JP6836554B2 - White tea-like fragrance composition for cosmetics - Google Patents
White tea-like fragrance composition for cosmetics Download PDFInfo
- Publication number
- JP6836554B2 JP6836554B2 JP2018133262A JP2018133262A JP6836554B2 JP 6836554 B2 JP6836554 B2 JP 6836554B2 JP 2018133262 A JP2018133262 A JP 2018133262A JP 2018133262 A JP2018133262 A JP 2018133262A JP 6836554 B2 JP6836554 B2 JP 6836554B2
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- JP
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- Prior art keywords
- mass
- white tea
- fragrance composition
- less
- fragrance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003205 fragrance Substances 0.000 title claims description 91
- 239000000203 mixture Substances 0.000 title claims description 71
- 239000002537 cosmetic Substances 0.000 title claims description 48
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 17
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims description 16
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims description 10
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 8
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 8
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 claims description 8
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims description 8
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims description 8
- 229930007744 linalool Natural products 0.000 claims description 8
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 claims description 5
- FQTLCLSUCSAZDY-SDNWHVSQSA-N (6E)-nerolidol Chemical compound CC(C)=CCC\C(C)=C\CCC(C)(O)C=C FQTLCLSUCSAZDY-SDNWHVSQSA-N 0.000 claims 1
- 235000020334 white tea Nutrition 0.000 description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 239000002304 perfume Substances 0.000 description 14
- -1 body cleansers Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 239000008213 purified water Substances 0.000 description 9
- 235000013616 tea Nutrition 0.000 description 9
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 244000269722 Thea sinensis Species 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 6
- 230000003749 cleanliness Effects 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000003599 detergent Substances 0.000 description 5
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 description 4
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- 239000005792 Geraniol Substances 0.000 description 4
- XMLSXPIVAXONDL-PLNGDYQASA-N Jasmone Chemical compound CC\C=C/CC1=C(C)CCC1=O XMLSXPIVAXONDL-PLNGDYQASA-N 0.000 description 4
- FQTLCLSUCSAZDY-ATGUSINASA-N Nerolidol Chemical compound CC(C)=CCC\C(C)=C\CC[C@](C)(O)C=C FQTLCLSUCSAZDY-ATGUSINASA-N 0.000 description 4
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000019634 flavors Nutrition 0.000 description 4
- 229940113087 geraniol Drugs 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- 235000006468 Thea sinensis Nutrition 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000002453 shampoo Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000001278 2-(5-ethenyl-5-methyloxolan-2-yl)propan-2-ol Substances 0.000 description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 241000402754 Erythranthe moschata Species 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- BRHDDEIRQPDPMG-UHFFFAOYSA-N Linalyl oxide Chemical compound CC(C)(O)C1CCC(C)(C=C)O1 BRHDDEIRQPDPMG-UHFFFAOYSA-N 0.000 description 2
- 239000004909 Moisturizer Substances 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000002386 air freshener Substances 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 2
- 230000001333 moisturizer Effects 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 235000020333 oolong tea Nutrition 0.000 description 2
- 235000019629 palatability Nutrition 0.000 description 2
- 229940067107 phenylethyl alcohol Drugs 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- YPZUZOLGGMJZJO-XRGAULLZSA-N (3as,5as,9as,9br)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1h-benzo[e][1]benzofuran Chemical compound CC([C@@H]1CC2)(C)CCC[C@]1(C)[C@@H]1[C@@]2(C)OCC1 YPZUZOLGGMJZJO-XRGAULLZSA-N 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- QWOZZTWBWQMEPD-UHFFFAOYSA-N 1-(2-ethoxypropoxy)propan-2-ol Chemical compound CCOC(C)COCC(C)O QWOZZTWBWQMEPD-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 description 1
- JAUFWPNLLLUYNV-UHFFFAOYSA-N 3-(16-methylheptadecoxy)propane-1,2-diol Chemical compound CC(C)CCCCCCCCCCCCCCCOCC(O)CO JAUFWPNLLLUYNV-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ZXGMMHMAGOAFGQ-UHFFFAOYSA-N 6-methyl-3-oxa-13-azatetracyclo[7.7.1.02,7.013,17]heptadeca-1(17),2(7),8-trien-4-one Chemical compound C1CCN2CCCC3=C2C1=C1OC(=O)CC(C)C1=C3 ZXGMMHMAGOAFGQ-UHFFFAOYSA-N 0.000 description 1
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 235000017763 Leptospermum ericoides Nutrition 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000745768 Pluchea carolinensis Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 235000002911 Salvia sclarea Nutrition 0.000 description 1
- 244000182022 Salvia sclarea Species 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- QVFOGJXHRGAFSH-UHFFFAOYSA-N acetic acid;1-dodecoxydodecane Chemical compound CC(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC QVFOGJXHRGAFSH-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 1
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- TUMGCEIAYMZKEM-UHFFFAOYSA-N benzyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC1=CC=CC=C1 TUMGCEIAYMZKEM-UHFFFAOYSA-N 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 235000020279 black tea Nutrition 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 229940031769 diisobutyl adipate Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000019225 fermented tea Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 229940053080 isosol Drugs 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000002324 mouth wash Substances 0.000 description 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 1
- BOPPSUHPZARXTH-UHFFFAOYSA-N ocean propanal Chemical compound O=CC(C)CC1=CC=C2OCOC2=C1 BOPPSUHPZARXTH-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Description
本発明は、香粧品用白茶様香料組成物に関する。 The present invention relates to a white tea-like fragrance composition for cosmetics.
白茶は、中国6大茶類の一つに分類される微発酵茶である。白茶は殺青(加熱して酵素を失活させる工程)や揉捻(揉み込む工程)を行うことなく、萎凋によって酸化発酵を進めるという単純な製法によって作られ、茶葉は白い産毛がそのまま残るため白い外観をしており、上品で爽やかな甘い香り、味わいを有する。白茶の中でも白毫銀針は大白茶樹から一芯一葉で摘んで製品としたもので、古来最も代表的かつ最上位のものとされている。 White tea is a slightly fermented tea that is classified as one of the six major teas in China. White tea is made by a simple manufacturing method in which oxidative fermentation is promoted by wilting without performing blue killing (process of heating to inactivate enzymes) or kneading (process of kneading), and tea leaves have a white appearance because white hair remains as it is. It has an elegant and refreshing sweet scent and taste. Among the white teas, Baihao Yin needle is a product made by picking one core and one leaf from a large white tea tree, and has been regarded as the most representative and highest grade since ancient times.
従来、緑茶、紅茶、烏龍茶等の一般的な茶フレーバーについては広く研究されており(非特許文献1、2、特許文献1参照)、烏龍茶抽出液を従来の香料に代えて化粧品に配合することによって望ましくない皮膚臭を消し、爽やかな香気を生じさせる技術も知られている(特許文献2参照)。また、近年、お茶の香りのリラックス効果に注目して、お茶の香りを香粧品に採用した製品が数多く発売されており、最近では白茶の香りを採用した製品も出現してきている。 Conventionally, general tea flavors such as green tea, black tea, and oolong tea have been widely studied (see Non-Patent Documents 1, 2 and 1), and oolong tea extract is added to cosmetics in place of conventional fragrances. There is also known a technique for eliminating unwanted skin odors and producing a refreshing aroma (see Patent Document 2). In recent years, paying attention to the relaxing effect of the scent of tea, many products using the scent of tea for cosmetics have been put on the market, and recently, products using the scent of white tea have also appeared.
しかしながら、茶類のなかでも白茶の香気を特徴づける組成については未だ解明が進んでいない。また、現在流通している白茶系の香料や、これを配合した白茶の香りを有するとされる既存の香粧品はいずれも、未だ白茶本来の香気を有しているとは言い難いものであるとともに、香粧品として好適な清潔感のある香りを有するという点においても十分といえるものではなかった。 However, the composition that characterizes the aroma of white tea among teas has not yet been elucidated. In addition, it is hard to say that the white tea-based fragrances currently on the market and the existing cosmetics that are said to have the scent of white tea containing them still have the original scent of white tea. At the same time, it was not sufficient in that it had a clean scent suitable for cosmetics.
そこで本発明は、白茶、特に白毫銀芯の上品で爽やかな甘い香気の特徴を再現すると共に香粧品として好適な清潔感のある香りを有し、優れた嗜好性を有する香粧品用白茶様香料組成物に関する。 Therefore, the present invention reproduces the characteristics of white tea, particularly the elegant and refreshing sweet fragrance of white tea silver core, and has a clean fragrance suitable for cosmetics, and has excellent palatability. Regarding the composition.
本発明者は、白茶の香気成分について鋭意検討した結果、シス-ジャスモン、リナロール及びシス-3-ヘキセノールを一定量比で組合せることで白茶様の香気が得られること、更には、一般的に茶飲料の天然香気の組成中に多量に存在するインドールが、白茶本来の香り且つ香粧品として好適な清潔感のある香りを得るうえで障害となっていることを見いだし、本発明を完成させた。 As a result of diligent studies on the aroma components of white tea, the present inventor can obtain a white tea-like aroma by combining cis-jasmon, linalol and cis-3-hexenol in a fixed amount ratio, and more generally, We have found that a large amount of indole present in the composition of the natural aroma of tea beverages is an obstacle to obtaining the original aroma of white tea and a clean aroma suitable for cosmetics, and completed the present invention. ..
本発明は、下記成分(a)〜(c)を含有する香粧品用白茶様香料組成物であって、添加後の香粧品の総量に対し、成分(a)の含有量が0.05質量%以上、成分(c)の含有量が0.005質量%以上であり、香粧品用白茶様香料組成物中における、成分(a)〜(c)の合計量に対する成分(a)及び(c)の合計量の質量比[(a)+(c)]/[(a)+(b)+(c)]が0.3を超え0.85未満、成分(a)及び(c)の合計量に対する下記成分(f)の含有量の最大許容質量比が0.4である、香粧品用白茶様香料組成物を提供するものである。
(a) シス-ジャスモン
(b) リナロール
(c) シス-3-ヘキセノール
(f) インドール
The present invention is a white tea-like fragrance composition for cosmetics containing the following components (a) to (c), and the content of the component (a) is 0.05% by mass or more with respect to the total amount of the cosmetics after addition. , The content of the component (c) is 0.005% by mass or more, and the total amount of the components (a) and (c) with respect to the total amount of the components (a) to (c) in the white tea-like fragrance composition for cosmetics. The mass ratio [(a) + (c)] / [(a) + (b) + (c)] of is more than 0.3 and less than 0.85, and the following component (f) with respect to the total amount of components (a) and (c) Provided is a white tea-like fragrance composition for cosmetics, which has a maximum permissible mass ratio of 0.4.
(a) Sis-Jasmon
(b) Linalool
(c) cis-3-hexenol
(f) Indole
更に本発明は、上記の白茶様香料組成物を添加してなる香粧品を提供するものである。 Further, the present invention provides a cosmetic product to which the above-mentioned white tea-like fragrance composition is added.
本発明の白茶様香料組成物は、白茶、特に白毫銀芯の上品で爽やかな甘い香気の特徴を再現すると共に、香粧品として好適な清潔感のある香りを有し、香粧品の賦香に用いることで、嗜好性の高い白茶様香気を有する香粧品を製造することができる。 The white tea-like fragrance composition of the present invention reproduces the characteristics of the elegant and refreshing sweet fragrance of white tea, especially white tea silver core, and has a clean scent suitable for cosmetics, and is suitable for flavoring cosmetics. By using it, it is possible to produce a cosmetic product having a white tea-like fragrance with high palatability.
本発明の香粧品用白茶様香料組成物(以下、単に「本発明の香料組成物」という)は、広く香粧品の賦香のために使用され。香料化合物として、以下に示す成分(a)〜(c)のほか、好ましくは成分(d)及び(e)を含有するほか、一定条件下で、その他の香料化合物、及び溶媒(希釈剤)を含有し得る。 The white tea-like fragrance composition for cosmetics of the present invention (hereinafter, simply referred to as "fragrance composition of the present invention") is widely used for fragrance of cosmetics. As the fragrance compound, in addition to the components (a) to (c) shown below, preferably the components (d) and (e) are contained, and under certain conditions, other fragrance compounds and a solvent (diluent) are added. May contain.
〔成分(a):シス-ジャスモン、成分(b):リナロール、成分(c):シス-3-ヘキセノール〕
本発明の香料組成物は、香料化合物として成分(a)シス-ジャスモン、成分(b)リナロール及び成分(c)シス-3-ヘキセノールを含有する。成分(a)〜(c)はいずれも公知の化合物であり、公知の方法で製造することができる。
[Ingredient (a): cis-jasmonic acid, ingredient (b): linalool, ingredient (c): cis-3-hexenol]
The fragrance composition of the present invention contains the component (a) cis-jasmon, the component (b) linalool and the component (c) cis-3-hexenol as fragrance compounds. All of the components (a) to (c) are known compounds and can be produced by a known method.
本発明の香料組成物は成分(a)のシス-ジャスモンを含有し、その含有量は、柔らかくボリュームのある白茶らしい香気を再現する観点から、添加後の香粧品の総量を基準として、0.05質量%以上であって、好ましくは0.08質量%以上、より好ましくは0.1質量%以上、更に好ましくは0.12質量%以上であり、また、ケミカル感を抑制する観点から、好ましくは1.2質量%以下、より好ましくは1質量%以下、更に好ましくは0.8質量%以下である。 The fragrance composition of the present invention contains the component (a) cis-jasmon, and the content thereof is 0.05 mass based on the total amount of the added cosmetics from the viewpoint of reproducing a soft and voluminous white tea-like fragrance. % Or more, preferably 0.08% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.12% by mass or more, and preferably 1.2% by mass or less, more preferably from the viewpoint of suppressing the chemical feeling. Is 1% by mass or less, more preferably 0.8% by mass or less.
本発明の香料組成物は成分(b)のリナロールを含有し、その含有量は、安心感のある白茶らしい香気を再現する観点から、添加後の香粧品の総量を基準として、好ましくは0.005質量%以上、より好ましくは0.01質量%以上、更に好ましくは0.02質量%以上、更により好ましくは0.05質量%以上であり、また、白茶らしい香気が薄まるのを抑制する観点から、好ましくは0.8質量%以下、より好ましくは0.6質量%以下、更に好ましくは0.5質量%以下である。 The fragrance composition of the present invention contains the component (b), linalol, and the content thereof is preferably 0.005 mass based on the total amount of the added cosmetics from the viewpoint of reproducing a white tea-like fragrance with a sense of security. % Or more, more preferably 0.01% by mass or more, still more preferably 0.02% by mass or more, still more preferably 0.05% by mass or more, and preferably 0.8% by mass or less from the viewpoint of suppressing the fading of white tea-like aroma. , More preferably 0.6% by mass or less, still more preferably 0.5% by mass or less.
本発明の香料組成物は成分(c)のシス-3-ヘキセノールを含有し、その含有量は、添加後の香粧品を基準として、フレッシュ感のある白茶らしい香気を再現する観点から、添加後の香粧品の総量を基準として、0.005質量%以上であって、好ましくは0.01質量%以上、より好ましくは0.02質量%以上、更に好ましくは0.04質量%以上であり、また、青臭さを抑制する観点から、好ましくは0.6質量%以下、より好ましくは0.4質量%以下、更に好ましくは0.2質量%以下である。 The fragrance composition of the present invention contains the component (c) cis-3-hexenol, and the content thereof is based on the cosmetic product after the addition, from the viewpoint of reproducing a fresh white tea-like aroma after the addition. Based on the total amount of the cosmetics in the above, 0.005% by mass or more, preferably 0.01% by mass or more, more preferably 0.02% by mass or more, still more preferably 0.04% by mass or more, and from the viewpoint of suppressing the green odor. Therefore, it is preferably 0.6% by mass or less, more preferably 0.4% by mass or less, and further preferably 0.2% by mass or less.
本発明の香料組成物は、成分(a)のシス-ジャスモン、成分(b)のリナロール、成分(c)のシス-3-ヘキセノールの3成分を必須とするが、フレッシュ感のある白茶らしい香気を再現する観点から、これら3成分中における成分(a)と成分(c)の2成分の合計比率が一定範囲内であることを要する。具体的には、成分(a)〜(c)の合計量に対する成分(a)及び(c)の合計量の質量比[(a)+(c)]/[(a)+(b)+(c)]は、0.3を超え、好ましくは0.4以上、より好ましくは0.42以上、更に好ましくは0.45以上、更により好ましくは0.55以上、殊更に好ましくは0.65以上であり、また、0.85未満であって、好ましくは0.82以下、より好ましくは0.78以下、更に好ましくは0.75以下である。 The fragrance composition of the present invention requires three components, cis-jasmon of component (a), linalool of component (b), and cis-3-hexenol of component (c), but has a fresh white tea-like fragrance. From the viewpoint of reproducing the above, it is necessary that the total ratio of the two components of the component (a) and the component (c) in these three components is within a certain range. Specifically, the mass ratio of the total amount of the components (a) and (c) to the total amount of the components (a) to (c) [(a) + (c)] / [(a) + (b) + (c)] is more than 0.3, preferably 0.4 or more, more preferably 0.42 or more, still more preferably 0.45 or more, even more preferably 0.55 or more, particularly preferably 0.65 or more, and less than 0.85. It is preferably 0.82 or less, more preferably 0.78 or less, still more preferably 0.75 or less.
白茶らしい香りの強さの観点から、本発明の香料組成物中に含まれる香料化合物の総量に対する成分(a)〜(c)の合計量の質量比[(a)+(b)+(c)]/[香料化合物の総量]は、好ましくは0.2を超え、より好ましくは0.22以上、更に好ましくは0.25以上であり、更により好ましくは0.3以上である。 From the viewpoint of the intensity of white tea-like fragrance, the mass ratio of the total amount of the components (a) to (c) to the total amount of the fragrance compound contained in the fragrance composition of the present invention [(a) + (b) + (c) )] / [Total amount of fragrance compound] is preferably more than 0.2, more preferably 0.22 or more, still more preferably 0.25 or more, and even more preferably 0.3 or more.
ここで、「香料化合物」とは、香料組成物中に含まれる溶媒、その他の添加物等を除いた香料成分のみを指す。したがって、香料組成物中に上記溶媒や添加物に該当する化合物が含まれる場合には、香料組成物の総量からこれら溶媒及び添加物を除き、前記「香料化合物の総量」とする。 Here, the "fragrance compound" refers only to the fragrance component excluding the solvent and other additives contained in the fragrance composition. Therefore, when the fragrance composition contains a compound corresponding to the above solvent or additive, the total amount of the fragrance composition is defined as the "total amount of the fragrance compound" by removing these solvents and additives.
〔成分(d):ネロリドール、成分(e):ゲラニオール〕
また、本発明の香料組成物には、残香性を高めるため、更に成分(d)としてネロリドールを含有することが好ましい。添加後の香粧品の総量に対する成分(d)の含有量は、好ましくは0.005質量%以上、より好ましくは0.01質量%以上、更に好ましくは0.02質量%以上であり、また、好ましくは1質量%以下、より好ましくは0.5質量%以下、更に好ましくは0.4質量%以下、更により好ましくは0.2質量%以下である。
[Ingredient (d): nerolidol, ingredient (e): geraniol]
Further, the fragrance composition of the present invention preferably further contains nerolidol as the component (d) in order to enhance the residual fragrance. The content of the component (d) with respect to the total amount of the cosmetic after addition is preferably 0.005% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.02% by mass or more, and preferably 1% by mass or less. , More preferably 0.5% by mass or less, still more preferably 0.4% by mass or less, still more preferably 0.2% by mass or less.
また、成分(a)〜(c)の合計量に対する成分(d)の質量比(d)/[(a)+(b)+(c)]は、好ましくは0.005を超え、より好ましくは0.01を超え、更に好ましくは0.03を超え、更に好ましくは0.05以上、更により好ましくは0.08以上であり、また、好ましくは2.5以下、好ましくは0.5以下、より好ましくは0.45以下、更に好ましくは0.4以下である。 The mass ratio (d) / [(a) + (b) + (c)] of the component (d) to the total amount of the components (a) to (c) preferably exceeds 0.005, more preferably 0.01. More than, more preferably more than 0.03, still more preferably 0.05 or more, even more preferably 0.08 or more, and preferably 2.5 or less, preferably 0.5 or less, more preferably 0.45 or less, still more preferably 0.4 or less. ..
更に本発明の香料組成物には、香料品としてのボリューム感を向上させるため、更に成分(e)としてゲラニオールを含有することが好ましい。添加後の香粧品の総量に対する成分(e)の含有量は、好ましくは0.003質量%以上、より好ましくは0.006質量%以上、更に好ましくは0.01質量%以上であり、また、好ましくは0.3質量%以下、より好ましくは0.25質量%以下、更に好ましくは0.2質量%以下である。 Further, the fragrance composition of the present invention preferably further contains geraniol as the component (e) in order to improve the volume feeling as a fragrance product. The content of the component (e) with respect to the total amount of the cosmetic after addition is preferably 0.003% by mass or more, more preferably 0.006% by mass or more, still more preferably 0.01% by mass or more, and preferably 0.3% by mass or less. , More preferably 0.25% by mass or less, still more preferably 0.2% by mass or less.
また、成分(a)〜(c)の合計量に対する成分(e)の質量比(e)/[(a)+(b)+(c)]は、好ましくは0.001質量%以上、より好ましくは0.01を超え、更に好ましくは0.05以上、更により好ましくは0.1以上であり、また、好ましくは15未満、より好ましくは10以下、更に好ましくは5以下、更に好ましくは3以下、更により好ましくは2以下である。 The mass ratio (e) / [(a) + (b) + (c)] of the component (e) to the total amount of the components (a) to (c) is preferably 0.001% by mass or more, more preferably 0.001% by mass or more. More than 0.01, more preferably 0.05 or more, even more preferably 0.1 or more, and preferably less than 15, more preferably 10 or less, still more preferably 5 or less, still more preferably 3 or less, still more preferably 2 or less. Is.
〔成分(f):インドール〕
なお、本発明の香料組成物は、成分(f)のインドールの含有量が一定濃度以下であることを要する。茶飲料の香気成分には多量のインドールが含まれており、お茶の香りを有する従来の香料組成物にもインドールが配合されている。しかし、本発明者は、インドールを含むと香粧品としての清潔感が損なわれることを見出した。このため本発明の香料組成物における成分(a)及び(c)の合計量に対する下記成分(f)の含有量の最大許容質量比は、0.4であって、好ましくは0.2以下、より好ましくは0.1以下、更に好ましくは0.05以下である。また、添加後の香粧品の総量に対する成分(f)の含有量は、好ましくは0.5質量%未満、より好ましくは0.3質量%以下、更に好ましくは0.1質量%以下、更により好ましくは0.05質量%以下である。
[Ingredient (f): indole]
The fragrance composition of the present invention requires that the indole content of the component (f) is a certain concentration or less. A large amount of indole is contained in the aroma component of the tea beverage, and the indole is also blended in the conventional flavor composition having the aroma of tea. However, the present inventor has found that the inclusion of indole impairs the cleanliness of a cosmetic product. Therefore, the maximum permissible mass ratio of the content of the following component (f) to the total amount of the components (a) and (c) in the fragrance composition of the present invention is 0.4, preferably 0.2 or less, more preferably 0.1. Hereinafter, it is more preferably 0.05 or less. The content of the component (f) with respect to the total amount of the cosmetics after addition is preferably less than 0.5% by mass, more preferably 0.3% by mass or less, still more preferably 0.1% by mass or less, still more preferably 0.05% by mass or less. Is.
〔その他の香料化合物〕
本発明の香料組成物には、以上の条件を満たし、白茶様香気の特徴を維持する限り、成分(a)〜(e)のほかにも、その他の香料化合物として、例えば、Steffen Arctander編著“Perfume and Flavor Chemicals” Montclair, N.J.(U.S.A.) (1969年)、合成香料編集委員会編集「合成香料−化学と商品知識」(化学工業日報社、2016年12月20日、増補新版)、中島基貴編著「香料と調香の基礎知識」産業図書(1995年初版)等に記載されている公知の香料化合物を含有することができる。
[Other fragrance compounds]
In addition to the components (a) to (e), other fragrance compounds, for example, edited by Steffen Arctander, can be used in the fragrance composition of the present invention as long as the above conditions are satisfied and the characteristics of white tea-like fragrance are maintained. Perfume and Flavor Chemicals ”Montclair, NJ (USA) (1969), edited by Synthetic Fragrance Editorial Committee,“ Synthetic Fragrances-Chemicals and Product Knowledge ”(Chemical Industry Daily, December 20, 2016, supplementary new edition), Motoki Nakajima It can contain known fragrance compounds described in the edited book "Basic knowledge of fragrances and fragrances" Sangyo Tosho (first edition in 1995).
〔溶媒(希釈剤)〕
本発明の香料組成物には、使用時の利便性のため、適宜溶媒(希釈剤)を含有することができる。溶媒としては、3-メトキシ-3-メチルブタノール、ジエチレングリコールモノエチルエーテル、フタル酸ジエチル、ジプロピレングリコール、ジプロピレングリコールモノエチルエーテル、ミリスチン酸イソプロピル、ミリスチン酸ベンジル、プロピレングリコール、アジピン酸ジイソブチル、エタノール、水添アビエチン酸メチル、クエン酸トリエチル、安息香酸ベンジル、ベンジルアルコール、フェノキシエタノール、グリセリン等が挙げられる。
[Solvent (diluent)]
The fragrance composition of the present invention may appropriately contain a solvent (diluent) for convenience during use. Solvents include 3-methoxy-3-methylbutanol, diethylene glycol monoethyl ether, diethyl phthalate, dipropylene glycol, dipropylene glycol monoethyl ether, isopropyl myristate, benzyl myristate, propylene glycol, diisobutyl adipate, ethanol, Examples thereof include hydrogenated methyl avietate, triethyl citrate, benzyl benzoate, benzyl alcohol, phenoxyethanol, glycerin and the like.
〔形態〕
更に、本発明の香料組成物においては香料一般に適用される製剤化技術の適用も可能であり、粉末化、カプセル化など、香料担持体を用いて所望の形態に調製することもできる。
〔form〕
Further, in the fragrance composition of the present invention, it is possible to apply a formulation technique generally applied to fragrances, and it is also possible to prepare a desired form by using a fragrance carrier such as powdering or encapsulation.
〔香粧品〕
本発明の香料組成物は、広く香粧品の賦香のために使用される。本発明において「香粧品」とは、石鹸、身体洗浄剤、シャンプー、リンス、ヘアトリートメント剤、整髪料、化粧水、基礎化粧料、洗顔剤、仕上げ化粧料、皮膚外用剤、衛生用品、制汗剤、デオドラント剤、浴用剤、洗口剤、ハミガキ、香水、コロン、オードトワレ等、人の身なりを清潔に又は美しくするための製品である化粧品やトイレタリー製品;衣料用洗剤、衣料用柔軟剤、衣料用糊剤、住居用洗剤、風呂用洗剤、食器用洗剤、漂白剤、カビ取り剤、床用ワックス、芳香剤、消臭剤、線香、インセンス等、住居や家庭製品の様々な物品の機能又は清潔性を維持するための製品であるハウスホールド製品や環境衛生製品;その他、インク、文具、玩具等の賦香されることがある物品も含む概念である。
[Cosmetics]
The fragrance composition of the present invention is widely used for flavoring cosmetics. In the present invention, the term "cosmetics" refers to soaps, body cleansers, shampoos, rinses, hair treatment agents, hair styling products, perfumes, basic cosmetics, facial cleansing agents, finishing cosmetics, external skin preparations, sanitary products, and antiperspirants. Cosmetics and toiletry products such as agents, deodorants, bathing agents, mouthwashes, shampoos, perfumes, colognes, eau de toiletries, etc.; Functions of various household and household products such as glue, household detergent, bath detergent, dishwashing detergent, bleaching agent, mold remover, floor wax, air freshener, deodorant, incense, incense, etc. Alternatively, it is a concept that includes household products and environmental hygiene products that are products for maintaining cleanliness; and other items that may be scented such as ink, stationery, and toys.
香粧品に対する本発明の香料組成物の添加量は、好ましくは0.01質量%以上、より好ましくは0.02質量%以上、更に好ましくは0.05質量%以上であり、また、好ましくは5質量%以下、より好ましくは3質量%以下、更に好ましくは2質量%以下である。 The amount of the fragrance composition of the present invention added to the cosmetic product is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, further preferably 0.05% by mass or more, and preferably 5% by mass or less, more preferably. Is 3% by mass or less, more preferably 2% by mass or less.
実施例1〜8、比較例1〜8
表1及び2に示す組成比の香料化合物から成る香料組成物(表中の香料化合物の合計を100質量%とする香料組成物)を調製し、身体用洗浄剤及び衣料用洗浄剤に対し、各香料化合物が表中に示す含有量となるように賦香した。
賦香された身体用洗浄剤又は衣料用洗浄剤の香りの「白茶らしさ」、「清潔感」について、下記基準に従って9段階評価を行った。また、各洗浄剤の香調について総合評価を行った。これらの結果を表1及び2に併せて示す。
Examples 1-8, Comparative Examples 1-8
A fragrance composition composed of the fragrance compounds having the composition ratios shown in Tables 1 and 2 (a fragrance composition in which the total of the fragrance compounds in the table is 100% by mass) was prepared, and the fragrance composition was prepared with respect to the body cleaning agent and the clothing cleaning agent. Each fragrance compound was fragranced so as to have the content shown in the table.
The "white tea-likeness" and "cleanliness" of the scented body cleanser or clothing cleanser were evaluated on a 9-point scale according to the following criteria. In addition, a comprehensive evaluation was performed on the aroma tone of each cleaning agent. These results are also shown in Tables 1 and 2.
「白茶らしさ」
非常に強い:8
とても強い:7
強い :6
やや強い :5
やや弱い :4
弱い :3
とても弱い:2
非常に弱い:1
無い :0
"White tea-ness"
Very strong: 8
Very strong: 7
Strong: 6
Somewhat strong: 5
Slightly weak: 4
Weak: 3
Very weak: 2
Very weak: 1
None: 0
「清潔感」
非常に高い:8
とても高い:7
高い :6
やや高い :5
やや低い :4
低い :3
とても低い:2
非常に低い:1
無い :0
"Cleanliness"
Very high: 8
Very expensive: 7
High: 6
Slightly high: 5
Slightly low: 4
Low: 3
Very low: 2
Very low: 1
None: 0
(賦香対象の身体用洗浄剤の処方)
(質量%)
ラウリン酸 8.6
ミリスチン酸 8.4
パルミチン酸 2.5
ポリオキシエチレンアルキルエーテル硫酸ナトリウム 2.9
グリセリン 1.9
プロピレングリコール 1.2
ヤシ油脂肪酸アミドプロピルベタイン 0.9
水酸化カリウム(pH9.6に調整する量) 適量
精製水 バランス
(Prescription of body cleanser for incense)
(mass%)
Lauric acid 8.6
Myristic acid 8.4
Palmitic acid 2.5
Polyoxyethylene alkyl ether sodium sulfate 2.9
Glycerin 1.9
Propylene glycol 1.2
Coconut oil fatty acid amide propyl betaine 0.9
Potassium hydroxide (amount adjusted to pH 9.6) Appropriate amount Purified water balance
(賦香対象の衣料用洗浄剤の処方)
(質量%)
直鎖アルキルベンゼンスルホン酸ソーダ 40
ゼオライト 22
炭酸ソーダ 10
ポリオキシエチレンアルキルエーテル 5.0
牛脂脂肪酸ソーダ 1.0
蛍光塗料 0.5
酵素 0.5
芒硝 バランス
(Prescription of cleaning agent for clothing to be incense)
(mass%)
Linear Alkylbenzene Sulfonic Acid Soda 40
Zeolite 22
Sodium carbonate 10
Polyoxyethylene alkyl ether 5.0
Beef tallow fatty acid soda 1.0
Fluorescent paint 0.5
Enzyme 0.5
Glauber's salt balance
比較例9
白茶の香りをうたう市販の香水(BVLGARI EAU PERFUMEE AU THE BLANC)について分析したところ、シス-ジャスモン及びリナロールは検出されたが、シス-3-ヘキセノールは検出されず、またムスク類が多量に配合されたものであった。
この製品で身体用洗浄剤又は衣料用洗浄剤に賦香して前記同様の香り評価を行ったところ、身体用洗浄剤に賦香した場合では「白茶らしさ」は3、「清潔感」は7、「お茶様だが白茶らしさは弱い」、衣料用洗浄剤に賦香した場合では「白茶らしさ」は3、「清潔感」は8、「ムスクが強く、白茶らしさは弱い」という結果であった。
Comparative Example 9
Analysis of a commercially available perfume (BVLGARI EAU PERFUMEE AU THE BLANC) that sings the scent of white tea revealed that cis-jasmonic acid and linalool were detected, but cis-3-hexenol was not detected, and a large amount of musk was mixed. It was a thing.
When this product was scented with a body cleanser or clothing cleanser and the same fragrance evaluation was performed as described above, when the body cleanser was scented, "white tea-likeness" was 3 and "cleanliness" was 7. , "Tea-like but weak white tea", "White tea" was 3, "Cleanliness" was 8, and "Musk was strong and white tea was weak" when the cleaning agent for clothing was incense. ..
処方例1(身体用洗浄剤用香料組成物)
(質量部)
ベルガモット油 50
リナロールオキサイド 10
シス-3-ヘキセノール 80
シス-3-ヘキセニルアセテート 5
セージクラリー油 5
ゲラニオール 60
フェニルエチルアルコール 60
ジャスミンアブソリュート 1
リナロール 100
ネロリドール 80
シス-ジャスモン 180
ジヒドロジャスモン酸メチル 250
イソ・イー・スーパー 15
クマリン 10
アンブロキサン(登録商標) 1
ジプロピレングリコール 93
合計 1000
Prescription Example 1 (fragrance composition for body cleanser)
(Mass part)
Bergamot oil 50
Linalool oxide 10
Sis-3-hexenol 80
Sis-3-hexenyl acetate 5
Sage clary oil 5
Geraniol 60
Phenylethyl alcohol 60
Jasmine Absolute 1
Linalool 100
Nerolidol 80
Sis-Jasmon 180
Methyl dihydrojasmonate 250
Iso E Super 15
Coumarin 10
Ambroxane® 1
Dipropylene glycol 93
1000 in total
処方例2(衣料用洗浄剤用香料組成物)
(質量部)
ジヒドロミルセノール 5
リモネン 50
リナロールオキサイド 20
シス-3-ヘキセノール 60
トリプラール 2
ヘリオナール 20
シトロネロール 20
ゲラニオール 60
フェニルエチルアルコール 40
リナロール 60
テトラヒドロリナロール 100
ネロリドール 40
シス-ジャスモン 150
ヘキシルシンナミックアルデヒド 200
アンバーコア 25
ベータヨノン 50
ジプロピレングリコール 98
合計 1000
Formulation Example 2 (Fragrance composition for cleaning agents for clothing)
(Mass part)
Dihydromilsenol 5
Limonene 50
Linalool oxide 20
Sis-3-hexenol 60
Triplar 2
Helional 20
Citronellol 20
Geraniol 60
Phenylethyl alcohol 40
Linalool 60
Tetrahydrolinalool 100
Nerolidol 40
Sis-Jasmon 150
Hexyl cinnamic aldehyde 200
Amber Core 25
Beta Yonon 50
Dipropylene glycol 98
1000 in total
処方例3(石けん)
(質量%)
ラウリン酸 12.0
ミリスチン酸 4.0
パルミチン酸 0.8
グリセリン 5.0
プロピレングリコール 2.0
ラウリルヒドロキシスルタイン(*1) 1.5
ジステアリン酸グリコール 1.5
水酸化カリウム (pH9.6に調整する量)
香料組成物(*2) (*3)
精製水 バランス
Prescription example 3 (soap)
(mass%)
Lauric acid 12.0
Myristic acid 4.0
Palmitic acid 0.8
Glycerin 5.0
Propylene glycol 2.0
Lauryl hydroxysultaine (* 1) 1.5
Glycol distearate 1.5
Potassium hydroxide (amount adjusted to pH 9.6)
Fragrance composition (* 2) (* 3)
Purified water balance
*1:アンヒトール20HD(30質量%;花王社製)の有効分
*2:実施例1〜4の香料組成物
*3:表1に示す香粧品中の含有量
* 1: Effective portion of Anchor 20HD (30% by mass; manufactured by Kao Corporation)
* 2: Perfume compositions of Examples 1 to 4
* 3: Content in cosmetics shown in Table 1
処方例4(身体用洗浄剤組成物)
(質量%)
ラウリン酸 2.0
ヤシ油脂肪酸 4.0
ポリオキシエチレン(4.5)ラウリルエーテル酢酸(*4) 6.0
ポリオキシエチレン(2)ラウリルエーテル硫酸ナトリウム(*5) 2.7
ラウリル硫酸ナトリウム(*6) 1.5
水酸化カリウム(48質量%) 適量
プロピレングリコール 5.0
アルキルグルコシド(*7) 3.0
ラウリルヒドロキシスルタイン(*1) 3.0
香料組成物(*2) (*3)
精製水 バランス
Prescription Example 4 (Body Cleansing Composition)
(mass%)
Lauric acid 2.0
Coconut oil fatty acid 4.0
Polyoxyethylene (4.5) Lauryl Ether Acetic Acid (* 4) 6.0
Polyoxyethylene (2) Sodium lauryl ether sulfate (* 5) 2.7
Sodium lauryl sulfate (* 6) 1.5
Potassium hydroxide (48% by mass) Appropriate amount Propylene glycol 5.0
Alkyl glucoside (* 7) 3.0
Lauryl hydroxysultaine (* 1) 3.0
Fragrance composition (* 2) (* 3)
Purified water balance
*1:アンヒトール20HD(30質量%;花王社製)の有効分
*2:実施例1〜4の香料組成物
*3:表1に示す香粧品中の含有量
*4:カオーアキポRLM-45(92質量%;花王社製)の有効分
*5:エマールE-27C(27質量%;花王社製)の有効分
*6:エマール2F-30(30質量%;花王社製)の有効分
*7:マイドール10(40質量%;花王社製)の有効分
* 1: Effective portion of Anchor 20HD (30% by mass; manufactured by Kao Corporation)
* 2: Perfume compositions of Examples 1 to 4
* 3: Content in cosmetics shown in Table 1
* 4: Effective portion of Kao Akipo RLM-45 (92% by mass; manufactured by Kao Corporation)
* 5: Effective portion of Emar E-27C (27% by mass; manufactured by Kao Corporation)
* 6: Effective portion of Emar 2F-30 (30% by mass; manufactured by Kao Corporation)
* 7: Effective portion of My Doll 10 (40% by mass; manufactured by Kao Corporation)
処方例6(化粧水)
(質量%)
保湿剤 10
柔軟剤 0.1
界面活性剤 1
エタノール 10
香料組成物(*2) 0.05
精製水 バランス
*2:実施例1〜4の香料組成物
Prescription example 6 (toner)
(mass%)
Moisturizer 10
Softener 0.1
Surfactant 1
Ethanol 10
Fragrance composition (* 2) 0.05
Purified water balance
* 2: Perfume compositions of Examples 1 to 4
処方例7(クリーム)
(質量%)
油分 31
保湿剤 10
界面活性剤 5
香料組成物(*2) 0.05
精製水 バランス
*2:実施例1〜4の香料組成物
Prescription example 7 (cream)
(mass%)
Oil 31
Moisturizer 10
Surfactant 5
Fragrance composition (* 2) 0.05
Purified water balance
* 2: Perfume compositions of Examples 1 to 4
処方例8(シャンプー)
(質量%)
シス-1,2-シクロヘキサンジカルボン酸 1.0
ポリオキシエチレン(3)ラウリルエーテル硫酸ナトリウム 10.0
ラウリル硫酸ナトリウム 5.0
ポリオキシエチレン(15)ラウリルエーテル 1.0
ラウリン酸ジエタノールアミド 1.0
ラウリン酸アミドプロピルベタイン 1.0
塩化ステアリルトリメチルアンモニウム 0.1
香料組成物(*2) 1.0
精製水 バランス
*2:実施例1〜4の香料組成物
Prescription example 8 (shampoo)
(mass%)
Sis-1,2-cyclohexanedicarboxylic acid 1.0
Polyoxyethylene (3) Sodium Lauryl Ether Sulfate 10.0
Sodium lauryl sulfate 5.0
Polyoxyethylene (15) Lauryl Ether 1.0
Lauric acid diethanolamide 1.0
Amidopropyl Betaine Laurate 1.0
Stearyltrimethylammonium chloride 0.1
Fragrance composition (* 2) 1.0
Purified water balance
* 2: Perfume compositions of Examples 1 to 4
処方例9(ヘアスプレー)
(質量%)
シス-1,2-シクロヘキサンジカルボン酸 1.0
グリセリン 2.0
セタノール 4.0
軽質流動イソパラフィン(日石三菱社、アイソゾール400) 4.0
ポリオキシエチレン(20)イソセチルエーテル 0.5
イソステアリルグリセリルエーテル 2.0
ジメチルポリシロキサン 1.0
香料組成物(*2) 1.0
95%エタノール バランス
*2:実施例1〜4の香料組成物
Prescription example 9 (hairspray)
(mass%)
Sis-1,2-cyclohexanedicarboxylic acid 1.0
Glycerin 2.0
Cetanol 4.0
Light Liquid Isoparaffin (Nippon Oil Mitsubishi, Isosol 400) 4.0
Polyoxyethylene (20) isosetyl ether 0.5
Isostearyl glyceryl ether 2.0
Dimethylpolysiloxane 1.0
Fragrance composition (* 2) 1.0
95% ethanol balance
* 2: Perfume compositions of Examples 1 to 4
処方例10(ゲル状芳香剤)
(質量%)
エタノール 10
ポリオキシエチレンオレイルエーテル 20
プロピレングリコール 3
カチオン性増粘剤 4
香料組成物(*2) 30
精製水 バランス
*2:実施例1〜4の香料組成物
Prescription Example 10 (Gel-like air freshener)
(mass%)
Ethanol 10
Polyoxyethylene oleyl ether 20
Propylene glycol 3
Cationic thickener 4
Fragrance composition (* 2) 30
Purified water balance
* 2: Perfume compositions of Examples 1 to 4
処方例11(入浴剤)
(質量%)
炭酸水素ナトリウム 25
炭酸ナトリウム 25
フマル酸 40
ポリエチレングリコール 5
香料組成物(*2) 1.0
ジプロピレングリコール バランス
*2:実施例1〜4の香料組成物
Prescription example 11 (bath salt)
(mass%)
Sodium bicarbonate 25
Sodium carbonate 25
Fumaric acid 40
Polyethylene glycol 5
Fragrance composition (* 2) 1.0
Dipropylene glycol balance
* 2: Perfume compositions of Examples 1 to 4
処方例12(食器用洗剤)
(質量%)
ポリオキシエチレンラウリルエーテル 20
ラウリルジメチルアミンオキサイド 5
アルキルポリグルコシド 5
ポリオキシエチレンアルキルエーテル 3
ラウリルジメチルヒドロキシスルホベタイン 3
エタノール 5
パラトルエンスルホン酸 3
香料組成物(*2) 0.5
精製水 バランス
*2:実施例1〜4の香料組成物
Prescription example 12 (dishwashing liquid)
(mass%)
Polyoxyethylene lauryl ether 20
Lauryldimethylamine oxide 5
Alkyl polyglucoside 5
Polyoxyethylene alkyl ether 3
Lauryl dimethyl hydroxysulfobetaine 3
Ethanol 5
Paratoluenesulfonic acid 3
Fragrance composition (* 2) 0.5
Purified water balance
* 2: Perfume compositions of Examples 1 to 4
処方例13(風呂場用洗剤)
(質量%)
界面活性剤 7
キレート剤 7
水溶性溶剤 5
香料組成物(*2) 0.5
精製水 バランス
*2:実施例1〜4の香料組成物
Prescription example 13 (bathroom detergent)
(mass%)
Surfactant 7
Chelating agent 7
Water-soluble solvent 5
Fragrance composition (* 2) 0.5
Purified water balance
* 2: Perfume compositions of Examples 1 to 4
Claims (8)
(a) シス-ジャスモン
(b) リナロール
(c) シス-3-ヘキセノール
(d) ネロリドール
(e) ゲラニオール
(f) インドール A white tea-like fragrance composition for cosmetics containing the following components (a) to (e) , wherein the content of the component (a) is 0.05% by mass or more and the component (c) is equal to or more than the total amount of the cosmetic after addition. ) Is 0.005% by mass or more , the content of component (d) is 0.005% by mass or more and 0.5% by mass or less, and the content of component (e) is 0.003% by mass or more and 0.3% by mass or less. Mass ratio of the total amount of the components (a) and (c) to the total amount of the components (a) to (c) in the fragrance composition [(a) + (c)] / [(a) + (b) ) + (c)] is less than 0.85 greater than 0.3, Ri maximum permissible weight ratio of 0.4 der the content of the component (a) and the following component to the total amount of (c) (f), has a white tea-like aroma , White tea-like fragrance composition for cosmetics.
(a) Sis-Jasmon
(b) Linalool
(c) cis-3-hexenol
(d) Nerolidol
(e) Geraniol
(f) Indole
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