KR20200113356A - Silicate and granular the soil improvement a component and Water-Soluble Fertilizer method production - Google Patents

Abstract

The present invention relates to a water-soluble fertilizer composition using silicic acid and bay salt, and method for producing the same. The method comprises the steps of: (a) evenly mixing a composition, and performing condensation-melting on the composition in a melting furnace at a temperature of 1400-1500°C, wherein the composition is composed of 40-80 parts by weight of silica sand (SiO2) or silica powder (SiO2), 1-20 parts by weight of sea salt, 15-38 parts by weight of sodium carbonate (Na2CO3), 2-5 parts by weight of borax (Na2B4O7), 62 to 7 parts by weight of soda hexametaphosphate (NaPO3), 0.5-3 parts by weight of potassium carbonate (K2CO3), 2-5 parts by weight of sodium pyrophosphate (Na4P2O7), 0.5-2 parts by weight of calcium carbonate (CaCO3), 0.1-0.5 parts by weight of manganese dioxide (MnO2), and 0.05-0.2 parts by weight of soda molybdate (Na2MOO4); and pulverizing and granularizing glass flakes. According to the present invention, by receiving photosynthetic energy, which is solar energy, the latent heat of soil is diffused to promote the growth of crops.

Description

Water-soluble fertilizer composition and manufacturing method using silicon and sea salt {Silicate and granular the soil improvement a component and Water-Soluble Fertilizer method production}

The present invention neutralizes acidic soil by supplying water-soluble fertilizers using silicate and sea salt to farmers inexpensively, strengthens the crop by strongly elongating the roots of the crop, and regenerates the soil with excellent efficacy of silicic acid and inorganic nutrients and trace amounts. Water-soluble fertilizers of natural sea salt containing elements supply soil and crops to provide benefits for soil conservation, support the activity and reproduction of beneficial microorganisms on the soil, and make cumbersome purchase of seawater or bittem with salt. It is to provide an eco-friendly water-soluble fertilizer that can reduce labor and cost.

The present invention relates to a composition and a method for producing a water-soluble fertilizer containing silicate and sea salt as main components.

Silicic acid (Si) is an element that forms the basic mineral and accounts for 28% of the crust after oxygen. Silicic acid is dissolved by the interaction of weather, soil physical and chemical resistance, the molecules according to the soil _{pH (H 4 SiO 4, H} 3 SiO 4 -, H 2 SiO 4 2-, HSO 4 3- and SiO ₄ ^4- ), and polysilicic acid (n(SiOH ₄ )), a complex of these, Al, Fe, Ca, Na, MgSO _4, etc., and inorganic compounds, and organic silicic acid complexes. Plants mainly absorb H ₄ SiO ₄ type, and ionic type is inhibited by antagonism with other inorganic ions. Monosilicic acid and polysilicic acid, which are mainly absorbed by plants, affect soil pH through their interaction.

The silicic acid content of rice paddy soil is suitable for 130~180 (mg/kg), but the silicic acid content of Korean rice paddies is 86 (mg/kg) on average, and 84.4% of the rice fields lack silicic acid. In rice cultivation, rice is grown by absorbing silicic acid more than eight times as much as nitrogen. Silicic acid has the effect of suppressing the onset of blast disease, white leaf disease, and paperback disease of rice, and also has the effect of preventing insects from various vegetables and fruit trees, and has the effect of reducing soil pollution. In particular, for blast disease, the effect of application of silicic acid is recognized by many researchers, and the total SiO ₂ content in the soil is 50-60%, but the effective SiO ₂ in the form that rice can absorb is only about 100 ppm. In Korea, SiO ₂ leached in 1N-NaOAC (pH 4.0) leaching solution at 60°C within 90 minutes is defined as effective silicic acid, and in Korea, the leached SiO ₂ content is reported to be an average of 78 ppm.

When the nitrogen fertilization amount is about 10kg/10a, it is known that it should be 130ppm, and since the silicic acid content of the rice soil, which is 94% of Korea's rice soil, is less than 130ppm, most of the rice field soils are in a state of lack of effective silicic acid.

Soluble silicic acid (Si) is absorbed from the roots and rises in the plant, and upon evaporation from the leaf surface, silicon deposits in its epidermal cell membrane and becomes silicified cells, making the plant strong. For this reason, various pathogens, including blast bacteria attached to the plant, cannot easily invade into the inside of the plant, and even if it has invaded, the growth of the crab is usually inhibited, so that the lesion does not become large and the number thereof decreases.

The sea salt used in the present invention has been used for flavoring food, preventing water spoilage, sterilizing and sterilizing human trauma, and inhibiting bacterial growth, as well as in the East and West, and the components of seawater are sulfur (S ), calcium (Ca), iron (Fe), iodine (I), cobalt (Co), magnesium (Mg), potassium (K), zinc (Zn), strontium (Sr), fluorine (B), manganese (Mn) ), etc. It is analyzed that it contains 61 elements including inorganic substances and trace elements.

Therefore, the fertilizer containing the sea salt of the present invention increases the physical strength of leaves by accumulating silicic acid in the cells of the plant, strengthens the stems and leaves of plants to make them stand upright, promotes photosynthetic efficiency due to the absorption of light from the leaves, It prevents infection of the disease, increases disease resistance against insects, and is resistant to the cold and eastern seas, so it does not fall easily.

A recent study has shown that chlorine, which is high in salt, plays an indispensable role in the reaction of producing oxygen by decomposing water during photosynthesis by plants.

Contrary to the present invention, Korean Patent No. 10-0653462'Concentrated aqueous solution composition for trace urea fertilizer' is a composition made of water-soluble iron, water-soluble zinc, chromium, cadmium, arsenic, nickel, titanium, nitrous acid, and sulfurous acid components. Patent 10-2018-0020549'Water-soluble silicate fertilizer' is composed of a chemical mixture other than water-soluble silicate (sodium silicate) and dried at 85°C. It can be clearly distinguished from the manufacturing method that melts and dissolves in a melting furnace.

The composition and manufacturing method of the composition of the present invention is silica powder (SiO ₂ ) 40 to 70 parts by weight, or 50 to 80 parts by weight of a cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ), sodium carbonate (Na ₂ CO ₃ ) 25 to 38 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 to 5 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ ) 2 to 7 parts by weight, cary carbonate (K ₂ CO ₃ ) 0.5 to 3 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 2 to 5 parts by weight, calcium carbonate (CaCO ₃ ) 0.5 to 2 parts by weight, magnesium oxide (MgO) 0.1 to 1 part by weight, sodium molybdate (Na ₂ M _O O ₄ ) It is made of 0.05 to 0.5 parts by weight of the composition, and it is evenly mixed and put into a melting furnace, and it is manufactured in a glass form by condensation melting at a melting point of 1,400°C to 1500°C in the melting furnace. It is cooled and solidified and pulverized into granules, or liquefied and packaged to be supplied as eco-friendly fertilizers.

Korean Patent No. 10-0653462 Patent Publication No. 10-2018-0020549

There are high purity silica ore scattered in Korea, and sodium silicate (Na ₂ SiO ₃ ) exists in various forms depending on the mixing ratio, but there are more than 40 types of sodium silicate commercialized according to various uses. It's okay.

The silicate and sea salt water-soluble fertilizer of the present invention is an eco-friendly, integrated water-soluble fertilizer that can reduce the troublesome purchase of seawater or the labor and cost of making bittem with salt. It improves and neutralizes, and becomes an inorganic nutrient source for the decomposition of organic matter of beneficial sub-microorganisms, promotes the growth of roots of crops, adjusts the soil soil to a pH suitable for plant growth, and is the most beneficial 5~ Emissivity in the wavelength band of 20 microns facilitates the metabolism of crops with the radiation effect of far-infrared rays in the 92% range, and promotes the growth of crops by spreading the latent heat of the soil by receiving photosynthetic energy, which is solar energy.

By neutralizing the acidified soil, bacterial diseases and pests can be reduced, the use of fungicides and pesticides can be greatly reduced, and the harvest can be increased.

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The present invention is a water-soluble fertilizer composition using silicon and sea salt (天日鹽) to neutralize the acidified soil with alkali components of silicon, and the excellent efficacy of silicon to regenerate the soil, effective silicic acid and inorganic nutrients are beneficial to the soil It supports active breeding, promotes root establishment and crop growth, prevents successive crop damage, increases crop yield, reduces pests, and supplies 61 elements including minerals and trace elements contained in sea salt to the soil, It is an eco-friendly water-soluble fertilizer that provides benefits for the inhibitory effect on the occurrence of pests.

It will be described below with reference to the accompanying drawings of the present invention.
Figure 1 (A) is a chemical composition analysis table of sea salt and edible salt used in the present invention.
Fig. 1(B) is a comparative analysis table analyzing the components of domestic and foreign sea salt.
Figure 2 is a component analysis table of the silica sand used in the present invention.
3 is a component analysis table of cutlets, a raw material of sodium silicate used in the present invention.

The silica sand is mixed with sodium carbonate and heated at high temperature to completely dissolve it, and when it becomes transparent, it is poured out to cool and solidify. This is called a cutlet, and a concentrated aqueous solution concentrated by vacuum evaporation is sodium silicate (Na ₂ SiO ₃ ). Or, it is called water glass. The general formula of sodium silicate is represented by Na ₂ O·nSiO ₂ ·+ H ₂ O.

There are two types of manufacturing methods, dry method and wet method,

Dry method Na ₂ CO ₃ + nSiO ₂ = Na ₂ O·nSiO ₂ + CO ₂ ↑

Wet method 2NaOH + nSiO ₂ = Na ₂ O·nSiO ₂ + H ₂ O

The silicate used as the raw material for the production of the present invention is a dry method with a purity of 99.8% or more silica sand or silica powder (SiO ₂ ) or sodium silicate (Na ₂ SiO ₃ ) with a SiO ₂ standard of 72 to 76%. Is condensed and melted with appropriately mixed sodium carbonate (Na ₂ CO ₃ ), so the higher the Na content, the lower the dissolution temperature and condensation and melting, so it is well soluble in water. When sprayed on the soil, it melts to neutralize acid soil and The absorbed soluble silicic acid rises inside the plant and deposits in the epidermal membrane on the leaf surface, strengthens the roots, makes the plant strong, inhibits nitrogen excess absorption, and makes it strong against diseases and pests. In the case of fruit trees, growth is promoted, fruit color is improved, and fallen fruits And prevent class.

The impurities contained in silicate and molten sea salt become hygienic salts by extinction at a high temperature of 1,500℃. Chlorine in sea salt has recently been found to be an essential element for plants.

Since ancient times, it has overcome drought by spraying sea salt soil on barley and wheat fields. It is essential for the growth of the above-ground and underground parts of plants, and is involved in the accumulation of sugar and photosynthesis. First, lime in the soil, By combining with magnesium to form lime chloride and magnesium chloride, the absorption of plants is increased, so that it has an anti-winter effect.Second, some of the salt components act as a substitute for potassium, thereby serving as a fertilizer, and third, insoluble nutrients distributed in the soil. It is converted into a possible condition and used as a nutrient for crops.

1 (B) Referring to the comparative analysis table analyzing the components of the domestic sea salt and the foreign sea salt, it is proved that the domestic sea salt is the best sea salt in the world due to its lower salinity and higher mineral content than the foreign sea salt.

In modern agriculture, it is reported that the growth of crops is much better due to the effect of promoting photosynthesis by diluting and spraying it in water 20 times with seawater and 600 times with salt. Recently, organic farming research teams have obtained positive preliminary test results for the activation of soil nutrients and the function of crop protection by using salt water for growing agricultural crops (especially horticultural crops).

In addition, trace elements such as Ca, K, Mg, Fe, and Cu contained in the sea salt activate the growth function of plants and strengthen resistance to diseases, thereby suppressing red fungal disease and spot disease spreading to wheat and barley.

Borax (Na ₂ B ₄ O ₇ ) contains the absolutely necessary element (B) for the initial development of crops, and is closely related to the synthesis of nucleic acids, proteins, growth hormones, and transport and movement of plant sugars, and fruit seed formation It is related to and is an indispensable element for the movement of carbohydrates and formation of cell membranes.

Sodium hexametaphosphate ((NaPO ₃ ) ₆ ) regulates the acidity of soil and increases mycorrhizal fungi and other beneficial soil microbes in plants. Heat transfer, decomposition of carbohydrates, and plant cells act to make sugar from carbon dioxide and water by chlorophyll and sunlight, increase sweetness, promote root growth, and increase the growth of branches and leaves, resulting in increased harvest. .

Kari carbonate (K ₂ CO ₃ ) promotes photosynthetic action, evaporation of moisture, and regulation of moisture supply to increase the resistance to the year, contributes to the production of plant fiber, and enhances the cell composition of plants.

Sodium pyrophosphate (Na ₄ P ₂ O ₇ ) is a nutrient that promotes germination, promotes plant maturation, and enhances the ability to make starch.

Calcium carbonate (CaCO ₃ ) is a component of cell membranes , has the effect of strengthening plants, and promotes the growth of roots and leaves. By neutralizing acidic soil and correcting the soil reaction, it promotes the activity of soil microorganisms and plays a great role in improving the soil environment suitable for plant growth. It acts as an antagonist to inhibit nitrogen assimilation, excessive absorption of magnesium, gari, and sodium, and improves the circulation of air and moisture in the soil.

Manganese dioxide (MnO ₂ ) is involved in many enzymatic systems and is a component of phosphatase. It is related to photosynthesis and chlorophyll, and it is also a forming component of chlorophyll, and is an indispensable element in green plants. In particular, it increases the activity of enzymes involved in phosphoric acid metabolism and photosynthesis.

Molybdic acid soda (Na _{2 O} M O ₄₎ has a key role in the generation of plant trace elements and amino acids and proteins are components of the reductase nitrogen Generally speaking the content of molybdenum in the soil is between 0.6 ~ 3.5ppm. The amount of molybdenum in plant weight is about 0.1 ppm, and it is mainly absorbed by plants in anionic state. Molybdenum is a component that is necessary when nitrogen nitrate reduces enzymes and nitrogen fixing enzymes.It is closely related to nitrogen metabolism, and acidic soils (pH 5.5 or less) easily cause molybdenum deficiency, and adjusting the acidity of the soil can increase the effectiveness of molybdenum. have.

The fertilizer containing silicate and sea salt of the present invention is completely harmless, non-toxic, and odorless to the human body and animals and plants, does not cause pollution problems when flowing into rivers or seas in wastewater, does not cause toxicity concerns, and is an environmentally friendly fertilizer to be.

In the manufacturing process of the present invention, the composition is evenly mixed with a blender and put into a melting furnace, and the melting temperature is a glassy crystal by cooling the molten material tapped by condensation melting in the furnace at a temperature of 1,400-1,500°C by appropriate mixing of the above composition. It is pulverized into granules to be measured and packaged into granular products, and the granules are put in a dissolving device together with purified water and dissolved, and then shipped as a liquid product after weighing, packaging, and inspection.

Hereinafter, an example according to the implementation of the present invention will be described.

(Example 1)

Mixing silica powder (SiO ₂ ) 55 parts by weight, sea salt 10 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 30 parts by weight, borax (Na ₂ B ₄ O ₇ ) 4 parts by weight, manganese dioxide (MnO ₂ ) 1 part by weight with a blender Then, it was put into a melting furnace, melted at a temperature of 1,500° C. for 6 hours, tapped and cooled, and then pulverized into 3 to 5 mm thick particles with a grinder to prepare granules.

(Example 2)

Silica powder (SiO ₂ ) 50 parts by weight, natural sea salt 12 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 27 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ ) 2 parts by weight, cary carbonate (K ₂ CO ₃ ) 2 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 4 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight, manganese dioxide (MnO ₂ ) 0.2 parts by weight, Mix 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) with a blender, put it in a melting furnace, melt it at a temperature of 1,450°C for 6 hours, tap and cool it, and then pulverize it into 3~5mm coarse particles with a grinder to granulate Prepared.

(Example 3)

Silica powder (SiO ₂ ) 53 parts by weight, sea salt 7 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 30 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ ) 2 parts by weight, cary carbonate (K ₂ CO ₃ ) 2 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 3 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight, manganese dioxide (MnO ₂ ) 0.2 parts by weight, Mix 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) with a blender, put it in a melting furnace, melt it at a temperature of 1,450°C for 6 hours, tap and cool it, and then pulverize it into 3~5mm coarse particles with a grinder to granulate Prepared.

(Example 4)

Silica powder (SiO ₂ ) 55 parts by weight, natural sea salt 5 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 30 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ ) 2 parts by weight, cary carbonate (K ₂ CO ₃ ) 2 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 3 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight, manganese dioxide (MnO ₂ ) 0.2 parts by weight, Mix 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) with a blender, put it in a melting furnace, melt it at a temperature of 1,450°C for 6 hours, tap and cool it, and then pulverize it into 3~5mm coarse particles with a grinder to granulate Prepared.

(Example 5)

Silica powder (SiO ₂ ) 60 parts by weight, natural sea salt 5 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 35 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ ) 2 parts by weight, cary carbonate (K ₂ CO ₃ ) 1 part by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 3 parts by weight, calcium carbonate (CaCO ₃ ) 1.6 parts by weight, manganese dioxide (MnO ₂ ) 0.3 parts by weight, Mix 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) with a blender, put it in a melting furnace, melt it at a temperature of 1,450°C for 6 hours, tap and cool it, and then pulverize it into 3~5mm coarse particles with a grinder to granulate Prepared.

(Example 6)

78 parts by weight of cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ), 5 parts by weight of sea salt, 15 parts by weight of sodium carbonate (Na ₂ CO ₃ ), 1.5 parts by weight of borax (Na ₂ B ₄ O ₇ ), carbonic acid 0.5 parts by weight of calcium (CaCO ₃ ) was mixed with a blender, added to the melting furnace, melted at a temperature of 1,400°C for 4 hours, tapped and cooled, and then pulverized into 3 to 5 mm thick particles with a grinder to prepare granules.

(Example 7)

71 parts by weight of a cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ), 4 parts by weight of sea salt, 15 parts by weight of sodium carbonate (Na ₂ CO ₃ ), ₂ parts by weight of borax (Na ₂ B ₄ O ₇ ), hexa Sodium metaphosphate ((NaPO ₃ ) ₆ ) 3 parts by weight, cari carbonate (K ₂ CO ₃ ) 1 part by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 3 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight , 0.2 parts by weight of manganese dioxide (MnO ₂ ) and 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) are mixed with a blender and put into a melting furnace, melted at a temperature of 1,400°C for 4 hours, tapped and cooled, and then It was pulverized into 3~5mm coarse particles to prepare granules.

(Example 8)

73 parts by weight of a cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ), 5 parts by weight of sea salt, 18 parts by weight of sodium carbonate (Na ₂ CO ₃ ), 1.5 parts by weight of borax (Na ₂ B ₄ O ₇ ), hexa Sodium metaphosphate ((NaPO ₃ ) ₆ ) 3 parts by weight, cari carbonate (K ₂ CO ₃ ) 1.5 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 3 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight , 0.2 parts by weight of manganese dioxide (MnO ₂ ) and 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) are mixed with a blender and put into a melting furnace, melted at a temperature of 1,400°C for 4 hours, tapped and cooled, and then It was pulverized into 3~5mm coarse particles to prepare granules.

(Example 9)

77 parts by weight of a cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ), 3 parts by weight of sea salt, 20 parts by weight of sodium carbonate (Na ₂ CO ₃ ), 2 parts by weight of borax (Na ₂ B ₄ O ₇ ), hexa Sodium metaphosphate ((NaPO ₃ ) ₆ ) 3 parts by weight, cari carbonate (K ₂ CO ₃ ) 1 part by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 3 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight , 0.2 parts by weight of manganese dioxide (MnO ₂ ) and 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) are mixed with a blender and put into a melting furnace, melted at a temperature of 1,400°C for 4 hours, tapped and cooled, and then It was pulverized into 3~5mm coarse particles to prepare granules.

(Example 10)

75 parts by weight of a cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ), 5 parts by weight of sea salt, 10 parts by weight of sodium carbonate (Na ₂ CO ₃ ), 1 part by weight of borax (Na ₂ B ₄ O ₇ ), hexa Sodium metaphosphate ((NaPO ₃ ) ₆ ) 3 parts by weight, cari carbonate (K ₂ CO ₃ ) 1 part by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 4 parts by weight, calcium carbonate (CaCO ₃ ) 0.7 parts by weight , 0.2 parts by weight of manganese dioxide (MnO ₂ ), 0.1 parts by weight of sodium molybdate (Na ₂ M _{O 4} ), mixed with a blender and put into a melting furnace, melted at a temperature of 1,400°C for 4 hours, tapped and cooled, and then It was pulverized into 3~5mm coarse particles to prepare granules.

Looking at the melting and dissolution process of the composition as described above, the proper composition of the composition of the present invention is 50 to 65 parts by weight of silica powder (SiO ₂ ) or the cutlet (Cullet), which is a base product of sodium silicate (Na ₂ SiO ₃ ), is 60 ~78 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 25 to 38 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 to 5 parts by weight, hexametaphosphate ((NaPO ₃ ) ₆ ) 2 to 7 parts by weight, Cary carbonate (K ₂ CO ₃ ) 0.5 to 3 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 2 to 5 parts by weight, calcium carbonate (CaCO ₃ ) 0.5 to 2 parts by weight, manganese dioxide (MnO ₂ ) 0.1 to 0.5 parts by weight of sodium molybdate (Na ₂ M _{O 4} ) 0.05 to 0.2 parts by weight of the composition, and the manufacturing method is to mix them evenly and put them into the melting furnace, which is the melting point through an automatic temperature sensor in the melting furnace. It is manufactured in a glassy form by condensation melting at a temperature of 1,400℃~1,500℃, cooled and solidified, pulverized into granules, and packaged, and the granules are dissolved and liquefied to provide packaging.

Prepared granular 1kg is mixed with an appropriate amount of fertilizer and spread in a 660㎡ green house for crops to obtain improved soil effect to control diseases and pests, and the pulp of cherry tomatoes is thick and doubled, and the quality of the 30% increase effect The cherry tomatoes were harvested.

As a result of dispersing the fertilizer of the present invention in the same way in an orchard, there is no occurrence of disease and pests, and it is resistant to cold damage and loam, so the apples are shiny, have high sugar content, and have a long freshness, so it is easy to store, and there is no dropping phenomenon, resulting in an increase of 20%. . In addition, 1 kg of fertilizer of the present invention was spread before planting on a basis of 1,000㎡ of rice paddy. As a result of harvesting, there was an effect of increasing the water quality of 18% and improving the quality of rice, contributing to the increase of farm household income.

[Effects of the Invention]

The present invention is a water-soluble fertilizer composition and manufacturing method using silicate and sea salt, neutralizes the acidified soil with the alkali component of sodium silicate and regenerates the soil. It is an eco-friendly water-soluble fertilizer that supports the activity and reproduction of microorganisms whose nutrients are beneficial to the soil and supplies the soil with trace elements contained in sea salt.

The composition consists mainly of silica sand, silica powder (SiO ₂ ), or sodium silicate (Na ₂ SiO ₃ ), which is a base product of cutlet and sea salt, and anhydrous sodium carbonate (Na ₂ CO ₃ ), borax (Na ₂ B ₄ O ₇ ), sodium hexametaphosphate ((NaPO ₃ ) ₆ ), cary carbonate (K ₂ CO ₃ ), sodium pyrophosphate (Na ₄ P ₂ O ₇ ), calcium carbonate It consists of (CaCO ₃ ), manganese dioxide (MnO ₂ ), molybdate sodium (Na ₂ M _{O 4} ), and it is mixed evenly and put into a melting furnace, and the melting point of 1,400~1,500℃ is condensed and melted into a glass phase. It is manufactured and pulverized into granules or liquefied to provide an eco-friendly water-soluble fertilizer.

The eco-friendly fertilizer manufactured using the silicate and sea salt of the present invention improves acidic soil and can quickly recover from the symptoms of deficiency of trace elements and when crops are debilitated due to diseases, pests, wind and flood damage, and weather disorders through foliar fertilization. In particular, it improves quality and maintains high sugar content in gardening facilities and vegetables and fruit tree cultivation.

As for the increase effect of the application of silicic acid by crops studied at home and abroad until recently, 10 to 46% of the effect of rice is recognized worldwide by country and by crop considering the weather and soil environment. It produced the highest effect. In wheat, barley, corn, 10-15% increase in water, sugar cane (Brazil) 5-13%, peanuts 15-25% (China), cucumbers 3-10%, tomatoes 8-9%, Academic research that rose rose to 4-8% increased yield, indicating that the role of fertilizer containing silicic acid is great for agriculture.

The present invention enhances the resistance to diseases and pests of horticultural crops and flowering plant crops by using the alkali component of sodium silicate and the efficacy of sea salt, and improves acidified soil and contaminated soil by excessive fertilization of chemical fertilizers, Therefore, the water-soluble fertilizer using silicate and sea salt of the present invention increases the physical strength of leaves by accumulating silicic acid in the cells of plants, and strengthens the stems and leaves of plants to make them stand upright, thereby increasing the photosynthetic efficiency due to the absorption of light from the leaves. It prevents infection of the disease, increases disease resistance against insects, and is resistant to the cold and eastern seas, so it does not fall easily.

By supplying trace elements contained in sea salt, it strengthens the stems and leaves of plants through side fertilization, improves disease resistance, activates the growth function of plants with excellent quality and increased harvest, and strengthens resistance to diseases to prevent red mold disease, wheat and barley. It suppresses smudges and mites, the natural enemy of tangerine farming.

In addition, it is an eco-friendly, water-soluble fertilizer that can reduce the troublesome purchase of seawater or the labor and cost of making bittem with salt. By supplying a water-soluble fertilizer using the silicate and sea salt of the present invention, it will greatly contribute to eco-friendly agriculture.

Claims (7)

A method of manufacturing fertilizer containing sea salt in silicate, including the following steps:
(a) silica sand (SiO ₂ ) or silica powder (SiO ₂ ) 40 to 80 parts by weight, sea salt 1 to 20 parts by weight, sodium carbonate (Na ₂ CO ₃ ) 15 to 38 parts by weight, borax (Na ₂ B ₄ O ₇ ) 2 to 5 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ 2 to 7 parts by weight, carbonic acid (K ₂ CO ₃ ) 0.5 to 3 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇ ) 2 to 5 parts by weight of calcium carbonate (CaCO ₃₎ 0.5 ~ 2 parts by weight of manganese dioxide (MnO ₂₎ 0.1 ~ 0.5 parts by weight of molybdic acid soda _{(Na 2 M O O 4)} 0.05 ~ 0.2 parts by weight in the negative composition by evenly mixing furnace Condensation melting at a temperature of 1,400~1,500℃
(b) pulverizing and granulating the glass phase manufactured through tapping, slow cooling, and cooling processes. A fertilizer manufacturing method containing the natural sea salt of Cullet, a base product of sodium silicate (Na ₂ SiO ₃ ), including the following steps:
(a) 55 to 80 parts by weight of natural sea salt, 1 to 20 parts by weight of sea salt, 15 to 38 parts by weight of sodium carbonate (Na ₂ CO ₃ ), and borax (Na ₂ B) in 55 to 80 parts by weight of a cutlet, a base product of sodium silicate (Na ₂ SiO ₃ ) ₄ O ₇ ) 2 to 5 parts by weight, sodium hexametaphosphate ((NaPO ₃ ) ₆ ) 2 to 7 parts by weight, carbonic acid (K ₂ CO ₃ ) 0.5 to 3 parts by weight, sodium pyrophosphate (Na ₄ P ₂ O ₇₎ 2-5 parts by weight of calcium carbonate (CaCO ₃₎ 0.5 ~ 2 parts by weight of manganese dioxide (MnO ₂₎ 0.1 ~ 0.5 parts by weight of a molybdenum oxygen composition Oda _{(Na 2 M O O 4)} 0.05 ~ 0.2 parts by weight of Mixing evenly and condensation melting at a temperature of 1,400~1,500℃ in a melting furnace
(b) pulverizing and granulating the glass phase manufactured through tapping, slow cooling, and cooling processes. A fertilizer manufacturing method that melts and dissolves the sea salt in a blending ratio of 1 to 20%. A fertilizer manufacturing method wherein the pH of claim 1 (b) is adjusted to a range of 7-14 by dissolving and liquefying it with purified water. A fertilizer manufacturing method in which the pH of claim 2 (b) is adjusted to a range of 7-14 by dissolving and liquefying it with purified water. The method of claim 1, further comprising sodium citrate, refined glucose, potassium lactate, amino acids, minerals (Trace Mineral), magnesium carbonate, illite, amino acids, and selenium. According to claim 1 and 2, nitrogen (N), phosphorus (P), cari (K), which are essential elements of crop growth. Sulfur (S ). Features include the addition of one or more compounds of iron (Fe), magnesium (Mg), calcium (Ca), zinc (Zn), copper (Cu), manganese (Mn), boron (B), and molybdenum (Mo) Method for producing a water-soluble fertilizer.

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