KR20190027850A - Salt bleaching composition - Google Patents

Abstract

The present invention provides a hair dye composition with reduced skin stickiness despite having sufficient dyeability to hair, wherein component A: basic blue 124, component B: basic color 31, basic red 51, basic red 76 , Basic yellow 87 and basic yellow 57, component C: HC blue 2, and component D: HC yellow 4 and HC yellow 2, and at least one dye selected from the group consisting of: . Wherein the content of the component A is 0.005 to 0.5 mass%, the content of the component B is 0.005 to 1.5 mass%, the content of the component C is 0.1 to 1.5 mass%, the content of the component D is 0.01 to 0.5 mass% .

Description

Salt bleaching composition

The present invention relates to a salt cake composition. The present application claims priority of Japanese Patent Application No. 2017-066453 filed on March 29, 2017, the contents of which are incorporated herein by reference.

Heretofore, as a treating agent for dyeing hair such as white hair dyeing or fashion dyeing, a first agent containing an alkali agent and a salt of an oxidizing salt and an oxidative dyeing agent comprising a second agent containing hydrogen peroxide are generally used. However, these oxidative hair dyeing agents exhibit an excellent dyeing effect and can be dyed with a desired hair color, while there is a drawback that damage to hair or scalp may occur. Further, since the medicines must be fixed on the hair at the time of the procedure and must be left for a long time, there is a drawback that not only a very long time is required in the case of performing the self-treatment but also irritation of the alkaline agent and skin irritation occur. In addition, there is a drawback that it is difficult to uniformly stain dyed stains depending on the procedure.

On the other hand, as a treatment agent having little damage to hair or scalp, a salt dye using a basic dye or an HC dye is known. Among the above-mentioned salts, color shampoo which can dye hair simultaneously with shampooing at the time of shaving, rinse after shaving, color rinse or color treatment which can dye hair at the same time as hair treatment is excellent in simplicity, And uniformity is also excellent (see Patent Document 1).

However, in the case of color shampoos, color rinses and color treatments, there is a drawback that the conventional salt waxes are highly adherent to the skin, that is, they are easily colored on the skin when attached to the skin. There is a problem that the fingertip or the scalp is colored because it is used without using gloves or the like at the time of trimming. In order to suppress the coloring, when the dye concentration in the salt base is lowered, the dyeability of the hair decreases. For this reason, it is a phenomenon that dyeability to hair is high and saltiness to skin is suppressed.

In recent years, there has been known a base composition containing a blue dye, Basic Blue 124 (Patent Documents 2 and 3). However, regarding the dyeability of the above-described salt fountain composition, it is a phenomenon that is not known at all.

Japanese Patent Application Laid-Open No. 2014-101292 Japanese Patent Application Laid-Open No. 2015-17108 Japanese Patent Application Laid-Open No. 2015-17109

SUMMARY OF THE INVENTION The present invention has been made in view of the above-described prior arts, and an object of the present invention is to provide a salt cake composition in which the dyeability to the skin is suppressed even though the skin has sufficient dyeability.

The inventors of the present invention have made intensive studies in order to achieve the above object and as a result, they have found that the composition of the present invention can be obtained from the group consisting of Component A: Basic Blue 124, Component B: Basic Color 31, Basic Red 51, Basic Red 76, Basic Yellow 87 and Basic Yellow 57 According to the salt emulsion composition containing at least one dye, at least one dye selected from the group consisting of Component C: HC Blue 2, Component D: HC Yellow 4 and HC Yellow 2, even though it has sufficient dyeability for hair, It has been found that a dye composition capable of inhibiting dyeing to the skin can be obtained. The present invention has been accomplished based on this finding.

That is, the present invention provides a salt base composition comprising the following component A, the following component B, the following component C and the following component D:

Component A: A dye represented by the following formula (1)

[Chemical Formula 1]

Component B: one or more dyes selected from the group consisting of basic or basic color 31, basic red 51, basic red 76, basic yellow 87 and basic yellow 57

Component C: HC Blue 2

Component D: at least one dye selected from the group consisting of HC Yellow 4 and HC Yellow 2.

The content of the component A is preferably 0.005 to 0.5% by mass, the content of the component B is preferably 0.005 to 1.5% by mass, the content of the component C is 0.1 to 1.5% by mass, Is preferably 0.01 to 0.5% by mass.

The salt flock composition preferably has a mass ratio of the content of the component B to the content of the component A [component B / component A] of 0.1 to 10.0, and a mass ratio of the content of the component D to the content of the component C [ The component D / the component C] is 0.005 to 1.0, and the mass ratio of the content of the component C to the content of the component A [component C / component A] is 1.5 to 70.0.

The content of HC Yellow 2 in 100 mass% of Component D is preferably 50.0 mass% or more.

It is preferable that the salt wipe composition is a color rinse or a color treatment.

It is preferable that the salt bleaching composition further contains the following component E.

Component E: at least one component selected from the group consisting of a cationic surfactant, a cationic polymer and a silicone oil.

The salt scarring composition of the present invention has dyeability to hair which is sufficiently excellent. Therefore, in the case of using as color shampoo, color rinse or color treatment, the hair dyeing effect can be sufficiently exhibited by a small number of times of use. In addition, even when used as hair nail polish, a sufficient dyeing effect can be obtained with a relatively short time of the procedure. Moreover, the salt scarring composition of the present invention has low dyeability to the skin, and the color of the fingers and the scalp when used is extremely small.

The salt scouring composition of the present invention is a composition used as a salt scourge. Examples of the salts include color rinses, color treatments, hair nail polish, and color shampoos. Among them, it is preferable that the salt scarring composition of the present invention is a color rinse or color treatment, or a color shampoo, from the viewpoint that the salt shampoo can be easily carried out and the treatment time per one time is short.

The salt scouring composition of the present invention comprises a dye represented by the formula (1) and at least one dye selected from the group consisting of basic or basic color 31, basic red 51, basic red 76, basic yellow 87 and basic yellow 57, At least one dye selected from the group consisting of blue 2, HC yellow 4 and HC yellow 2 at least. In the present specification, the "dye represented by formula (1)" may be referred to as "component A". The above-mentioned "at least one dye selected from the group consisting of basic color 31, basic red 51, basic red 76, basic yellow 87 and basic yellow 57" may be referred to as "component B". The above-mentioned " HC Blue 2 " may be referred to as " Component C ". Further, the "at least one dye selected from the group consisting of HC Yellow 4 and HC Yellow 2" may be referred to as "Component D".

The salt bleaching composition of the present invention comprises at least the component A, the component B, the component C and the component D. The salt scouring composition of the present invention may further contain components other than the above-mentioned components A to D, which are essential components, depending on the use. In particular, when the salt scouring composition of the present invention is a color rinse or color treatment, the salt scouring composition of the present invention may further comprise one or more components selected from the group consisting of a cationic surfactant, a cationic polymer and a silicone oil . In the present specification, the "at least one component selected from the group consisting of a cationic surfactant, a cationic polymer and a silicone oil" is occasionally referred to as "component E".

The salt scouring composition of the present invention may further contain components other than A to E (other components). The above components, for example, the component A, the component B, the component C, the component D, the component E and the other components may be used alone or two or more of them may be used.

Hereinafter, the components A to D which are essential components of the salt scouring composition of the present invention will be described.

[Component A: dye represented by formula (1)

Component A is a dye represented by the following formula (1). Component A, although highly dyed to hair, is extremely low in dyability to the skin. Therefore, by using the component A, it is possible to obtain a bleaching composition having both high dyeability on the hair and dentin resistance on the skin.

(2)

Component A is a compound designated INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Volume 1, 2014, p.329): BASIC BLUE 124 (Basic Blue 124) (Dimethylamino) -2-methoxyphenoxazin-5-ium chloride: 3-Amino-7- (dimethylamino) -2-methoxyphenoxazin-5-ium chloride.

Component A may be commercially available. As a commercially available product of the component A, for example, a trade name " Vibracolor Moonlight Blue "

The content of the component A in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 0.005 to 0.5 mass%, more preferably 0.01 to 0.2 mass%, further preferably 0.02 to 0.1 mass% to be. If the content is 0.005% by mass or more, the dyeing property to hair, particularly the effect of dyeing white hair, is improved. When the content is 0.5% by mass or less, the safety is further improved, which is preferable. In addition, it is preferable since the dye transferred to the water after rinsing is further prevented from transferring into the towel or clothes.

[Component B: at least one dye selected from the group consisting of basic color 31, basic red 51, basic red 76, basic yellow 87 and basic yellow 57]

Component B is at least one dye (at least one dye) selected from the group consisting of basic color 31, basic red 51, basic red 76, basic yellow 87 and basic yellow 57. Component B may be used alone or in combination of two or more.

Among them, it is preferable to adjust the color of the component B to be the color of the equisimple system by combining these dyes. Concretely, a combination of an isochromatic monochromatic color and a combination of yellow and red colors is preferable. That is, as for component B, the basic color 31, the combination of basic red 51 and basic yellow 87, the combination of basic red 51 and basic yellow 57, the combination of basic red 76 and basic yellow 87, or the combination of basic red 76 and basic yellow 57 Combinations are preferred. More preferably, it is a combination of Basic Orange 31, Basic Red 51 and Basic Yellow 87, or Basic Red 76 and Basic Yellow 57. Among them, the component B is particularly preferably a combination of basic orange color 31, basic red color 51 and basic yellow color 87. By combining the component B prepared with the colorimetric system and the blue component A, it is possible to form a gray color (coloring) in a salt fountain composition by combining only a cationic dye. The component C and the component D to be described later are both nonionic dyes and can be colored in gray by a combination thereof. Thus, as described later, the salt scouring composition of the present invention uses a cationic dye and a non-ionic dye, and each color is gray, so that the dyeability in a short time, the color persistence, the discoloration It is preferable because color irregularities such as suppression and bleeding-treated hair can be further improved.

The basic equilibrium 31 is a compound represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Volume 1, 2014, p.331-332) BASIC ORANGE 31 (basic orange 31) [(4-aminophenyl) azo] -1,3-dimethyl-1H-imidazolium chloride.

The basic red 51 is a compound represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.333) BASIC RED 51 (Basic Red 51) - (dimethylamino-phenylazo) 1,3-dimethyl-1,3-dimethyl-3H-imidazol-1-yuch chloride: 2- (4- (Dimethylamino- -dimethyl-3H-imidazol-1-ium chloride. The basic red 51 is 2 - [((4-dimethylamino) phenyl) azo] -1,3-dimethyl-1H-imidazolium chloride: 2- [((4-Dimethylamino) phenyl) azo] -1,3-dimethyl-1H-imidazolium chloride.

The basic red 76 is a compound represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.333-334) BASIC RED 76 (Basic Red 76) N, N, N-trimethyl-2-naphthalenaminium chloride: 7-Hydroxy-8 - [(2-methoxyphenyl) azo] -trimethyl-2-naphthalenaminium chloride. The basic red 76 was prepared in the same manner as in [7-hydroxy-8 - [(2-methoxyphenyl) azo] -2-naphthyl] -trimethylammonium chloride: [7-Hydroxy- ] -2-naphthyl] -trimethylammonium chloride.

The basic yellow 87 is a compound represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.337-338): BASIC YELLOW 87 (Basic Yellow 87) Methyl-4 - [(methylphenylhydrazono) methyl] -, methylsulfate: Pyridinium, 1-methyl-4 - [(methylphenylhydrazono) methyl] -, methyl sulfate. The basic yellow 87 is also referred to as 1-methyl-4 - [(methylphenylhydrazano) methyl] pyridinium methylsulfate: 1-Methyl-4 - [(methylphenylhydrazono) methyl] pyridinium methylsulfate.

The basic yellow 57 is a compound represented by BASIC YELLOW 57 (BASIC YELLOW 57), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.337) N, N, N-trimethyl-, chloride: Benzenaminium, 3, 4-dihydro- - [(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H- pyrazol-4- yl) azo] -N, N, N-trimethyl- chloride. The basic yellow 57 is a mixture of 5-hydroxy-3-methyl-1-phenyl-4- (3'-trimethylammoniophenyl azo) 3'-trimethylammoniophenylazo) -pyrazol.

Component B may be a commercially available product. A commercially available product of the basic color 31 is, for example, a trade name "Vibracolor Flame Orange" manufactured by BASF. Commercially available products of the basic red 51 include, for example, "Vibracolor Ruby Red", trade name, manufactured by BASF. As a commercial product of the basic red 76, for example, trade name "ARIANOR MADDER RED" manufactured by Sensient Technologies Japan Ltd. may be mentioned. A commercially available product of Basic Yellow 87 is, for example, a trade name "Vibracolor Citrus Yellow" manufactured by BASF. As a commercially available product of basic yellow 57, for example, trade name "ARIANOR STRAW YELLOW" manufactured by Sensient Technologies Japan Ltd. may be mentioned.

The content of the component B in 100% by mass of the salt fountain composition of the present invention is not particularly limited, but is preferably 0.005 to 1.5% by mass, and more preferably 0.01 to 1.0% by mass. When the content is 0.005% by mass or more, it is preferable that the dyeing property to hair, especially the effect of dyeing white hair, is further improved. When the content is 1.5% by mass or less, the safety is further improved, which is preferable. Further, it is preferable to further reduce the transfer of the dye to the towel and clothes, which are dissolved in the water after washing. The content of the component B is the total amount of all the component B in the salt scarce composition of the present invention.

The content of the basic color is 31 is not particularly limited, but is preferably 0.005 to 0.5% by mass, and more preferably 0.01 to 0.2% by mass in 100% by mass of the salt base composition of the present invention. The content of the basic red 51 in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 0.005 to 0.5 mass%, and more preferably 0.01 to 0.2 mass%. The content of the basic red 76 in 100% by mass of the salt base composition of the present invention is not particularly limited, but is preferably 0.01 to 1.5% by mass, and more preferably 0.05 to 1.0% by mass. The content of the basic yellow 87 in 100% by mass of the salt base composition of the present invention is not particularly limited, but is preferably 0.005 to 0.5% by mass, and more preferably 0.01 to 0.2% by mass. The content of the basic yellow 57 in 100 mass% of the salt base composition of the present invention is not particularly limited, but is preferably from 0.01 to 1.5 mass%, and more preferably from 0.05 to 1.0 mass%.

The content of component B in the 100% by mass of the salt base composition of the present invention is preferably 0.005 to 0.5% by mass (particularly, 0.01 to 0.2% by mass) . Component B is composed of basic red 51 and basic yellow 87 only. The content of basic red 51 in 100% by mass of the composition of the present invention is 0.005 to 0.5% by mass (particularly 0.01 to 0.2% by mass) And the content of yellow 87 is preferably 0.005 to 0.5 mass% (particularly 0.01 to 0.2 mass%). Component B is composed of basic red 76 and basic yellow 57 only. The content of basic red 76 in 100% by mass of the composition of the present invention is 0.01 to 1.5% by mass (particularly 0.05 to 1.0% by mass) The content of yellow 57 is preferably 0.01 to 1.5% by mass (particularly 0.05 to 1.0% by mass).

[Component C: HC Blue 2]

Component C is HC Blue 2. The HC Blue 2 is a compound represented by the name INCI (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.1447): HC BLUE NO.2, and 2,2 '- [ 4 - [(2-Hydroxyethyl) amino] -3-nitrophenyl] imino] bisethanol .

Component C may be a commercially available product. As a commercially available product of component C, for example, trade name " COLOREX HCB2 "

The content of the component C in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 0.1 to 1.5 mass%, more preferably 0.2 to 1.5 mass%, and still more preferably 0.5 to 1.0 mass% . If the content is 0.1% by mass or more, it is preferable because the fastness (fastness) is further improved. When the content is 1.5% by mass or less, the safety is further improved, which is preferable. Further, it is preferable to further reduce the transfer of the dye to the towel and clothes, which are dissolved in the water after washing.

[Component D: at least one dye selected from the group consisting of HC yellow 4 and HC yellow 2]

Component D is at least one dye (at least one dye) selected from the group consisting of HC Yellow 4 and HC Yellow 2, i.e. HC Yellow 4 and / or HC Yellow 2. The HC Yellow 4 is a compound represented by the name INCI (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Vol. 1, p. 2014, p.1455): HC YELLOW NO. 4, 2-hydroxyethoxy) -4-nitrophenyl] amino] ethanol: 2 - [[2- (2-Hydroxyethoxy) -4-nitrophenyl] amino] ethanol. HC Yellow 2 is a compound represented by the name of INCI (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Vol. 1, p. 2014, p.1455): HC YELLOW NO.2, Phenyl) amino] ethanol: 2 - [(2-Nitrophenyl) amino] ethanol. Only one kind of the component D may be used, or two or more kinds of the component D may be used.

Component D may be commercially available. Commercially available products of HC Yellow 4 include, for example, trade name "COLOREX HCY4" manufactured by Teruka Corporation. Commercially available products of HC Yellow 2 include, for example, trade name "COLOREX HCY2" manufactured by Teruka Corporation.

The content of the component D in 100 mass% of the salt scouring composition of the present invention is not particularly limited, but is preferably 0.01 to 0.5 mass%, more preferably 0.01 to 0.2 mass%, and still more preferably 0.02 to 0.1 mass% . When the content is 0.01 mass% or more, it is preferable because the fastness is further improved. When the content is 0.5% by mass or less, the safety is further improved, which is preferable. Further, it is preferable to further reduce the transfer of the dye to the towel and clothes, which are dissolved in the water after washing. The content of the component D is the total amount of all the component D in the salt scouring composition of the present invention.

As component D, HC yellow 2 is more preferable from the viewpoint of further excellent light resistance (light stability). That is, the component D preferably contains HC yellow 2 as an essential component, more preferably HC yellow 2. The content of HC Yellow 2 in 100 mass% of Component D is preferably 50.0 mass% or more (that is, 50.0 to 100 mass%), more preferably 70.0 mass% or more, and further preferably 90.0 mass% or more. And the component D is most preferably composed of only HC yellow 2. It is preferable that the component D contains HC yellow 2 as an essential component because yellow discoloration is further suppressed. Particularly, in the case of a salt cake prepared by coloring a gray prepared by using a yellow dye, the use of HC yellow 2 in the above range is effective because the color tone of the entire salt cake tends to change due to discoloration of the yellow component Do.

In the salt fountain composition of the present invention, both the component A and the component B are cationic dyes, and are gray-colored with a combination of only the cationic dyes. The components C and D are both nonionic dyes, and gray color is obtained by combining only nonionic dyes. Therefore, in the salt dye composition of the present invention, each combination of the combination of only the cationic dye and the nonionic dye alone is gray. Cationic dyes have a fast dyeing rate and are excellent in fastness, but they are easy to adsorb on damage sites or damage sites, and have a characteristic that dyeing unevenness easily occurs. On the other hand, nonionic dyes have characteristics that they are uniformly adsorbed regardless of the presence or absence of damage although the dyeing rate is relatively slow. For this reason, when the cationic dye and the nonionic dye are different in color tone, color unevenness tends to occur due to the difference in degree of damage caused by the standing time and the site. In the present invention, as described above, cationic dyes and non-ionic dyes are used, and since they are colored in gray, they are excellent in dyeability in a short period of time, color persistence, discoloration inhibition at the extension of the settling time, The color irregularities of the damage of the first lens group can be further improved.

In the salt bleaching composition of the present invention, the mass ratio of the content of the component B to the content of the component A (component B / component A) is not particularly limited, but is preferably 0.1 to 10.0, 8.0. By setting the mass ratio within the above range, it is possible to dye the gray hair in a more natural color tone. When the mass ratio is less than 0.1, the color tone of the hair becomes blue, and when the mass ratio is more than 10.0, the color tone of the hair becomes red, and in particular, an unnatural color tone may be obtained in white hair dyeing.

The mass ratio [component D / component C] of the content of the component D to the content of the component C in the salt scouring composition of the present invention is not particularly limited, but is preferably 0.005 to 1.0, more preferably 0.01 to 1.0, 0.5. By setting the mass ratio within the above range, it is possible to dye the gray hair in a more natural color tone. When the mass ratio is less than 0.005, the color tone of the hair becomes purple, and when the mass ratio is more than 1.0, the color tone of the hair becomes yellow, and in particular, an unnatural color tone may be obtained in white hair dyeing.

The mass ratio [component C / component A] of the content of component C to the content of component A in the salt scarce composition of the present invention is not particularly limited, but is preferably 1.5 to 70.0, 60.0. When the mass ratio is 1.5 or more, the dyeing speed can be appropriately adjusted, and color unevenness of the damage caused by the bleached mother is hard to occur. On the other hand, if the mass ratio is 70.0 or less, dyeability and color persistence are preferable.

Hereinafter, desirable optional ingredients in the case where the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish will be described.

[Component E: at least one component selected from the group consisting of a cationic surfactant, a cationic polymer and a silicone oil]

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention preferably contains the component E. Component E is at least one component (at least one component) selected from the group consisting of a cationic surfactant, a cationic polymer and a silicone oil. The inclusion of the component E is preferable because the effect of reducing the feeling of discoloration during flushing by the salt fountain composition improves. The component E may be used alone or two or more thereof may be used.

Examples of the cationic surfactant (cationic surfactant) include monoalkyl type quaternary ammonium salts, dialkyl type quaternary ammonium salts, trialkyl type quaternary ammonium salts, monoalkyl ether type quaternary ammonium salts, alkylamines, And doamin.

Examples of the monoalkyl type quaternary ammonium salt include lauryltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) chloride, Trimethylammonium chloride, alkyl (20-22) trimethylammonium chloride, stearyldimethylbenzylammonium chloride, myristyldimethylbenzylammonium chloride, tri (polyoxyethylene) stearylammonium chloride, di (polyoxyethylene) oleylmethylammonium chloride .

Examples of the fatty acid amidoamine include myristic acid dimethylaminoethylamide, myristic acid dimethylaminopropylamide, diethylaminoethyl myristate, diethylaminopropylamide myristate, dimethylaminoethyl palmitate Amide, dimethylaminopropylamide of palmitic acid, diethylaminoethylamide of palmitic acid, diethylaminopropylamide of palmitic acid, dimethylaminoethylamide of stearic acid, dimethylaminopropylamide of stearic acid, diethylaminoethylamide of stearic acid, diethylaminopropylamide of stearic acid, Propylaminoethylamide, dipropylaminopropylamide stearate, dimethylaminoethylamide of behenic acid, dimethylaminopropylamide of behenic acid, diethylaminoethylamide of behenic acid, and diethylaminopropylamide of behenic acid. The.

The fatty acid amidoamine is preferably used as a salt with an organic acid and / or an inorganic acid. Examples of the organic acid include lactic acid, malic acid, citric acid, tartaric acid, acetic acid and the like. Examples of the inorganic acid include phosphoric acid, hydrochloric acid, and sulfuric acid. Above all, lactic acid is preferable. The content of the organic acid and the inorganic acid is not particularly limited as long as it is an amount capable of neutralizing the fatty acid amidoamine to be incorporated.

As the cationic surfactant, monoalkyl type quaternary ammonium salts and fatty acid amidoamines are preferable among them, more preferred are stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) Trimethylammonium chloride, alkyl (20-22) trimethylammonium chloride, and dimethylaminopropylamide stearate.

Examples of the cationic polymer (cationic polymer) include quaternary nitrogen-containing cellulose ether derivatives such as chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose; Quaternary nitrogen-containing guar gum derivatives such as O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum chloride; A cationic starch, a diallyl quaternary ammonium salt polymer, a diallyl quaternary ammonium salt / acrylamide copolymer, a quaternized polyvinylpyrrolidone derivative, a polyglycol polyamine condensate, adipic acid · dimethylaminohydroxypropylethylenetriene Amine copolymers, and cationized dextran. Of these, preferred are chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, diallyl quaternary ammonium salt polymer and diallyl quaternary ammonium salt / acrylamide copolymer, Preferably, it is poly (methylmethylene) piperidinium chloride.

Examples of the silicon flow path include methyl polysiloxane, high polymerized methylpolysiloxane having an average degree of polymerization of 650 to 7000, methylphenyl polysiloxane, methylhydrogen polysiloxane, dimethiconol and other chain silicon; Cyclic silicones such as methylcyclopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane; Amino-modified silicones such as aminopropylmethylsiloxane-dimethylsiloxane copolymer, aminoethylaminopropylsiloxane-dimethylsiloxane copolymer, aminoethylaminopropylmethylsiloxane-dimethylsiloxane copolymer, carboxy-modified silicone, fatty acid-modified silicone, alcohol- Modified silicone such as aliphatic alcohol-modified silicone, epoxy-modified silicone, fluorine-modified silicone, and alkyl-modified silicone. Of these, chain-like silicone and amino-modified silicone are preferred.

When the salt scouring composition of the present invention comprises the component E, the content of the component E in 100% by mass of the salt scouring composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0% by mass, 5.0% by mass. When the content is 0.5% by mass or more, the feeling of discoloring at the time of flushing is further reduced, which is preferable. When the content is more than 10.0% by mass, the component E is accumulated in the hair by continuous use, and stiffness may occur in the hair. The content of the component E is the total amount of all the components E in the salt scouring composition of the present invention.

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention preferably contains a polyhydric alcohol. Examples of the polyhydric alcohol include polyhydric alcohols such as ethylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1,3-butylene glycol, glycerin, concentrated glycerin, diglycerin, triglycerin, glucose, maltose, maltitol, sucrose, Mannitol, sorbitol, 1,2-pentanediol, 1,2-hexanediol, and 1,2-octanediol. When the salt scouring composition of the present invention contains a polyhydric alcohol, the content of the polyhydric alcohol in 100% by mass of the salt scouring composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0% by mass from the viewpoint of solubility of the dye , And more preferably 1.0 to 5.0 mass%. The content of the polyhydric alcohol is the total amount of all the polyhydric alcohols in the salt fountain composition of the present invention.

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention preferably contains a higher alcohol. Examples of the higher alcohols include alcohols having from 16 to 22 carbon atoms such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, oleyl alcohol, behenyl alcohol and the like. . When the salt scouring composition of the present invention contains a higher alcohol, the content of the higher alcohol in 100 mass% of the salt scouring composition of the present invention is not particularly limited, but is preferably 1.0 to 10.0 By mass, more preferably from 3.0 to 8.0% by mass. The content of the higher alcohol is the total amount of the contents of all the higher alcohols in the salt fountain composition of the present invention.

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention preferably contains hydrocarbon oil. The hydrocarbon flow path may be, for example, an? -Olefin oligomer, a light isoparaffin, a light flowing isoparaffin, a squalane, a synthetic squalane, a vegetable squalane, a flowing isoparaffin or a liquid paraffin. When the salt scavenging composition of the present invention contains hydrocarbon oil, the content of the hydrocarbon oil in 100 mass% of the salt scavenger composition of the present invention is not particularly limited, but from the viewpoint of the ease of absorption of the salt scavenger composition at the time of application, By mass, more preferably 1.0 to 5.0% by mass. The content of the hydrocarbon oil is the total amount of the contents of all the hydrocarbon oils in the flame-retardant composition of the present invention.

The salt scouring composition of the present invention may contain an ester compound having a carbon number of 12 or less in the fatty acid moiety from the viewpoint of further improving hair dyeability. Examples of the ester compound include caprylic acid esters such as capric acid glyceryl, caprylic acid esters, cetyl 2-ethylhexanoate, isononyl isononanoate, and the like. When the salt scouring composition of the present invention contains the ester compound, the content of the ester compound in 100% by mass of the salt scouring composition of the present invention is not particularly limited, but is preferably 0.5 to 5.0% by mass from the viewpoint of dyeability , And more preferably 1.0 to 3.0 mass%. The content of the ester compound is the total amount of the content of all the ester compounds in the salt scarce composition of the present invention.

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention contains a nonionic surfactant (nonionic surfactant) from the viewpoint of stability over time . Examples of the nonionic surfactant include polyoxyethylene fatty acids, glycerin fatty acid esters, polyoxyethylene glycerin fatty acid esters, polyglycerin fatty acid esters, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, Polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyglycerin alkyl ether, polyoxyethylene (hardened) castor oil, fatty acid alkylolamide and the like. When the salt fountain composition of the present invention contains a nonionic surfactant, the content of the nonionic surfactant in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0 By mass, more preferably 1.0 to 5.0% by mass. The content of the nonionic surfactant is the total amount of the contents of all the nonionic surfactants in the salt fountain composition of the present invention.

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention comprises water. Water is not particularly limited, but purified water is preferable. The content of water in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 50.0 to 90.0 mass%, and more preferably 60.0 to 80.0 mass%.

When the salt whitening composition of the present invention is any of color rinse, color treatment and hair nail polish, the salt whitening composition of the present invention may contain a refreshing agent such as l-menthol, 1,8-cineol and camphor; Preservatives such as phenoxyethanol; Vegetable oils such as olive oil, macadamia nut oil and argan oil; A hygroscopic agent such as silica; An antioxidant, a metal blocker, a vitamin, an extract of plant and animal extract, a pearlizing agent, a coloring agent, a flavoring agent, and the like.

Hereinafter, preferable components in the case where the salt scent composition of the present invention is a color shampoo will be described.

When the salt whitening composition of the present invention is a color shampoo, the salt whitening composition of the present invention is an anionic surfactant (anionic surfactant), a cationic surfactant, a nonionic surfactant and a cationic surfactant And at least one surfactant (at least one surfactant) selected from the group consisting of surfactants. Above all, nonionic surfactants and / or amphoteric surfactants are preferable from the viewpoint of improving cleaning property while maintaining dyeability. The content of the surfactant in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 1.0 to 20.0 mass%, and more preferably 5.0 to 15.0 mass% from the viewpoint of dyeability and cleanability. The content of the surfactant is the total amount of the content of all the surfactants in the salt scouring composition of the present invention.

Examples of the anionic surfactant include alkyl sulfuric acid ester salts such as sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium myristyl sulfate, sodium stearyl sulfate, sodium oleyl sulfate, and sodium cetyl sulfate; Polyoxyethylene alkyl ether sulfate such as sodium polyoxyethylene lauryl ether sulfate and polyoxyethylene myristyl ether sodium sulfate; Alpha -olefin sulfonic acid salts such as sodium tetradecenesulfonate; N-acylmethyltaurine salts such as myristoylmethyltaurine sodium, palmitoylmethyltaurin sodium, stearoylmethyltaurin sodium, oleoylmethyltaurin sodium and coconut oil fatty acid methyltaurin sodium; Sulfo succinic acid alkyl salts such as sodium dioctyl sulfo succinate and disodium lauryl sulfosuccinate; Sulfo succinic acid polyoxyethylene alkyl salts such as disodium polyoxyethylene lauryl sulfo succinate; Monoalkyl phosphoric acid ester salts such as sodium lauryl phosphate, sodium cetyl phosphate and diethanolamine cetyl phosphate; Polyoxyethylene alkyl ethers such as sodium polyoxyethylene lauryl ether phosphate, sodium polyoxyethylene cetyl ether phosphate, sodium polyoxyethylene oleyl ether phosphate, sodium polyoxyethylene alkylphenyl ether phosphate, and polyoxyethylene alkylphenyl ether phosphate triethanolamine Ether phosphate ester salts; N-acyl sarcosinate salts such as lauroyl sarcosine potassium, lauroyl sarcosinate ethanolamine, myristoyl sarcosine sodium and coconut oil fatty acid sarcosine sodium; N-acyl-N-methyl-? - alanine salts such as lauroylmethylalanine sodium, lauroylmethylalanine triethanolamine, myristoylmethylalanine sodium and palm oil fatty acid methylalanine sodium; Sodium lauryl glutamate, triethanolamine lauroyl glutamate, sodium myristoyl glutamate, potassium stearoyl glutamate, disodium stearoyl glutamate, sodium coconut fatty acid acyl glutamate, and coconut fatty acid acyl glutamic acid triethanol amine. salt; N-acyl glycine salts such as coconut fatty acid acylglycine potassium and coconut fatty acid acylglycine sodium; Sodium lauryl glycolate, sodium lauryl glycolate (sodium dodecane-1,2-diol acetate), potassium lauryl glycol acetate, sodium myristyl glycol acetate, potassium myristyl glycol acetate, sodium palmityl glycol sodium acetate, Alkyl ether glycol acetates such as sodium glycolate, sodium glycolate, potassium stearyl glycol acetate, sodium behenyl glycolate and behenyl glycol glycol acetate. Among them, anionic surfactants derived from amino acids such as N-acyl-N-methyl-β-alanine salts and N-acylglutamate are preferred from the viewpoint of dyeability. When the salt scouring composition of the present invention contains an anionic surfactant, the content of the anionic surfactant in 100 mass% of the salt scouring composition of the present invention is not particularly limited, but from 0.5 to 5.0 mass% %, More preferably 0.5 to 2.0% by mass. The content of the anionic surfactant is the total amount of the content of all the anionic surfactants in the salt scouring composition of the present invention.

Examples of the amphoteric surfactant include alkylamidobetaine type amphoteric surfactants such as lauric acid amidopropyl betaine and palm oil fatty acid amidopropyl betaine; Glycine-type amphoteric surfactants such as alkyl glycine salts, carboxymethyl glycine salts and N-acylaminoethyl-N-2-hydroxyethyl glycine salts; Aminopropionic acid-type amphoteric surfactants such as alkylaminopropionic acid salts and alkyliminodipropionic acid salts; Aminoacetic acid betaine type amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, alkylamidopropyldimethylaminoacetic acid betaine and alkyldihydroxyethylaminoacetic acid betaine; Alkyl-N, N-dimethylammonium-N- (2-hydroxypropyl) sulfonate and N-fatty acid amidopropyl-N, N - sulfobetaine-type amphoteric surfactants such as dimethylammonium-N- (2-hydroxypropyl) sulfonate, and alkylhydroxysulfobetaine; Imidazolinium-type amphoteric surfactants such as alkylcarboxymethylhydroxyethylimidazolinium betaine, and the like. Among them, alkylamido betaine-type amphoteric surfactants are preferable from the viewpoint of cleaning ability. When the salt scouring composition of the present invention contains an amphoteric surfactant, the content of the amphoteric surfactant in 100 mass% of the salt scouring composition of the present invention is not particularly limited, but is preferably 1.0 to 20.0 mass% , And more preferably 5.0 to 15.0 mass%. The content of the amphoteric surfactant is the total amount of all the amphoteric surfactant in the salt fountain composition of the present invention.

Examples of the nonionic surfactant include nonionic surfactants exemplified as optional components in the case where the salt scouring composition of the present invention is any of color rinses, color treatments and hair nail polishes. Of these, fatty acid alkylol amides are preferred from the viewpoint of viscosity application. When the salt fountain composition of the present invention contains a nonionic surfactant, the content of the nonionic surfactant in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 0.5 to 10.0 mass% By mass, and more preferably 1.0 to 5.0% by mass. The content of the nonionic surfactant is the total amount of the contents of all the nonionic surfactants in the salt fountain composition of the present invention.

Examples of the cationic surfactant include the cationic surfactant exemplified as the component E. Among them, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, alkyl (16,18) trimethylammonium chloride and alkyl (20-22) trimethylammonium chloride are preferable from the viewpoint of improving the feeling of hair after use. When the salt scarcer composition of the present invention contains a cationic surfactant, the content of the cationic surfactant in 100 mass% of the salt scouring composition of the present invention is not particularly limited, but from the viewpoint of texture of the hair after use, 5.0 mass%, and more preferably 0.5 mass% to 3.0 mass%. The content of the cationic surfactant is the total amount of the content of all the cationic surfactants in the salt scouring composition of the present invention.

When the salt-fading composition of the present invention is a color shampoo, the salt-fading composition of the present invention comprises water. Water is not particularly limited, but purified water is preferable. The content of water in 100 mass% of the salt fountain composition of the present invention is not particularly limited, but is preferably 50.0 to 90.0 mass%, and more preferably 60.0 to 80.0 mass%.

When the salt scouring composition of the present invention is a color shampoo, the salt scent composition of the present invention may contain a refreshing agent such as l-menthol, 1,8-cineole, camphor; Preservatives such as phenoxyethanol; Vegetable oils such as olive oil, macadamia nut oil and argan oil; A hygroscopic agent such as silica; An antioxidant, a metal blocker, a vitamin, an extract of plant and animal extract, a pearlizing agent, a coloring agent, a flavoring agent, and the like.

Hereinafter, the characteristics and manufacturing method of the salt scouring composition of the present invention will be described.

The method for producing the salt scouring composition of the present invention is not particularly limited and can be produced by a conventional method. Specifically, the following methods and the like can be mentioned. For example, in the case of color rinses or color treatments, an oil phase heated to 70 to 90 占 폚 is slowly added to an aqueous phase which is sufficiently dissolved by heating at 70 to 90 占 폚, Followed by stirring and emulsification. After emulsification, the mixture is cooled to 20 to 40 캜, and a dye dissolved in purified water is added thereto. The mixture is homogeneously stirred sufficiently, and then a pH adjusting agent is added thereto and sufficiently uniformly stirred to obtain a creamy salt composition. In the case of color shampoo, various surfactants are slowly added to the aqueous phase in which the dye has been sufficiently dissolved at room temperature, and the mixture is stirred. A stabilizer and a pH adjuster are added thereto and sufficiently uniformly stirred to obtain a viscous liquid salt composition.

The pH of the salt scouring composition of the present invention is not particularly limited, but is preferably 4.0 to 8.0, more preferably 5.0 to 8.0 from the viewpoint of dyeability. Further, from the viewpoint of stability of the salt bleaching composition, the pH is preferably 6.5 or less. In particular, when the salt wipe composition of the present invention is color rinse, color treatment or hair nail polish, the pH is preferably 4.0 to 6.5, and in the case of color shampoo, the pH is preferably 5.0 to 6.5.

The formulation of the salt wool scum composition of the present invention is not particularly limited, and examples thereof include liquid, viscous liquid, gel, oil, cream and the like. Among them, a cream phase is preferable from the viewpoint of dyeability and feeling.

The hair dye composition of the present invention can dye hair with gray, black, brown, green, bluish purple, and the like. More preferably, it is gray, black and brown, and more preferably gray. For this reason, it can be used as a bleaching composition such as white hair dyeing and fashion dyeing, and is preferably a bleaching dye composition for white hair dyeing in terms of color tone.

It is preferable that the salt wipe composition of the present invention is a color rinse or color treatment, a hair manicure, or a color shampoo.

The color shampoo is a detergent for hair used for hair removal, and hair can be stained simultaneously with hair removal. The color shampoo is used as a method of using a method of applying hair to hair, foaming hair to clean the hair, and washing the hair after washing.

The color rinses and color treatments are generally used for curing, and are hair treatment agents used after being applied to hair after curing and then washed. The color rinses and color treatments can be used by washing the hair with a shampoo, applying a color rinse or color treatment to the hair, absorbing the hair immediately after application or for 3 to 10 minutes, and then washing the hair . In addition, the color rinses and color treatments may be used before trimming. In such a case, the color rinses and color treatments may be prepared by applying color rinses or color treatments to wet hair, washing them immediately after application or after they have been absorbed into the hair for 3 to 10 minutes, It is used as a method of use.

The hair manicure is generally a hair treatment agent applied to dry hair. The hair nail polish is used, for example, as a method of applying hair nail polish to dry hair, allowing it to stand for about 5 to 30 minutes after application, washing it, and further shaving it with shampoo.

Example

Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples. The compounding amount shown in the table is the compounding amount of each component (that is, the blending amount of the active ingredient in each raw material, so-called pure component) and is expressed as "% by mass" unless otherwise specified. However, the amount of the dimethylpolysiloxane diphenylmethylpiperidinium liquid and the aminoethylaminopropylaminosiloxane-dimethylsiloxane copolymer emulsion in the table is expressed by the blend amount of the product itself.

Examples 1-1 to 1-22, Comparative Examples 1-1 to 1-9: Color rinses (or color treatments)

According to the compositions shown in Tables 1 and 2, each salt-fired composition was prepared and provided in the evaluation tests of the following Tests 1 to 6. Each of the salt-fading compositions is a color rinse (or color treatment). The evaluation results are stipulated in the table.

Examples 2-1 to 2-3: Color shampoo

According to the composition shown in Table 3, each salt-fading composition was prepared and provided in the evaluation tests of the following Tests 1 to 6. Each of the salt-fading compositions is a color shampoo. The evaluation results are stipulated in the table.

The pH of each salt-fading composition of the examples and comparative examples was measured using a pH meter (trade name: Tabletop type pH meter F-74, manufactured by Horiba Seisakusho Co., Ltd.).

[Test 1: Evaluation of dyeability]

As a test hair bundle, an untreated white hair mother liquor (manufactured by Showa Kagaku Bulex, length 10 cm, weight 1 g) was used.

(Preparation for evaluation: for color rinse)

The test hair was washed with a commercially available shampoo, and the hair was removed lightly and used in the following preparation. 0.5 g of each of the salt fountain compositions obtained in Examples and Comparative Examples immediately after the preparation was applied to the test hair, and the hair fescue was absorbed into the entire hair (hair) using a brush for 1 minute. Then, after leaving for 5 minutes, the salt fountain composition was thoroughly washed away from the mother liquor using lukewarm water at 40 占 폚, towel-dried, and sufficiently dried by using a dryer to prepare a mother liquor for evaluation.

(Preparation for evaluation: for color shampoo)

After thoroughly washing the test mother liquor with lukewarm water at 40 캜, it was used in the following preparation. 0.2 g each of the salt flakes composition obtained in Examples and Comparative Examples just after the preparation was applied to the test hair, and the floss was hand-bubbled for 1 minute to absorb. Then, after leaving for 5 minutes, the salt fountain composition was thoroughly washed away from the mother liquor using lukewarm water at 40 占 폚, towel-dried, and sufficiently dried by using a dryer to prepare a mother liquor for evaluation.

The dye for evaluation obtained above was observed, and the dyeability was evaluated according to the following criteria. The evaluation of the dyeability was carried out by four professional evaluators.

<Evaluation Criteria of Dyeability>

◎ (excellent): Very dyed.

(Good): It is sufficiently dyed.

× (poor): Dyeing is light.

In addition, the color tone of the evaluation hair obtained in Test 1 is shown in the table.

[Test 2: Evaluation of dirt (durability)] [

0.5 g each of the salt fountain compositions obtained in the Examples immediately after the preparation and the Comparative Examples were applied to a circular area having a diameter of 1 cm in the inside of the forearm. After allowing to stand for 5 minutes, the coated portion was rinsed with lukewarm water, then rubbed lightly with soap for 30 seconds, and rinsed with lukewarm water.

The coated portion was observed and evaluated according to the following criteria. In addition, the evaluation of skin dirt was carried out by four professional evaluators.

<Evaluation Criteria of Skin Dirt>

◎ (excellent): No dirt remains on the skin.

○ (Good): Some dirt remains on the skin.

× (poor): The dirt remains clearly.

[Test 3: Evaluation of fastness property]

After evaluation of test 1 (evaluation of dyeability), each evaluation blast was thoroughly washed with lukewarm water at 40 DEG C, and then cleaned with a commercially available shampoo for one minute. Furthermore, washing was sufficiently performed with lukewarm water at 40 DEG C, and after the towel was dried, it was sufficiently dried using a dryer.

The evaluation hatching obtained above was observed, and fastness was evaluated based on the following criteria. In addition, the evaluation of fastness was made by four professional evaluators.

<Evaluation Criteria of Fastness>

○ (Good): The degree of color deviation of the hair after the test is small.

× (poor): The degree of color deviation of the hair after the test is great.

[Test 4: Evaluation of discoloration inhibition at extended standing time]

A parent hair for evaluation was prepared in the same manner as in Test 1 except that the preparation of the parent hair for evaluation of Test 1 (evaluation of dyeability) was changed from "left for 5 minutes" to "left for 30 minutes".

For each example and each comparative example, the degree of discoloration inhibition at the extension of the standing time was evaluated based on the following criteria in comparison with the dyed hue of the evaluation hood prepared in Test 4 and the evaluation hood prepared in Test 1. The evaluation was carried out by four professional evaluators.

&Lt; Evaluation Criteria of Suppression of Discoloration at Extended Time of Standing &gt;

(Good): The color tone of the evaluation color tone prepared in Test 4 was not changed from the color tone of the evaluation color tone prepared in Test 1.

× (poor): The color tone of the test pattern prepared in Test 4 varies from the color tone of the test pattern prepared in Test 1.

[Table 1]

[Table 2]

[Table 3]

[Test 5: evaluation of light resistance]

After evaluation of test 1 (evaluation of dyeability), each of the evaluation patterns was subjected to a fastness test using a steel fast xenon fade meter (manufactured by Suga Kenshi Kogyo K.K., trade name &quot; xenon weather meter X-25 &quot;) at 6300 kJ / M &lt; 2 &gt;.

The mother lambs for evaluation obtained above were observed, and the light resistance was evaluated according to the following criteria. In addition, the evaluation of light fastness was carried out by four professional evaluators.

[Evaluation Criteria of Light Resistance]

(Good): The hue of the model prepared in Test 5 has little or no change from the hue of the model prepared in Test 1.

△ (Slightly defective): The shade of the shade prepared in Test 5 clearly varies from the shade of shade prepared in Test 1.

× (poor): The color tone of the evaluation sample prepared in Test 5 has a great change from the color tone of the evaluation sample prepared in Test 1.

As a result of Test 5 (evaluation of light resistance), Example 1-19 had slightly poor light resistance (?), And Example 1-12 and Comparative Example 1-9 had poor light resistance (X). In other Examples and Comparative Examples, the light resistance was good (O).

[Test 6: Evaluation of color unevenness against damage moth]

In the preparation of the hair dye for evaluation of Test 1 (evaluation of dyeability), "untreated white hair mother yarn (manufactured by Kabushiki Kaisha Bulex, length 10 cm, weight 1 g)" was replaced with "bleached mother yarn (manufactured by Kabushiki Kaisha Quot ;, level 14, length 10 cm, weight 1 g) &quot;, the mother lambs for evaluation were prepared in the same manner as in Test 1.

The evaluation blindness obtained above was observed to evaluate the color unevenness of damage caused by the following criteria. In addition, the evaluation of color unevenness by damage experts was performed by four professional evaluators.

&Lt; Evaluation standard of color unevenness for damage mother &

○ (Good): All of the parent hair is uniformly dyed.

× (bad): The entire mother line is not uniformly colored, and there is color unevenness.

As a result of Test 6 (evaluation of color unevenness with respect to damage), Comparative Example 1-1 and Comparative Example 1-2 showed poor color unevenness (X) with respect to damage. In the other examples and comparative examples, the color unevenness of damage was good (O).

The components listed in the table are as follows.

Basic Blue 124: manufactured by BASF, trade name "Vibracolor Moonlight Blue"

Basic Blue 75: Hodogaya Kagaku Kogyo K.K., trade name "AHC BLUE SP"

Basic color 31: Vibracolor Flame Orange, trade name, manufactured by BASF

Basic red 51: Manufactured by BASF, trade name "Vibracolor Ruby Red"

Basic Red 76: "ARIANOR MADDER RED", manufactured by Senshi Entrotechnologies Japan,

Basic yellow 87: Manufactured by BASF, trade name "Vibracolor Citrus Yellow"

Basic yellow 57: manufactured by Sensien Technologies Japan, trade name &quot; ARIANOR STRAW YELLOW &quot;

HC Blue 2: trade name "COLOREX HCB2" manufactured by Teruka Corporation

HC Yellow 2: manufactured by Teruka Corporation, trade name "COLOREX HCY2"

HC Yellow 4: manufactured by Teruka, trade name "COLOREX HCY4"

Stearyl alcohol: manufactured by Kao Corporation, trade name &quot; Kalcol 8688 &quot;

Cetanol: manufactured by Kao Corporation, trade name &quot; Kalcol 6870 &quot;

Alkyltrimethylammonium chloride: trade name "GENAMIN KDMP-J", manufactured by Clariant Japan K.K.

Stearyltrimethylammonium chloride: manufactured by Kao Corporation, trade name "Kotamine 86W"

Stearic acid dimethylaminopropylamide: manufactured by Nikko Chemicals Co., Ltd., trade name "NIKKOL Amidoamine MPS"

Polyoxyethylene cetyl ether (5EO): trade name "Browon CH-305", manufactured by Aoki Yushi Kogyo Co., Ltd.

Polyoxyethylene cetyl ether (20EO): trade name "Browon CH-320L" manufactured by Aoki Yushi Kogyo Co., Ltd.

Liquid paraffin: manufactured by Sonneborn Inc, trade name "CARNATION"

Dipropylene glycol: trade name &quot; Dipropylene glycol DPG-FC &quot;, manufactured by Asahi Glass Co.,

Polypropylene glycol: trade name "SANNIX PP-400", manufactured by Sanyo Chemical Industries, Ltd.

Cetyl 2-ethylhexanoate: "CIO-N" manufactured by Nippon Specialty Chemicals Co., Ltd.

Capric acid glyceryl: product name "SunSoft 760-C" manufactured by Daiyo Kagaku Co., Ltd.

Polychlorinated dimethylmethylene piperidinium liquid: "Makoto 100" manufactured by Narco Corporation, 40% by mass of purified water,

O-[2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose chloride: trade name "Katanal HC-100" manufactured by Tohoku Kagaku Kogyo K.K.

Methylpolysiloxane: manufactured by Dow Corning Toray Co., Ltd., trade name: DOW CORNING TORAY SH200 C FLUID 20CS

Aminoethylaminopropylsiloxane-dimethylsiloxane copolymer emulsion: DOW CORNING TORAY SM8704C, manufactured by Dow Corning Toray Co., Ltd., 40 mass%

Lauroylmethyl-? - alanine sodium: manufactured by Kawaken Fine Chemicals Co., Ltd., trade name "Aranon ALE"

N-coconut oil fatty acid acyl-L-glutamic acid triethanolamine: trade name "Aminosurfact ACMT-L" manufactured by Asahi Kasei Chemicals Co.,

Lauric acid amidopropyl betaine: manufactured by Shin-Nippon Rikagaku Co., Ltd., trade name "Ricavion B-300"

Palm oil fatty acid amidopropyl betaine: manufactured by Shin-Nippon Rikagaku Co., Ltd., trade name "Ricavion B-200"

Palm oil fatty acid N-methylethanolamide: trade name "Aminon C-11S", manufactured by Kao Corporation

In addition, the following is a prescription example of the salt scouring composition of the present invention.

(Prescription Example 1) Color rinse (cream)

Basic Blue 124 0.05 mass%

Basic coloration 31 0.05 mass%

HC Yellow 2 0.06 mass%

HC Blue 2    0.6 mass%

Stearyl alcohol    7.0 mass%

Alkyltrimethylammonium chloride solution (80 mass% pure water)  3.0 mass%

Stearic acid dimethylaminopropylamide  1.0 mass%

Polyoxyethylene cetyl ether (5EO)    0.5 mass%

Liquid paraffin    3.0 mass%

Dipropylene glycol    5.0 mass%

Cetyl 2-ethylhexanoate  2.0 mass%

Chloride O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose   0.5 mass%

Methylpolysiloxane  2.0 mass%

Legacy Appropriate amount (adjusted to pH 5)

Phenoxyethanol  0.5 mass%

Water soluble collagen (3)  0.1 mass%

Argan oil  0.1 mass%

L-glutamic acid  0.1 mass%

Purified water    Balance

Sum  100 mass%

(Prescription Example 2) Color rinse (emulsion)

Basic Blue 124      0.1 mass%

Basic red 51 0.08 mass%

Basic yellow 87 0.24 mass%

HC Yellow 2 0.08 mass%

HC Blue 2  1.2 mass%

Cetanol  6.0 mass%

Polyoxyethylene cetyl ether (5EO)  2.0 mass%

Polyoxyethylene cetyl ether (20EO)  2.0 mass%

Liquid paraffin  5.0 mass%

Dipropylene glycol  3.0 mass%

Capric acid glyceryl  2.0 mass%

Polydimethylmethylene piperidinium chloride solution (pure water 40 mass%) 1.0 mass%

Aminoethylaminopropylsiloxane-dimethylsiloxane copolymer emulsion (40 mass% pure)  1.5 mass%

Citric acid Appropriate amount (adjusted to pH 5)

Sodium benzoate  0.5 mass%

Hydroxypropyltrimonium hyaluronic acid  0.5 mass%

Silica  0.2 mass%

Seaweed Extract (1)  0.1 mass%

l-menthol  0.1 mass%

Purified water  Balance

Sum  100 mass%

(Prescription Example 3) Hair Manicure (Gel)

Basic Blue 124 0.07 mass%

Basic coloration 31 0.07 mass%

HC Yellow 2  0.1 mass%

HC Blue 2  1.5 mass%

Hydroxyethylcellulose  2.5 mass%

ethanol 10.0 mass%

Benzyl alcohol  5.0 mass%

Polypropylene glycol  3.0 mass%

Isononyl isononanoate  1.5 mass%

Chloride O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose  0.5 mass%

Polyoxyethylene-methylpolysiloxane copolymer  0.5 mass%

Disodium edetate  0.2 mass%

Glycolic acid Appropriate amount (adjusted to pH 5)

Camellia oil  0.1 mass%

Panthenol  0.1 mass%

Purified water  Balance

Sum  100 mass%

(Prescription Example 4) Color shampoo

Basic Blue 124 0.05 mass%

Basic coloration 31 0.05 mass%

HC Yellow 4  0.2 mass%

HC Blue 2  1.5 mass%

Sodium lauroylmethyl-beta -alanine (30 mass% pure)  5.0 mass%

Lauric acid amidopropyl betaine solution (pure water 30% by mass) 30.0 mass%

Palm oil fatty acid N-methylethanolamide  2.0 mass%

Chloride O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose  0.2 mass%

Dipropylene glycol  3.0 mass%

Capric acid glyceryl  1.0 mass%

Polyglyceryl monolaurate  0.1 mass%

Highly polymerized methylpolysiloxane (1)  0.1 mass%

Methylpolysiloxane  0.4 mass%

Citric acid Appropriate amount (adjusted to pH 5)

Phenoxyethanol  0.5 mass%

Water soluble collagen (3)  0.1 mass%

Jojoba oil  0.1 mass%

Purified water  Balance

Sum  100 mass%

(Prescription Example 5) Color shampoo

Basic Blue 124  0.4 mass%

Basic red 51 0.05 mass%

Basic yellow 87 0.15 mass%

HC Yellow 2 0.01 mass%

HC Blue 2  0.8 mass%

N-coconut oil fatty acid acyl-L-glutamic acid triethanolamine solution (pure substance 30 mass%)  5.0 mass%

Palm oil fatty acid amidopropyl betaine solution (30 mass% pure) 30.0 mass%

Palm oil fatty acid N-methylethanolamide  2.0 mass%

Chloride O- [2-hydroxy-3- (trimethylammonio) propyl] guanidol propylene glycol  0.2 mass%

Polypropylene glycol  3.0 mass%

Glyceryl caprylate  1.0 mass%

Aminoethylaminopropylsiloxane-dimethylsiloxane copolymer emulsion (40 mass% pure)  0.5 mass%

Citric acid Appropriate amount (adjusted to pH 5)

Sodium benzoate  0.5 mass%

Sodium hyaluronate  0.1 mass%

Lavender oil  0.1 mass%

Mulberry Extract  0.1 mass%

Purified water  Balance

Sum  100 mass%

(Prescription Example 6) Color rinse (cream)

Basic Blue 124 0.05 mass%

Basic red 76 0.15 mass%

Basic yellow 57  0.1 mass%

HC Yellow 2 0.03 mass%

HC Blue 2  0.6 mass%

Stearyl alcohol  5.0 mass%

Behenyl alcohol  2.0 mass%

Alkyltrimethylammonium chloride solution (80 mass% pure water)  3.0 mass%

Stearic acid dimethylaminopropylamide  1.0 mass%

Polyoxyethylene cetyl ether (5EO)  0.5 mass%

Liquid paraffin  3.0 mass%

Dipropylene glycol  5.0 mass%

Cetyl 2-ethylhexanoate  2.0 mass%

Chloride O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose  0.5 mass%

Decamethylcyclopentasiloxane  1.0 mass%

Polymethylsilsesquioxane  0.5 mass%

ethanol  5.0 mass%

Legacy Appropriate amount (adjusted to pH 5)

Shea province  1.0 mass%

Phenoxyethanol  0.5 mass%

Water soluble collagen (3)  0.1 mass%

Hydrolyzed silk liquid  0.1 mass%

Purified water  Balance

Sum  100 mass%

(Prescription Example 7) Color rinse (cream)

Basic Blue 124 0.05 mass%

Basic red 51 0.04 mass%

Basic yellow 57  0.1 mass%

HC Yellow 2           0.035 mass%

HC Yellow 4      0.015 mass%

HC Blue 2  0.4 mass%

Cetanol  8.0 mass%

Stearyltrimethylammonium chloride (28 mass% pure)  5.8 mass%

Stearic acid dimethylaminopropylamide  1.0 mass%

Liquid paraffin  3.0 mass%

1,3-butylene glycol  5.0 mass%

(Eicosanic acid / tetradecanedioic acid) decaglyceryl solution  1.2 mass%

Concentrated glycerin  0.8 mass%

Polydimethylmethylene piperidinium chloride solution (pure water 40 mass%) 1.0 mass%

Microcrystalline wax  1.0 mass%

ethanol  3.0 mass%

Legacy Appropriate amount (adjusted to pH 5)

Sodium benzoate  0.5 mass%

Cinnamon extract  0.1 mass%

Licorice extract powder  0.1 mass%

Purified water  Balance

Sum  100 mass%

Industrial availability

The salt scouring composition of the present invention is a composition used as a salt scourge. Examples of the salts include color rinses, color treatments, hair nail polish, and color shampoos.

Claims (6)

A salt foment composition comprising the following component A, the following component B, the following component C and the following component D:
Component A: A dye represented by the following formula (1)
[Chemical Formula 1]

Component B: one or more dyes selected from the group consisting of basic or basic color 31, basic red 51, basic red 76, basic yellow 87 and basic yellow 57
Component C: HC Blue 2
Component D: at least one dye selected from the group consisting of HC Yellow 4 and HC Yellow 2. The method according to claim 1,
The content of the component A is 0.005 to 0.5% by mass,
The content of the component B is 0.005 to 1.5% by mass,
The content of the component C is 0.1 to 1.5% by mass,
Wherein the content of the component D is 0.01 to 0.5 mass%. 3. The method according to claim 1 or 2,
The mass ratio [component B / component A] of the content of the component B to the content of the component A is 0.1 to 10.0,
, The mass ratio [component D / component C] of the content of the component D to the content of the component C is 0.005 to 1.0,
Wherein the mass ratio of the content of the component C to the content of the component A [component C / component A] is 1.5 to 70.0. 4. The method according to any one of claims 1 to 3,
Wherein the content of HC Yellow 2 in 100 mass% of Component D is 50.0 mass% or more. 5. The method according to any one of claims 1 to 4,
A color rinse or a color treatment. 6. The method of claim 5,
In addition, a salt bleaching composition comprising the following component E:
Component E: at least one component selected from the group consisting of a cationic surfactant, a cationic polymer and a silicone oil.