KR20210058354A - (Water improvement agent and water manufacturing method for using water improvement agent - Google Patents

(Water improvement agent and water manufacturing method for using water improvement agent Download PDF

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KR20210058354A
KR20210058354A KR1020190145689A KR20190145689A KR20210058354A KR 20210058354 A KR20210058354 A KR 20210058354A KR 1020190145689 A KR1020190145689 A KR 1020190145689A KR 20190145689 A KR20190145689 A KR 20190145689A KR 20210058354 A KR20210058354 A KR 20210058354A
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water
water quality
powder
weight
improvement agent
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KR1020190145689A
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Korean (ko)
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민석진
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동명생명과학원 주식회사
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents

Abstract

The present invention relates to a method for producing water quality-improvement water using a water quality-improvement agent. According to the present invention, the method comprises: a stirring step (S10) of mixing and stirring a water quality-improvement agent (1) in a stirring tank (10), wherein the water quality-improvement agent includes 5 to 23 wt% of loess powder, 12 to 28 wt% of porcelain powder, 6 to 8 wt% of feldspar powder, 2 to 4 wt% of carbon, and 10 to 30 wt% of waste fossil powder; an ion exchange step (S20) of mixing water with the mixed and stirred water quality-improvement agent (1) in the stirring tank (10) to perform ion exchange between hydrogen ions of the water and cations which are calcium, iron, and aluminum ions contained in the water quality-improvement agent (1), thereby allowing a hydrogen ion concentration of the water to have at least a strong basicity of 10 or more; and an outflow step (S30) of discharging the water in which the cations are mixed in the stirring tank (10). According to the present invention, since a water quality-improvement agent mixed with powder of natural minerals consisting of loess, porcelain, feldspar, carbon, and waste fossils and water quality-improvement water are sprayed in rivers, seas, and the like, etc., acidified water becomes basic water, inorganic phosphorus in the water is combined with aluminum and iron to be precipitated and removed, and hydrogen sulfide in the water is removed. Moreover, a water molecule cluster has a frequency of 30 to 60 Hz, an oxidation-reduction potential of -300 to -600 mV, and a high degree of biodegradation, so that the oxygen solubility in water is increased thereby improving water quality and preventing occurrence of green or red algae.

Description

수질개선제 및 이를 이용한 수질개선용 물 제조방법{(Water improvement agent and water manufacturing method for using water improvement agent}Water improvement agent and water manufacturing method for using water improvement agent {(Water improvement agent and water manufacturing method for using water improvement agent})

본 발명은 수질개선제 및 이를 이용한 수질개선용 물 제조방법에 관한 것으로, 특히 천연광물들인 황토, 도석, 장석, 카본 및 폐화석을 분쇄한 후 이들을 혼합한 수질개선제와 수질개선제에 물을 혼합하여 수질개선용 물을 제조하여 수질개선제 또는 수질개선용 물을 하천 또는 바다 등에 살포하여 하천 또는 바다 등의 수질을 개선할 수 있는 수질개선제 및 이를 이용한 수질개선용 물 제조방법에 관한 것이다.The present invention relates to a water quality improving agent and a method for producing water for improving water quality using the same.In particular, after pulverizing natural minerals such as loess, pottery stone, feldspar, carbon, and waste fossil, water is mixed with a water quality improving agent and a water quality improving agent. The present invention relates to a water quality improving agent capable of improving water quality in a river or sea by spraying a water quality improving agent or water for improving water quality into a river or sea by producing water for improvement, and a method for producing water for improving water quality using the same.

일반적으로 하천 또는 바다 등은 인위적으로 투입되는 쓰레기, 정화되지 않은 폐수의 방류, 석유 화학계 원료를 사용하는 합성세제나 비누 사용에 의한 물의 방류 등에 의해 질소(N) 및 인(P)의 퇴적율을 높여 수질을 오염시키게 된다.In general, rivers or seas increase the deposition rate of nitrogen (N) and phosphorus (P) by discharging artificially introduced waste, discharging unpurified wastewater, and discharging water by using synthetic detergent or soap using petrochemical materials. It will pollute the water quality.

또한, 자연적으로 발생되는 녹조 및 적조현상에 의해 식물성 플랑크톤이 부영양화 등에 의한 이상 증식에 의해 물의 용존산소량이 크게 감소되어 어류와 수중 생물이 죽게 되고, 산소가 없는 상태에서는 유해한 황화수소 등 이 발생되고 물이 산성으로 되는 등 화학적 성분이 악화되고, 악취가 발생된다.In addition, the amount of dissolved oxygen in water is greatly reduced due to abnormal growth of phytoplankton due to eutrophication due to the naturally occurring green algae and red tide phenomena, resulting in the death of fish and aquatic organisms. In the absence of oxygen, harmful hydrogen sulfide is generated and water is lost. Chemical components deteriorate, such as becoming acidic, and odors are generated.

종래의 경우 오염된 물을 정화처리하는 하폐수처리시설을 설치하여 하천 또는 바다에 정화처리된 물이 유입되도록 하여 하천 또는 바다 등이 오염되는 것을 방지하거나, 석회계 수처리제를 살포하거나 인공습지를 조성하여 하천 또는 바다 등이 오염되는 것을 방지하였다.In the conventional case, a sewage treatment facility that purifies contaminated water is installed to allow the purified water to flow into the river or sea to prevent contamination of the river or sea, or by spraying a lime-based water treatment agent or creating an artificial wetland. It prevented contamination of rivers or seas.

하폐수처리시설을 설치하거나, 인공습지를 조성하는 경우 비용이 과다하게 소모되고, 석회계 수처리제의 살포는 수생생물의 서식환경을 파괴하는 문제점을 가지고 있다.When installing a sewage treatment facility or constructing an artificial wetland, the cost is excessive, and spraying of lime-based water treatment agents has a problem of destroying the habitat environment of aquatic organisms.

본 발명의 목적은 황토, 도석, 장석, 카본 및 폐화석으로 이루어진 천연광물의 분말을 혼합한 수질개선제를 하천 또는 바다 등에 살포하여 산성화된 물을 염기성으로 만들어 주고, 수중의 인은 알루미늄과 철과 결합되어 침전되어 수중의 인을 제거시키고, 수중의 황화수소를 제거시키고, 수중의 산소용존도를 높여 수질을 개선시키고, 녹조나 적조의 발생을 방지할 수 있는 수질개선제를 제공하는 데 있다.An object of the present invention is to make acidified water basic by spraying a water quality improving agent mixed with natural mineral powder consisting of ocher, pottery stone, feldspar, carbon and waste fossil to make acidified water basic. It is combined and precipitated to remove phosphorus in water, remove hydrogen sulfide in water, improve water quality by increasing oxygen solubility in water, and provide a water quality improving agent that can prevent the occurrence of green algae or red algae.

본 발명의 다른 목적은 수질개선제에 물을 혼합교반하여 교반조 내의 물의 수소이온과 수질개선제의 칼슘이온, 철이온 및 알루미늄이온인 양이온과 이온교환이 이루어져, 교반조 내의 물은 강염기성을 가지며, 교반조 내의 물분자의 클러스터는 30헤르쯔에서 60헤르쯔를 가지며, 산화환원전위는 -300㎷ 내지 -600㎷를 가지며, 높은 생분해도를 가지게 되어, 교반조 내의 양이온이 혼재된 물을 외부로 유출시켜, 유출된 물을 하천 또는 바다 등에 살포시켜 산성화된 물을 염기성으로 만들어 주고, 수중의 인은 알루미늄과 철과 결합되어 침전되어 수중의 인을 제거시키고, 수중의 황화수소를 제거시키고, 수중의 산소용존도를 높여 수질을 개선시키고, 녹조나 적조의 발생을 방지할 수 있는 수질개선제를 이용한 수질개선용 물 제조방법을 제공하는 데 있다.Another object of the present invention is to mix and stir water with a water quality improver to exchange hydrogen ions of water in a stirring tank with cations, which are calcium ions, iron ions and aluminum ions of the water quality improver, and the water in the stirring tank has a strong basicity, The cluster of water molecules in the stirring tank has a 30Hz to 60Hz redox potential, and has a high biodegradability, so that the water containing cations in the stirring tank is discharged to the outside. , Spraying the spilled water into rivers or seas to make acidified water basic, and phosphorus in the water is combined with aluminum and iron to precipitate and remove phosphorus in the water, remove hydrogen sulfide in water, and dissolve oxygen in the water. To improve water quality by raising the degree, and to provide a water production method for improving water quality using a water quality improving agent that can prevent the occurrence of green algae or red tide.

상기의 목적을 달성하기 위하여 본 발명의 수질개선제는 황토분말 5 내지 23 중량%와, 도석분말 12 내지 28 중량%와, 장석분말 6 내지 8 중량%와, 카본 2 내지 4 중량%와, 폐화석분말 10 내지 30 중량%를 포함하여 이루어진 것을 특징으로 한다.In order to achieve the above object, the water quality improving agent of the present invention includes 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, 6 to 8% by weight of feldspar powder, 2 to 4% by weight of carbon, and waste fossils. It characterized in that it comprises 10 to 30% by weight of powder.

또한, 상기의 목적을 달성하기 위하여 본 발명의 수질개선제를 이용한 수질개선용 물 제조방법은 5 내지 23 중량%의 황토분말과, 12 내지 28 중량%의 도석분말과, 6 내지 8 중량%의 장석분말과, 2 내지 4 중량%의 카본과, 10 내지 30 중량%의 폐화석분말로 이루어진 수질개선제를 교반조에서 혼합하여 교반하는 교반단계; 상기 교반조 내에 혼합교반된 수질개선제에 물을 혼합한 후 교반시켜 상기 수질개선제가 함유하고 있는 칼슘이온, 철이온 및 알루미늄이온들인 양이온과 상기 물의 수소이온과 이온교환되면서 상기 물은 적어도 수소이온농도가 10이상의 강염기성을 갖게 되는 이온교환단계; 및 상기 교반조 내의 양이온이 혼재된 물을 유출시키는 유출단계를 구비한 것을 특징으로 한다.In addition, in order to achieve the above object, the water production method for improving water quality using the water quality improving agent of the present invention includes 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, and 6 to 8% by weight of feldspar. A stirring step of mixing and stirring a water quality improving agent composed of powder, 2 to 4% by weight of carbon and 10 to 30% by weight of waste fossil powder in a stirring tank; Water is mixed with the water quality improving agent mixed and stirred in the stirring tank, and then stirred. As the water is ion-exchanged with the hydrogen ions of the water and calcium ions, iron ions, and aluminum ions contained in the water quality improving agent, the water has at least a hydrogen ion concentration. An ion exchange step of having a strong basicity of 10 or more; And an outflow step of discharging water in which cations are mixed in the stirring tank.

또한, 본 발명의 수질개선제를 이용한 수질개선용 물 제조방법은 상기 유출단계시 정촉매를 사용하여 상기 유출되는 물의 이온교환반응을 촉진시켜주는 촉매반응단계를 더 구비한 것을 특징으로 한다.In addition, the method for producing water for improving water quality using the water quality improving agent of the present invention is characterized in that it further comprises a catalytic reaction step for accelerating the ion exchange reaction of the outflow water using a positive catalyst during the outflow step.

본 발명의 수질개선제와 수질개선제를 이용한 수질개선용 물 제조방법은 황토, 도석, 장석, 카본 및 폐화석으로 이루어진 천연광물의 분말을 혼합한 수질개선제와 수질개선용 물을 하천 또는 바다 등에 살포하여 산성화된 물을 염기성으로 만들어주고, 수중의 무기인은 알루미늄과 철과 결합되어 침전되어 수중의 무기인을 제거시키고, 수중의 황화수소를 제거시키고, 물분자의 클러스터는 30헤르쯔에서 60헤르쯔를 가지며, 산화환원전위는 -300㎷내지 -600㎷를 가지며, 높은 생분해도를 가지게 되어 수중의 산소용존도를 높여 수질을 개선시키고, 녹조나 적조의 발생을 방지할 수 있다.The water quality improvement agent of the present invention and the water quality improvement method using the water quality improvement agent are sprayed with a water quality improving agent mixed with natural mineral powder consisting of loess, pottery stone, feldspar, carbon and waste fossil, and water for improving water quality in rivers or seas. It makes acidified water basic, and inorganic phosphorus in water is combined with aluminum and iron and precipitated to remove inorganic phosphorus in water, remove hydrogen sulfide in water, and clusters of water molecules have 30Hz to 60Hz. The oxidation-reduction potential is -300㎷ to -600㎷, and it has a high biodegradability, which improves the water quality by increasing the oxygen solubility in water, and prevents the occurrence of green algae or red algae.

도 1은 본 발명의 수질개선제를 이용한 수질개선용 물 제조방법의 순서도이고,
도 2는 본 발명의 수질개선용 물 제조방법을 위한 장치의 개략도이다.
1 is a flow chart of a water production method for improving water quality using the water quality improving agent of the present invention,
2 is a schematic diagram of an apparatus for a method for producing water for improving water quality of the present invention.

이하, 첨부된 도면을 참조하여 본 발명의 수질개선제와 수질개선제를 이용한 수질개선용 물 제조방법을 상세히 설명하고자 한다.Hereinafter, with reference to the accompanying drawings will be described in detail the water quality improving agent of the present invention and a method for producing water for improving water quality using the water quality improving agent.

본 발명의 수질개선제는 황토분말 5 내지 23 중량%와, 도석분말 12 내지 28 중량%와, 장석분말 6 내지 8 중량%와, 카본 2 내지 4 중량%와, 폐화석분말 10 내지 30 중량%를 포함하여 이루어진다.The water quality improving agent of the present invention comprises 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, 6 to 8% by weight of feldspar powder, 2 to 4% by weight of carbon, and 10 to 30% by weight of waste fossil powder. Including.

도 1은 본 발명의 수질개선제를 이용한 수질개선용 물 제조방법의 순서도이고, 도 2는 수질개선용 물 제조방법을 위한 장치의 개략도이다.1 is a flow chart of a method for producing water for improving water quality using a water quality improving agent of the present invention, and FIG. 2 is a schematic diagram of an apparatus for a method for producing water for improving water quality.

도 1 및 도 2에 도시된 바와 같이 본 발명의 수질개선제를 이용한 수질개선용 물 제조방법은 5 내지 23 중량%의 황토분말과, 12 내지 28 중량%의 도석분말과, 6 내지 8 중량%의 장석분말과, 2 내지 4 중량%의 카본과, 10 내지 30 중량%의 폐화석분말로 이루어진 수질개선제(1)를 교반조(10)에서 혼합하여 교반하는 교반단계(S10)와, 교반조(10) 내에 혼합교반된 수질개선제(1)에 물(40)을 혼합한 후 교반시켜 수질개선제(1)가 함유하고 있는 칼슘이온, 철이온 및 알루미늄이온들인 양이온과 물의 수소이온과 이온교환되면서 물은 적어도 수소이온농도가 10 이상의 강염기성을 갖게 되는 이온교환단계(S20)와, 교반조(10) 내의 양이온이 혼재된 물을 유출시키는 유출단계(S30)로 구성된다.As shown in Figures 1 and 2, the water production method for improving water quality using the water quality improving agent of the present invention includes 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, and 6 to 8% by weight. A stirring step (S10) of mixing and stirring the water quality improving agent (1) consisting of feldspar powder, 2 to 4% by weight of carbon and 10 to 30% by weight of waste fossil powder in a stirring tank 10, and a stirring tank ( 10) Water (40) is mixed with the water quality improver (1) mixed and stirred in the water quality improving agent (1) by ion exchange with the cation of calcium ions, iron ions and aluminum ions contained in the water quality improving agent (1), and the hydrogen ions of water. Silver consists of an ion exchange step (S20) in which at least a hydrogen ion concentration has a strong basicity of 10 or more, and an outflow step (S30) in which water in which cations are mixed in the stirring tank 10 is discharged.

또한, 유출단계(S30)시 정촉매(20)를 사용하여 유출되는 물의 이온교환반응을 촉진시켜주는 촉매반응단계(S40)를 더 구비할 수 있다.In addition, the outflow step (S30) may further include a catalytic reaction step (S40) for accelerating the ion exchange reaction of the outflow water using the forward catalyst 20.

상기의 구성에 따른 본 발명인 수질개선제와 수질개선제를 이용한 수질개선용 물 제조방법의 동작은 다음과 같다.The operation of the method for producing water for improving water quality using the water quality improving agent and the water quality improving agent according to the above configuration is as follows.

본 발명의 수질개선제는 5 내지 23 중량%의 황토분말과, 12 내지 28 중량%의 도석을 일정크기로 분쇄한 도석분말과, 6 내지 8 중량%의 장석을 일정크기로 분쇄한 장석분말과, 2 내지 4 중량%의 카본과, 10 내지 30 중량%의 폐화석분말을 교반조(10)에서 혼합 교반시켜 상기 분말의 천연광물들이 골고루 혼합되도록 한다.The water quality improving agent of the present invention includes 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder to a certain size, and 6 to 8% by weight of feldspar to a certain size, 2 to 4% by weight of carbon and 10 to 30% by weight of waste fossil powder are mixed and stirred in a stirring tank 10 so that the natural minerals of the powder are evenly mixed.

상기 천연광물들인 황토, 도석, 장석 및 폐화석의 분말들의 입도는 크기가 작을 수록 좋으나, 경제성을 고려하여 100미크론(micron) 내지 15000미크론의 입도크기의 분말을 사용하는 것이 바람직하다.The smaller the size of the powders of the natural minerals, such as loess, pottery, feldspar, and waste fossil, the better, but it is preferable to use a powder having a particle size of 100 microns to 15000 microns in consideration of economy.

황토는 실트 크기의 입자들로 구성되어 있으며, 실리카(SiO2), 알루미나(Al2O3), 산화제2철(Fe2O3), 산화제1철(FeO), 석회(CaO), 산화마그네슘(MgO) 등 수많은 무기질이 함유되어 있다. 이러한 황토는 흡수력, 자정력, 생명력이 뛰어나며, 향균, 탈취효과 및 오염물질 제거에 의한 수질정화기능을 갖는다.Ocher is composed of silt-sized particles and contains numerous inorganic substances such as silica (SiO2), alumina (Al2O3), ferric oxide (Fe2O3), ferrous oxide (FeO), lime (CaO), and magnesium oxide (MgO). Contains. These loess have excellent absorption, self-cleaning, and vitality, and have antibacterial, deodorizing effects, and water purification functions by removing pollutants.

도석은 무수규산(SiO2), 알루미나(Al2O3), 산화제2철(Fe2O3), 석회(CaO), 산화마그네슘(MgO)이 함유되어 있으며, 장석은 염기성이 높은 칼슘장석(CaAl2Si2O8)을 사용한다.The pottery stone contains silicic anhydride (SiO2), alumina (Al2O3), ferric oxide (Fe2O3), lime (CaO), and magnesium oxide (MgO), and feldspar uses calcium feldspar (CaAl2Si2O8) with high basicity.

카본은 참숯인 카본은 탄소질이 80%이고, 나머지가 칼슘, 나트륨, 철, 마그네슘, 칼륨, 인 등의 미네랄로 구성되어 있으며, 다공성을 가지고 있어 유해한 세균과 냄새를 흡착한다.Carbon, which is a true charcoal, has 80% carbon quality, and the rest is composed of minerals such as calcium, sodium, iron, magnesium, potassium, and phosphorus, and has porosity to adsorb harmful bacteria and odors.

폐화석은 굴 껍데기와 같은 광물로서, 칼슘, 알카리 성분의 다종의 미량 미네랄이 함유되어 있고, 다공질의 입자로 통기, 통수성이 좋아 미생물의 번식을 증가시켜 어류의 먹이를 공급하여 어류의 성장을 촉진시킬 수 있고, 수질 개선에 도움이 된다.Waste fossils are minerals such as oyster shells and contain a variety of trace minerals such as calcium and alkali. Porous particles have good ventilation and water permeability, increasing the reproduction of microorganisms and supplying fish food to support fish growth. It can be promoted, and it helps to improve water quality.

상기와 같은 다수의 천연광물들로 이루어진 본 발명의 수질개선제를 하천 또는 바다에 살포하면, 상기 분쇄된 천연광물이 가지고 있는 칼슘이온, 철이온 및 알루미늄이온들인 양이온과 물의 수소이온과 이온교환이 이루어지면서 수소이온농도가 증가되어 산성화된 하천수 또는 바닷물은 염기성으로 변하게 된다.When the water quality improving agent of the present invention composed of a plurality of natural minerals as described above is sprayed on rivers or seas, ion exchange with hydrogen ions of water and cation, which are calcium ions, iron ions, and aluminum ions of the pulverized natural minerals, is performed. As the hydrogen ion concentration increases, the acidified river water or sea water becomes basic.

또한, 본 발명의 천연광물들의 구성 성분들 중 칼슘은 수중에서 가수분해가 이루어져 아래의 반응을 거쳐 수중의 산소용존도(DO)를 증가시키게 된다.In addition, calcium among the constituents of the natural minerals of the present invention is hydrolyzed in water to increase oxygen dissolution (DO) in water through the following reaction.

CaCO3 + H2O ------ Ca(OH)2 + CO2CaCO3 + H2O ------ Ca(OH)2 + CO2

CO2 + H2O + 광합성 ------- CH2O(탄수화물) + O2CO2 + H2O + Photosynthesis ------- CH2O (carbohydrate) + O2

또한, 칼슘에 의해 다음과 같은 반응을 거쳐 수중의 황화수소가 제거된다.In addition, hydrogen sulfide in water is removed through the following reaction by calcium.

CaCO3 + H2S ------ CaS + H2O + CO2CaCO3 + H2S ------ CaS + H2O + CO2

또한, 수중의 무기인은 알루미늄과 철과 결합되어 수중 바닥으로 침전되게 되어 수중의 무기인을 제거시킬 수 있다.In addition, inorganic phosphorus in water is combined with aluminum and iron and precipitated to the bottom of the water, so that inorganic phosphorus in water can be removed.

이와 같이 황토분말과, 도석분말과, 장석분말과, 카본과, 폐화석분말을 배합한 본 발명의 수질개선제를 하천 또는 바다에 살포함으로써 산성화된 수질을 염기성으로 변화시키고, 수중의 산소용존도를 높여주고, 황화수소나무기인을 제거시켜주어 부영양화를 억제하여 수질을 개선시킬 수 있고, 녹조나 적조의 발생을 방지할 수 있다.In this way, the acidified water quality is changed to basic by spraying the water quality improving agent of the present invention, which is a mixture of loess powder, pottery powder, feldspar powder, carbon, and waste fossil powder, to rivers or seas, and improves the oxygen solubility in water. It raises and removes the hydrogen sulfide tree cause, suppresses eutrophication, improves water quality, and prevents the occurrence of green algae or red algae.

도 1 및 도 2에 도시된 바와 같이 본 발명의 수질개선제를 이용한 수질개선용 물 제조방법의 동작은 다음과 같다.As shown in Figs. 1 and 2, the operation of the water production method for improving water quality using the water quality improving agent of the present invention is as follows.

교반단계(S10)는 5 내지 23 중량%의 황토분말과, 12 내지 28 중량%의 도석분말과, 6 내지 8 중량%의 장석분말과, 2 내지 4 중량%의 카본과, 10 내지 30 중량%의 폐화석분말로 이루어진 수질개선제(1)를 교반조(10)에서 혼합하여 교반한다.The stirring step (S10) includes 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, 6 to 8% by weight of feldspar powder, 2 to 4% by weight of carbon, and 10 to 30% by weight The water quality improving agent (1) consisting of waste fossil powder is mixed and stirred in a stirring tank (10).

이온교환단계(S20)는 교반조(10) 내에 혼합교반된 수질개선제(1)에 물(40), 특히 정화장치(50)를 통해 정제된 정제수를 혼합한 후 교반시킨다. 이와 같이 교반조(10) 내에서 수질개선제(1)와 물을 혼합 교반함으로써 물분자의 클러스터(cluster)는 30헤르쯔에서 60헤르쯔를 가지게 되어, 본 발명에 의한 물은 일반적인 수돗물에 비해 약 1/10 내지 1/20의 클러스터를 가지게 된다. 이와 같이 물분자의 클러스터가 통상의 수돗물의 클러스터에 비해 상대적으로 작기 때문에 물속에 함유된 유기물들이 미생물의 의해 분해가 잘된다.In the ion exchange step (S20), water 40, particularly purified water purified through the purification device 50 is mixed with the water quality improving agent 1 mixed and stirred in the stirring tank 10 and then stirred. In this way, by mixing and stirring the water quality improving agent 1 and water in the stirring tank 10, the cluster of water molecules has 30 to 60 Hz, and the water according to the present invention is about 1/ It will have a cluster of 10 to 1/20. As described above, since the cluster of water molecules is relatively small compared to the cluster of ordinary tap water, organic matter contained in the water is well decomposed by microorganisms.

또한, 이온교환단계(S20)에서 수질개선제(1)가 함유하고 있는 칼슘이온, 철이온 및 알루미늄이온들인 양이온과 물의 수소이온과 이온교환되면서 물은 적어도 수소이온농도가 10 이상의 강염기성을 갖게 되고, 산화환원전위는 -300㎷ 내지 -600㎷를 유지하게 되어 유기물이 산화되는 것을 어렵게 만들어 주고 방부효과를 얻을 수 있다.In addition, in the ion exchange step (S20), water has a strong basicity of at least 10 or more by ion-exchanging with the cation of calcium ions, iron ions, and aluminum ions contained in the water quality improving agent 1 and the hydrogen ions of water. , The oxidation-reduction potential is maintained between -300㎷ and -600㎷, making it difficult for organic matter to be oxidized, and an antiseptic effect can be obtained.

유출단계(S30)는 교반조(10) 내의 상등액을 외부로 유출시킨다. 상등액에는 상기 수질개선제의 천연광물들 중 부유되는 광물들과 양이온이 혼재된 물이 유출되게 된다.Outflow step (S30) is to outflow the supernatant in the stirring tank (10) to the outside. Water in which floating minerals and cations are mixed among the natural minerals of the water quality improving agent flows into the supernatant.

촉매반응단계(S40)는 교반조(10) 내에서 물이 유출되는 과정에서 정촉매(20)를 사용하여 물과 함께 유출되는 광물들과의 양이온의 이온교환반응을 더 촉진시킬 수 있다. 촉매반응단계(S40)를 거쳐 교반조(10)로부터 유출되는 물을 저장조(30)에 저장한다.In the catalytic reaction step (S40), the ion exchange reaction of cations with minerals flowing out with water may be further promoted by using the positive catalyst 20 in the course of the water flowing out of the stirring tank 10. The water flowing out of the stirring tank 10 through the catalytic reaction step (S40) is stored in the storage tank 30.

상기와 같이 본 발명에 의한 수질개선제 용 물을 하천이나 바다에 살포함으로써, 수중의 산소용존도를 높여 수질을 개선시키고, 녹조나 적조의 발생을 방지할 수 있다.As described above, by spraying the water for the water quality improving agent according to the present invention to rivers or seas, it is possible to improve water quality by increasing the oxygen dissolution in water, and to prevent the occurrence of green algae or red tide.

Claims (3)

황토분말 5 내지 23 중량%와, 도석분말 12 내지 28 중량%와, 장석분말 6 내지 8 중량%와, 카본 2 내지 4 중량%와, 폐화석분말 10 내지 30 중량%를 포함하여 이루어진 것을 특징으로 하는 수질개선제.
It is characterized in that it comprises 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, 6 to 8% by weight of feldspar powder, 2 to 4% by weight of carbon, and 10 to 30% by weight of waste fossil powder. Water quality improvement agent.
5 내지 23 중량%의 황토분말과, 12 내지 28 중량%의 도석분말과, 6 내지 8 중량%의 장석분말과, 2 내지 4 중량%의 카본과, 10 내지 30 중량%의 폐화석분말로 이루어진 수질개선제를 교반조에서 혼합하여 교반하는 교반단계;
상기 교반조 내에 혼합교반된 수질개선제에 물을 혼합한 후 교반시켜 상기 수질개선제가 함유하고 있는 칼슘이온, 철이온 및 알루미늄이온들인 양이온과 상기 물의 수소이온과 이온교환되면서 상기 물은 적어도 수소이온농도가 10 이상의 강염기성을 갖게 되는 이온교환단계; 및
상기 교반조 내의 양이온이 혼재된 물을 유출시키는 유출단계를 구비한 것을 특징으로 하는 수질개선제를 이용한 수질개선용 물 제조방법.
Consisting of 5 to 23% by weight of loess powder, 12 to 28% by weight of pottery powder, 6 to 8% by weight of feldspar powder, 2 to 4% by weight of carbon, and 10 to 30% by weight of waste fossil powder A stirring step of mixing and stirring the water quality improving agent in a stirring tank;
Water is mixed with the water quality improving agent mixed and stirred in the stirring tank, and then stirred. As the water is ion-exchanged with the hydrogen ions of the water and calcium ions, iron ions, and aluminum ions contained in the water quality improving agent, the water has at least a hydrogen ion concentration. An ion exchange step of having a strong basicity of 10 or more; And
Method for producing water for improving water quality using a water quality improving agent, characterized in that it comprises an outflow step of outflowing water in which cations are mixed in the stirring tank.
제 1 항에 있어서, 상기 유출단계시 정촉매를 사용하여 상기 유출되는 물의 이온교환반응을 촉진시켜주는 촉매반응단계를 더 구비한 것을 특징으로 하는 수질개선제를 이용한 수질개선용 물 제조방법. The method of claim 1, further comprising a catalytic reaction step of accelerating the ion exchange reaction of the outflow water using a positive catalyst during the outflow step.
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Publication number Priority date Publication date Assignee Title
KR20230060876A (en) 2021-10-28 2023-05-08 농업회사법인 주식회사 에코레스트 microbial mineral complex

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230060876A (en) 2021-10-28 2023-05-08 농업회사법인 주식회사 에코레스트 microbial mineral complex

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