KR20200119136A - Air conditioning arficial flowers and method of the same - Google Patents

Abstract

The present application relates to artificial flowers having an air purification function including antibacterial activity, antifungal activity, deodorization, moisture control and harmful substance removal by coating zeolites or similar materials that adsorb, decompose, or adsorb and remove harmful substances such as formaldehyde, and a method of manufacturing the artificial flowers.

Description

Air conditioning arficial flowers and method of the same}

In this application, the artificial flowers are coated with zeolite or similar substances that adsorb or decompose or adsorb and remove harmful substances such as antibacterial, anti-fungal, deodorant, moisture control, formaldehyde, etc. , And to a method for producing the artificial flower.

Recently, people spend most of their time indoors such as offices and homes, but indoor air pollution is intensifying due to insufficient ventilation and increased sources of indoor pollutants, leading to new diseases such as building sickness, sick house syndrome, and chemical hypersensitivity. As it emerges, the demand for proper management of indoor air is increasing.

In addition, the outdoor atmosphere is diluting pollutants by natural wind or atmospheric circulation, but in the case of indoor air, indoor airtight is reinforced to save energy, and due to insufficient ventilation and cleaning, pollutants continue to circulate inside the room. Pollution concentration is increasing.

However, purifying indoor air through indoor plant cultivation is all soil cultivation in pots or containers, so it is difficult to properly manage moisture and nutrients, and it is difficult to cultivate in large quantities in a limited space. In order to substantially purify contaminated indoor spaces, a significant number of indoor plants must be cultivated, but in a limited indoor space, there is a problem that the number of individuals required for indoor air purification cannot be cultivated.

Accordingly, there is still a need for a way to purify indoor air more efficiently.

[Prior literature]

Korean Patent Publication No. 10-2014-0022177.

The present application is an artificial flower in which an air purifying function is added to the artificial flower by coating a zeolite or similar material that adsorbs, decomposes, or adsorbs and removes harmful substances such as antibacterial, anti-fungal, deodorant, moisture control, and formaldehyde. , And to a method for producing the artificial flower.

However, the problem to be solved by the present application is not limited to the problem mentioned above, and other problems that are not mentioned will be clearly understood by those skilled in the art from the following description.

A first aspect of the present application provides arficial flowers coated with an adsorbent.

A second aspect of the present application provides a method of manufacturing air purifying air conditioners (arficial flowers) according to the first aspect of the present application, comprising coating an adsorbent on the surface of the conditioner or conditioner component.

According to the embodiments of the present application, an air purification function may be added to the conditioner by coating a zeolite or similar material that adsorbs, decomposes, or adsorbs and removes harmful substances such as antibacterial, antifungal, deodorant, moisture control, formaldehyde, etc. In addition, it is possible to efficiently purify indoor and outdoor air using such an air purifying conditioner.

1A is an electron micrograph of an artificial incidence ear without zeolite coating as a comparative example, and FIG. 1B is an electron microscopic photo of an artificial incidence coated with zeolite in the present Example.
2 is a photograph of a device used to measure the formaldehyde removal function before and after zeolite coating on the blend.
3 is a graph showing the ability of adsorbing and decomposing formaldehyde of a blend coated with zeolite molecular sieve crystal particles according to the present embodiment compared with a blend without zeolite coating (Comparative Example).

Hereinafter, exemplary embodiments of the present application will be described in detail with reference to the accompanying drawings so that those of ordinary skill in the art may easily implement the present application. However, the present application may be implemented in various different forms and is not limited to the embodiments described herein. In addition, in the drawings, parts not related to the description are omitted in order to clearly describe the present application, and similar reference numerals are attached to similar parts throughout the specification.

Throughout the present specification, when a member is said to be positioned “on” another member, this includes not only the case where a member is in contact with the other member, but also the case where another member exists between the two members.

Throughout the specification of the present application, when a certain part "includes" a certain constituent element, it means that other constituent elements may be further included rather than excluding other constituent elements unless otherwise specified. The terms "about", "substantially", etc. of the degree used throughout the present specification are used at or close to the numerical value when manufacturing and material tolerances specific to the stated meaning are presented. To assist, accurate or absolute figures are used to prevent unfair use of the stated disclosure by unscrupulous infringers. As used throughout the specification of the present application, the term "step (to)" or "step of" does not mean "step for".

Throughout the present specification, the term “combination(s) thereof” included in the expression of the Makushi format refers to one or more mixtures or combinations selected from the group consisting of components described in the expression of the Makushi format, It means to include at least one selected from the group consisting of the above components.

Throughout this specification, the description of “A and/or B” means “A or B, or A and B”.

Hereinafter, embodiments and examples of the present application will be described in detail with reference to the accompanying drawings. However, the present application may not be limited to these embodiments and examples and drawings.

A first aspect of the present application provides arficial flowers coated with an adsorbent.

In one embodiment of the present application, the air purification function may include antibacterial, anti-fungal, deodorant, contaminant adsorption and/or decomposition, or moisture control, but may not be limited thereto.

In one embodiment of the present application, the air conditioning conditioner may include an adhesive in addition to the adsorbent, but may not be limited thereto.

In one embodiment of the present application, the adhesive may be coated between the blender and the adsorbent, or may be mixed with the adsorbent and coated on the blender, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the particles of the adsorbent may be arranged and bonded to the surface of the roughened in a predetermined direction, but the present disclosure may not be limited thereto.

In the exemplary embodiment of the present disclosure, the adsorbent may be one selected from the group consisting of molecular sieve, clay, silica gel, photocatalyst, and combinations thereof, but may not be limited thereto.

In one embodiment of the present application, the artificial flower includes, but is not limited to, a artificial flower made of various known materials such as plastic, fiber, paper, clay, or metal.

In the exemplary embodiment of the present disclosure, the molecular sieve may be a crystal particle, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the molecular sieve may include ion-exchanged or adsorbed metal or metal cations, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the metal or metal cation included in the molecular sieve may be a metal having antimicrobial or catalytic or photocatalytic properties, or a cation of the metal, but may not be limited thereto. For example, the metal or metal cation may be one or more metals selected from the group consisting of Ag, Cu, Zn, Ti, Pt, and Pd, or a cation of the metal, but may not be limited thereto.

In one embodiment of the present application, the molecular sieve may be crystal particles of the molecular sieve.

In the exemplary embodiment of the present disclosure, the molecular sieve may include a catalyst or a material having photocatalytic properties, but may not be limited thereto.

In one embodiment of the present application, the first molecular sieve particle and/or a composition such as a solution containing the first molecular sieve particle and/or the second particle as the adsorbent is coated on the surface of the roughened surface. Alternatively, the second particles may be bonded to the surface of the harmony, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the first molecular sieve particle may include ion-exchanged or adsorbed metal or metal cations, but may not be limited thereto.

In one embodiment of the present application, the metal or metal cation included in the first molecular sieve particle may be a metal having antimicrobial or catalytic or photocatalytic properties, or a cation of the metal, but may not be limited thereto. . For example, the metal or metal cation may include one or more metals selected from the group consisting of Ag, Cu, Zn, Ti, Pt, and Pd, or a cation of the metal, but may not be limited thereto.

In one embodiment of the present application, the first molecular sieve particle may be a crystal particle of the molecular sieve.

In the exemplary embodiment of the present disclosure, the second particle may include a catalyst or a material having photocatalytic properties, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the second particles may include ZnO, SiO ₂ or TiO ₂ , but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the second particle may further include a metal or a metal cation supported on the catalyst or a material having photocatalytic properties, but may not be limited thereto. For example, the metal or metal cation may be one or more metals selected from the group consisting of Ag, Cu, Zn, Ti, Pt, and Pd, or a cation of the metal, but may not be limited thereto.

The molecular sieve may include a material selected from the group consisting of, or may include an organic and/or inorganic molecule contained in the molecular sieve, but may not be limited thereto:

(i) zeolite

(ii) Zeolite, ZSM-5, silicalite-1, TS-1 or metallo-silicalite-1 having an MFI structure

(iii) Zeolite with MEL structure, ZSM-11, silicalite-2, TS-2 or metallo-silicalite-2

(iv) Zeolite A, X, Y, L, beta, mordenite, ferrierite, ETS-4 or ETS-10

(v) Mesoporous silica of any one of MCM series, SBA series, MSU series or KIT series

(vi) Organic-inorganic complex mesoporous structure or layered material

(vii) Organic zeolite, organometallic zeolite or coordination compound zeolite in which a metal ion and a ligand are three-dimensionally bonded

(viii) a composite containing organic, inorganic, organic-inorganic mixed dyes, luminescent dyes or pigments inside the pores of a porous material or between layers of a layered structure material, and

(ix) Metal Organic Framework (MOF) substances, Covalent Organic Framework (COF) substances, or complexes thereof.

In one embodiment of the present application, an adhesive compound bonded to the blend, the first molecular sieve particle, or the second particle, or bonded between the blend and the first molecular sieve particle and/or the second particle It may further include, but may not be limited thereto.

In one embodiment of the present application, the particle-coating composition may further include the blend, the first molecular sieve particle, or an adhesive compound bonded between the blend and the first molecular sieve particle, but is limited thereto. May not be.

In one embodiment of the present application, the harmony and the molecular sieve crystal first particle may be used as such without any pretreatment. As described above, the roughened crystal and the molecular sieve crystal without pretreatment are referred to as a bare substrate and a bare molecular sieve crystal, respectively. The harmonic and the molecular sieve crystal are chemically bonded to each other through a functional group in the bare harmonic and the bare molecular sieve crystal itself. Typically, the bond between the bare roughened and the bare molecular sieve crystal may be formed by hydrogen bonding, but is not limited thereto.

In one embodiment of the present application, the hydrogen bonding between the roughened and the molecular sieve crystal may be made using a suitable hydrogen bonding mediator for the roughened and/or molecular sieve crystal, whereby the hydrogen bonding is stronger. It can be formed stably with strength. For example, by coating (spin coating or dip coating) the surface of a roughened and/or molecular sieve crystal with a hydrogen bonding mediator, and applying pressure to the roughened surface, the molecular sieve crystal can be stably bonded with strong intensity. What can be used as a hydrogen bonding mediator includes, but is not limited to, polyethylene imine (PEI), 4-pyridinecarboxylic acid (PyC), and PyA[trans -3-(3-pyridyl)-acrylic acid]. Preferably, the hydrogen bonding mediator used in the present invention is PEI.

In one embodiment of the present application, the harmony and the first particle of the molecular sieve are chemically bonded through the adhesive compound. In this case, an adhesive compound is bonded to the roughened, molecular sieve first particles, or the roughened and molecular sieve first particles.

In the present specification, the term "adhesive compound" refers to any compound having a functional group at the terminal that enables the coordination and bonding between the first particle and/or the second particle of the molecular sieve.

In one embodiment of the present application, the adhesive compound may include a compound derived from one or two or more organic compounds selected from the group consisting of compounds of Formulas 1 to 8 below, but may not be limited thereto. have:

[Formula 1]

Z-L1-X

[Formula 2]

MR' ₄

[Formula 3]

R ₃ Si-L1-Y

[Formula 4]

HS-L1-X

[Formula 5]

HS-L1-SiR ₃

[Formula 6]

HS-L1-Y

[Formula 7]

Z-L2(+) L3(-)-Y or Z-L3(-) L2(+)-Y:

In the above formula, Z is R ₃ Si or an isocyanate group (-NCO), where R represents a halogen group, a C1-C4 alkoxy or a C1-C4 alkyl group, and at least one of the three R is a halogen group or an alkoxy group,

L1 is a hydrocarbon residue such as a substituted or unsubstituted C1-C17 alkyl, aralkyl or aryl group, which may contain one or more oxygen, nitrogen or sulfur atoms, and X is a halogen group, an isocyanate (-NCO) group, or An actual group or an azide group, R'is the same as R, at least two of the four R'are halogen or alkoxy groups, and M is silicon, titanium or zirconium,

Y is a hydroxy group, a thiol group, an amine group, an ammonium group, a sulfone group and a salt thereof, a carboxylic acid and a salt thereof, an acid anhydride, an epoxy group, an aldehyde group, an ester group, an acrylic group, an isocyanate group (-NCO), a sugar residue, It is a coordination compound capable of double bond, triple bond, diene, diyne, alkyl phosphine, alkyl acin and ligand exchange,

Y may be located in the middle as well as the end of the adhesive compound,

L2(+) represents a functional group having at least one positive charge (+) on the terminal, straight or side chain of a substituted or unsubstituted C1-C17 hydrocarbon compound that may contain one or more oxygen, nitrogen or sulfur atoms,

L3(-) refers to a functional group having at least one negative charge (-) on the terminal, straight or side chain of a substituted or unsubstituted C1-C17 hydrocarbon compound that may contain one or more oxygen, nitrogen, or sulfur atoms) . The intermediate adhesive compound is fullerene (C60, C70), carbon nanotubes, α,ω-dialdehyde, dicarboxylic acid, dicarboxylic anhydride, amine-dendrimer, polyethyleneimine, α,ω-diamine, metal porphyrin and M (saline) A compound selected from the group consisting of a complex compound represented by (M is cobalt, nickel, chromium, manganese or iron, and saline is N,N'-bis(salicylidene)ethylenediamine);

[Formula 8]

H ₂ NP-NH ₂ ;

In the above formula, P is a C1-C20 monomolecular or linear or branched polymer amines (eg, polyehtylene imine).

In one embodiment of the present application, prior to combining the harmonic and the molecular sieve first particle and/or second particle, the harmonic, molecular sieve first particle and/or second particle, or harmonic and the molecular sieve agent The first particle and/or the second particle are treated with the adhesive compound described above to have a functional group suitable for bonding. In this way, (adhesive-adhesive compound) intermediate and/or (adhesive compound-molecular sieve first particle and/or second particle) intermediate are prepared.

In one embodiment of the present application, the (harmonized-adhesive compound) intermediate and/or (adhesive compound-molecular body first particle and/or second particle) intermediate may be performed according to various compounds and processes known in the art. I can. In one embodiment of the present disclosure, the surface of the first particle and/or the second particle of the molecular sieve and the roughening generally has a functional group such as a hydroxy group, or a functional group convertible to a hydroxy group precursor or a hydroxy group. Examples of a hydroxy group precursor or a functional group convertible to a hydroxy group include an acyloxy group, a methoxy group and a Si=O group.

In one embodiment of the present application, the (combination-adhesive compound) intermediate and the (adhesive compound-molecular body first particle and/or second particle) intermediate may form a direct chemical bond by themselves, but are bonded between the intermediates Chemical bonding can be indirectly through the intermediate adhesive compound that mediates

In the present specification, the term “intermediate adhesive compound” refers to the (combination-adhesive compound) intermediate and the (adhesive compound-molecular body first particle and/or second particle) intermediate at the end allowing bonding between two adhesive compounds. It means all compounds having a functional group. Preferably, the intermediate adhesive compound is fullerene (C ₆₀ , C ₇₀ ), carbon nanotubes, α,ω-dialdehyde, amine, sulfonic acid, dicarboxylic acid, dicarboxylic anhydride, amine-dendrimer, polyethyleneimine , α,ω-diamine, a metal porphyrin and a complex compound represented by M (saline) (M is cobalt, nickel, chromium, manganese or iron, and saline is N,N' -bis(salicylidene)ethylenediamine) It may be selected from the group consisting of, but is not limited thereto.

In one embodiment of the present application, when the composition is sprayed by the adhesive compound additionally included in the particle-coating composition, the bonding between the surface of the harmony and the first particle and/or second particle of the molecular sieve is mediated. If so, ionic bonding is typically involved. For example, the effect of rubbing the intermediate (adhesive compound-molecular body first particle and/or second particle) to the intermediate (harmonized-adhesive compound) occurs by the pressure (injection pressure) applied by spraying the composition Thus, a stable ionic bond is formed between the adhesive compounds of the two intermediates.

In another embodiment of the present application, in order to improve the rubbing effect after spraying of the composition by the adhesive compound additionally included in the particle-coating composition, the first molecular sieve particles further sprayed into the roughener and /Or additional pressure can be applied to the second particles. For example, such physical pressure addition is preferably carried out by rubbing or pressing against the substrate of the first and/or second particles of the molecular sieve, more preferably In the lower part, pressure is applied by rubbing. The compression of the first and/or second particles of the molecular sieve to the roughened surface, and the forced surface migration of the first and/or second particles of the molecular sieve during the scrubbing process can lead to high density. Molecular sieves are the two most important factors that induce bonding of the first and/or second particles to the harmonic phase.

In one embodiment of the present application, the rubbing is a chemical bond between the roughening and the adhesive compound, the molecular sieve first particle and/or the second particle and the adhesive compound, the adhesive compound and the adhesive compound, or the adhesive compound and the intermediate adhesive compound, in particular By increasing the reaction activity of molecules (especially functional groups) involved in ionic or hydrogen bonding, the bonding is formed in a short time.

In one embodiment of the present application, in order to prepare the coarse-molecular sieve first particle and/or second particle composite, the method of applying pressure to the molecular sieve crystal first particle and/or second particle is described in the art. This can be done by various methods known in For example, it is possible to apply pressure to the first and/or second particles of molecular sieve crystals using only bare hands, and may be done by hand with a scrubbing tool, or by using a scrubbing machine. Pressure can be applied to the molecular sieve crystal.

In the exemplary embodiment of the present disclosure, the first molecular sieve particles and/or the second particles may be arranged and bonded to the surface of the harmony in a predetermined direction, but may not be limited thereto.

In one embodiment of the present application, by spraying a composition such as the adsorbent or a solution containing the adsorbent and the adhesive into the roughening, the molecular sieve first particles and/or second particles are bonded and arranged on the surface of the roughening. May represent one or more functions of antimicrobial, contaminant adhesion and/or decomposition performance, deodorization, and humidity control, but may not be limited thereto.

In one embodiment of the present application, by spraying a composition such as the adsorbent or a solution containing the adsorbent and the adhesive into the blend, the molecular sieve crystal first particles and/or second particles are coated on the surface of the blend. As a result, the surface of the harmony can achieve effects such as adsorption, deodorization, and antibacterial effects of pollutants.

In one embodiment of the present application, by spraying a composition such as the adsorbent or a solution containing the adsorbent and the adhesive into the blend to coat the surface of the blend with the molecular sieve crystal first particles and/or second particles The air purification function can be achieved by adsorbing and blocking harmful substances from indoors and outdoors. For example, by coating a composition such as the adsorbent or a solution containing the adsorbent and the adhesive on the surface of the various blends, adsorption and decomposition of volatile organic solvents such as formaldehyde, benzene, toluene, etc., which exhibit sick house syndrome, and It can be usefully used to adsorb chemical toxic gases such as mustard gas, phosgen, sarin, chlorine gas, and radioactive iodine as a radioactive gas.

In one embodiment of the present application, the molecular sieve crystal may be a microcrystal, but is not limited thereto. The term “microcrystal” means a crystal having a size of 0.1-500 μm.

In the exemplary embodiment of the present disclosure, the second particle may have a nanometer size to a micrometer size, but is not limited thereto.

According to the conventional method of self-assembly and sonication with stacking (SS), molecular sieve crystals of 3 μm or more could not be densely bonded to the roughened phase. However, in one embodiment of the present application, crystals of a molecular sieve of 3 μm or more can be bonded to the roughened phase with high density (density) and high adhesion rate.

In one embodiment of the present application, the molecular sieve crystal directly or indirectly forms a chemical bond on the roughened surface. The chemical bonds include non-covalent bonds, ionic bonds, covalent bonds, and coordination bonds. Preferably, the chemical bond formed by the method of the present invention is an ionic bond or a hydrogen bond. For example, in the bonding pattern according to the present invention described above, the complex formed by hydrogen bonds is (i) a harmonic-molecular body complex, (ii) a harmonic-hydrogen bond mediator-molecular body complex, and (iii) a harmonic-adhesive It is a compound-molecular body complex. The complexes formed by ionic bonds are (iv) rough-adhesive compound-adhesive compound-molecular body complex, and (v) rough-adhesive compound-intermediate adhesive compound-adhesive compound-molecular body complex.

In one embodiment of the present application, the molecular sieve crystal bonded to the harmonic may have an orientation along a certain crystal axis with respect to a plane of the harmonic. For example, when a composition such as the adsorbent or a solution containing the adsorbent and the adhesive is sprayed into the harmony, the molecular sieve crystals are aligned with a single orientation, and the channels in the crystal are also aligned in a single direction. Has been. Such unidirectionality can maximize the applicability and utilization efficiency of the molecular sieve.

In one embodiment of the present application, by first forming a molecular sieve crystal monolayer film in harmony according to the above-described method, and combining a second molecular sieve crystal capable of bonding with the molecular sieve monolayer film, a two-layer film can be stacked in harmony. In addition, the multilayer film can be manufactured by repeating this process. The second molecular sieve crystal may be of the same type as or different from the molecular sieve crystal in which the monolayer film is formed. The lamination pattern is not limited to a specific method, but, for example, (harmonized-adhesive compound-molecular sieve crystal)-(adhesive compound-molecular sieve crystal), (harmonized-adhesive compound)-(adhesive compound-molecular sieve crystal-adhesive compound )-(Adhesive compound-molecular sieve crystal).

In one embodiment of the present application, according to the above-described method, when a monolayer of molecular sieves is first formed in the roughness and then fired at high temperature to remove the adhesive compound, the harmonics and molecular sieves are silicon-oxygen-silicon, etc. Are bonded by direct chemical bonds. If this process is repeated, a multilayer in which harmonics and molecular sieves are directly bonded can be obtained. Meanwhile, it is clear that the above-described method of the present invention can be used in the production of a film of molecular sieve crystals according to conventional techniques in the art, considering the technical level of the present technical field.

A second aspect of the present application provides a method of manufacturing an air conditioning conditioner according to the first aspect of the present application, comprising coating an adsorbent on the surface of the conditioner or conditioner.

Anything described with respect to the first aspect of the present application applies to the second aspect of the present application.

In one embodiment of the present application, coating the adsorbent may include spraying a solution containing the adsorbent onto the surface of the blender or immersing the blender in a solution containing the adsorbent, but is limited thereto. May not be.

In one embodiment of the present application, coating the adsorbent may include an additional drying process, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the method of manufacturing the air conditioner for purifying air may include coating a mixture with an adhesive added to the adsorbent on the surface of the conditioner, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the method of manufacturing the air conditioner for air purification may further include coating an adhesive before coating the adsorbent on the surface of the conditioner, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the adsorbent may be one selected from the group consisting of molecular sieve, clay, silica gel, photocatalyst, and combinations thereof, but may not be limited thereto.

In the exemplary embodiment of the present disclosure, the molecular sieve may be a crystal particle, but may not be limited thereto.

In one embodiment of the present application, by spraying a composition containing the first molecular sieve particle and/or second particle on the roughened surface, a physical pressure is applied to each of the particles to the surface of the roughened. A bond may be formed between the surface and each of the particles, but is not limited thereto. In one embodiment of the present application, the first molecular sieve particle and/or the second particle are in a powder state or in a solvent. It may be coated on the surface of the harmony in a dispersed state, but is not limited thereto.

In the exemplary embodiment of the present disclosure, a drying process may be additionally included after coating of the first molecular sieve particle and/or the second particle, but is not limited thereto. For example, after the drying process, it may further include applying a physical pressure, but is not limited thereto. By the application of the physical pressure, it is possible to promote the strong adhesion of the first molecular sieve particles and/or the second particles to the surface of the roughening.

In one embodiment of the present application, the coating of the first molecular sieve particles and/or the second particles may be performed by spraying, rubbing, immersion, or ultrasonic waves, but is not limited thereto.

In one embodiment of the present application, the method of manufacturing the air conditioning conditioner may further include a step of applying a physical pressure after coating of the first molecular sieve particle and/or the second particle, or a drying step. , But is not limited thereto.

In one embodiment of the present disclosure, the physical pressure may be applied by rubbing, wind power, or a roller, but is not limited thereto.

For example, the wind power is a device that generates hot air, such as a heat gun, a hair dryer, etc., to promote the strong adhesion of the first molecular sieve particles and/or the second particles to the surface of the blend. can do.

For example, the roller is made of an elastic material, and the roller is used to rub the first molecular sieve particle and/or the coated surface of the blend on which the second particle is coated, or press it with a light material. It is possible to promote the strong adhesion of the first molecular sieve particles and/or the second particles to the surface of the roughening.

In one embodiment of the present application, it may further include coating an adhesive compound on the surface of the roughened surface before or after coating the first molecular sieve particle and/or the second particle, but is not limited thereto.

In one embodiment of the present application, the artificial flower includes, but is not limited to, a artificial flower made of various known materials such as plastic, fiber, paper, clay, or metal.

In one embodiment of the present application, the zeolite as the adsorbent may be sprayed in a dry powder state or dispersed in an aqueous solution, but is not limited thereto.

For example, in the implementation of the method of manufacturing the air conditioning conditioner, the adhesive compound is first sprayed and then zeolite is sprayed; Spraying a zeolite and adhesive compound mixture; The zeolite can be sprayed first, and then the adhesive compound can be sprayed. After the zeolite is attached to the wall through the spraying, it can be rubbed while pressing with a roller made of an elastic material or pressed with a light material. In addition, it is possible to promote the strong adhesion of zeolite particles to the wall by applying warm air with a device that produces hot air, such as a heat gun or hair dryer, to ensure that the zeolite particles attached to the wall stick well to the wall.

According to the manufacturing method of the air conditioner for air purification, by spraying the air conditioner and coating the first molecular sieve crystal particles and/or the second particles on the surface of the conditioner, the indoor and outdoor environmental harmful substances are adsorbed and blocked to achieve an air purification function can do. For example, by coating the particle-coating composition on the surface of the various blends, adsorption and decomposition of volatile organic solvents such as formaldehyde, benzene, toluene, etc., indicating sick house syndrome, and mustard gas, a chemical toxic gas. ), phosgen, sarin, chlorine gas, and radioactive iodine, which is a radioactive gas, can be usefully used.

Hereinafter, the present invention will be described in more detail through the examples of the present application, but the following examples are merely illustrative to aid understanding of the present application, and the contents of the present application are not limited to the following examples.

[Example]

In this embodiment, the artificial flowers are coated with a zeolite or a similar adsorbent material that adsorbs, decomposes, or adsorbs and removes harmful substances such as antibacterial, antifungal, deodorant, formaldehyde, etc. And it implemented the manufacturing method of the artificial flower.

Specifically,

1. After immersing the crude oil in the solution containing the zeolite adsorbent, take it out and dry it.

2. Coat the finished blend with a zeolite solution with a spray, or

3. A method of immersing the components for conditioning in the solution containing the zeolite adsorbent, taking them out and drying them, or spraying the solution on the components for conditioning and drying them, and then assembling the components for conditioning to prepare a finished artificial flower. I can.

In addition, in order to measure the adhesion and decomposition ability of the roughened formaldehyde coated by the zeolite crystal particles, after placing the harmonic in an incubator, the formaldehyde was vaporized and supplied to the incubator. The decrease in the concentration of the supplied formaldehyde in the incubator was measured. As a comparative example, an uncoated blend of zeolite was used.

1A is an electron micrograph of an artificial incidence ear without zeolite coating as a comparative example, and FIG. 1B is an electron microscopic photo of an artificial incidence coated with zeolite in the present Example. It can be seen from FIG. 1B that zeolite molecular sieve crystal particles are bonded to the roughened surface and coated.

2 is a photograph of a device used to measure the formaldehyde removal function before and after zeolite coating on the blend.

3 is a graph showing the ability of adsorbing and decomposing formaldehyde of a blend coated with zeolite molecular sieve crystal particles according to the present embodiment compared with a blend without zeolite coating (Comparative Example). Referring to FIG. 3, it can be seen that the roughness coated with the zeolite molecular sieve crystal particles adsorbed and decomposed a remarkably large amount of formaldehyde compared to the roughened zeolite (Comparative Example).

The foregoing description of the present application is for illustrative purposes only, and those of ordinary skill in the art to which the present application pertains will be able to understand that it is possible to easily transform it into other specific forms without changing the technical spirit or essential features of the present application. Therefore, it should be understood that the embodiments described above are illustrative in all respects and not limiting. For example, each component described as a single type may be implemented in a distributed manner, and similarly, components described as being distributed may also be implemented in a combined form.

The scope of the present application is indicated by the claims to be described later rather than the detailed description, and all changes or modified forms derived from the meaning and scope of the claims and their equivalent concepts should be interpreted as being included in the scope of the present application.

Claims (20)

Arficial flowers coated with adsorbent.
The method of claim 1,
The air purification function includes antibacterial, anti-fungal, deodorant, pollutant adsorption and/or decomposition, or moisture control.
The method of claim 1,
Air conditioning conditioner comprising an adhesive in addition to the adsorbent.
The method of claim 1,
The adsorbent comprises a molecular sieve, clay, silica gel, a photocatalyst, and a combination thereof.
The method of claim 4,
The molecular sieve will contain a metal or metal cations ion-exchanged or adsorbed to the molecular sieve, air purification conditioner.
The method of claim 5,
The metal or metal cations are those containing a metal or cations of the metal having antibacterial properties or catalytic or photocatalytic properties.
The method of claim 5,
The metal or metal cation is Ag, Cu, Zn, Ti, Pt, and Pd containing one or more metals selected from the group consisting of or a cation of the metal, air purification conditioner.
The method of claim 4,
The molecular sieve is one containing a material selected from the group consisting of, air purification conditioner:
(i) zeolite
(ii) Zeolite, ZSM-5, silicalite-1, TS-1 or metallo-silicalite-1 having an MFI structure
(iii) Zeolite with MEL structure, ZSM-11, silicalite-2, TS-2 or metallo-silicalite-2
(iv) Zeolite A, X, Y, L, beta, mordenite, ferrierite, ETS-4 or ETS-10
(v) Mesoporous silica of any one of MCM series, SBA series, MSU series or KIT series
(vi) Organic-inorganic complex mesoporous structure or layered material
(vii) Organic zeolite, organometallic zeolite or coordination compound zeolite in which a metal ion and a ligand are three-dimensionally bonded
(viii) a composite containing organic, inorganic, organic-inorganic mixed dyes, luminescent dyes or pigments inside the pores of a porous material or between layers of a layered structure material, and
(ix) Metal Organic Framework (MOF) substances, Covalent Organic Framework (COF) substances, or complexes thereof.
The method of claim 3,
The adhesive is coated between the conditioner and the adsorbent, or mixed with the adsorbent and coated on the conditioner.
The method of claim 3,
The adhesive is one containing a compound derived from one or two or more organic compounds selected from the group consisting of compounds of Formulas 1 to 8 below:
[Formula 1]
Z-L1-X
[Formula 2]
MR'4
[Formula 3]
R ₃ Si-L1-Y
[Formula 4]
HS-L1-X
[Formula 5]
HS-L1-SiR ₃
[Formula 6]
HS-L1-Y
[Formula 7]
Z-L2(+) L3(-)-Y or Z-L3(-) L2(+)-Y:
In the above formula,
Z is R ₃ Si or an isocyanate group (-NCO), wherein R represents a halogen group, a C1-C4 alkoxy or a C1-C4 alkyl group, and at least one of the three R is a halogen group or an alkoxy group,
L1 is a hydrocarbon residue such as a substituted or unsubstituted C1-C17 alkyl, aralkyl or aryl group, which may contain one or more oxygen, nitrogen or sulfur atoms, and X is a halogen group, an isocyanate (-NCO) group, or An actual group or an azide group, R'is the same as R, at least two of the four R'are halogen or alkoxy groups, and M is silicon, titanium or zirconium,
Y is a hydroxy group, a thiol group, an amine group, an ammonium group, a sulfone group and a salt thereof, a carboxylic acid and a salt thereof, an acid anhydride, an epoxy group, an aldehyde group, an ester group, an acrylic group, an isocyanate group (-NCO), a sugar residue, A double bond, triple bond, diene, diyne, alkyl phosphine, alkyl acin, and a coordination compound capable of ligand exchange, and Y may be located in the middle as well as the end of the adhesive compound, and L2( +) represents a functional group having at least one positive charge (+) on the terminal, straight or side chain of a substituted or unsubstituted C1-C17 hydrocarbon compound that may contain one or more oxygen, nitrogen or sulfur atoms, and L3(- ) Means a functional group having at least one negative charge (-) on the terminal, straight or side chain of a substituted or unsubstituted C1-C17 hydrocarbon compound that may contain one or more oxygen, nitrogen, or sulfur atoms;
[Formula 8]
H ₂ NP-NH ₂ ;
In the above formula, P is a C1-C20 single molecule or a linear or branched polymer amines.
The method of claim 1,
The particles of the adsorbent are arranged and bonded to the surface of the conditioner in a predetermined direction.
A method for manufacturing an air conditioner according to any one of claims 1 to 11, comprising coating an adsorbent on the surface of the conditioner or conditioner component.
The method of claim 12,
Coating the adsorbent comprises spraying a solution containing the adsorbent onto the surface of the conditioner or immersing the conditioner in a solution containing the adsorbent.
The method of claim 13,
Coating the adsorbent further comprises a drying process, the method of manufacturing an air conditioner for purifying air.
The method of claim 12,
A method of manufacturing an air conditioner for purifying air, comprising coating a mixture with an adhesive added to the adsorbent on the surface of the conditioner.
The method of claim 12,
The method of manufacturing an air conditioning conditioner, further comprising coating an adhesive before coating the adsorbent on the surface of the conditioner.
The method of claim 12,
The adsorbent comprises a molecular sieve, clay, silica gel, a photocatalyst, and a combination thereof.
The method of claim 17,
The molecular sieve is ion-exchanged or adsorbed to the molecular sieve containing metal or metal cations.
The method of claim 18,
The metal or metal cations include metals or cations of the metals having antimicrobial properties or catalyst or photocatalytic properties.
The method of claim 17,
The molecular sieve comprises a material selected from the group consisting of, or contains organic and/or inorganic molecules in the molecular sieve.
(i) zeolite
(ii) Zeolite, ZSM-5, silicalite-1, TS-1 or metallo-silicalite-1 having an MFI structure
(iii) Zeolite with MEL structure, ZSM-11, silicalite-2, TS-2 or metallo-silicalite-2
(iv) Zeolite A, X, Y, L, beta, mordenite, ferrierite, ETS-4 or ETS-10
(v) Mesoporous silica of any one of MCM series, SBA series, MSU series or KIT series
(vi) Organic-inorganic complex mesoporous structure or layered material
(vii) Organic zeolite, organometallic zeolite or coordination compound zeolite in which a metal ion and a ligand are three-dimensionally bonded
(viii) a composite containing organic, inorganic, organic-inorganic mixed dyes, luminescent dyes or pigments inside the pores of a porous material or between layers of a layered structure material, and
(ix) Metal Organic Framework (MOF) substances, Covalent Organic Framework (COF) substances, or complexes thereof.

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