JP6887214B2 - Composition with improved base odor and method for improving base odor - Google Patents
Composition with improved base odor and method for improving base odor Download PDFInfo
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- JP6887214B2 JP6887214B2 JP2015199297A JP2015199297A JP6887214B2 JP 6887214 B2 JP6887214 B2 JP 6887214B2 JP 2015199297 A JP2015199297 A JP 2015199297A JP 2015199297 A JP2015199297 A JP 2015199297A JP 6887214 B2 JP6887214 B2 JP 6887214B2
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- 239000000203 mixture Substances 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 10
- 239000003205 fragrance Substances 0.000 claims description 44
- 150000001875 compounds Chemical class 0.000 claims description 40
- 229920000642 polymer Polymers 0.000 claims description 39
- 125000002091 cationic group Chemical group 0.000 claims description 25
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims description 17
- HZPKNSYIDSNZKW-UHFFFAOYSA-N Ethyl 2-methylpentanoate Chemical compound CCCC(C)C(=O)OCC HZPKNSYIDSNZKW-UHFFFAOYSA-N 0.000 claims description 16
- 229920002907 Guar gum Polymers 0.000 claims description 14
- 239000000665 guar gum Substances 0.000 claims description 14
- 235000010417 guar gum Nutrition 0.000 claims description 14
- 229960002154 guar gum Drugs 0.000 claims description 14
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 13
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 13
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims description 12
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 claims description 12
- HCRBXQFHJMCTLF-UHFFFAOYSA-N ethyl 2-methylbutyrate Chemical compound CCOC(=O)C(C)CC HCRBXQFHJMCTLF-UHFFFAOYSA-N 0.000 claims description 11
- 239000001813 ethyl (2R)-2-methylbutanoate Substances 0.000 claims description 10
- 239000001449 ethyl (2R)-2-methylpentanoate Substances 0.000 claims description 9
- 150000001768 cations Chemical group 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 235000019645 odor Nutrition 0.000 description 37
- 241000220225 Malus Species 0.000 description 17
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 description 15
- 239000002537 cosmetic Substances 0.000 description 10
- 230000000873 masking effect Effects 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- -1 aliphatic aldehyde Chemical class 0.000 description 3
- 229960000956 coumarin Drugs 0.000 description 3
- 235000001671 coumarin Nutrition 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000021016 apples Nutrition 0.000 description 2
- 229920006319 cationized starch Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000003676 hair preparation Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 2
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 2
- 239000000213 tara gum Substances 0.000 description 2
- 235000010491 tara gum Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 description 2
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 description 1
- NNOKXWHHOOMPPR-UHFFFAOYSA-N 1-ethenyl-1h-imidazol-1-ium;trichloride Chemical compound [Cl-].[Cl-].[Cl-].C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1 NNOKXWHHOOMPPR-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-BYPYZUCNSA-N 2-Methylbutanoic acid Natural products CC[C@H](C)C(O)=O WLAMNBDJUVNPJU-BYPYZUCNSA-N 0.000 description 1
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000000731 Fagus sylvatica Species 0.000 description 1
- 235000010099 Fagus sylvatica Nutrition 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241000219492 Quercus Species 0.000 description 1
- 235000016976 Quercus macrolepis Nutrition 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- GXANMBISFKBPEX-ARJAWSKDSA-N cis-3-hexenal Chemical compound CC\C=C/CC=O GXANMBISFKBPEX-ARJAWSKDSA-N 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- PHXATPHONSXBIL-JTQLQIEISA-N gamma-Undecalactone Natural products CCCCCCC[C@H]1CCC(=O)O1 PHXATPHONSXBIL-JTQLQIEISA-N 0.000 description 1
- 229940020436 gamma-undecalactone Drugs 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002969 pentanoic acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Description
本発明はカチオン基を有する高分子化合物の基剤臭が改善された組成物に関し、好ましくは該カチオン基を有する高分子化合物がカチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物及びこれらの誘導体からなる群から選択される高分子化合物であり、さらに好ましくはカチオン基を有する高分子化合物が、カチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物及びこれらの誘導体からなる群から選択される高分子化合物である組成物に関し、これらの組成物を化粧品組成物とするものに関する。さらに、本発明はカチオン基を有する高分子化合物グアーガムの基剤臭を改善する方法に関するものである。 The present invention relates to a composition in which the base odor of a polymer compound having a cationic group is improved, and preferably the polymer compound having a cationic group is a cationized guar gum, a diallyldialkyl quaternary ammonium salt / acrylamide copolymer and these. The polymer compound selected from the group consisting of derivatives of the above, and more preferably the polymer compound having a cationic group consists of a cationized guar gum, a diallyldialkyl quaternary ammonium salt / acrylamide copolymer and a group consisting of derivatives thereof. With respect to the compositions which are selected polymer compounds, those which make these compositions cosmetic compositions. Furthermore, the present invention relates to a method for improving the base odor of a polymer compound guar gum having a cationic group.
カチオン基を有する高分子化合物は、高分子化合物を４級アンモニウム化することにより得られるカチオン化ポリマーであり、化粧品においてはシャンプー、リンス、ヘアトリートメント等の毛髪化粧料にコンディショニング成分として好適に配合される成分である（特許文献１−３）。ここで、カチオン基を有する高分子化合物は構造中の４級アンモニウムに起因するアミン臭を有するため、各種製品として製造する際には香料等を用い該臭気をマスキングすることが行われている。 The polymer compound having a cation group is a cationized polymer obtained by quaternary ammonium conversion of the polymer compound, and is suitably blended as a conditioning component in hair cosmetics such as shampoos, rinses and hair treatments in cosmetics. (Patent Document 1-3). Here, since the polymer compound having a cationic group has an amine odor due to quaternary ammonium in the structure, the odor is masked by using a fragrance or the like when produced as various products.
また、化粧品等の分野において、製品を製造する際に好ましくない臭気を様々な香料を用いてマスキングすることは汎用の技術である（特許文献４−６、非特許文献１−２）。 Further, in the field of cosmetics and the like, masking an unfavorable odor with various fragrances when manufacturing a product is a general-purpose technique (Patent Documents 4-6, Non-Patent Documents 1-2).
しかしながら、従来のマスキングの場合にはカチオン基を有する高分子化合物と用いる香料が相互に影響し合うため、香料本来の香気もカチオン基を有する高分子化合物の臭気の影響を受け、所望の香調の製品を調製するのが困難になる（マッチング力不足）という課題が存在し、カチオン基を有する高分子化合物が有するアミン臭等の臭気をマスキングしつつ所望の香調を得られる香料の組み合わせが望まれていた。 However, in the case of conventional masking, since the polymer compound having a cationic group and the fragrance used interact with each other, the original fragrance of the fragrance is also affected by the odor of the polymer compound having a cationic group, and a desired fragrance tone is obtained. There is a problem that it becomes difficult to prepare the product of (insufficient matching power), and a combination of fragrances that can obtain a desired fragrance tone while masking the odor such as amine odor of the polymer compound having a cationic group is available. It was desired.
本発明の課題は、カチオン基を有する高分子化合物に起因する基剤臭が改善された組成物、及びカチオン基を有する高分子化合物の基剤臭改善方法を提供することである。 An object of the present invention is to provide a composition having an improved base odor caused by a polymer compound having a cationic group, and a method for improving the base odor of a polymer compound having a cationic group.
本発明者らがこれらの問題を解決するため、カチオン基を有する高分子化合物と様々な香料の組み合わせを検討した結果、（Ａ）カチオン基を有する高分子化合物と、（Ｂ）２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オンから選択される香料を組み合せた場合に優れたマスキング効果及びマッチング効果が得られることを見いだし、本発明を完成した。 As a result of investigating combinations of a polymer compound having a cationic group and various fragrances in order to solve these problems, the present inventors have found that (A) a polymer compound having a cationic group and (B) 2-methylpentane. Excellent masking effect and matching effect can be obtained when a fragrance selected from ethyl acid acid, apple base, cis-3-hexenol, undecanal, ethyl 2-methylbutanoate, and 3-chromen-2-one is combined. I found it and completed the present invention.
本発明は、（Ａ）カチオン基を有する高分子化合物、及び（Ｂ）２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オンから選択される１種以上の香料を含有してなる組成物に関するものであり、更にはカチオン基を有する高分子化合物がカチオン化グァーガム及びその誘導体、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物及びその誘導体からなる群から選択される高分子化合物である組成物、及びカチオン基を有する高分子化合物が、グアーヒドロキシプロピルトリモニウムクロリド、ポリクオタニウム−７からなる群から選択される高分子化合物である前記組成物、詳しくはこれらが化粧品組成物であるものに関する。また、本発明は（Ａ）カチオン基を有する高分子化合物を含有する組成物に、（Ｂ）２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オンから選択される１種以上の香料を配合することによりカチオン基を有する高分子化合物の基剤臭を改善する方法に関するものである。 The present invention relates to (A) a polymer compound having a cationic group, and (B) ethyl 2-methylpentanoate, apple base, cis-3-hexenol, undecal, ethyl 2-methylbutanoate, 3-chromen-2-. It relates to a composition containing one or more fragrances selected from on, and further, a polymer compound having a cation group is a cationized guar gum and a derivative thereof, a diallyldialkyl quaternary ammonium salt / acrylamide copolymer. The composition which is a polymer compound selected from the group consisting of and its derivatives, and the polymer compound having a cationic group is a polymer compound selected from the group consisting of guarhydroxypropyltrimonium chloride and polyquaternium-7. The compositions, more particularly those which are cosmetic compositions. Further, in the present invention, (A) a composition containing a polymer compound having a cationic group, (B) ethyl 2-methylpentaneate, apple base, cis-3-hexenol, undecal, ethyl 2-methylbutanoate, The present invention relates to a method for improving the base odor of a polymer compound having a cationic group by blending one or more fragrances selected from 3-chromen-2-one.
本発明の組成物は、カチオン基を有する高分子化合物に起因する基剤臭が改善された組成物であり、香料本来の匂いが損なわれないため各種製品として用いる場合に所望の香調に調製することが容易となる。 The composition of the present invention is a composition in which the base odor caused by the polymer compound having a cationic group is improved, and the original odor of the fragrance is not impaired. It becomes easy to do.
本発明で用いる（Ａ）カチオン基を有する高分子化合物は構造中にカチオン基を有する高分子化合物である。カチオン基を有する高分子化合物としてはカチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物、カチオン化セルロース、カチオン化澱粉、カチオン化キサンタンガム、カチオン化タラガム、カチオン化ローカストビーンガム、カチオン化フェヌグリークガム、ビニルイミダゾリウムトリクロライド／ビニルピロリドン共重合体、ヒドロキシエチルセルロース／ジメチルジアリルアンモニウムクロライド共重合体、ビニルピロリドン／四級化ジメチルアミノエチルメタクリレート共重合体、ポリビニルピロリドン／アルキルアミノアクリレート共重合体、ポリビニルピロリドン／アルキルアミノアクリレート／ビニルカプロラクタム共重合体、アルキルアクリルアミド／アクリレート／アルキルアミノアルキルアクリルアミド／ポリエチレングリコールメタクリレート共重合体等のカチオン性ポリマー等及びこれらの誘導体を用いることができ、カチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物、カチオン化セルロース、カチオン化澱粉、カチオン化キサンタンガム、カチオン化タラガム及びこれらの誘導体を用いることが好ましく、特にカチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物又はこれらの誘導体を用いることが好ましい。本発明において用いるカチオン基を有する高分子化合物は特に制限されるものではなく、例えばカチナールＣＧ−１００Ｓ、カチナールＣＧ−１００、カチナールＣＬＢ−１００等のカチナールシリーズ（いずれも東邦化学工業株式会社製）や、マーコート５５０、マーコート２９５等のマーコートシリーズ（いずれもナルコ社製）を用いることができ、更には公知の方法に基づき製造したものを用いてもよい。 The polymer compound having a cationic group (A) used in the present invention is a polymer compound having a cationic group in the structure. Polymer compounds with a cation group include cationized guar gum, diallyldialkyl quaternary ammonium salt / acrylamide copolymer, cationized cellulose, cationized starch, cationized xanthan gum, cationized tara gum, cationized locust bean gum, and cationized phenuglique. Gum, vinyl imidazolium trichloride / vinylpyrrolidone copolymer, hydroxyethyl cellulose / dimethyldialylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone / alkylaminoacrylate copolymer, polyvinyl Cationic polymers such as pyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, alkylacrylamide / acrylate / alkylaminoalkylacrylamide / polyethylene glycol methacrylate copolymer and derivatives thereof can be used, and cationized guar gum and diallyldialkyl can be used. It is preferable to use a quaternary ammonium salt / acrylamide copolymer, cationized cellulose, cationized starch, cationized xanthan gum, cationized tara gum and derivatives thereof, particularly cationized guar gum, diallyldialkyl quaternary ammonium salt / acrylamide copolymer. It is preferable to use a product or a derivative thereof. The polymer compound having a cationic group used in the present invention is not particularly limited, and for example, Katinal series such as Katinal CG-100S, Katinal CG-100, and Katinal CLB-100 (all manufactured by Toho Chemical Industry Co., Ltd.). , Marcourt series such as Marcourt 550 and Marcourt 295 (all manufactured by Narco) can be used, and further, those manufactured based on a known method may be used.
成分（Ａ）として用いるカチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物及びこれらの誘導体としては、各種原料を４級アンモニウム化することで得られるアミン臭を有するカチオン化ポリマーであればよく、その由来は特に限定されない。カチオン化グアーガム誘導体としては、例えばカチナールＣＧ−１００Ｓ、カチナールＣＧ−１００（いずれも東邦化学工業株式会社製）等、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物としてはマーコート５５０、マーコート２９５等のマーコートシリーズ（いずれもナルコ社製）等を用いることができ、更には公知の方法に基づき製造したものを用いてもよい。カチオン化グアーガム誘導体としてはグアーヒドロキシプロピルトリモニウムクロリド、ヒドロキシプロピルグアーヒドロキシプロピルトリモニウムクロリド等を用いることができ、グアーヒドロキシプロピルトリモニウムクロリドが好ましい。また、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物誘導体としては、ポリクオタニウム−７、ポリクオタニウム−２２等を用いることができ、ポリクオタニウム−７が好ましい。カチオン化グアーガム誘導体及びジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物誘導体は、シャンプーやコンディショナーに配合した場合には毛髪の感触、光沢、まとめ易さ、櫛通り等を改善し、スキンケア製品に配合した場合には皮膚の柔軟効果、保水効果、ｐＨ緩衝効果、ケラチン損傷抑制効果等を改善することが知られている。 The cationized guar gum, diallyldialkyl quaternary ammonium salt / acrylamide copolymer and derivatives thereof used as the component (A) may be any cationized polymer having an amine odor obtained by quaternary ammonium conversion of various raw materials. Often, its origin is not particularly limited. Examples of cationized guar gum derivatives include Katinal CG-100S and Katinal CG-100 (both manufactured by Toho Kagaku Kogyo Co., Ltd.), and diallyldialkyl quaternary ammonium salt / acrylamide copolymers include Marcoat 550 and Marcoat 295. A series (all manufactured by Narco) or the like can be used, and further, those manufactured based on a known method may be used. As the cationized guar gum derivative, guar-hydroxypropyltrimonium chloride, hydroxypropylgua-hydroxypropyltrimonium chloride and the like can be used, and guarhydroxypropyltrimonium chloride is preferable. Further, as the diallyldialkyl quaternary ammonium salt / acrylamide copolymer derivative, polyquaternium-7, polyquaternium-22 and the like can be used, and polyquaternium-7 is preferable. Cated guar gum derivatives and diallyl dialkyl quaternary ammonium salt / acrylamide copolymer derivatives were added to skin care products to improve the feel, luster, ease of grouping, combing, etc. of hair when blended in shampoos and conditioners. In some cases, it is known to improve skin softening effect, water retention effect, pH buffering effect, keratin damage suppressing effect and the like.
本発明の組成物における成分（Ａ）の配合量は特に限定されるものではないが、組成物中に０．００１％〜１０質量％、好ましくは０．００５〜５質量％、更には０．０１〜５質量％含有することが好ましい。 The blending amount of the component (A) in the composition of the present invention is not particularly limited, but 0.001% to 10% by mass, preferably 0.005 to 5% by mass, and further 0. It is preferably contained in an amount of 01 to 5% by mass.
本発明の組成物は、（Ｂ）２−メチルペンタン酸エチル（マンザネート）、アップルベース（APPLE OLIFAC S PCMF：International Flavors & Fragrances社製等）、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オン（クマリン）から選択される香料を用いるものであり、好ましくは２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチルから選択される香料を用いるものであり、更に好ましくは２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、２−メチルブタン酸エチルから選択される香料を用いるものである。 The compositions of the present invention include (B) ethyl 2-methylpentanoate (manzanate), apple base (APPLE OLIFAC S PCMF: manufactured by International Flavors & Fragrances, etc.), cis-3-hexenol, undecanal, 2-methylbutanoic acid. It uses a fragrance selected from ethyl, 3-chromen-2-one (coumarin), preferably from ethyl 2-methylpentanoate, apple base, cis-3-hexenol, undecanal, ethyl 2-methylbutanoate. A fragrance of choice is used, more preferably a fragrance selected from ethyl 2-methylpentanoate, apple base, cis-3-hexenol, ethyl 2-methylbutanoate.
以下、成分（Ｂ）として用いられる各成分について詳述する。２−メチルペンタン酸エチル（ＣＡＳ番号：39255-32-8）は吉草酸エステルの一種であり、リンゴの芳香に似た臭気を有する化合物である。アップルベースはリンゴの芳香を再現した代替物であり、ｃｉｓ−３−ヘキセノール、２−メチルペンタン酸エチル、γ−ウンデカラクトン等の香料から構成される香料である。アップルベースとしてはAPPLE OLIFAC S PCMF（製品名。International Flavors & Fragrances社製）等を用いることができ、リンゴの香調を有する香料であれば特に制限されるものではない。ｃｉｓ−３−ヘキセノール（ＣＡＳ番号：6789-80-6）は青葉アルデヒドとも呼ばれる脂肪族アルデヒドの一種であり、草や葉の匂いの主要な成分として天然にはホウレンソウやクローバー、ブナ、クリ、カシの葉や生の茶葉等の植物に含まれることが知られている。ウンデカナール（ＣＡＳ番号：112-44-7）は、バラに似た芳香を有する脂肪族アルデヒドの一種であり、天然にはオレンジ、レモン等の果皮に含まれることが知られている。２−メチルブタン酸エチル（ＣＡＳ番号：7452-79-1）は甘く、フルーティーな香気特徴を有する化合物であり、デリシャスリンゴの特徴香気成分として知られている。３−クロメン−２−オン（ＣＡＳ番号：91-64-5）はバニラに似た芳香があり、苦く、芳香性の刺激的な味を有する化合物であり、桜湯や天然のオオシマザクラの塩蔵葉を用いた桜餅の香りとして知られている。 Hereinafter, each component used as the component (B) will be described in detail. Ethyl 2-methylpentanoate (CAS No .: 39255-32-8) is a type of valeric acid ester and is a compound having an odor similar to the aroma of apples. Apple base is a substitute that reproduces the aroma of apple, and is a fragrance composed of fragrances such as cis-3-hexenol, ethyl 2-methylpentaneate, and γ-undecalactone. APPLE OLIFAC S PCMF (product name; manufactured by International Flavors & Fragrances) or the like can be used as the apple base, and is not particularly limited as long as it is a fragrance having an apple scent. cis-3-hexenol (CAS number: 6789-80-6) is a type of aliphatic aldehyde, also called green leaf aldehyde, and is naturally a major component of grass and leaf odors such as spinach, clover, beech, chestnut, and oak. It is known to be contained in plants such as leaves and raw tea leaves. Undecanal (CAS No .: 112-44-7) is a kind of aliphatic aldehyde having a rose-like aroma, and is known to be naturally contained in the peels of oranges, lemons and the like. Ethyl 2-methylbutanoate (CAS No .: 7452-79-1) is a compound having a sweet and fruity aroma characteristic, and is known as a characteristic aroma component of Delicious apples. 3-Chromen-2-one (CAS No .: 91-64-5) is a compound with a vanilla-like aroma, a bitter taste, and a pungent aroma. It is known as the scent of Sakuramochi used.
成分（Ｂ）は単独又は２種以上を組み合せて使用することができ、本発明の組成物における配合量は限定されるものではないが、組成物中に０．００００１質量％〜１０質量％、好ましくは０．００１〜５質量％、更には０．０１〜３質量％含有することが好ましい。 The component (B) can be used alone or in combination of two or more, and the blending amount in the composition of the present invention is not limited, but 0.00001% by mass to 10% by mass in the composition. It is preferably contained in an amount of 0.001 to 5% by mass, more preferably 0.01 to 3% by mass.
本発明の組成物において、成分（Ａ）と成分（Ｂ）の質量比は特に限定されるものではないが、成分（Ａ）：成分（Ｂ）の質量比として０．０００１：１〜１：０００１であれば良く、好ましくは０．００１：１〜１：０．００１であり、更に好ましくは０．００５：１〜１：０．００５の範囲である。 In the composition of the present invention, the mass ratio of the component (A) to the component (B) is not particularly limited, but the mass ratio of the component (A): the component (B) is 0.0001: 1 to 1: It may be 0001, preferably 0.001: 1 to 1: 0.001, and more preferably 0.005: 1 to 1: 0.005.
本発明の組成物は、毛髪化粧料、皮膚化粧料、トイレタリー製品等として用いることができる。毛髪化粧料としては、シャンプー等の毛髪洗浄剤、リンス、コンディショナー、スタイリング剤等を挙げることができ、皮膚化粧料としては洗顔料、ボディシャンプー等の身体洗浄剤、メイク製品、フェイスケア製品、ボディケア製品等を挙げることができる。本発明の組成物の剤型としては好ましくは毛髪化粧料、皮膚化粧料であり、好ましくは毛髪洗浄剤、洗顔料、ボディシャンプーである。 The composition of the present invention can be used as a hair cosmetic, a skin cosmetic, a toiletry product and the like. Examples of hair cosmetics include hair cleansers such as shampoos, rinses, conditioners, and styling agents. Examples of skin cosmetics include facial cleansers, body cleansers such as body shampoos, makeup products, face care products, and bodies. Care products and the like can be mentioned. The dosage form of the composition of the present invention is preferably a hair cosmetic or a skin cosmetic, and preferably a hair cleanser, a facial cleanser or a body shampoo.
本発明の組成物は所望の剤型に応じて公知の製造技術、処方に基づき製造することができ、必要に応じて界面活性剤、油脂類、炭化水素類、ロウ類、高分子化合物、粘度調整剤、防腐剤、キレート剤、安定化剤、顔料、成分（Ｂ）以外の香料等の成分を配合することができる。 The composition of the present invention can be produced based on known production techniques and formulations according to a desired dosage form, and if necessary, surfactants, fats and oils, hydrocarbons, braces, polymer compounds, and viscosities. Ingredients such as modifiers, preservatives, chelating agents, stabilizers, pigments, and fragrances other than the ingredient (B) can be blended.
以下に、実施例により本発明をさらに詳細に説明する。なお、本発明はこれにより限定されるものではない。 Hereinafter, the present invention will be described in more detail by way of examples. The present invention is not limited thereto.
（実施例１）試料の調製
以下の処方例に記載の配合量で各原料を混合し、ボディーソープＩを調製した。香料としては表１及び表２に記載の各香料を配合した。以下の実施例２及び３の結果において、各試料を調製後室温で１週間保存したものをＲＴ、４０℃で６ヶ月保存したものを加速試験として記載する。また、カチオン基を有する高分子化合物としてカチナールＣＧ−１００Ｓを、３−クロメン−２−オンとしてクマリンを、２−メチルペンタン酸エチルとしてマンザネートを用いた。また、香料を添加しないボディーソープを作成し各評価の基準品（各評価における１点の品）とした。
処方例 ボディソープＩ
ラウリン酸カリウム １０質量％
ミリスチン酸カリウム １０質量％
パルミチン酸カリウム ５質量％
ココイルグルタミン酸ナトリウム ２質量％
ココイルトレオニンナトリウム ２質量％
カチナールＣＧ−１００Ｓ ０．２質量％
塩化ナトリウム ０．２質量％
塩化カリウム ０．３質量％
香料 ０．１質量％
純水 残余
(Example 1) Preparation of sample Each raw material was mixed in the blending amount described in the following formulation example to prepare body soap I. As the fragrance, each fragrance shown in Tables 1 and 2 was blended. In the results of Examples 2 and 3 below, the sample prepared and stored at room temperature for 1 week is described as RT, and the sample stored at 40 ° C. for 6 months is described as an accelerated test. In addition, Katinal CG-100S was used as the polymer compound having a cation group, coumarin was used as 3-chromen-2-one, and manzanate was used as ethyl 2-methylpentaneate. In addition, a body soap to which no fragrance was added was prepared and used as a reference product for each evaluation (one product in each evaluation).
Prescription example Body soap I
Potassium laurate 10% by mass
Potassium myristate 10% by mass
Potassium palmitate 5% by mass
Sodium cocoyl glutamate 2% by mass
Cocoylthreonine sodium 2% by mass
Katinal CG-100S 0.2% by mass
Sodium chloride 0.2% by mass
Potassium chloride 0.3% by mass
Fragrance 0.1% by mass
Pure water residue
（実施例２）マスキング力試験
パネラー１０人により以下の評価基準に基づき、各香料のマスキング力の評価を行った。
１点：非常に強く基剤臭が感じられる。
２点：強く基剤臭が感じられる。
３点：基剤臭が感じられる。
４点：基剤臭が微かに感じられる。
５点：全く基剤臭が感じられない。
(Example 2) Masking power test The masking power of each fragrance was evaluated by 10 panelists based on the following evaluation criteria.
1 point: Very strong base odor is felt.
2 points: A strong base odor is felt.
3 points: A base odor is felt.
4 points: A faint base odor is felt.
5 points: No base odor is felt.
マスキング力試験の結果を表１に示す。
（実施例３）マッチング力試験
パネラー１０人により以下の評価基準に基づき、各香料のマッチング力の評価を行った。
１点：基剤臭と香料の匂いが容易に独立して感じられる。
２点：集中すると基剤臭と香料の匂いが独立して感じられる。
３点：基剤臭が感じられないが、香料の匂いが変化して感じられる。
４点：基剤臭が感じられないが、香料の匂いが少し変化して感じられる。
５点：基剤臭が感じられず、香料本来の匂いが損なわれていない。
(Example 3) Matching ability test Ten panelists evaluated the matching ability of each fragrance based on the following evaluation criteria.
1 point: The odor of the base and the odor of the fragrance can be easily felt independently.
2 points: When concentrated, the base odor and the fragrance odor can be felt independently.
3 points: The odor of the base is not felt, but the scent of the fragrance changes.
4 points: The odor of the base is not felt, but the scent of the fragrance is slightly changed.
5 points: No base odor is felt, and the original fragrance odor is not impaired.
マッチング試験の結果を表２に示す。
表１及び表２に記載の結果から、２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オンから選ばれる香料群は、調製後室温で１週間保存した場合及び４０℃で６ヶ月保存した加速試験のいずれにおいても、カチオン化グアーガムが有するアミン臭等の基剤臭を良好にマスキングできるのみならず、香料本来の匂いを損なわないマッチング力に優れることが確認された。 From the results shown in Tables 1 and 2, the fragrance group selected from ethyl 2-methylpentanoate, apple base, cis-3-hexenol, undecanal, ethyl 2-methylbutanoate, and 3-chromen-2-one was selected. In both the accelerated test stored at room temperature for 1 week after preparation and the accelerated test stored at 40 ° C. for 6 months, not only can the base odor such as amine odor of cationized guar gum be well masked, but also the original fragrance odor can be preserved. It was confirmed that it has excellent matching power that does not impair.
（実施例４）処方例
以下の処方例に記載の配合量で各原料を混合し、ボディーソープＩＩを調製した。香料としては表１及び表２に記載の各香料を配合した。また、カチオン基を有する高分子化合物としてポリクオタニウム−７を、３−クロメン−２−オンとしてクマリンを、２−メチルペンタン酸エチルとしてマンザネートを用いた。
処方例 ボディソープＩＩ
ラウリン酸カリウム １０質量％
ミリスチン酸カリウム １０質量％
パルミチン酸カリウム ５質量％
ココイルグルタミン酸ナトリウム ２質量％
ココイルトレオニンナトリウム ２質量％
ポリクオタニウム−７ ５質量％
塩化ナトリウム ０．２質量％
塩化カリウム ０．３質量％
香料 ０．１質量％
純水 残余
(Example 4) Formulation example Each raw material was mixed in the blending amount described in the following formulation example to prepare Body Soap II. As the fragrance, each fragrance shown in Tables 1 and 2 was blended. In addition, polyquaternium-7 was used as the polymer compound having a cation group, coumarin was used as 3-chromen-2-one, and manzanate was used as ethyl 2-methylpentanoate.
Prescription example Body soap II
Potassium laurate 10% by mass
Potassium myristate 10% by mass
Potassium palmitate 5% by mass
Sodium cocoyl glutamate 2% by mass
Cocoylthreonine sodium 2% by mass
Polyquaternium-7 5% by mass
Sodium chloride 0.2% by mass
Potassium chloride 0.3% by mass
Fragrance 0.1% by mass
Pure water residue
ボディソープＩＩの処方においても、２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オンから選ばれる香料群は、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物が有するアミン臭等の基剤臭を良好にマスキングできるのみならず、香料本来の匂いを損なわないマッチング力に優れることが確認された。 In the formulation of Body Soap II, the fragrance group selected from ethyl 2-methylpentanoate, apple base, cis-3-hexenol, undecanal, ethyl 2-methylbutanoate, and 3-chromen-2-one is diallyldialkylquaternary. It was confirmed that not only can the base odor such as the amine odor of the quaternary ammonium salt / acrylamide copolymer be masked well, but also the matching ability that does not impair the original odor of the fragrance is excellent.
以上のことから、２−メチルペンタン酸エチル、アップルベース、ｃｉｓ−３−ヘキセノール、ウンデカナール、２−メチルブタン酸エチル、３−クロメン−２−オンから選ばれる香料群は、カチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物のようなカチオン基を有する高分子化合物のマスキング力、マッチング力に優れることが確認された。 Based on the above, the fragrance group selected from ethyl 2-methylpentanoate, apple base, cis-3-hexenol, undecanal, ethyl 2-methylbutanoate, and 3-chromen-2-one is cationized guar gum and diallyldialkyl. It was confirmed that the polymer compound having a cationic group such as a quaternary ammonium salt / acrylamide copolymer has excellent masking power and matching power.
本発明により、カチオン基を有する高分子化合物に起因する基剤臭が改善された組成物、及びカチオン基を有する高分子化合物に起因する基剤臭の改善方法が提供される。
The present invention provides a composition in which the base odor caused by a polymer compound having a cationic group is improved, and a method for improving the base odor caused by a polymer compound having a cationic group.
Claims (1)
（Ａ）カチオン化グアーガム、ジアリルジアルキル四級アンモニウム塩／アクリルアミド共重合物及びこれらの誘導体からなる群から選択される１種以上のカチオン基を有する高分子化合物(A) Polymer compound having one or more cation groups selected from the group consisting of cationized guar gum, diallyldialkyl quaternary ammonium salt / acrylamide copolymers and derivatives thereof.
（Ｂ）２−メチルペンタン酸エチル、ｃｉｓ−３−ヘキセノール、２−メチルブタン酸エチル、３−クロメン−２−オンからなる群から選択される１種以上の香料(B) One or more fragrances selected from the group consisting of ethyl 2-methylpentanoate, cis-3-hexenol, ethyl 2-methylbutanoate, and 3-chromen-2-one.
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| JPH02242899A (en) * | 1989-03-15 | 1990-09-27 | Lion Corp | Aroma-retaining composition |
| JP3186037B2 (en) * | 1995-05-09 | 2001-07-11 | 花王株式会社 | Masking fragrance composition for tertiary amine compound and amine catalyst composition for polyurethane production |
| US6126930A (en) * | 1997-02-13 | 2000-10-03 | The Procter & Gamble Company | Spray compositions |
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