KR20210007200A - Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion - Google Patents

Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion Download PDF

Info

Publication number
KR20210007200A
KR20210007200A KR1020190083194A KR20190083194A KR20210007200A KR 20210007200 A KR20210007200 A KR 20210007200A KR 1020190083194 A KR1020190083194 A KR 1020190083194A KR 20190083194 A KR20190083194 A KR 20190083194A KR 20210007200 A KR20210007200 A KR 20210007200A
Authority
KR
South Korea
Prior art keywords
dispersion
cationic polymer
fluidity
cationic
producing
Prior art date
Application number
KR1020190083194A
Other languages
Korean (ko)
Inventor
배병수
Original Assignee
배병수
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 배병수 filed Critical 배병수
Priority to KR1020190083194A priority Critical patent/KR20210007200A/en
Publication of KR20210007200A publication Critical patent/KR20210007200A/en

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers

Abstract

A method for producing a stable, flowable dispersion from a cationic polymer used for conditioning of cosmetics is described. The cationic polymer is polyquaternium-10 or cationic guar gum. The dispersion produced by the method provides the advantage of having no dust during operation compared to conventional powder, dissolving well even when added at high temperature, and being freely transferred with a general pump.

Description

유동성이 있는 안정한 양이온 폴리머 분산물의 제조 방법 및 이를 포함하는 화장품 조성물{Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion}TECHNICAL FIELD [Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion]

본 발명은 유동성이 있는 안정한 양이온 폴리머 분산물의 제조 방법, 상기 방법에 의하여 제조되는 양이온 폴리머 분산물을 포함하는 화장품에 관한 것이다.The present invention relates to a method for producing a stable cationic polymer dispersion with fluidity, and to a cosmetic product comprising a cationic polymer dispersion prepared by the method.

화장품에는 모발을 윤기있고 부드러우며 촉촉하고 가지런하게 정돈하는 컨디셔닝제가 사용된다.In cosmetics, conditioning agents are used to keep the hair shiny, soft, moist and tidy.

컨디셔닝제로 주로 사용되는 물질은 양이온 폴리머, 실리콘 오일, 고급알코올, 양이온 계면활성제 등이 있다.Materials mainly used as conditioning agents include cationic polymers, silicone oils, higher alcohols, and cationic surfactants.

양이온 폴리머는 주로 양이온 폴리사카라이드계가 사용되며 건조된 파우더 형태로 사용된다. 그러나 가루의 특성 상 흡입 위험과 비산 먼지에 의한 오염의 위험이 존재한다. 또한 이러한 제품은 기계, 칭량 장비 등에 쉽게 달라붙는 성질이 있어 사용하기 까다롭고 변질될 우려가 높다. 또한 고온의 물에 쉽게 뭉치는 경향이 있어 찬물에서 장기간 녹여 사용해야 하는 단점도 가지고 있다. Cationic polymers are mainly cationic polysaccharides and are used in the form of dried powder. However, due to the nature of the powder, there is a risk of inhalation and contamination by flying dust. In addition, these products are difficult to use and are highly susceptible to deterioration because they easily stick to machines and weighing equipment. In addition, it tends to clump easily in hot water, so it has a disadvantage that it must be dissolved in cold water for a long time.

이러한 단점을 극복하고자 양이온 폴리머를 폴리올에 분산시킨 후 사용하기도 하나 분산물이 쉽게 분리되거나 분산 과정에서 화장품에 사용이 어려운 실리카, 광물유 등의 사용이 필요해 제약이 있다.In order to overcome these shortcomings, a cationic polymer may be dispersed in a polyol and used, but there is a limitation because the dispersion is easily separated or silica, mineral oil, etc., which are difficult to use in cosmetics during the dispersion process, are required.

본 발명은 상기 문제점을 해결하고자 화장품에 사용이 가능한 원료를 이용하여 안정성이 높은 폴리머 분산물의 제조 방법을 제공한다.The present invention provides a method for producing a polymer dispersion having high stability using raw materials that can be used in cosmetics to solve the above problems.

상기의 목적을 달성하기 위하여 본 발명의 양상은,Aspects of the present invention in order to achieve the above object,

양이온 폴리사카라이드;피이지-400;글리세린;카보머;실리콘에멀젼;를 포함하는 폴리머 분산물에 있어서, 양이온 폴리사카라이드는 10 내지 65wt%, 피이지-400은 30 내지 80wt%, 글리세린은 10 내지 65wt%, 카보머는 0.1 내지 5wt%, 실리콘 에멀젼은 0.1 내지 20wt%이다.In the polymer dispersion comprising a cationic polysaccharide; PEG-400; glycerin; carbomer; silicone emulsion; wherein the cationic polysaccharide is 10 to 65 wt%, PEG-400 is 30 to 80 wt%, glycerin is 10 To 65 wt%, carbomer is 0.1 to 5 wt%, silicone emulsion is 0.1 to 20 wt%.

본 발명에서 양이온 폴리사카라이드는 폴리쿼터늄-10, 양이온 구아검 중 하나이다.In the present invention, the cationic polysaccharide is one of polyquaternium-10 and cationic guar gum.

본 발명의 폴리머 분산물은,The polymer dispersion of the present invention,

상온에서 3개월 이상 안정된 폴리머 분산물을 제공한다.It provides a polymer dispersion that is stable for at least 3 months at room temperature.

고온의 물에서 엉킴이 없이 잘 풀어져 녹는다.It dissolves well without tangling in hot water.

분진이 발생하지 않고 일반적인 펌프를 이용하여 쉽게 이송이 가능하다.It does not generate dust and can be easily transferred using a general pump.

본 발명에 의하여 제조된 안정된 분산물Stable dispersion prepared according to the invention

본 발명은 양이온 폴리사카라이드;피이지-400;글리세린;카보머;실리콘 에멀젼;를 포함하는 폴리머 분산물에 있어서, 양이온 폴리사카라이드는 10 내지 65중량%이다. 피이지-400는 30 내지 80중량%, 글리세린은 0.1 내지 20중량%, 카버모는 0.1 내지 5중량%, 실리콘 에멀젼은 0.1 내지 5중량%이다.In the present invention, in the polymer dispersion comprising a cationic polysaccharide; PG-400; glycerin; carbomer; silicone emulsion;, the cationic polysaccharide is 10 to 65% by weight. PEG-400 is 30 to 80% by weight, glycerin is 0.1 to 20% by weight, carbermo is 0.1 to 5% by weight, and silicone emulsion is 0.1 to 5% by weight.

양이온 폴리사카라이드는 폴리쿼터늄-10(Polyquta 3000KC), 양이온 구아검(Guargquat C140KC) 중 하나이다.The cationic polysaccharide is one of polyquaternium-10 (Polyquta 3000KC) and cationic guar gum (Guargquat C140KC).

피이지-400(POLYOXYETHYLENE 400)은 저 분자량 폴리에틸렌 글리콜로 투명하고 무색의 점성이 있는 액체이다. 독성이 낮아 화장품, 의약품에 널리 사용된다.POLYOXYETHYLENE 400 is a low molecular weight polyethylene glycol, a transparent, colorless, viscous liquid. Due to its low toxicity, it is widely used in cosmetics and pharmaceuticals.

카보머(Carbomer 980)는 폴리아크릴릭 액시드(Polyacrylic acid)로 고 분자량 물질로 화장품, 의약품의 점도를 높이는 목적으로 널리 사용된다.Carbomer 980 is a polyacrylic acid, a high molecular weight substance, and is widely used for increasing the viscosity of cosmetics and pharmaceuticals.

실리콘 에멀젼은 SI6010Z(Dimethicone, Laureth-23, Laureth-3)를 사용했으며, 컨디셔닝 효과를 주는 물질로 화장품에 널리 사용된다.SI6010Z (Dimethicone, Laureth-23, Laureth-3) was used as a silicone emulsion, and it is widely used in cosmetics as a material that gives a conditioning effect.

상기 분산물을 칭량한 후 In-Line mixer(Silverson)를 이용하여 분산한다.After weighing the dispersion, it is dispersed using an In-Line mixer (Silverson).

이하 본 발명의 실시예는 단지 예시적인 것으로, 기술되고 청구된 본 발명의 범위를 어떠한 방식으로든지 제한하는 것이 아니다.The following embodiments of the present invention are illustrative only and are not intended to limit the scope of the invention described and claimed in any way.

본 발명에 따라, 하기 표1과 같이 실시예 및 비교예의 샴푸 조성물을 제조한다.According to the present invention, shampoo compositions of Examples and Comparative Examples were prepared as shown in Table 1 below.

실시예1Example 1 실시예2Example 2 비교예1Comparative Example 1 폴리쿼터늄-10Polyquaternium-10 20%20% 22%22% 10%10% 피이지-400PEG-400 67.5%67.5% 66.6%66.6% 90%90% 카보머Carbomer 2%2% 2%2% 실리콘 에멀젼Silicone emulsion 3%3% 2%2% 글리세린glycerin 7.5%7.5% 7.4%7.4%

상기 표1에 언급된 실시예 및 비교예에 따른 본 조성물은 실버슨 In-Lne mixer로 충분히 분산되도록 교반한다.The present composition according to the Examples and Comparative Examples mentioned in Table 1 is stirred so as to be sufficiently dispersed with a Silverson In-Lne mixer.

실시예1Example 1 실시예2Example 2 비교예1Comparative Example 1 1da1da 안정stability 안정stability 분리Separation 1month1month 안정stability 안정stability -- 2month2month 안정stability 안정stability -- 3month3month 안정stability 안정stability --

상기 표1과 표2에서 알 수 있듯이 본 발명을 통해 제조한 양이온 폴리머는 상온에서 3개월 이상 안정함을 알 수 있다. 여기서 안정이라함은 경시적으로 5% 이상 상 분리가 일어나지 않고 유동성을 가짐을 의미하며, 분리라함은 경시적으로 5%이상 상 분리가 일어나거나 제형이 유동성을 가지지 않는 것을 의미한다. 유동성이란 견본을 기울였을 때 흐름성을 가지는 것을 의미한다.As can be seen in Tables 1 and 2, it can be seen that the cationic polymer prepared through the present invention is stable at room temperature for 3 months or more. Here, "stable" means that no more than 5% phase separation occurs over time and has fluidity, and separation means that more than 5% of phase separation occurs over time or that the formulation does not have fluidity. Fluidity means having fluidity when the sample is tilted.

또한 상기 실시예1, 실시예2에서 제조한 견본은 화장품 제조시 일반적으로 사용하는 펌프를 이용하여 이송이 가능하였다. 비교예1의 견본은 점도가 높아 이송이 불가능 하였다.In addition, the samples prepared in Examples 1 and 2 could be transferred using a pump generally used in manufacturing cosmetics. The sample of Comparative Example 1 had a high viscosity and was not transportable.

섭씨 60도의 뜨거운 물에 분산시킨 바, 실시예1과 실시예2는 모두 쉽게 분산되어 녹는 것을 관찰할 수 있었으며, 비교예1은 분리되기 전의 제조 직후의 제품만 분산되어 녹고 분리가 된 제품은 60분 이상 녹지 않는 것을 알 수 있었다.(Agi, 200rpm)Disperse in hot water at 60 degrees Celsius, it could be observed that both Example 1 and Example 2 were easily dispersed and melted. It was found that it did not melt for more than a minute (Agi, 200rpm).

Claims (3)

양이온 폴리머;피이지-400;글리세린;카보머;실리콘 에멀젼;를 포함하는 폴리머 분산물에 있어서, 양이온 폴리머는 10 내지 65wt%, 피이지-400sms 30 내지 80wt%, 글리세린은 0.1 내지 20wt%, 카보머는 0.1 내지 5wt%, 실리콘 에멀젼은 0.1 내지 5wt%이며, In-Line mixer를 이용한 조성물의 제조 방법
In the polymer dispersion comprising a cationic polymer; PEG-400; glycerin; carbomer; silicone emulsion; the cationic polymer is 10 to 65 wt%, PEG-400 sms 30 to 80 wt%, glycerin is 0.1 to 20 wt%, carbo The polymer is 0.1 to 5 wt%, the silicone emulsion is 0.1 to 5 wt%, and the method for preparing a composition using an In-Line mixer
 제1항에 있어서, 양이온 폴리머는 폴리쿼터늄-10, 양이온 구아검 중 하나이다.The method of claim 1, wherein the cationic polymer is one of polyquaternium-10 and cationic guar gum. 제1항의 방법에 의하여 제조되는 양이온 폴리머 분산물을 포함하는 화장품
Cosmetics comprising a cationic polymer dispersion prepared by the method of claim 1
KR1020190083194A 2019-07-10 2019-07-10 Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion KR20210007200A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020190083194A KR20210007200A (en) 2019-07-10 2019-07-10 Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020190083194A KR20210007200A (en) 2019-07-10 2019-07-10 Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion

Publications (1)

Publication Number Publication Date
KR20210007200A true KR20210007200A (en) 2021-01-20

Family

ID=74304956

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020190083194A KR20210007200A (en) 2019-07-10 2019-07-10 Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion

Country Status (1)

Country Link
KR (1) KR20210007200A (en)

Similar Documents

Publication Publication Date Title
WO2001051558A1 (en) Microgels and external preparations containing the same
KR20110103456A (en) Silicone paste compositions
JPS6359422B2 (en)
SE449111B (en) Aqueous liquid liquid concentrated textile softening composition and process for its preparation
KR102541257B1 (en) Nanoemulsion composition comprising polyglyceryl emulsifier
KR20210007200A (en) Process for producing a stable cationic polymer dispersion having fluidity amd cosmetics containing this dispersion
KR20100133111A (en) Stable inverse emulsion
KR20170038315A (en) Shapable composition for hair care
KR101813835B1 (en) PEG free solubilizer and Manufacturing method thereof
CN107412012A (en) A kind of microemulsified makeup removing gel and preparation method thereof
KR20140070719A (en) Cosmetic Composition for High Internal Phase Water-in-oil Type Emulsion and Method For Preparing Thereof
KR20120053874A (en) Thickener, emulsifying stabilizer and composition for skin external application containing natural polymer
KR20200109539A (en) Silicone emulsion composition and manufacturing method thereof
KR101852249B1 (en) Emulsion composition for cosmetic and method for preparing the same
KR101638013B1 (en) Stable o/w emulsion cosmetic composition
EP3660098A1 (en) Oil-in-water-type emulsion composition, method for producing same, and use of same
KR101577796B1 (en) Integrated cosmetic compound of basic makeup with high moisture for impregnating to pad and impregnated pad using thereof
KR20200049150A (en) Oil-in-water type cosmetic composition with a low viscosity comprising a high content of oil
JP6122646B2 (en) Topical skin preparation
KR20150000371A (en) Solubilizing composition of insoluble cosmetic compounds and the method for preparing the same
JPH10298149A (en) Dispersion of quaternary ammonium salt at high concentration and its preparation
JP6359302B2 (en) Cosmetic gel and cosmetics containing the same
KR100905132B1 (en) Gel lotion manufacturing method
KR100905131B1 (en) Gel lotion manufacturing method
KR101434298B1 (en) Dome Shape Pressed Powder Cosmetic Compositions Comprising Starch and Inorganic Gelling Agents and Manufacturing Method Thereof

Legal Events

Date Code Title Description
E601 Decision to refuse application