준비하는 단계이다.The material preparation step is a step of preparing a material used for manufacturing the tape-type lane.

이때, 상기 재료는, 바인더, 탄성재, 충전재, 글라스비드, 무기안료, 형광증백 혼합조성물, 침강방지제 및 점도조절제를 포함한다.In this case, the material includes a binder, an elastic material, a filler, a glass bead, an inorganic pigment, a fluorescent whitening mixed composition, an anti-settling agent, and a viscosity control agent.

구체적으로는, 무게비를 기준으로 바인더 100중량부에 대하여, 탄성재 50중량부, 충전재 350중량부, 글라스비드 200중량부, 무기안료 20중량부, 형광증백 혼합조성물 50중량부, 침강방지제 10중량부 및 점도조절제 20~30중량부를 사용한다.Specifically, based on the weight ratio, 50 parts by weight of elastic material, 350 parts by weight of filler, 200 parts by weight of glass beads, 20 parts by weight of inorganic pigment, 50 parts by weight of fluorescent whitening mixed composition, 10 parts by weight of antisettling agent, based on weight ratio of 100 parts by weight of binder 20 to 30 parts by weight of part and viscosity modifier are used.

상기 바인더는 하이드로카본으로 이루어지는데, 상기 재료들을 물리적으로 결속하는 바인더의 역할을 한다.The binder is made of hydrocarbon and serves as a binder that physically binds the materials.

또한, 상기 탄성재는 에틸렌비닐아세테이트(EVA, Ethylene Vinylacetate) 및 스티렌부타디엔스티렌 공중합체(SBS, Styrene Butadiene Styrene Copolymer)를 포함하며, 탄성 부여의 목적으로 사용된다.In addition, the elastic material includes ethylene vinyl acetate (EVA, Ethylene Vinylacetate) and styrene butadiene styrene copolymer (SBS, Styrene Butadiene Styrene Copolymer), and is used for the purpose of imparting elasticity.

즉, 테이프형 차선이 노면에 형성된 후, 외력(外力)에 의한 충격이 발생하였을 때 손상되는 것을 방지하도록 한다.That is, after the tape-type lanes are formed on the road surface, they are prevented from being damaged when an impact due to an external force occurs.

또한, 상기 충전재는 탄산칼슘(CaCO3) 또는 활석(Talc)으로 이루어지며, 테이프형 차선의 내마모성 및 내충격성과 같은 기계적 물성을 향상시키는 역할을 한다.In addition, the filler is composed of calcium carbonate (CaCO3) or talc (Talc), and serves to improve mechanical properties such as abrasion resistance and impact resistance of the tape-type lane.

이때, 전술한 탄산칼슘 또는 활석은 150 내지 200 메시의 입자크기를 갖는 것이 바람직한데, 150 내지 200 메시의 입자크기를 갖도록 미분쇄된 충전재를 사용하게 되면, 상기의 바인더, 오염방지제 및 탄성재에 고르게 혼합될 수 있다.At this time, the calcium carbonate or talc described above preferably has a particle size of 150 to 200 mesh. When a finely ground filler having a particle size of 150 to 200 mesh is used, the above binder, antifouling agent and elastic material can be mixed evenly.

또한, 상기 글라스비드는 직경이 300 내지 600 마이크로미터인 것이 사용되는데, 테이프형 차선의 재귀반사(retroreflection, 再歸反射)성을 향상시킨다.In addition, the glass beads having a diameter of 300 to 600 micrometers are used, which improve retroreflection (retroreflection) of the tape-type lane.

상기 글라스비드의 직경이 300 마이크로미터 미만이면, 재귀반사 효율을 향상되지 않으면서 원가가 증가하고, 글라스비드의 직경이 600 마이크로미터를 초과하게 되면, 재귀반사 효율이 감소한다. 아울러, 상술된 바인더와의 접착력이 저하되어, 외력에 의해 쉽게 이탈된다.If the diameter of the glass bead is less than 300 micrometers, cost increases without improving the retroreflection efficiency, and if the diameter of the glass bead exceeds 600 micrometers, the retroreflection efficiency is reduced. In addition, the adhesive force with the above-mentioned binder is lowered, and it is easily separated by external force.

또한, 상기 무기안료는 테이프형 차선에 다양한 색을 부여하는 역할을 하는데, 이때, 무기안료는 내열성 및 내광성이 우수하여, 자동차 타이어의 마찰력 및 자외선에 오랜시간 노출되어도 물성의 저하를 발생하지 않는 효과를 나타내며, 노면표시용 페인트, 도료 및 테이프 조성물에 적용가능한 것이라면 특별히 한정되지 않고 어떠한 것이든 사용가능하나, 산화티탄(TiO2)으로 이루어지는 것이 바람직하다.In addition, the inorganic pigment serves to impart various colors to the tape-type lane, and at this time, the inorganic pigment has excellent heat resistance and light resistance, so that the frictional force of automobile tires and the effect of not deteriorating physical properties even when exposed to ultraviolet rays for a long time It is not particularly limited and any paint can be used as long as it is applicable to road marking paints, paints and tape compositions, but it is preferably made of titanium oxide (TiO 2 ).

또한, 상기 침강방지제는 실리카 분말로 이루어지며, 상기 재료들을 혼합할 때, 글라스비드가 바닥으로 가라앉지 못하도록 하는 역할을 한다.In addition, the anti-settling agent is composed of silica powder, and serves to prevent the glass beads from sinking to the bottom when the materials are mixed.

또한, 상기 점도조절제는 아마인유 또는 대두유로 이루어진다. 이러한 점도조절제는 상기 재료의 흐름성을 개선하여, 노면에 시공하는 과정에서 작업효율을 향상시키는 역할을 한다.In addition, the viscosity modifier consists of linseed oil or soybean oil. These viscosity modifiers improve the flowability of the material and serve to improve work efficiency in the process of constructing on the road surface.

또한, 상기 형광증백 혼합조성물은 통상의 형광염료를 사용할 수 있다. 이러한 형광증백 혼합조성물은 테이프형 차선의 시인성을 향상시키는 역할을 한다.In addition, the fluorescent whitening mixed composition may use a conventional fluorescent dye. This fluorescent whitening mixed composition serves to improve the visibility of tape-type lanes.

이러한 상술된 재료를 포함하여 이루어진 테이프형 차선은 노면과의 접착성, 내오염성 및 야간이나 우천시에 시야 확보 탁월하며, 시공 후에 건조공정 시간이 짧아, 작업의 효율성이 우수하고, 휘발성 유기화합물이 방출되지 않아 친환경적이다.Tape-type lanes made of the above-mentioned materials are excellent in adhesion to the road surface, stain resistance, and securing visibility at night or in rainy weather, and the drying process time is short after construction, so the work efficiency is excellent, and volatile organic compounds are released It is eco-friendly because it does not

나. 용융물 금형 투입단계me. Step of inserting melt into mold

용융물 금형 투입단계는, 상기 재료 준비단계에서 준비된 재료 중, 바인더, 탄성재, 충전재, 글라스비드, 무기안료, 형광증백 혼합조성물, 침강방지제 및 점도조절제를 용융시켜 용융물로 금형에 투입하는 단계이다.In the molten mold injection step, among the materials prepared in the material preparation step, a binder, an elastic material, a filler, a glass bead, an inorganic pigment, a fluorescent whitening mixed composition, an anti-settling agent, and a viscosity control agent are melted and introduced into the mold as a molten material.

이때, 금형이란, 테이프형 차선의 형상에 대응되는 형태를 가지는 것을 의미하며, 테이프형 차선의 형상이란, 도로 노면에 형성된 차선의 종래 다양한 형상을 모두 포함하는 의미이다.In this case, the mold means having a shape corresponding to the shape of the tape-type lane, and the shape of the tape-type lane means including all conventional various shapes of lanes formed on the road surface.

다. 글라스비드 혼입단계all. Glass bead mixing step

글라스비드 혼입단계는, 상기 용융물 금형 투입단계 후 수행되는 단계로서, 상기 재료 중 글라스비드를 용융시킨 용융물을 상기 용융물 금형 투입단계에서 투입된 용융물에 혼입하여 혼합 용융물을 획득하는 단계이다.The glass bead incorporation step is performed after the melt mold input step, and is a step of obtaining a mixed melt by incorporating the molten material in which the glass beads among the materials are melted into the melt input in the melt mold input step.

이때, 글라스비드의 혼입은 골고루 분포될 수 있도록 한다.At this time, the incorporation of glass beads makes it evenly distributed.

라. 형광증백 혼합조성물 혼입단계la. Incorporation step of fluorescent whitening mixed composition

형광증백 혼합조성물 혼입단계는, 상기 글라스비드 혼입단계를 통해 획득된 혼합 용융물에 형광증백 혼합조성물을 혼입하여, 최종 혼합물을 획득하는 단계이다.The step of incorporating the fluorescent whitening mixed composition is a step of mixing the fluorescent whitening mixed composition into the mixed melt obtained through the glass bead incorporation step to obtain a final mixture.

이때, 상기 형광증백 혼합조성물은 다음의 과정으로 제조된 것을 사용하도록 한다.At this time, the fluorescent whitening mixed composition is prepared by the following process.

(1) 곡물 미강분 획득단계(1) Grain Rice Flour Acquisition Step

곡물 미강분 획득단계는, 쌀 등의 일반적인 곡물을 이용하여 미강분(미세가루)로 획득하는 단계이다.The grain rice flour obtaining step is a step of obtaining rice flour (fine powder) using general grains such as rice.

이때, 미강분으로 제조하는 것은, 종래 다양하게 공지된 기술을 이용하도록 한다.At this time, manufacturing with rice bran is to use various conventionally known techniques.

(2) 미강분 반죽단계(2) Rice flour kneading step

미강분 반죽단계는, 상기 곡물 미강분 획득단계에서 획득된 미강분에 계면활성제와 물을 혼합하여 반죽함으로써 반죽된 고형제를 획득하는 단계이다.The rice flour kneading step is a step of obtaining a kneaded solid preparation by mixing and kneading the rice flour obtained in the grain rice flour obtaining step with a surfactant and water.

이때, 계면활성제는 미강분의 무게비 기준으로 100중량부에 대하여 1~3중량부를 사용하고, 물은 미강분을 100중량부 기준으로 40~50중량부 만큼 사용하도록 한다.At this time, the surfactant is used in an amount of 1 to 3 parts by weight based on 100 parts by weight of rice bran powder, and the water is used in an amount of 40 to 50 parts by weight based on 100 parts by weight of rice bran powder.

(3) 침강을 이용한 형광증백제 코팅단계(3) Optical whitening agent coating step using sedimentation

침강을 이용한 형광증백제 코팅단계는, 상기 미강분 반죽단계에서 획득된 반죽물을, 형광증백제가 수용된 수조에 침강하여 코팅시키는 단계이다.The fluorescent whitening agent coating step using sedimentation is a step of depositing and coating the dough obtained in the rice flour kneading step in a water tank containing the fluorescent whitening agent.

이때 침강을 통한 코팅이 종료되면, 다음 단계에서 냉각을 수행하는데, 냉각 후 코팅하지 않는 이유는 형광증백제가 반죽물 내측으로 골고루 코팅될 수 있도록 하기 위함이다.At this time, when the coating through sedimentation is completed, cooling is performed in the next step. The reason for not coating after cooling is to ensure that the fluorescent whitening agent is evenly coated on the inside of the dough.

예컨대, 코팅의 시간은 1~3시간 사이에서 다양하게 선택적으로 수행될 수 있다. 또한, 형광증백제의 양은 반죽물이 침강되어 완전히 잠길정도면 충분하다.For example, the coating time may be variously and selectively performed between 1 and 3 hours. In addition, the amount of the fluorescent whitening agent is sufficient if the dough is completely submerged by sedimentation.

(4) 분말 획득단계(4) powder acquisition step

분말 획득단계는, 상기 침강을 이용한 형광증백제 코팅단계가 종료된 반죽물을 얼리고 파쇄하는 급속동결 파쇄를 이용하여, 형광증백 혼합조성물의 분말을 획득하는 단계이다.The powder obtaining step is a step of obtaining the powder of the fluorescent whitening mixture composition by using quick freeze crushing to freeze and crush the dough after the fluorescent whitening agent coating step using the sedimentation.

마. 디자인 형성단계mind. design formation stage

디자인 형성단계는, 상기 형광증백 혼합조성물 혼입단계까지 종료됨에 따라 금형에 투입된 최종 혼합물이 경화되기 전에 디자인을 형성하는 단계이다.The design forming step is a step of forming a design before the final mixture injected into the mold is cured as the mixing step of the fluorescent whitening mixed composition is completed.

이때, 디자인의 형성은, 금형의 상측으로 상부금형을 위치시키되, 상기 상부금형의 하면에 소정의 패턴이나 디자인을 음각 또는 양각으로 형성하고 금형을 향해 가압함으로써 형성하는 것일 수 있다.At this time, the formation of the design may be formed by placing the upper mold on the upper side of the mold, forming a predetermined pattern or design on the lower surface of the upper mold in a negative or embossed shape and pressing it toward the mold.

혹은, 수작업을 통해 직접 디자인 하는 것일 수도 있다.Or, it may be designed by hand.

바. 냉각단계bar. cooling step

냉각단계는, 상기 디자인 형성단계가 종료되면 금형 내부의 용융물을 냉각시켜 고체의 제품(테이프형 차선)으로 제작하고, 금형으로부터 테이프형 차선을 분리하는 단계이다.The cooling step is a step of cooling the melt inside the mold to produce a solid product (tape-type lane) and separating the tape-type lane from the mold when the design forming step is completed.

상술된 과정으로 제조된 테이프형 차선은, 도로 노면 상의 이물질을 제거하는 세척작업을 수행한 후, 차선 형성 영역에 테이프형 차선을 설치(안착)한 뒤, 통상의 열융착 장비를 이용하여 노면 상에 테이프형 차선이 융착될 수 있도록 한다.The tape-type lane manufactured by the above-described process is cleaned by removing foreign substances on the road surface, then the tape-type lane is installed (seated) in the lane formation area, to allow the tape-type lane to be fused.

Claims (2)

바인더, 탄성재, 충전재, 글라스비드, 무기안료, 형광증백 혼합조성물, 침강방지제 및 점도조절제를 재료로 하여, 도로 노면에 융착방식으로 설치되는 테이프형 차선의 제조방법에 있어서,
상기 재료는,
무게비를 기준으로 바인더 100중량부에 대하여, 탄성재 50중량부, 충전재 350중량부, 글라스비드 200중량부, 무기안료 20중량부, 형광증백 혼합조성물 50중량부, 침강방지제 10중량부 및 점도조절제 20~30중량부를 사용하는 것을 특징으로 하는, 시인성이 향상된 테이프형 차선의 제조방법.
In the manufacturing method of a tape-type lane installed on a road surface by a fusion method using a binder, an elastic material, a filler, a glass bead, an inorganic pigment, a fluorescent whitening mixed composition, an anti-settling agent and a viscosity modifier as materials,
The material is
Based on the weight ratio, with respect to 100 parts by weight of binder, 50 parts by weight of elastic material, 350 parts by weight of filler, 200 parts by weight of glass beads, 20 parts by weight of inorganic pigment, 50 parts by weight of fluorescent whitening mixed composition, 10 parts by weight of anti-settling agent and viscosity modifier A method for manufacturing a tape-type lane with improved visibility, characterized in that 20 to 30 parts by weight is used.
청구항 1에 있어서,
상기 테이프형 차선의 제조방법은,
상기 재료를 준비하는 a단계;
상기 a단계에서 준비된 재료 중, 바인더, 탄성재, 충전재, 무기안료, 침강방지제 및 점도조절제를 용융시켜 용융물로 금형에 투입하는 b단계;
상기 b단계 후 수행되는 단계로서, 상기 a단계의 재료 중, 글라스비드를,
상기 b단계에서 투입된 용융물에 혼입하여 혼합 용융물을 획득하는 c단계;
상기 c단계 후 수행되는 단계로서, 상기 a단계의 재료 중 형광증백 혼합조성물을 혼입하여 최종 용융물을 획득하는 d단계;
상기 d단계까지 종료됨에 따라 금형에 투입된 최종 용융물이 경화된기 전에 디자인을 형성하는 e단계; 및
상기 e단계가 종료되면 금형 내부의 용융물을 냉각시켜 고체의 제품으로 제작하고, 금형으로부터 테이프형 차선을 분리하는 f단계;를 포함하는 것을 특징으로 하는, 시인성이 향상된 테이프형 차선의 제조방법.
The method of claim 1,
The manufacturing method of the tape-type lane,
a step of preparing the material;
Step b of melting a binder, an elastic material, a filler, an inorganic pigment, an anti-settling agent, and a viscosity control agent among the materials prepared in step a, and introducing the melt into a mold;
As a step performed after step b, among the materials of step a, glass beads,
step c of obtaining a mixed melt by mixing with the melt introduced in step b;
As a step performed after step c, step d of obtaining a final melt by incorporating the fluorescent whitening mixed composition among the materials of step a;
Step e of forming a design before the final melt injected into the mold is cured upon completion of step d; and
When the step e is completed, step f of cooling the melt inside the mold to produce a solid product and separating the tape-type lane from the mold; characterized in that it comprises a tape-type lane manufacturing method with improved visibility.
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