KR20220149939A - Method for producing chlorine dioxide generator - Google Patents
Method for producing chlorine dioxide generator Download PDFInfo
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- KR20220149939A KR20220149939A KR1020210056973A KR20210056973A KR20220149939A KR 20220149939 A KR20220149939 A KR 20220149939A KR 1020210056973 A KR1020210056973 A KR 1020210056973A KR 20210056973 A KR20210056973 A KR 20210056973A KR 20220149939 A KR20220149939 A KR 20220149939A
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- chlorine dioxide
- chlorite
- chlorate
- dioxide generator
- oil
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 110
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 55
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 55
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 31
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- 238000002156 mixing Methods 0.000 claims abstract description 25
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims abstract description 24
- 239000012190 activator Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 19
- 150000007524 organic acids Chemical class 0.000 claims abstract description 14
- 229910001919 chlorite Inorganic materials 0.000 claims abstract description 12
- 229910052619 chlorite group Inorganic materials 0.000 claims abstract description 12
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003513 alkali Substances 0.000 claims abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 12
- 235000019198 oils Nutrition 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000005909 Kieselgur Substances 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 239000000741 silica gel Substances 0.000 claims description 4
- 229910002027 silica gel Inorganic materials 0.000 claims description 4
- 239000003549 soybean oil Substances 0.000 claims description 4
- 235000012424 soybean oil Nutrition 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical group CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 2
- 239000005662 Paraffin oil Substances 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- WOHVONCNVLIHKY-UHFFFAOYSA-L [Ba+2].[O-]Cl=O.[O-]Cl=O Chemical compound [Ba+2].[O-]Cl=O.[O-]Cl=O WOHVONCNVLIHKY-UHFFFAOYSA-L 0.000 claims description 2
- ISFLYIRWQDJPDR-UHFFFAOYSA-L barium chlorate Chemical compound [Ba+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O ISFLYIRWQDJPDR-UHFFFAOYSA-L 0.000 claims description 2
- YALMXYPQBUJUME-UHFFFAOYSA-L calcium chlorate Chemical compound [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O YALMXYPQBUJUME-UHFFFAOYSA-L 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- QXIKMJLSPJFYOI-UHFFFAOYSA-L calcium;dichlorite Chemical compound [Ca+2].[O-]Cl=O.[O-]Cl=O QXIKMJLSPJFYOI-UHFFFAOYSA-L 0.000 claims description 2
- 239000000828 canola oil Substances 0.000 claims description 2
- 235000019519 canola oil Nutrition 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 239000008169 grapeseed oil Substances 0.000 claims description 2
- XQHAGELNRSUUGU-UHFFFAOYSA-M lithium chlorate Chemical compound [Li+].[O-]Cl(=O)=O XQHAGELNRSUUGU-UHFFFAOYSA-M 0.000 claims description 2
- KAGBQTDQNWOCND-UHFFFAOYSA-M lithium;chlorite Chemical compound [Li+].[O-]Cl=O KAGBQTDQNWOCND-UHFFFAOYSA-M 0.000 claims description 2
- NNNSKJSUQWKSAM-UHFFFAOYSA-L magnesium;dichlorate Chemical compound [Mg+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O NNNSKJSUQWKSAM-UHFFFAOYSA-L 0.000 claims description 2
- NWAPVVCSZCCZCU-UHFFFAOYSA-L magnesium;dichlorite Chemical compound [Mg+2].[O-]Cl=O.[O-]Cl=O NWAPVVCSZCCZCU-UHFFFAOYSA-L 0.000 claims description 2
- 239000004006 olive oil Substances 0.000 claims description 2
- 235000008390 olive oil Nutrition 0.000 claims description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 claims description 2
- VISKNDGJUCDNMS-UHFFFAOYSA-M potassium;chlorite Chemical compound [K+].[O-]Cl=O VISKNDGJUCDNMS-UHFFFAOYSA-M 0.000 claims description 2
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical group [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 2
- 229960002218 sodium chlorite Drugs 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 239000002600 sunflower oil Substances 0.000 claims 1
- 235000013305 food Nutrition 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 3
- 238000003860 storage Methods 0.000 description 9
- 238000004806 packaging method and process Methods 0.000 description 5
- 235000020188 drinking water Nutrition 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000007938 effervescent tablet Substances 0.000 description 1
- 230000009246 food effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 238000009461 vacuum packaging Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
- A23L3/3418—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/024—Preparation from chlorites or chlorates from chlorites
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Abstract
Description
본 발명은 이산화염소 발생제 제조방법에 관한 것으로서, 더욱 상세하게는 식품의 신선도 유지 및 악취 제거기능을 위한 이산화염소가 지속적으로 발생될 수 있는 이산화염소 발생제 제조방법에 관한 것이다.The present invention relates to a method for producing a chlorine dioxide generator, and more particularly, to a method for producing a chlorine dioxide generator in which chlorine dioxide can be continuously generated for maintaining food freshness and removing odors.
일반적으로 이산화염소는 소독, 살균 및 악취 제거와 같은 많은 용도에서 유용한 수성용액을 생성하는 반응성이 매우 높은 등황색의 가스이다.In general, chlorine dioxide is a highly reactive orange-yellow gas that produces aqueous solutions useful in many applications such as disinfection, sterilization and odor removal.
이산화염소 가스는 강력한 산화제로 작용하며 항 미생물제, 표백제 및 살균제로서 식수처리를 하는 정수장과 건물에 식수를 공급하는 저수탱크와 냉각탑 및 가금류 냉각수 탱크 및 식품가공현장에서의 세척수 등으로 그 사용 범위를 점점 확대하고 있다.Chlorine dioxide gas acts as a strong oxidizing agent, and as an antimicrobial agent, bleaching agent and disinfectant, its use is gradually expanding to water purification plants that treat drinking water, water storage tanks that supply drinking water to buildings, cooling towers, poultry cooling water tanks, and washing water at food processing sites. is expanding
통상적으로 이산화염소는 자연적으로 얻어지는 물질이 아니라 화합물질로서 소금 또는 여러 화합물의 화학처리를 함으로써 얻어지는 물질이다.In general, chlorine dioxide is not a substance obtained naturally, but a substance obtained by chemical treatment of salt or various compounds as a compound.
이산화염소를 식수나 식품 등에 사용할 수 있도록 친환경적이며 인체에 해롭지 않고 안정적인 방법으로 얻기 위하여 다양한 기술들이 발생하고 있는데, 대표적으로 하나 이상의 첨가물을 혼합하여 이산화염소가 희석되어 있는 액상 또는 발포정과 같은 형태로 조성하거나 또는 수ppm 수준의 이산화염소를 만들 수 있는 기기장치들을 형성하는 등의 기술이 공지되어 있다.Various technologies are being developed to obtain chlorine dioxide in an eco-friendly, non-harmful and stable way so that it can be used in drinking water or food. Typically, one or more additives are mixed to form a liquid or effervescent tablet with diluted chlorine dioxide Or, the technology is known, such as forming a device capable of producing a few ppm level of chlorine dioxide.
하지만, 이산화염소가 희석되어 있는 액상의 조성물인 경우 저장안정성이 낮고, 액상 조성물을 포장시 누출 및 저장성에 문제점이 발생하여 소포장 형태로 포장판매하는데 어려움이 많다. 이에 따라 소포장으로 포장이 용이한 고형조성물 형태로 변형시켜 포장 안정성을 개선하였으며 진공상태 포장에서 저장성이 대폭 향상되게 되었다.However, in the case of a liquid composition in which chlorine dioxide is diluted, storage stability is low, and problems occur in leakage and storability when packaging the liquid composition, making it difficult to package and sell the liquid composition in the form of small packaging. Accordingly, the packaging stability was improved by transforming it into a solid composition that can be easily packaged in small packaging, and storage performance was greatly improved in vacuum packaging.
본 발명은 상기한 종래 기술에서의 문제점을 개선하기 위해 제안된 것으로서, 이산화염소 가스가 지속적으로 발생될 수 있는 발생제의 제조가 보다 간단하면서 효율적으로 이루어질 수 있는 제조방법을 제공함으로써 사용 편의성을 향상시키도록 하는데 목적이 있다.The present invention is proposed to improve the problems in the prior art, and improves convenience of use by providing a manufacturing method in which the production of a generator that can continuously generate chlorine dioxide gas can be made more simply and efficiently The purpose is to make it happen.
상기 목적을 이루기 위한 본 발명의 이산화염소 발생제 제조방법은, 담체입자와, 염소산염 또는 아염소산염, 알칼리제를 혼합하여 A제를 제조하는 A제 제조단계와; 상기 제조된 A제에 유기산이 함침된 활성화제를 혼합하는 혼합단계;를 포함하는 것을 특징으로 한다.A method for producing a chlorine dioxide generator of the present invention for achieving the above object includes: a preparation step of agent A for preparing agent A by mixing carrier particles, chlorate or chlorite, and an alkali agent; and a mixing step of mixing the prepared agent A with an activator impregnated with an organic acid.
이러한 본 발명의 이산화염소 발생제 제조방법은, 이산화염소 발생제의 제조가 보다 용이하게 이루어질 수 있게 되어 생산 비용을 절감시킴과 함께 이산화염소가 일정하게 방출될 수 있게 되어 식품의 선도유지 효과가 향상되어질 수 있게 된다.The chlorine dioxide generator production method of the present invention enables the production of the chlorine dioxide generator to be made more easily, thereby reducing the production cost and allowing the chlorine dioxide to be constantly released, thereby improving the freshness effect of food. can become
또한, 식품의 신선도를 유지하기 위한 저장시 식품의 수분을 유지하기 위하여 고습도 저장시 활성화제를 사용함으로써 고습도에서도 이산화염소가 안정적으로 방출될 수 있는 이점을 나타낸다.In addition, it shows the advantage that chlorine dioxide can be stably released even at high humidity by using an activator during storage at high humidity to maintain moisture of food during storage to maintain freshness of food.
도 1은 본 발명의 일 실시 예에 따른 이산화염소 발생제 제조과정 순서도.
도 2는 본 발명의 다른 실시 예에 따른 이산화염소 발생제 제조과정 순서도.
도 3은 본 발명의 이산화염소 발생제 방출 실험 데이터(고습도).
도 4는 본 발명의 이산화염소 발생제 방출 실험 데이터(저습도).1 is a flowchart of a chlorine dioxide generator manufacturing process according to an embodiment of the present invention.
Figure 2 is a flow chart of the production process of the chlorine dioxide generator according to another embodiment of the present invention.
Figure 3 is the chlorine dioxide generator release experimental data (high humidity) of the present invention.
Figure 4 is the chlorine dioxide generator release experimental data of the present invention (low humidity).
이하, 본 발명의 구체적인 실시 예를 첨부 도면을 참조하여 상세히 살펴보면 다음고 같다.Hereinafter, specific embodiments of the present invention will be described in detail with reference to the accompanying drawings.
본 발명의 실시 예는 여러 가지 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상세히 설명하는 실시 예로 한정되는 것으로 해석되어서는 안 된다. 본 실시 예는 당 업계에서 평균적인 지식을 가진 자에게 본 발명을 더욱 완전하게 설명하기 위하여 제공되는 것이다.Embodiments of the present invention may be modified in various forms, and the scope of the present invention should not be construed as being limited to the embodiments described in detail below. This embodiment is provided to more completely explain the present invention to those of ordinary skill in the art.
따라서, 도면에서 표현한 구성요소의 형상 등은 더욱 명확한 설명을 강조하기 위해서 과장되어 표현될 수 있다. 각 도면에서 동일한 구성은 동일한 참조부호로 도시한 경우가 있음을 유의하여야 한다. 또한, 본 발명의 요지를 불필요하게 흐릴 수 있다고 판단되는 공지 기술의 기능 및 구성에 관한 상세한 설명은 생략될 수 있다.Accordingly, the shape of the components expressed in the drawings may be exaggerated to emphasize a clearer description. It should be noted that the same configuration in each drawing is sometimes illustrated with the same reference numerals. In addition, detailed descriptions of functions and configurations of known technologies that may unnecessarily obscure the gist of the present invention may be omitted.
먼저, 본 발명의 일 실시 예에 따른 이산화염소 발생제 제조과정을 도 1의 순서도를 통해 살펴보면 다음과 같다.First, looking through the flowchart of FIG. 1, a process for producing a chlorine dioxide generator according to an embodiment of the present invention is as follows.
본 실시 예에서는 제오라이트, 규조토, 벤토나이트 또는 실리카겔 등의 성분으로 이루어지는 무기 다공질 담체입자와, 염소산염 또는 아염소산염, 알칼리제를 혼합하여 A제를 제조하는 A제 제조단계와, 상기 제조된 A제에 유기산이 함침된 활성화제를 혼합하는 혼합단계를 통해 제조가 이루어지게 된다.In this embodiment, the agent A manufacturing step of preparing agent A by mixing inorganic porous carrier particles made of components such as zeolite, diatomaceous earth, bentonite or silica gel, chlorate or chlorite, and an alkali agent, and organic acid in the prepared agent A Manufacturing is performed through a mixing step of mixing the impregnated activator.
이때, 상기 A제 제조단계에서는 담체입자 100중량%를 기준으로 염소산염 또는 아염소산염 1~25중량%, 알칼리제 1~20중량%의 비율로 혼합이 이루어짐이 바람직하다. At this time, in the preparation step of the agent A, it is preferable that mixing is performed in a ratio of 1 to 25% by weight of chlorate or chlorite, and 1 to 20% by weight of the alkali agent based on 100% by weight of the carrier particles.
특히, 본 실시 예에서의 염소산염은 염소산나트륨, 염소산칼륨, 염소산칼슘, 염소산 마그네슘, 염소산리튬, 염소산바륨 중 적어도 어느 하나 이상의 성분이 사용된다.In particular, as the chlorate in this embodiment, at least one of sodium chlorate, potassium chlorate, calcium chlorate, magnesium chlorate, lithium chlorate, and barium chlorate is used.
또한, 본 실시 예에서의 아염소산염은 아염소산나트륨, 아염소산칼륨, 아염소산칼슘, 아염소산 마그네슘, 아염소산리튬, 아염소산바륨 중 적어도 어느 하나 이상의 성분이 사용된다.In addition, as the chlorite in this embodiment, at least one component of sodium chlorite, potassium chlorite, calcium chlorite, magnesium chlorite, lithium chlorite, and barium chlorite is used.
그리고, 상기 알칼리제는 수산화나트륨, 수산화칼륨, 수산화칼슘, 규산소다 중 어느 하나 이상의 성분이 사용된다.And, the alkali agent is sodium hydroxide, potassium hydroxide, calcium hydroxide, any one or more components of sodium silicate are used.
한편, 상기 혼합 단계에서 혼합이 이루어지는 활성화제는 담체입자에 액상의 유기산을 함침한 후 건조과정을 거쳐서 제조된 유기산 담체입자와 혼합되어지게 되는데, 이때의 유기산은 구연산 또는 사과산 성분이 선택적으로 사용됨이 바람직하다.On the other hand, the activator to be mixed in the mixing step is mixed with the organic acid carrier particles prepared through a drying process after impregnating the carrier particles with a liquid organic acid. In this case, citric acid or malic acid is selectively used. desirable.
즉, 활성화제는 담체입자(규조토, 제오라이트, 벤토나이트, 실리카겔) 100중량% 기준으로 유기산 용액이 5~30중량%로 함침된 상태에서 건조 작업이 이루어지게 된다.That is, the activator is dried in a state impregnated with an organic acid solution in an amount of 5 to 30% by weight based on 100% by weight of the carrier particles (diatomaceous earth, zeolite, bentonite, silica gel).
또한, 상기 혼합단계에서는 A제 100중량% 기준으로 활성화제가 5~100중량%의 비율로 혼합이 이루어지게 된다.In addition, in the mixing step, the activator is mixed in a ratio of 5 to 100% by weight based on 100% by weight of agent A.
도 2는 본 발명의 다른 실시 예에 따른 이산화염소 발생제 제조과정을 나타낸 것으로서, 담체입자와, 염소산염 또는 아염소산염, 오일을 혼합하여 A제를 제조하는 A제 제조단계와, 상기 제조된 A제에 유기산이 함침된 활성화제를 혼합하는 혼합단계를 통해 제조가 이루어지게 된다.2 is a view showing a process for producing a chlorine dioxide generator according to another embodiment of the present invention, the preparation step of preparing agent A by mixing carrier particles, chlorate or chlorite, and oil, and the prepared agent A It is manufactured through a mixing step of mixing an activator impregnated with an organic acid.
이때, 상기 A제 제조단계에서는 담체입자 100중량%를 기준으로 염소산염 또는 아염소산염 1~25중량%, 오일 1~25중량%의 비율로 혼합이 이루어짐이 바람직하다.In this case, in the preparation step of the agent A, it is preferable that mixing is performed in a ratio of 1 to 25% by weight of chlorate or chlorite, and 1 to 25% by weight of oil, based on 100% by weight of carrier particles.
특히, 본 실시 예에서의 오일은 염소산염 또는 아염소산염 등이 담체입자 내에 잔존하는 수분과의 직접적인 접촉을 막아주면서 염소산염 또는 아염소산염 성분이 담체입자에 원활하게 코팅될 수 있도록 도와주는 중요한 기능을 수행하게 된다. 이와 같은 기능을 하는 오일은 콩기름, 포도씨유, 올리브유, 카놀라유, 해바라기씨유, 피마자오일, 파라핀오일 중 적어도 어느 하나 이상이 단독 또는 혼합 사용될 수 있다.(이 외에도 수분과 직접적인 접촉을 막아주는 기능을 수행할 수 있는 식용오일 또는 공업용 오일이 사용될 수 있다)In particular, the oil in this embodiment performs an important function of helping the chlorate or chlorite component to be smoothly coated on the carrier particles while preventing direct contact of the chlorate or chlorite with moisture remaining in the carrier particles. do. At least one or more of soybean oil, grape seed oil, olive oil, canola oil, sunflower seed oil, castor oil, and paraffin oil may be used alone or in combination. Edible oil or industrial oil that can be used can be used)
또한, 상기 혼합 단계에서 혼합이 이루어지는 활성화제는 담체입자에 액상의 유기산을 함침한 후 건조과정을 거쳐서 제조된 유기산 담체입자와 혼합되어지게 되는데, 이때의 유기산은 구연산 또는 사과산 성분이 선택적으로 사용됨이 바람직하다.In addition, the activator to be mixed in the mixing step is mixed with the organic acid carrier particles prepared through a drying process after impregnating the carrier particles with a liquid organic acid, and the organic acid at this time is citric acid or malic acid. desirable.
즉, 활성화제는 담체입자(규조토, 제오라이트, 벤토나이트, 실리카겔) 100중량% 기준으로 유기산 용액이 5~30중량%로 함침된 상태에서 건조 작업이 이루어지게 된다.That is, the activator is dried in a state impregnated with an organic acid solution in an amount of 5 to 30% by weight based on 100% by weight of the carrier particles (diatomaceous earth, zeolite, bentonite, silica gel).
또한, 상기 혼합단계에서는 A제 100중량% 기준으로 활성화제가 5~100중량%의 비율로 혼합이 이루어지게 된다.In addition, in the mixing step, the activator is mixed in a ratio of 5 to 100% by weight based on 100% by weight of agent A.
이와 같은 제조과정을 통해 제조된 본 발명의 이산화염소 발생제는 입자 형태로 제조가 이루어지는 것으로 소분하여 통기성 필름에 포장하여 사용이 이루어지게 되는데, 도 3 및 도 4의 실험 데이타에서 나타내어지는 같이 고습도 및 저습도에서 이산화염소 발생이 안정적으로 유지될 수 있게 됨을 확인할 수 있다.The chlorine dioxide generator of the present invention prepared through this manufacturing process is made in the form of particles, and is used by subdividing it and packaging it in a breathable film. As shown in the experimental data of FIGS. 3 and 4, high humidity and It can be confirmed that chlorine dioxide generation can be stably maintained at low humidity.
그중, 도 3의 고습도 실험의 경우 1) 알칼리제(수산화나트륨) 사용시 이산화염소 발생제를 고습도환경에서 보관시 활성화제를 사용하지 않은 이산화염소 발생제에서는 이산화염소가 전혀 발생되지 못했다. 즉, 식품저장시 저장환경의 습도는 고습도의 조건이 일반적으로 활성화제를 적절히 사용한 결과의 이산화염소 발생제 효과가 우수하게 나타남을 확인할 수 있었다. Among them, in the case of the high-humidity experiment of FIG. 3, 1) when the alkali agent (sodium hydroxide) was used, chlorine dioxide was not generated at all in the chlorine dioxide generator that did not use the activator when the chlorine dioxide generator was stored in a high-humidity environment. In other words, it was confirmed that the chlorine dioxide generator effect was excellent as a result of using the activator appropriately under conditions of high humidity for the humidity of the storage environment during food storage.
또한, 활성화제를 다량 사용시 초기 발생되는 이산화염소의 농도는 높으나 단기적으로 이산화염소가 발생되었으며, 활성화제를 소량 사용시 초기 발생되는 이산화염소의 농도는 낮으나 장기적으로 이산화염소가 발생되었다.In addition, when a large amount of the activator was used, the concentration of chlorine dioxide initially generated was high, but chlorine dioxide was generated in the short term.
또한, 고통기도의 포장지를 사용시 초기 발생되는 이산화염소의 농도는 높으나 단기적으로 이산화염소가 발생 되었으며, 저통기도의 포장지를 사용시에는 초기 발생되는 이산화염소의 농도는 낮으나 장기적으로 이산화염소가 발생되었다.In addition, when the high airway wrapping paper was used, the initially generated chlorine dioxide concentration was high, but chlorine dioxide was generated in the short term.
한편, 2) 오일(콩기름) 사용시 이산화염소 발생제는 고습도환경에서도 활성화제를 사용하지 않은 경우에도 안정적으로 발생이 되었다. 활성화제를 사용시 초기 발생되는 이산화염소의 농도는 높으나 단기적으로 이산화염소가 발생되었으며, 활성화제를 사용하지 않거나 소량사용시 초기의 이산화염소의 농도는 낮으나 장기적으로 이산화염소가 발생되었다. 즉, 식품 저장시 장기적으로 저장할 식품과 단기적으로 유통되어야 할 식품의 종류에 따라 활성화제와 포장지의 통기도를 적절히 사용하여 최적의 이산화염소 농도를 조절하여 각 식품에 맞는 이산화염소 발생제의 배합이 필요한다.Meanwhile, 2) when oil (soybean oil) was used, chlorine dioxide generator was stably generated even in a high humidity environment even when no activator was used. When an activator was used, the initial concentration of chlorine dioxide generated was high, but chlorine dioxide was generated in the short term. That is, it is necessary to mix the chlorine dioxide generator suitable for each food by adjusting the optimum chlorine dioxide concentration by appropriately using the air permeability of the activator and the wrapping paper according to the type of food to be stored in the long term and the food to be distributed in the short term during food storage. do.
또한, 도 4의 저습도 실험의 경우 1) 알칼리제(수산화나트륨) 사용시 이산화염소 발생제는 고습도와 달리 저습도에서는 활성화제를 사용하지 않는 경우에도 이산화염소가 발생이 되었다.In addition, in the case of the low-humidity experiment of FIG. 4, 1) when an alkali agent (sodium hydroxide) was used, chlorine dioxide was generated even when the activator was not used at low humidity, unlike the high-humidity chlorine dioxide generator.
그리고, 2) 오일(콩기름) 사용시 이산화염소 발생제는 저습도환경에서도 활성화제를 사용하지 않은 경우에도 안정적으로 발생이 되었으며, 저통기도 필름을 사용시 이산화염소 발생이 고통기도 필름 사용시 보다 장기적으로 이산화염소가 발생이 되었다. 즉, 식품저장과 달리 탈취제 등 저습도에서 사용시는 활성화제의 배합을 선택적으로 사용할 수 있으며, 알칼리제와 오일 등을 사용목적에 따라 생산안정성 및 선도유지제, 탈취 등 대상제품의 종류에 따라 알칼리제 및 오일 등을 선택적으로 사용할 수 있게됨을 알 수 있다.And, 2) When oil (soybean oil) is used, chlorine dioxide generator is generated stably even in low humidity environment even when no activator is used. has occurred In other words, unlike food storage, when using at low humidity, such as a deodorant, the combination of an activator can be selectively used. Depending on the purpose of use, alkaline agents and oils can be used for production stability, freshness retention, deodorization, etc., depending on the type of product. It can be seen that oil and the like can be selectively used.
따라서 본 발명의 이산화염소 발생제 제조방법은, 이산화염소 발생제의 제조가 보다 효율적으로 이루어질 수 있게 되어 제품의 생산 비용을 절감시킴과 함께 식품의 선도유지제로 활용하였을 때 선도유지 효과가 극대화되어질 수 있게 됨을 알 수 있다.Therefore, in the chlorine dioxide generator manufacturing method of the present invention, the production of the chlorine dioxide generator can be made more efficiently, thereby reducing the production cost of the product and maximizing the freshness retention effect when used as a freshness maintenance agent for food. It can be seen that there will be
그리고 상기에서 본 발명의 특정한 실시 예가 설명 및 도시되었지만 본 발명의 이산화염소 발생제 제조과정이 당업자에 의해 다양하게 변형되어 실시될 수 있음은 자명한 일이다. And although specific embodiments of the present invention have been described and illustrated in the above, it is obvious that the chlorine dioxide generator manufacturing process of the present invention can be practiced with various modifications by those skilled in the art.
예를 들면, 상기 다른 실시 예에서는 A제에 활성화제의 혼합이 생략된 상태로 오일이 혼합된 A제를 그대로 이산화염소 발생제로 사용이 이루어질 수 있게 된다.For example, in the other embodiment, agent A in which oil is mixed in a state in which mixing of the activator is omitted in agent A can be used as a chlorine dioxide generator as it is.
따라서 이와 같은 변형된 실시 예들은 본 발명의 기술적 사상이나 범위로부터 개별적으로 이해되어져서는 안되며, 이와 같은 변형된 실시 예들은 본 발명의 첨부된 특허청구범위 내에 포함된다 해야 할 것이다.Accordingly, such modified embodiments should not be individually understood from the technical spirit or scope of the present invention, and such modified embodiments should be included within the appended claims of the present invention.
Claims (8)
상기 제조된 A제에 유기산이 함침된 활성화제를 혼합하는 혼합단계;
를 포함하는 것을 특징으로 하는 이산화염소 발생제 제조방법.A preparation step of preparing agent A by mixing carrier particles, chlorate or chlorite, and an alkali agent;
a mixing step of mixing an activating agent impregnated with an organic acid with the prepared agent A;
A method for producing a chlorine dioxide generator comprising a.
상기 알칼리제는 수산화나트륨, 수산화칼륨, 수산화칼슘, 규산소다 중 어느 하나 이상의 성분이 사용됨을 특징으로 하는 이산화염소 발생제 제조방법.The method according to claim 1,
The alkali agent is a chlorine dioxide generator manufacturing method, characterized in that any one or more components of sodium hydroxide, potassium hydroxide, calcium hydroxide, sodium silicate is used.
를 포함하는 것을 특징으로 하는 이산화염소 발생제 제조방법.A preparation step of preparing agent A by mixing carrier particles, chlorate or chlorite, and oil;
A method for producing a chlorine dioxide generator comprising a.
상기 담체입자은 제오라이트, 규조토, 벤토나이트, 실리카겔 중 적어도 어느 하나 이상의 성분이 사용되고; 상기 염소산염은 염소산나트륨, 염소산칼륨, 염소산칼슘, 염소산 마그네슘, 염소산리튬, 염소산바륨 중 적어도 어느 하나 이상의 성분이 사용되며; 상기 아염소산염은 아염소산나트륨, 아염소산칼륨, 아염소산칼슘, 아염소산 마그네슘, 아염소산리튬, 아염소산바륨 중 적어도 어느 하나 이상의 성분이 사용됨을 특징으로 하는 이산화염소 발생제 제조방법.4. The method according to claim 1 or 3,
At least one component of zeolite, diatomaceous earth, bentonite, and silica gel is used as the carrier particle; The chlorate is sodium chlorate, potassium chlorate, calcium chlorate, magnesium chlorate, lithium chlorate, at least any one or more components of barium chlorate are used; The chlorite is sodium chlorite, potassium chlorite, calcium chlorite, magnesium chlorite, lithium chlorite, a method for producing a chlorine dioxide generator, characterized in that at least one component is used, barium chlorite.
상기 오일은 콩기름, 포도씨유, 올리브유, 카놀라유, 해바라기씨유, 피마자오일, 파라핀오일 중 어느 하나가 사용됨을 특징으로 하는 이산화염소 발생제 제조방법.4. The method of claim 3,
The oil is a chlorine dioxide generator manufacturing method, characterized in that any one of soybean oil, grape seed oil, olive oil, canola oil, sunflower oil, castor oil, and paraffin oil is used.
상기 제조된 A제에 유기산이 함침된 활성화제를 혼합하는 혼합단계가 추가로 실시됨을 특징으로 하는 이산화염소 발생제 제조방법.4. The method of claim 3,
A method for producing a chlorine dioxide generator, characterized in that the mixing step of mixing the organic acid-impregnated activator with the prepared agent A is additionally performed.
상기 활성화제는 담체입자에 액상의 유기산을 함침한 후 건조과정을 거친 후 혼합이 이루어지는 것을 특징으로 하는 이산화염소 발생제 제조방법.7. The method of any one of claims 1 or 6,
The method for producing a chlorine dioxide generator, characterized in that the activator is mixed after the carrier particles are impregnated with a liquid organic acid and then dried.
상기 유기산은 구연산 또는 사과산이 선택적으로 사용됨을 특징으로 하는 이산화염소 발생제 제조방법.
8. The method of claim 7,
The organic acid is a chlorine dioxide generator manufacturing method, characterized in that citric acid or malic acid is selectively used.
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