KR20190019984A - Fragrance composition for deodorizing in formulation comprising an amine - Google Patents

Abstract

The present invention relates to a fragrance composition comprising a fragrance component of aldehyde. More particularly, the present invention relates to a fragrance composition capable of inhibiting off-odors and unpleasant odors that may occur when a formulation comprising amines is used. The fragrance composition of the present invention contains a green aldehyde fragrance, so that it is possible to inhibit off-odors and unpleasant odors caused by cationic materials containing amines. In addition, by mixing fragrance of floral or citrus series, the scent is luxurious, and an effect of increasing fragrance remaining properties is excellent.

Description

[0001] The present invention relates to a fragrance composition for deodorizing in an amine-

The present invention relates to a perfume composition comprising an aldehyde perfume ingredient, and more particularly to a perfume composition capable of masking odor and unpleasant odors that may occur when using a formulation containing an amine compound.

In general, household goods and cosmetics are used to maintain a clean and healthy life. It is customary to blend various raw materials and materials to enhance its function and effectiveness. Some of the raw materials, besides the positive functions, have bad odors and unpleasant odors, which impairs usability and emotional needs.

In particular, amphoteric surfactants used for constituting the product, amines of cationic polymer are often used to cause decay, intracutaneous and the like. This odor is something that should be improved because it is perceived as a significant defect of the product even at a very small degree. In addition, there is an adverse effect of directly influencing the purchasing power and lowering the satisfaction degree of the product after use, and many companies are trying to control it.

In general, the perfume used for masking the odor of the preparation often contains a perfume having a volatility (bp) of 250 ° C or lower. The fragrance material with low volatility is characterized by strong and easy volatilization, which makes it possible to instantaneously remove odor masking. However, there is a limit in that the masking effect of the odor felt during or after storage of the product is inconsistent. In addition, there is a limitation in implementing and differentiating excellent sensitivity quality that can be obtained by using the fragrance because the fragrance characteristic is simple.

The usual way to lower the odor and offensive odor of a product is to increase the inversion rate. However, the excessively high incidence rate is highly likely to occur due to the stability of the product and over time, and raises the cost of the product. Another method is to increase the reverberation and mask the odor. Other methods of enhancing reverberation include using raw materials having a boiling point of 250 ° C or higher and fragrances having a high ratio of raw materials having ClogP of 3 or more indicating the solubility (US Pat. No. 6,086,903). The vapor pressure is characterized by the inverse relationship with the boiling point of the substance, so that the higher the boiling point of the perfume, the more the reverberation is increased. ClogP is the value obtained by taking a log of the value P representing the ratio of solubility in the case of dissolving a single perfume in octanol and in water. The larger the ClogP value, the more lipophilic the fragrance. Therefore, The amount of incense that is washed down is reduced, leaving much reverberation. However, when such a perfume is used, there is a disadvantage that fragrance dissipation during use of the product is weak and there is a limit to the perfume series.

Since the fragrance has a very important influence on the sensibility quality of consumers, various methods are used to remove odor or unpleasant odor in the formulations containing amines. However, it is very difficult to obtain both the desired fragrance and the strength, It does not satisfy emotions.

SUMMARY OF THE INVENTION The present invention provides a perfume composition capable of masking unpleasant odors such as decay, intestine and the like in a product containing a cationic raw material such as a cationic polymer containing an amine, a cationic surfactant and the like will be.

Another object of the present invention is to provide a personal care composition or a home care composition containing the perfume composition, which is free from odor and unpleasant odor.

In order to solve the above-mentioned technical problems, the present invention provides a fragrance composition for suppressing odor of amines including an aldehyde fragrance. The aldehyde fragrance is characterized by being a compound having an aldehyde group as a functional group.

The present inventors investigated to solve the problem of unpleasant odor in a personal care or home care composition containing an amine compound. When an aldehyde flavor together with an amine compound is included in the composition, the odor is masked, And it is possible to exert a sensible quality of a luxurious aroma. Thus, the present invention has been completed.

In general, a combination perfume can be used for masking odor of household goods or cosmetics, and the combination perfume may contain one or more kinds of aldehyde perfume ingredients. The aldehyde fragrance which is generally used as a component of the completed combination fragrance is 2 - [(4-methylphenyl) methylene] -heptanal (2 - [(4-Methylphenyl) methylene] -heptanal (mimosa heptanal) 2,6-nonadienal, octanal, nonanal, 8,9,10-undecenal, 2-dodecenyl, (2-Dodecenal (Mandarine aldehyde)), 9-undecenal, 10-undecenal, Undecanal, hypoxanthine (2,6,10- Adoxal (2,6,10-trimethylundec-9-enal)), Ald. C-12 (Lauric), 2-Methyl Undecanal (MNA, Ald. C-12), Ald. C-14, anisic aldehyde, Bergamal (3,7-Dimethyl-2-methylene-6-octenal) (2-Methyl-3- (4-methoxyphenyl) propanal), Citral, Cuminic (Cuminic) Cyclamen ald., Cyclamax (3- (p-cumenyl) propionaldehyde), Cymal, Decyl aldehyde (decyl) aldehyde, Florahydral, floral super (4,8-Dimethyl-4,9-decadienal), floral ozone (3,8-dimethyl- - (o- (and p-) ethylphenyl) -2,2, -dimethylpropionaldehyde) (Floralozone (3- (o- (and p-) Ethylphenyl) -2,2-dimethylpropionaldehyde) Fluoropal), gelaldehyde (5,9-dimethyl-4,8-decadienal), Heliolane (alpha-methyl-1,3-benzo Dioxol-5-propanol) (Helional (alpha-Methyl-1,3-benzo dioxole-5-propanal), trans-2-hexenal, cis-3-hexenal, hexyl cinnamic aldehyde, Hydroxycitronellal, Isocyclocitral ((2,4,6-) & (3,5,6-) trimethyl-3-cyclohexene-1-carboxaldehyde) (3,5,4-trimethyl-3-cyclohexene-1-carboxaldehyde), and lycoric acid (?, 4-dimethylcyclo-3-hexene- (3-ene-4-methyl-pentyl) cyclohexene-1-carboxaldehyde) (Lyral (3-ene-1-propan- (5,5-dimethyl-octahydro-2-naphthalenecarboxaldehyde) (Melafleur (5,5-Dimethyl) cyclohexene-1-carboxaldehyde) 2-naphthalenecarboxaldehyde), melzone (octahydro-4,7-methano-1H-indenecarbaldehyde), methylnonyl acetaldehyde ( Met (3,7-Dimethyl-6-octenyl) oxy) acetaldehyde), amaldehyde ((3,7-dimethyl-6-octenyl) oxy) acetaldehyde) (3- (and 4 -) (4-Methyl-3-pentyl) cyclohexanecarboxylic acid) -3-ene-1-carboxaldehyde), PT Bushin (P. T. bucinal, Phenyl acetaldehyde, Phenoxy acetaldehyde, Phenyl acetaldehyde dimethyl acetal, 1-methyl-4- (4-methyl-3-pentenyl) Cyclohex-3-ene-1-carboxaldehyde, undecyl aldehyde, undecylenic aldehyde, 1-methyl-4- (3,6-Dimethylcyclohex-3-ene-1-carboxaldehyde), tertiary butyl-tertiary butyl aldehyde, methylhydrocinnamic aldehyde, tert-butylhydrocinnaminic aldehyde, tolylacetaldehyde (Parmanyl), butral (octahydro-1H-4,7-methanone (Octahydro-1H-4,7-methanoindene-5-carbaldehyde), boronal ((2E) -2-methyl-4- (2,6,6-trimethylcyclo- -Hexen-1-yl) -2-butenyl) (B (2E) -2-Methyl-4- (2,6,6-trimethylcyclohex-1-en-1-yl) but-2-enal), centenal (octahydro- 5-methoxy-4,7-methano-1H-indene-2-carboxaldehyde), Trifenal (benzene propanol) (Trifernal Benzeneepropanal), Acalea TT (2 - [(4-methylphenyl) methylene] -heptanal), acetal CD (phenylacetaldehyde glyceryl acetal (4-tert-butylphenyl) propanal), Cetonel (2-methyl-4 (4-tert-butylphenyl) propanal), Acetal CD (Phenylacetaldehyde glycerylacetal) - (2,6,6-trimethyl-2 (1) -cyclohexane (Cetonal®) (2-Methyl- -1-yl) butanal), Citral Lemarome (N ((E / Z) -3,7-dimethyl-2,6-octadienyl ((E / Z) 6-octadienal), citronellal (3,7-dimethyloct-6-enal), Citrathal® TECH (3,7- Octadai Decene-4-trans ((E) -4-decenal), decane-4,6-octadienal) Decenal-9 (9-Decenal), Leguminal (Propanal-3-hexenyl methyl acetal), Liffarome ™ (Cis- 3-Hexen-1-yl methyl carbonate), mefranal (3-Methyl-5-methylphenyl) phenylpentanal), melonal (2,6-Dimethylhept-5-enal), myralden (4 (3) - (4-methylpen- ) Cyclohex-3-enecarbaldehyde), propanezel ((5E) -2,6,10-tricarboxaldehyde) (Myraldene (4 (3) (5E) -2,6,10-Trimethylundeca-5,9-dienal), syringal aldehyde ((4-methylphenyl) acetaldehyde) (Syringa Aldehyde (4-methylphenyl) acetaldehyde), tetrahydrocitral (3,7-dimethyloctanal), Tripla (2,4-dimethyl-3-cyclohexene-1-carboxaldehyde), berthocitral (2,4-dimethylcyclohexyl- (2,4-Dimethylcyclohex-3-ene-1-carbaldehyde), and Bertholip ISO (3,6 (and 4,6) -dimethylcyclohexyl- 1-carboxaldehyde) (Vertoliff ISO (3,6 (and 4,6) -dimethylcyclohex-3-ene-1-carboxaldehyde). These fragrances not only have different flavor characteristics but also have different physical and chemical properties.

In the composition according to the present invention, the aldehyde fragrance is a fragrance of a green-based fragrance composition.

In addition, the present invention provides a fragrance composition for suppressing odor control of amines, which further comprises a floral-type perfume in the composition.

In addition, the present invention provides a fragrance composition for suppressing odor-elimination of amines, which further comprises a perfume of the citrus series in the composition.

The present inventors have completed the present invention by finding an optimal combination of fragrances that effectively mask the odor of amines among the perfume ingredients. In the present invention, it was confirmed that the green-based scent exhibits the best masking effect, and it is confirmed that the green-based scent has a more excellent effect when the floral-like scent is added. In addition, a perfume of the citrus series can be added for the perfection of the sensibility quality of the perfume.

In Table 1, green-based flavor, floral-based flavor, and citrus-based flavor ingredients are indicated. The perfume ingredients that can be used in the composition of the present invention are not limited to the ingredients shown in Table 1 below.

The green series of flavors include trans-2-hexenal, cis-3-hexenal, 2,6-nonadienal, (2,6,10-Trimethylundec-9-enal), Nonanal, Isocyclo citral, Propanal (2,6,10-trimethylundec- Propanal-3-hexenyl methyl acetal, cis-3-hexen-1-yl methyl carbonate, 2,6-dimethylheptane, 2,6-dimethylhept-5-enal, tricyclo [5.2.1.02,6] decane-3-carbaldehyde, 2, 2,6-nonadienal, phenylacetaldehyde, p-Tolylacetaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxaldehyde (2 Dimethyl-cyclohexene-1-carboxaldehyde, 2,4-dimethylcyclohex-3-ene-1-carbaldehyde, - Dimethyl 3-ene-1-carboxaldehyde, 3,6 (and 4,6) -dimethylcyclohexy-3-en-1-carboxaldehyde (3,6-dimethylcyclohex- (4,6) -dimethylcyclohex-3-ene-1-carboxaldehyde and octahydro-1H-4,7-methanoindene-5-carbaldehyde (Octahydro- -methanoindene-5-carbaldehyde), and the like, but the present invention is not limited thereto. Preferably, two or more of the above green series flavors may be used in combination in order to achieve a high-grade flavor when using the composition of the present invention.

The above-mentioned floral-type fragrance is used to more effectively mask the odor of amines, and it can be used in a variety of applications such as 2- [(4-methylphenyl) methylene] -heptanal, Phenylacetaldehyde, Phenylacetaldehyde glycerylacetal, Bergamal, Boronal, Bourgeonal, 2-methyl-4- (2,6,6-trimethyl- 1) -cyclohexen-1-yl) butanal, Cyclamen Aldehyde, 2-Methyl-4- (2,6,6- 4,8-Dimethyl-4,9-decadienal, 3 (p-cumenyl) propionaldehyde, 3- - (o- (and p-) ethylphenyl) -2,2-dimethylpropionaldehyde, 3- (o- (and p-) Ethylphenyl) -2,2-dimethylpropionaldehyde, 3- 3- (3-Isopropylphenyl) butanal, Helional, 10-undecenal, Lyral, Selected from the group consisting of Melafleur, Muguet aldehyde, Profarnesal and Syringa aldehyde ((4-Methylphenyl) acetaldehyde)) Any one or more of them may be used, but the present invention is not limited thereto.

The perfume of the citrus series is used to improve the sensibility quality of the fragrance, and (E / Z) -3,7-dimethyl-2,6-octadienal ((E / Z) 2,6-octadienal, citronellal, 3,7-dimethyl-2,6-octadienal, decenal- -4-Trans, Decenal-9, Geraldehyde, Limoxal, Mandarine Aldehyde, Mefranal, Myraldene and Tetrahydro Tetrahydro Citral, and the like may be used, but the present invention is not limited thereto.

In addition, the present invention provides a perfume composition, wherein the perfume composition has a ClogP of 4 or less based on the total weight of the composition. The above-mentioned ClogP means a value obtained by taking a log of a value P representing the ratio of solubility when a single perfume is dissolved in octanol and dissolved in water. In order to obtain a better amine masking effect of a more excellent amine, the perfume having a ClogP of 4 or less is more preferably contained in an amount of 50% by weight or more, and most preferably 70% by weight or more.

The aldehyde fragrance may be included in an amount of 5% by weight to 50% by weight based on the total weight of the fragrance. If the aldehyde flavor is less than 5% by weight based on the total weight of the flavor, the odor masking effect is insignificant. When the aldehyde flavor is more than 50% by weight, the palatability of the flavor decreases.

The present invention provides a personal care composition or a home care composition comprising the aldehyde perfume composition. The personal care composition may be a skin care composition such as a skin, essence, lotion, eye cream or cream; Hair care compositions such as hair dye, shampoo, conditioner, treatment or hair essence; Or a body-care composition such as a body cleanser, a body lotion or a soap, but is not limited thereto, and can be applied to a personal care composition into which a perfume is added. The above-mentioned home care composition may be a fiber care composition such as a detergent or a fabric softener, a kitchen detergent or a fragrance, but is not limited thereto and may be applied to a home care composition into which a perfume is injected.

The home care product or personal care product may typically include a cationic polymer, a cationic surfactant, an amphoteric surfactant, a nonionic surfactant, or a nonionic polymer as the cationic raw material, The kind used and the amount of injection vary. The cationic raw material plays an important role in maintaining the reverberation of the perfume after use in the product. Products typically used to maintain reverberation after a wash-off include hair products such as shampoos, hair conditioners, hair dye, fabric care products such as detergents and fabric softeners. The dyeing agent for dyeing is composed of a cationic material and has odor, so it is necessary to maintain reverberation.

The present invention provides a hair care composition comprising at least one selected from the group consisting of a cationic surfactant, an amphoteric surfactant, a nonionic surfactant, and a cationic polymer.

The cationic surfactant used in the hair care composition may be at least one selected from the group consisting of cetrimonium chloride, stearamidopropyldimethylamine, dicetyldimethylammonium chloride and ester quaternary. It is not.

The amphoteric surfactant used in the hair care composition may be at least one selected from the group consisting of cocamidopropyl betaine, cocoamphocarboxy glycinate and cocoamphocarboxy propionate, but is not limited thereto .

The nonionic surfactant used in the hair care composition may be any one or more selected from the group consisting of lauryl acid diethanolamide, coconut fatty acid diethanolamide, coconut fatty acid monoethanolamide, lauryldimethylamine oxide and palm oil alkyldimethylamine oxide May be used, but is not limited thereto.

The cationic polymer used in the hair care composition is a natural cationic polymer group consisting of guar hydroxypropyl trimonium chloride, hydroxypropyl guar hydroxypropyl trimonium chloride and quaternary hydroxyethyl cellulose; And a synthetic cationic polymer group composed of dimethyldiallylammonium chloride polymer, acrylamide dimethyl allylammonium chloride copolymer and polyvinyl pyrrolidone dimethyl amino ethyl methacrylate copolymer, may be used. But is not limited thereto.

The present invention also provides a fiber care composition comprising the perfume composition and a cationic polymer, an amphoteric surfactant or a mixture thereof.

The cationic polymer used in the fiber care composition may be selected from the group consisting of cationic guar, cationic cellulose, dimethyldiallylammonium chloride polymer, acrylamide-dimethyldiallylammonium chloride copolymer, PVP-dimethylaminoethyl methacrylate copolymer, A dimethyldiallylammonium chloride copolymer, an acrylamide-dimethylaminoethyl methacrylate methyl chloride copolymer, and a trimethylaminoethyl methacrylate polymer. However, the present invention is not limited thereto.

The amphoteric surfactant used in the fiber care composition is selected from the group consisting of alkylamidopropyl betaine, alkyldimethylbetaine, alkylmonoamphoacetate, cocoamphocarboxyglycinate, sarcosinate and alkylamphodiacetate, and the like. Any one or more of them may be used, but the present invention is not limited thereto.

The present invention also provides a hair dye composition comprising the perfume composition, precursor and coupler.

The precursors used in the hair dye composition are selected from the group consisting of 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, N, N-bis (2-hydroxyethyl) (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethyl-paraphenylenediamine, 4,4'-diaminodiphenylamine, 1,3-bis Amino-2-propanol, PEG-3,3,2'-paraphenylenediamine, para-aminophenol, para-methylaminophenol, 3- Aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2- amino- Aminosalicylic acid, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4, , 5-diamino-1- (4'-chlorobenzyl) pyrazole, 4,5-diamino-1- Aminophenol, toluene-2,5-diamine hydrochloride, p-phenylenediamine hydrochloride, toluene-2,5-diamine, p-phenylenediamine, p-methylaminophenol sulfate, At least one selected from the group consisting of o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate and p-phenylenediamine sulfate may be used, but the present invention is not limited thereto.

The couplers used in the hair dye composition are selected from the group consisting of metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino- Phenethol, 2,4-diamino-5- (2-hydroxyethoxy) toluene, 2,4-dimethoxy-1,3-diaminobenzene, 2,6- (2,4-diaminophenoxy) propane, metaaminophenol, 2-methyl-5-aminophenol, 2-methyl- Amino-6-methylphenol, 2-methyl-4-chloro-5-aminophenol, N- (2-hydroxyethylamino) phenol, (2-hydroxyethylamino) phenol, 2-methyl-4-fluoro-5-aminophenol, resorcin, 2-methylresorcin , 4-chlororesorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaph Tetrahydrofuran, 2-isopropyl-5-methylphenol, 4-hydroxyindole, 5-hydroxyindole, 6-hydroxyindole, 7-hydroxyindole, 6-hydroxybenzomorpholine, Methylene dioxy aniline, 1- (2-hydroxyethyl) amino-3,4-methylenedioxybenzene, 2,6- Dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine, 2,3-diamino-6-methoxypyridine, 2- Methoxypyridine, 2-amino-3-hydroxypyridine, 2,6-diaminopyridine, salts thereof, and the like may be used, but the present invention is not limited thereto.

The perfume composition of the present invention contains a green-based aldehyde perfume, so that it is possible to suppress odor and unpleasant odors caused by a cationic material containing an amine. In addition, by mixing the fragrance of the floral or citrus series, the fragrance is high and the effect of improving the reverberation is excellent.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

In order to demonstrate the effect of the perfume composition of the present invention, the following examples use the dye as the example in which the odor due to amines is strongest and the evaluation is relatively immediate. However, the scope of the present invention is not limited to the dye do.

Fragrance bases 1 to 3 containing aldehyde fragrances were prepared with the respective compositions shown in Table 2 below.

Characteristic Perfume name Fragrance base 1 Fragrance base 2 Fragrance base 3 green Adoxal 10.0 10.0 10.0 trans-2-hexenal 2.0 2.0 2.0 cis-3-hexenal 1.0 1.0 1.0 2, 6-nonadienal 2.0 2.0 2.0 Leguminal 15.0 10.0 10.0 Triplal® 12.0 10.0 10.0 Vertral 8.0 5.0 5.0 floral hydroxy citronellal - 3.0 5.0 cyclamen ald. - 3.0 5.0 helional - 5.0 5.0 lyral - 3.0 5.0 melafleur - 5.0 5.0 hexyl cinnamic aldehyde - 1.0 2.0 jasmal - 3.0 5.0 Muguet aldehyde - 5.0 5.0 Vertral - 2.0 3.0 citrus citronellal - - 2.0 citral - - 2.0 Mandarine Aldehyde - - 6.0 solvent DPG 50.0 20.0 10.0 Total 100.0 100.0 100.0

The perfume compositions of Production Examples 1 to 9 were prepared by mixing the three fragrance bases shown in Table 2 above with the general fragrance by the weight ratios shown in Table 3 below. The following general fragrances were used for the Angel berry fragrance supplied by Givaudan. Examples of the ingredients of the Angelberry flavoring include linalool (dimethyl-1,6-octadien-3-ol), 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylindeno (2E) -3,7-dimethyl-2,6-octadien-2-yl) benzene, 3-ene-2-one, 3-Methyl-4- (2,6,6-trimethyl-2 2-phenoxyethyl 2-methylpropanoate, hexyl acetate and 6-acetyl-1,1,2,4,4,7-hexamethyl-1,2,3,4- 4-tetrahydronaphthalene, and the like.

division
(weight%) Production Example 1 Production Example 2 Production Example 3 Production Example 4 Production Example 5 Production Example 6 Production Example 7 Production Example 8 Production Example 9 General fragrance 95.0 95.0 95.0 80.0 80.0 80.0 50.0 65.0 60.0 Fragrance base 1 5.0 20.0 50.0 Fragrance base 2 5.0 20.0 50.0 Fragrance base 3 5.0 20.0 50.0 Sum 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0 100.0

Ninety kinds of hair dye preparation compositions (Examples 1 to 9) were prepared by bringing the perfume compositions of Production Examples 1 to 9 shown in Table 3 above into each of the hair dye preparation 1 agents shown in Table 4 in amounts of 0.7% by weight. Comparative Example 1 containing no perfume and Comparative Example 2 containing a perfume of a conventional product were prepared as Comparative Examples. Dipropylene glycol (DPG), which is mainly used as a fragrance solvent, was used as a perfume portion in Comparative Example 1, and fragrance of a general hair dyeing agent was used as a perfume of a conventional product of Comparative Example 2.

division No. Ingredients content(%) 1 One Toluene-2,5-diamine 0.50 2 Resorcinol 0.40 3 Methanamine phenol 0.10 4 Sodium cocoylglutamate 7.20 5 Alkyl (8-16) glucoside 2.00 6 Polyoxyethylene lauryl ether 2.00 7 Polyoxyethylene tridecyl ether 0.50 8 Propylene glycol 4.00 9 ethanol 9.50 10 ammonia 1.68 11 Ammonium bicarbonate 8.00 12 Monoethanolamine 2.40 13 Ascorbic acid Suitable amount 14 Anhydrous sodium sulphate Suitable amount 15 4 sodium 2 adduct of edetate Suitable amount 16 Spices 0.70 17 Purified water To 100.0 2 One Stearyltrimethylammonium chloride 0.70 2 Polyoxyethylene (40) cetyl ether 0.46 3 Cetanol 0.74 4 Myristyl alcohol 0.21 5 Hydroxyanetane diphosphonic acid 0.04 6 Oxyquinoline sulfate 0.01 7 Sodium hydroxide Suitable amount 8 Hydrogen peroxide 5.70 9 Purified water To 100.0

Experimental Example: Evaluation of the odor of the amine

After mixing 50g and 2g of 1 in Table 4, the hair was coated on a hair tress like a general hair dye and dyed, and the odor of the amine was evaluated immediately after dyeing, after 20 minutes and after wash off.

Sensory evaluation was performed on 15 persons who were in their 20s ~ 40s who had direct dyeing experience. The average age was 31.5 years for 5 males and 10 females. The criteria for sensory evaluation are as follows.

- Sensory evaluation criteria -

1 point: The odor of amine (similar to the smell of squid) is very strong.

2 points: strong odor of amine.

3 point: Usually the odor of amine.

4 point: weak odor of amine.

5 points: The odor of amine is very weak.

The results of the sensory evaluation immediately after dyeing are shown in Table 5, the sensory evaluation results after 20 minutes of dyeing are shown in Table 6, and the sensory evaluation results after wash-off are shown in Table 7 below.

division Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Average 1.32 1.98 2.45 2.54 2.54 2.93 3.01 3.02 3.27 3.29 3.20 Standard Deviation 0.62 0.62 0.56 0.64 0.70 0.80 0.70 0.72 0.80 0.59 0.86

division Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Average 1.47 2.13 2.80 2.93 2.93 3.37 3.45 3.43 3.60 3.61 3.53 Standard Deviation 0.64 0.64 0.68 0.59 0.70 0.70 0.70 0.72 0.83 0.74 0.83

division Comparative Example 1 Comparative Example 2 Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Average 2.87 3.00 3.40 3.48 3.48 4.08 4.10 4.10 4.08 4.44 4.42 Standard Deviation 0.64 0.65 0.63 0.62 0.62 0.74 0.63 0.70 0.64 0.70 0.72

From the results of Table 5, it can be seen that there is a significant difference between the odor of amine immediately after dyeing and that of Comparative Example 1 which was treated with the conventional fragrance, and that the higher the content of aldehyde fragrance is, It was evaluated as excellent.

From the results of Table 5 and Table 6, it can be seen that compared to the results obtained immediately after dyeing and 20 minutes after the dyeing of Comparative Example 1 and Comparative Example 2, Respectively. However, in Examples 1 to 9 containing an aldehyde flavor, it was confirmed that the odor of the amine was equal or slightly weakened after 20 minutes of dyeing.

From the results of Table 7, it can be seen that, after rinsing the dye, the odor of the amine was evaluated to be excellent in the degree of masking of the odor according to Comparative Example 2, It was confirmed that there was an odor masking effect.

Furthermore, in Examples 1 to 9 containing an aldehyde perfume composition, the odor masking effect was evaluated to be superior to that of Comparative Example 2. The correlation coefficient was 0.976, and it was confirmed that the higher the content of aldehyde fragrance, the better the effect of the amine on the odor masking.

Claims (7)

And an aldehyde perfume. ≪ RTI ID = 0.0 > 11. < / RTI > The method of claim 1, wherein the aldehyde flavor is selected from the group consisting of trans-2-hexenal, cis-3-hexenal, 2,6- (2,6,10-trimethylundec-9-enal), nonanal, isocyclo (2,6,10-trimethylundec-9-enal) Isocyclo citral, propanal-3-hexenyl methyl acetal, cis-3-hexen-1-ylmethyl carbonate carbonate, 2,6-dimethylhept-5-enal, tricyclo [5.2.1.02,6] decane-3-carbaldehyde (tricyclo [5.2.1.02,6] decane-3-carbaldehyde, 2,6-nonadienal, phenylacetaldehyde, p-Tolylacetaldehyde, 2,4-dimethyl- 2,4-Dimethyl-3-cyclohexene-1-carboxaldehyde, 2,4-dimethylcyclohexy-3-enyl-1-carbaldehyde, 2,4- 3 cyclohex-3-ene-1-carbaldehyde, 3,6-dimethylcyclohex-3-ene-1-carboxaldehyde, , 6) -dimethylcyclohexyl-3-ene-1-carboxaldehyde (3,6 (and 4,6) -dimethylcyclohex-3-ene-1-carboxaldehyde) and octahydro- Decahydro-1H-4,7-methanoindene-5-carbaldehyde. The perfume composition according to claim 1, wherein the perfume is at least one selected from the group consisting of octahydro-1H-4,7-methanoindene-5-carbaldehyde. [3] The composition according to claim 2, wherein the composition is selected from the group consisting of 2- [(4-methylphenyl) methylene] -heptanal, phenylacetaldehyde, phenyl Phenylacetaldehyde glycerylacetal, Bergamal, Boronal, Bourgeonal, 2-methyl-4- (2,6,6-trimethyl-2 (1) Cyclohexen-1-yl) butanal), cyclamen aldehyde, 3- (p-methyl-4- (4,8-dimethyl-4,9-decadienal), 3- (o-cumenyl) propionaldehyde, (And p-) ethylphenyl) -2,2-dimethylpropionaldehyde, 3- (o- (and p-) Ethylphenyl) -2,2-dimethylpropionaldehyde, 3- - (3-Isopropylphenyl) butanal, Helional, 10-undecenal, Lyral, Melafleur, (4-Methylphenyl) acetaldehyde), which is characterized in that it further comprises at least one selected from the group consisting of uguet aldehyde, Profarnesal and Syringa aldehyde ((4-methylphenyl) acetaldehyde) Wherein the perfume composition is a perfume composition. 4. The composition of claim 3, wherein the composition comprises (E / Z) -3,7-dimethyl-2,6-octadienal ((E / Z) -3,7-Dimethyl- octadienal, citronellal, 3,7-dimethyl-2,6-octadienal, decenal-4- Trans, Decenal-9, Geraldehyde, Limoxal, Mandarine Aldehyde, Mefranal, Myraldene and Tetrahydrocitol Tetrahydro Citral). ≪ RTI ID = 0.0 > 11. < / RTI > 5. The perfume composition of claim 1, wherein the composition comprises 5 to 50% by weight of an aldehyde perfume based on the total weight of the composition. 5. The perfume composition according to any one of claims 1 to 4, wherein the composition comprises at least 30% by weight, based on the total weight of the composition, of a perfume having a ClogP of 4 or less. A fiber care composition characterized in that it comprises a perfume composition according to any one of claims 1 to 4 and a cationic polymer, an amphoteric surfactant or a mixture thereof.