KR20200064147A - 난연성 및 색상 안정성 폴리아미드 성형 컴파운드 - Google Patents

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Publication number

KR20200064147A

KR20200064147A KR1020207014097A KR20207014097A KR20200064147A KR 20200064147 A KR20200064147 A KR 20200064147A KR 1020207014097 A KR1020207014097 A KR 1020207014097A KR 20207014097 A KR20207014097 A KR 20207014097A KR 20200064147 A KR20200064147 A KR 20200064147A

Authority

KR

South Korea

Prior art keywords

component

acid

formula

polyamide composition

retardant polyamide

Prior art date

2017-10-16

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• 239000004952 Polyamide Substances 0.000 title claims abstract description 98
• 229920002647 polyamide Polymers 0.000 title claims abstract description 98
• 239000003063 flame retardant Substances 0.000 title claims abstract description 79
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 69
• 150000001875 compounds Chemical class 0.000 title claims description 26
• 238000000465 moulding Methods 0.000 title description 16
• 239000000203 mixture Substances 0.000 claims abstract description 69
• 229920000642 polymer Polymers 0.000 claims abstract description 36
• 229920000877 Melamine resin Polymers 0.000 claims abstract description 25
• JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 25
• 229920000728 polyester Polymers 0.000 claims abstract description 24
• 239000007795 chemical reaction product Substances 0.000 claims abstract description 23
• 150000003839 salts Chemical class 0.000 claims abstract description 23
• 239000002253 acid Substances 0.000 claims abstract description 19
• 229910052782 aluminium Inorganic materials 0.000 claims abstract description 19
• 229910052742 iron Inorganic materials 0.000 claims abstract description 18
• 150000002148 esters Chemical class 0.000 claims abstract description 14
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 12
• 229920001971 elastomer Polymers 0.000 claims abstract description 12
• 239000000806 elastomer Substances 0.000 claims abstract description 10
• ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims abstract description 10
• 229910052749 magnesium Inorganic materials 0.000 claims abstract description 9
• 229910052718 tin Inorganic materials 0.000 claims abstract description 9
• 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
• 229910052787 antimony Inorganic materials 0.000 claims abstract description 8
• 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
• 229910052732 germanium Inorganic materials 0.000 claims abstract description 8
• 229910052744 lithium Inorganic materials 0.000 claims abstract description 8
• 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
• 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
• 229910052712 strontium Inorganic materials 0.000 claims abstract description 8
• 229920001169 thermoplastic Polymers 0.000 claims abstract description 8
• 229910052719 titanium Inorganic materials 0.000 claims abstract description 8
• 229910052726 zirconium Inorganic materials 0.000 claims abstract description 8
• 239000007859 condensation product Substances 0.000 claims abstract description 7
• 239000000945 filler Substances 0.000 claims abstract description 7
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
• 239000012779 reinforcing material Substances 0.000 claims abstract description 7
• 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 7
• 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 6
• 125000003118 aryl group Chemical group 0.000 claims abstract description 6
• 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 6
• 239000000194 fatty acid Substances 0.000 claims abstract description 6
• 229930195729 fatty acid Natural products 0.000 claims abstract description 6
• 150000004665 fatty acids Chemical class 0.000 claims abstract description 6
• 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
• 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
• 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims abstract description 4
• 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 3
• 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 3
• 125000004122 cyclic group Chemical group 0.000 claims abstract description 3
• ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 3
• 150000002829 nitrogen Chemical class 0.000 claims abstract description 3
• 229920006345 thermoplastic polyamide Polymers 0.000 claims abstract description 3
• OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract 2
• -1 polyethylene terephthalate Polymers 0.000 claims description 65
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
• HJJOHHHEKFECQI-UHFFFAOYSA-N aluminum;phosphite Chemical compound [Al+3].[O-]P([O-])[O-] HJJOHHHEKFECQI-UHFFFAOYSA-N 0.000 claims description 25
• XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
• 229920000388 Polyphosphate Polymers 0.000 claims description 17
• 239000001205 polyphosphate Substances 0.000 claims description 17
• 235000011176 polyphosphates Nutrition 0.000 claims description 17
• 239000000654 additive Substances 0.000 claims description 16
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
• 229920002292 Nylon 6 Polymers 0.000 claims description 12
• 229920000139 polyethylene terephthalate Polymers 0.000 claims description 12
• 239000005020 polyethylene terephthalate Substances 0.000 claims description 12
• 229920002302 Nylon 6,6 Polymers 0.000 claims description 11
• 238000000034 method Methods 0.000 claims description 11
• 239000003381 stabilizer Substances 0.000 claims description 11
• 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 10
• AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 9
• 125000004432 carbon atom Chemical group C* 0.000 claims description 9
• 239000003365 glass fiber Substances 0.000 claims description 9
• 150000005846 sugar alcohols Polymers 0.000 claims description 8
• 241000219112 Cucumis Species 0.000 claims description 7
• 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 7
• FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 7
• 239000000463 material Substances 0.000 claims description 7
• YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 claims description 7
• 229910052760 oxygen Inorganic materials 0.000 claims description 7
• 239000011701 zinc Substances 0.000 claims description 7
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
• 239000003963 antioxidant agent Substances 0.000 claims description 6
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 6
• 229920001707 polybutylene terephthalate Polymers 0.000 claims description 6
• 229920000137 polyphosphoric acid Polymers 0.000 claims description 6
• 239000010936 titanium Substances 0.000 claims description 6
• YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 claims description 5
• 125000001931 aliphatic group Chemical group 0.000 claims description 5
• 229910052783 alkali metal Inorganic materials 0.000 claims description 5
• 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
• 238000002347 injection Methods 0.000 claims description 5
• 239000007924 injection Substances 0.000 claims description 5
• 150000004668 long chain fatty acids Chemical class 0.000 claims description 5
• 150000003751 zinc Chemical class 0.000 claims description 5
• IORMLXYGTOTABZ-UHFFFAOYSA-N 2,4,5-trioxa-1-phospha-3-aluminabicyclo[1.1.1]pentane tetrahydrate Chemical compound O.O.O.O.[Al+3].[O-]P([O-])[O-] IORMLXYGTOTABZ-UHFFFAOYSA-N 0.000 claims description 4
• 229910018626 Al(OH) Inorganic materials 0.000 claims description 4
• 229910019142 PO4 Inorganic materials 0.000 claims description 4
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 4
• NCPIYHBOLXSJJR-UHFFFAOYSA-H [Al+3].[Al+3].[O-]P([O-])=O.[O-]P([O-])=O.[O-]P([O-])=O Chemical compound [Al+3].[Al+3].[O-]P([O-])=O.[O-]P([O-])=O.[O-]P([O-])=O NCPIYHBOLXSJJR-UHFFFAOYSA-H 0.000 claims description 4
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
• 125000005442 diisocyanate group Chemical group 0.000 claims description 4
• FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
• 239000002667 nucleating agent Substances 0.000 claims description 4
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
• 235000021317 phosphate Nutrition 0.000 claims description 4
• 239000000049 pigment Substances 0.000 claims description 4
• 229920006375 polyphtalamide Polymers 0.000 claims description 4
• SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 4
• 239000004593 Epoxy Substances 0.000 claims description 3
• 239000004609 Impact Modifier Substances 0.000 claims description 3
• LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 3
• 239000004954 Polyphthalamide Substances 0.000 claims description 3
• 230000000996 additive effect Effects 0.000 claims description 3
• 125000003545 alkoxy group Chemical group 0.000 claims description 3
• 125000002947 alkylene group Chemical group 0.000 claims description 3
• 239000002216 antistatic agent Substances 0.000 claims description 3
• 239000011324 bead Substances 0.000 claims description 3
• JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 3
• 239000003990 capacitor Substances 0.000 claims description 3
• 150000001718 carbodiimides Chemical class 0.000 claims description 3
• 238000000576 coating method Methods 0.000 claims description 3
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 3
• 239000003995 emulsifying agent Substances 0.000 claims description 3
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
• 239000000835 fiber Substances 0.000 claims description 3
• ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 claims description 3
• 239000011521 glass Substances 0.000 claims description 3
• 150000002505 iron Chemical class 0.000 claims description 3
• 239000012764 mineral filler Substances 0.000 claims description 3
• CZQYVJUCYIRDFR-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O CZQYVJUCYIRDFR-UHFFFAOYSA-N 0.000 claims description 3
• 239000004014 plasticizer Substances 0.000 claims description 3
• 229920000098 polyolefin Polymers 0.000 claims description 3
• 229910052717 sulfur Inorganic materials 0.000 claims description 3
• BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
• 239000011787 zinc oxide Substances 0.000 claims description 3
• BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 claims description 3
• KKKKCPPTESQGQH-UHFFFAOYSA-N 2-(4,5-dihydro-1,3-oxazol-2-yl)-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=NCCO1 KKKKCPPTESQGQH-UHFFFAOYSA-N 0.000 claims description 2
• 239000006057 Non-nutritive feed additive Substances 0.000 claims description 2
• 239000012963 UV stabilizer Substances 0.000 claims description 2
• 229910001413 alkali metal ion Inorganic materials 0.000 claims description 2
• 125000001118 alkylidene group Chemical group 0.000 claims description 2
• 239000002585 base Substances 0.000 claims description 2
• SPWAXFLJYHRRJL-UHFFFAOYSA-N butyl(ethyl)phosphinic acid Chemical group CCCCP(O)(=O)CC SPWAXFLJYHRRJL-UHFFFAOYSA-N 0.000 claims description 2
• BMHINTNZTDUTBX-UHFFFAOYSA-N butyl(hexan-3-yl)phosphinic acid Chemical compound C(C)C(CCC)P(O)(=O)CCCC BMHINTNZTDUTBX-UHFFFAOYSA-N 0.000 claims description 2
• 229910052799 carbon Inorganic materials 0.000 claims description 2
• 229920006236 copolyester elastomer Polymers 0.000 claims description 2
• DGZNEHPVXXRBIU-UHFFFAOYSA-N di(butan-2-yl)phosphinic acid Chemical compound CCC(C)P(O)(=O)C(C)CC DGZNEHPVXXRBIU-UHFFFAOYSA-N 0.000 claims description 2
• NNPWWKQUTCVLAD-UHFFFAOYSA-N di(nonyl)phosphinic acid Chemical compound CCCCCCCCCP(O)(=O)CCCCCCCCC NNPWWKQUTCVLAD-UHFFFAOYSA-N 0.000 claims description 2
• KSHDLNQYVGBYHZ-UHFFFAOYSA-N dibutylphosphinic acid Chemical compound CCCCP(O)(=O)CCCC KSHDLNQYVGBYHZ-UHFFFAOYSA-N 0.000 claims description 2
• 239000000975 dye Substances 0.000 claims description 2
• VARVNAIBQYSVKZ-UHFFFAOYSA-N ethyl(hexan-2-yl)phosphinic acid Chemical compound C(C)P(O)(=O)C(CCCC)C VARVNAIBQYSVKZ-UHFFFAOYSA-N 0.000 claims description 2
• RMMXRAVNFLSFDE-UHFFFAOYSA-N ethyl(hexyl)phosphinic acid Chemical compound CCCCCCP(O)(=O)CC RMMXRAVNFLSFDE-UHFFFAOYSA-N 0.000 claims description 2
• IGOFCXYCMKELMG-UHFFFAOYSA-N ethyl(octyl)phosphinic acid Chemical compound CCCCCCCCP(O)(=O)CC IGOFCXYCMKELMG-UHFFFAOYSA-N 0.000 claims description 2
• 239000011888 foil Substances 0.000 claims description 2
• 230000005251 gamma ray Effects 0.000 claims description 2
• 125000001072 heteroaryl group Chemical group 0.000 claims description 2
• 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
• PUVAXSWBDZLKPZ-UHFFFAOYSA-N hexyl(nonyl)phosphinic acid Chemical compound C(CCCCC)P(O)(=O)CCCCCCCCC PUVAXSWBDZLKPZ-UHFFFAOYSA-N 0.000 claims description 2
• XPMBDFJXHYJGEW-UHFFFAOYSA-N hexyl(propyl)phosphinic acid Chemical compound CCCCCCP(O)(=O)CCC XPMBDFJXHYJGEW-UHFFFAOYSA-N 0.000 claims description 2
• 230000007062 hydrolysis Effects 0.000 claims description 2
• 238000006460 hydrolysis reaction Methods 0.000 claims description 2
• 150000002500 ions Chemical class 0.000 claims description 2
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
• 229910052751 metal Inorganic materials 0.000 claims description 2
• 239000002184 metal Substances 0.000 claims description 2
• 150000002739 metals Chemical class 0.000 claims description 2
• 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
• 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
• 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
• 238000004382 potting Methods 0.000 claims description 2
• 239000000047 product Substances 0.000 claims description 2
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
• 239000004753 textile Substances 0.000 claims description 2
• 230000003078 antioxidant effect Effects 0.000 claims 2
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
• FGKKMNKQKVYHMG-UHFFFAOYSA-N butan-2-yl(ethyl)phosphinic acid Chemical compound CCC(C)P(O)(=O)CC FGKKMNKQKVYHMG-UHFFFAOYSA-N 0.000 claims 1
• NGKCHGKFHQDOPZ-UHFFFAOYSA-N dihexylphosphinic acid Chemical compound CCCCCCP(O)(=O)CCCCCC NGKCHGKFHQDOPZ-UHFFFAOYSA-N 0.000 claims 1
• 229920001778 nylon Polymers 0.000 description 26
• 239000004677 Nylon Substances 0.000 description 25
• 235000002639 sodium chloride Nutrition 0.000 description 24
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
• 238000003860 storage Methods 0.000 description 10
• KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 9
• 239000012170 montan wax Substances 0.000 description 9
• 230000008859 change Effects 0.000 description 8
• ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 8
• 150000001450 anions Chemical class 0.000 description 7
• PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
• CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
• WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
• 159000000014 iron salts Chemical class 0.000 description 6
• ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 6
• 238000012360 testing method Methods 0.000 description 6
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
• 150000004715 keto acids Chemical class 0.000 description 5
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
• 229920006055 Durethan® Polymers 0.000 description 4
• MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 4
• 235000006708 antioxidants Nutrition 0.000 description 4
• 239000004615 ingredient Substances 0.000 description 4
• QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
• 239000011777 magnesium Substances 0.000 description 4
• 150000002815 nickel Chemical class 0.000 description 4
• 229910052757 nitrogen Inorganic materials 0.000 description 4
• 238000012545 processing Methods 0.000 description 4
• 239000000126 substance Substances 0.000 description 4
• HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 3
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
• VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 3
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
• 229920000299 Nylon 12 Polymers 0.000 description 3
• 239000004793 Polystyrene Substances 0.000 description 3
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
• 239000001361 adipic acid Substances 0.000 description 3
• 235000011037 adipic acid Nutrition 0.000 description 3
• 150000001408 amides Chemical class 0.000 description 3
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
• 235000019437 butane-1,3-diol Nutrition 0.000 description 3
• 239000011575 calcium Substances 0.000 description 3
• 150000001735 carboxylic acids Chemical class 0.000 description 3
• 239000003795 chemical substances by application Substances 0.000 description 3
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
• 229920001577 copolymer Polymers 0.000 description 3
• RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
• XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 3
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
• 238000001746 injection moulding Methods 0.000 description 3
• 239000011572 manganese Substances 0.000 description 3
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• VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 description 1
• 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
• ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
• NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
• CENHPXAQKISCGD-UHFFFAOYSA-N trioxathietane 4,4-dioxide Chemical compound O=S1(=O)OOO1 CENHPXAQKISCGD-UHFFFAOYSA-N 0.000 description 1
• AUTOISGCBLBLBA-UHFFFAOYSA-N trizinc;diphosphite Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])[O-].[O-]P([O-])[O-] AUTOISGCBLBLBA-UHFFFAOYSA-N 0.000 description 1
• 150000003672 ureas Chemical class 0.000 description 1
• 229940070710 valerate Drugs 0.000 description 1
• NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
• 239000011709 vitamin E Substances 0.000 description 1
• 235000019165 vitamin E Nutrition 0.000 description 1
• 229940046009 vitamin E Drugs 0.000 description 1
• 239000001993 wax Substances 0.000 description 1
• 239000010456 wollastonite Substances 0.000 description 1
• 229910052882 wollastonite Inorganic materials 0.000 description 1
• AKJVMGQSGCSQBU-UHFFFAOYSA-N zinc azanidylidenezinc Chemical compound [Zn++].[N-]=[Zn].[N-]=[Zn] AKJVMGQSGCSQBU-UHFFFAOYSA-N 0.000 description 1
• LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
• 229910000165 zinc phosphate Inorganic materials 0.000 description 1
• XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
• 229910052984 zinc sulfide Inorganic materials 0.000 description 1
• DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
• BHTBHKFULNTCHQ-UHFFFAOYSA-H zinc;tin(4+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Sn+4] BHTBHKFULNTCHQ-UHFFFAOYSA-H 0.000 description 1
• 239000002076 α-tocopherol Substances 0.000 description 1
• 235000004835 α-tocopherol Nutrition 0.000 description 1
• 239000011590 β-tocopherol Substances 0.000 description 1
• 235000007680 β-tocopherol Nutrition 0.000 description 1
• 239000002478 γ-tocopherol Substances 0.000 description 1
• QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
• QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
• 239000002446 δ-tocopherol Substances 0.000 description 1