KR20190011962A - Preparing method of natural soap and shampoo with triglyceride and calcium oxide - Google Patents

Abstract

The present invention relates to a natural soap and a natural shampoo composition manufactured by a saponification process using mediums which are triglycerides, a main component of natural oil, and suspension and clusters of calcined oxide which are obtained by calcining at high temperature by using a ultra-high temperature calcining method, at more than or equal to 1,200°C, removing impurities and ultra-fine pulverizing. By containing the calcined calcium oxide of the present invention, soaps and shampoos are provided that can prevent skin oxidation and have antimicrobial and anti-inflammatory properties.

Description

TECHNICAL FIELD The present invention relates to a natural soap and a natural shampoo containing triglyceride and ultrafine calcined calcium oxide,

The present invention relates to a natural soap and a natural shampoo composition prepared using a calcined calcium oxide suspension obtained by dispersing ultrafine palm oil calcium oxide in triglyceride, which is a main component of natural oil.

Shell shells were industrial wastes that were left on the shore and were difficult to treat. However, shells were crushed at high temperature by crushing them at high temperature. Crushed shells were shell plastic materials, and there are sanitary goods, food, and cosmetics. It is listed as a food additive for the Food and Drug Administration of Korea and is registered as a raw material for use as a cleaning agent of the Public Health Law of the Ministry of Health and Welfare. When the shell is calcined at high temperature (1,000 ~ 1,300 ° C), it becomes a ceramic form of calcium carbonate, calcium oxide, calcium hydroxide and compound. This material is produced only by physical action without using 100% It is an eco-friendly substance harmless to the human body because it is a substance that has been made.

Therefore, the inventors of the present invention have found a method of applying the effect of calcined calcium oxide, which is reported to be excellent in antioxidation, antibacterial, deodorization and self-purification ability, cellulite management effect and prevention of skin aging, The inventors of the present invention have completed the present invention by paying attention to a method of ultrafinely dispersing calcined calcium oxide which is insoluble in water and dispersing it in a method of adding calcined calcium oxide to a natural product made by saponification.

The present invention provides a method for homogenizing a calcined calcium oxide with a suspension or a cluster in a state suitable for application to soaps, shampoos and cosmetics.

It is another object of the present invention to provide a natural soap and a natural shampoo containing calcined calcium oxide.

In order to achieve the above object, 400 mg of calcined calcium oxide having a purity of 95% by weight or more and a purity of 95% by weight or more in 3 ml of triglyceride is added to 2-5% by weight of copolymer polyethylene glycol (PEG) % To a surface tension of not more than 40 dyne / cm (20 DEG C), and a calcined calcium oxide suspension.

Also, the natural soap of the present invention comprises 50.0-60.0% by weight of the crude calcined calcium carbonate, 9.5-10.0% by weight of caustic soda, 27.0-32.0% by weight of purified water, 1.0-2.0% by weight of polyethylene glycol, 2.0 wt%, calcined calcium oxide 0.5-1.0 wt%, and various additives 1.0-3.0 wt%.

The natural shampoo of the present invention may further contain 15.0 to 30.0% by weight of the calcined calcium oxide raw material, 0.05 to 0.25% by weight of calcined calcium oxide cluster, 15.0 to 25.0% by weight of ethyl alcohol, 0.0001 to 2.0% by weight of polyethylene glycol (PEG) %, 0.0001-10.0% by weight of herbal extract, 0.0001-0.5% by weight of a moisturizer, and 0.0001-0.5% by weight of fragrance, with the balance being water.

The present invention uses calcined shells at a temperature of 1,200 ° C or higher in the form of molecular clusters to produce and use calcium oxide. The shells are calcined at high temperature to mechanically decompose them to ultrafine nano. Disassemble mechanically. This is based on the mechanical degradation of water, alcohol, and fluorite caused by hydrostatic impact in natural oil triglycerides, the core of the present invention.

The unique properties of the calcined calcium produced here create the unique physical and chemical properties of the solid. For example, calcined calcium oxide molecular crystals have a very high intermolecular attraction of molecules, much larger than the molecular crystals of organic materials of most similar size. The high strength of the calcined calcium oxide molecule crystals leads to significantly different chemical and biochemical behaviors as compared to individual calcined calcium oxide molecules, such as behavior in a true solution, so that the calcined calcium oxide molecule itself is in the form of a cosmetic, Veterinary composition.

The macroscopic size of the calcined calcium oxide molecule does not allow it to be incorporated into the skin tissue and other biological structures. Only surface molecules that occupy about 0.4% of all molecules in a typical micrometer sized powder particle are allowed to react with solution components by exposure to the solution.

Due to its importance, a new manufacturing method thereof is also being continuously developed.

Therefore, in order to dissolve calcined calcium oxide, the present invention provides ultrafine dispersion in the form of an oil-in-water or a water-in-oil emulsion, a suspension, a powder or a cream.

 As described in the present invention, the present invention uses calcium oxide produced by calcining a shell at 1,200 DEG C or higher and mechanically decomposes into individual small molecular masses. This is based on water, alcohol, and mechanical degradation caused by hydraulic impact in natural oil triglycerides, the core of the present invention. In this case, it has been found that the soluble complex of the polymer and the calcined calcium oxide contains a small type of powder in which the polymer and the porphyrin molecule are bonded as a ligand. Examples of the water-soluble polymer useful for forming the calcined calcium oxide using this method include polyvinylpyridine (EG), propylene glycol (PG) or the like as a medium, such as polyvinyl pyrrolidone (PVP), polyethylene glycol (PEG), polypropylene glycol (PPG), vinyl pyrrolidone, ethylene glycol (EG) and the like.

 Consumers expect natural soaps, natural cosmetic hair and skin care emulsions to meet a number of requirements. Apart from the cleansing and care effects that determine a particular application, a variety of factors are important, such as high skin compatibility, good lipid layer build-up, good appearance, optimal sensory feel and half-life.

The calcined calcium oxide thus prepared is a component capable of strongly removing the active oxygen because it has an excellent constant action more than several tens times higher than the vitamin C which has the effect of removing the active oxygen. In order to remove active oxygen which affects the aging of skin, herbal soap containing calcined calcium oxide component is applied to skin treatment. The manufactured powder used for making the soap is more stable than the artificial powder, and helps to prevent and treat the aging of the skin such as wrinkles, elasticity decrease and stain. Because it does not contain any surfactant, it does not irritate sensitive skin.

Since calcined calcium oxide does not dissolve well in water, calcium oxide and water are generally mixed and stirred, and saturated steam is supplied to induce ionic reaction and thereby make an aqueous solution of ionized calcium.

The present invention relates to a process for the preparation of an oil-in-water or water-in-oil emulsion, a suspension, a powder and a cream in the course of saponification of triglyceride, And a method for manufacturing the same.

The saponification reaction is made by adding a water component (aqueous alkali solution) to the oil component (the same vegetable oil) and since they are not mixed with each other, the saponification reaction is not easy. All chemical reactions must be brought into contact with each other to form a reaction. Therefore, to overcome these problems, it is necessary to treat the maintenance physically and chemically. The physical treatment of triglyceride refers to the application of a hydrophilic solvent such as ethanol in advance before the saponification reaction.

All triglycerides are present in trace amounts even though they are purified, free fatty acids that are not linked to glycerol. However, since free fatty acid dissolves well in ethanol, once the ethanol is added, the free fatty acid in the oil is dissolved in ethanol, so that the soap is first contacted with the aqueous alkali solution. The soap produced is a good emulsifier. The remaining oil components are emulsified together with water by the emulsifier, and calcined calcium oxide and alkali are contacted with each other to proceed the saponification reaction. The small amount of soap produced in the initial stage of the saponification reaction by the reaction of triglyceride and alkali makes the calcined calcium oxide and unreacted oil become small particles and dispersed in the alkali solution. When the triglyceride and the calcined calcium oxide are dispersed in the form of small particles, the surface area in contact with the alkali solution becomes large, and the saponification reaction proceeds very quickly. Because of this effect of the natural soap, a small amount of soap scum is dissolved in a small amount of water in advance, mixed with an alkali solution, and then added to the glass to accelerate the saponification. Once the saponification is complete, there should be no excess unreacted alkali. That is, all the alkali must be bound to the fatty acid and should not remain free.

 Hereinafter, the present invention will be described in detail.

  Triglyceride as a main component in the natural soap, natural shampoo and mask pack composition obtained by the production method of the present invention refers specifically to a natural oil having a structure in which three fatty acids are bonded to glycerin. The weakest part of triglycerides, the main component of natural oils, is an ester (-COO-) bond, as seen in the saponification process. In the human body, the first change that occurs when fat is digested and absorbed is the process by which this ester bond breaks down and fatty acids and glycerin fall off. The process by which the triglyceride is decomposed and returned to the original fatty acid and glycerin is called hydrolysis. Natural soap is made by reacting natural animal or vegetable oil with alkali and water. This reaction process is called saponification, in which glycerol (= glycerin) is produced together.

  The main component of natural oils is mainly composed of three fatty acids (fatty acids) and one glycerol in one molecule, called triglycerides. The reaction process is a two-step process, preceded by a process in which the triglyceride is first hydrolyzed with three fatty acids and two glycerol by a strong alkali (sodium hydroxide or potassium hydroxide), followed by the liberation of fatty acids liberated in this process Of sodium or potassium ions to neutralize the fatty acid salt, i.e., the soap. One (a fat) fatty acid requires three caustic soda for the reaction. The ionized caustic soda binds to the O + of the carboxyl group and the OH + of CH2 + to form carboxylate (soap) and glycerol (glycerol).

Most fatty acids in natural oils have a single carboxyl group attached to a straight chain hydrocarbon chain. Fatty acids used in saponification are generally fatty acids with a total carbon number of 10-20. A saturated fatty acid is a fatty acid in which both carbon-carbon bonds are single bonds, and an unsaturated fatty acid is a fatty acid having at least one double bond in a carbon-carbon bond.

 The triglyceride in the present invention is a mixture of glycerol and three molecules of fatty acids, and is the most widely distributed fatty acid derivative that can be found in nature. It is also referred to as simple lipid or neutral lipids and differs in the nature of constituent fatty acids, ie, carbon number, saturation, and unsaturation. When hydrolyzed, the fatty acid is lowered and becomes glycerol via diglyceride and monoglyceride. There are various methods of hydrolyzing triglyceride. The aforementioned saponification reaction corresponds to hydrolysis using an alkali. In addition, there are various methods such as decomposition with water, decomposition with acid, and a method using hydrolytic enzyme.

The oil that makes glycerin and fatty acid among our natural oils is palm oil, which is produced worldwide, mainly in Indonesia and Malaysia, and the world's leading multinational chemical companies set up local factories to produce fatty acids from palm oil It produces glycerin.

A method of using calcined fortified calcium in the saponification process to utilize the characteristics thereof to inactivate the toxins of healthy skin or mucous membranes; a method of applying an effective amount of fullerene to the skin in the presence of sunlight to antimicrobial activity of the skin and mucous membranes or antiviral infection Or to prevent or reduce the risk of infection. Further, the present invention relates to a method for protecting skin and mucous membranes against strong visible light irradiation, for example, sunlight, by applying the present invention to skin.

 When the method for preparing calcined calcium oxide particles in triglycerides, which is the main component of the natural oil of the present invention, is used for hair protection, they may be shampoos, lotions or gels; May be provided in the form of a composition before or after rinsing or shampooing, before or after dyeing or discoloring, during wave medicine or straight treatment, before and after the composition. They may also be provided in the form of a hair styling or treating lotion or gel, a gel for lotion or blow dyeing or hair setting, a hair spray, a composition for wave or straight parmenans, or a hair dyeing or decolorizing composition.

Natural soaps and natural shampoo compositions of the present invention may contain natural or artificial waxes. Natural waxes include animal and carnauba such as lanolin, beeswax, spermaceti or lanolin alcohol, hardened or acetylated lanolin, lanolin derivatives such as lanolin fatty acids or acetylated lanolin alcohols, carnauba, candelilla, There are vegetable such as kapok, rice, hardened jojoba, alfa or yaguan wax or cork fiber, sugar cane wax, cocoa butter and the like. Alternatively, the inorganic wax may include paraffin, montan, lignite, petrolatum, petrolatum wax or microcrystalline wax, ceresin, or ozokerite. Examples of the synthetic waxes used include linear waxes such as myristyl myristate, a reaction product of a polyethylene wax obtained by Fischer-Tropsch synthesis and a saturated C ₁₀ -C ₄₀ carboxylic acid and a saturated C ₁₀ -C ₄₀ alcohol . Other waxes used include calcium lanolate or stearate or hardened coconut oil and the like.

The term " fat " of the present invention is understood to be triacylglycerol, i.e. triple ester of fatty acid and glycerol. The triacylglycerol preferably contains a saturated, unbranched, unsubstituted fatty acid component. They may also be mixed esters, i.e. triple esters of various fatty acids and glycerol. The so-called hardened fats and oils obtained by partial hydrogenation can be used according to the invention, which is particularly suitable as a hardness factor. The composition may include modified or unmodified oils of vegetable or animal oils. For example, sweet almond oil, avocado oil, castor oil olive oil, jojoba oil, sunflower oil, turmeric oil, sesame oil, peanut oil, grape seed oil, soy milk, safflower oil, coconut oil, maze oil, hazelnut oil, Butter, palm oil, apricot seed oil, calf pill oil or perhydro-squalene. Furthermore, the oil phase may be an inorganic oil such as liquid paraffin, liquid petrolatum, and the like. The oil may be selected from the group consisting of fatty acid esters such as isopropyl myristate, isopropyl palmitate, 2-ethylhexyl palmitate, penicillin oil (stearyloctonate), unsaturated fatty acids such as oleate, palmitate, stearate, behen, linoleic, Volatile or non-volatile isoparaffins such as fatty acids or C ₈ -C ₁₆ isoparaffins, and the like. Moreover, the oil may be C ₁₂ -C ₁₈ fatty alcohols such as oleyl alcohol, cetyl alcohol and stearyl alcohol, and the like. If provided as an emulsion, the emulsified composition of the present invention comprises an oil phase and an aqueous phase. The oil phase is preferably provided in an amount of 1 to 75% by weight, more preferably 5 to 60% by weight, and most preferably 40 to 60% by weight based on the total weight of the composition.

 When the silicon-containing compound is added to the composition of the present invention, it is preferably provided in the range of 1 to 50 wt%, more preferably 5 to 30 wt%, and most preferably 10 to 25 wt% .

 A moisturizing agent may also be added to the composition of the present invention. "Humectant" refers to a reagent that provides a moisturizing effect to the skin such as a wetting agent. The moisturizing agent is provided with a moisturizing amount. Examples of the moisturizing agent include glycerin, butylene glycol, propylene glycol, sorbitol, sodium PCA, Glucam E-10, Glucam E-20 and the like. The moisturizing agent is preferably provided in a range of 0.1 to 10% by weight, more preferably 0.1 to 5% by weight, and most preferably 1 to 5% by weight based on the total weight of the composition.

 The deodorant component neutralizes, shields or eliminates body odors. Body odors are formed through the action of skin bacteria against apocrine sweating, which forms degradation products of unpleasant odors. Thus, suitable deodorant components are in particular bactericide inhibitors, enzyme inhibitors, odor absorbers or odor masking agents. In addition, dissolution aids, such as ethanol, isopropyl alcohol or polyols, can be used to improve fluidity. Suitable polyols preferably have from 2 to 15 carbons and at least two hydroxyl groups. The polyol may have other functional groups, more specifically an amino group, or may be modified with nitrogen.

 The natural soap and natural shampoo compositions comprising the triglycerides and calcined calcium oxide of the present invention have been found to have some beneficial effects. First, it exhibits a remarkable restorative effect of the skin. The greater the number of double bonds in the calcined fortified calcium that can be immediately applied to the oxidation-reduction reaction, the more the natural soap and natural shampoo composition of the calcined fortified calcium clusters of the present invention induce strong counter- Which has a strong antioxidant property. It was confirmed that free radicals generated during metabolic reaction in skin cells were one of the main factors of skin aging. The application of an effective amount of the natural soap and natural shampoo composition of the present invention to the skin prevents damage to free radicals on the cells and thus restores the skin.

The natural soap and natural shampoo compositions of the present invention can be applied to the skin daily and preferably more than once a day. In order to achieve the above-mentioned stable recovery effect, it is preferable to periodically apply several weeks or several months even if a visible effect is obtained by the first few times of application. The rate and duration of the application or cleansing depends on the concentration of the active ingredient. Those skilled in the art will be able to design suitable application methods and cleansing methods to provide the required restoration effect.

By containing the calcined calcium oxide of the present invention, it is possible to provide antioxidant, soap and shampoo having anti-bacterial and anti-wrinkle effect, and antioxidant, antibacterial and skin improving effect which depend on cosmetics only can be expected from the skin cleansing step.

The present invention will be described in detail with reference to examples. However, the following examples are illustrative of the present invention, and the present invention is not limited by the following examples.

Example  1: Preparation of dispersion of calcined calcium oxide dispersion

5% by weight of a polymer copolymer (PEG or the like) and 10% by weight of ethyl alcohol were added to and dispersed in a suspended suspension of 400 mg of calcined calcium oxide having a purity of 95% by weight in 3 ml of triglyceride (olive oil) The suspension was stored in a cooling device. The surface tension was measured to be below 40 dyne / cm (20 ℃).

Example 2 : Production of natural soap of the present invention

50.0% by weight of the calcined calcium carbonate solution prepared in Example 1, 10% by weight of caustic soda, 32.0% by weight of purified water, 2.0% by weight of polyethylene glycol, 2.0% by weight of ethyl alcohol, 1.0% by weight of calcined calcium oxide, By weight were mixed to prepare a natural soap.

Example 3 : Preparation of natural shampoo of the present invention

15.0 wt% of the calcined calcium carbonate solution prepared in Example 1, 0.25 wt% of calcined calcium oxide cluster, 25.0 wt% of ethyl alcohol, 2.0 wt% of polyethylene glycol (PEG), 10.0 wt% of herbal extract, 0.5 wt% of moisturizer, 0.5 % By weight, and the remaining weight was filled with water to prepare a natural shampoo.

Claims (3)

400 mg of calcined calcium oxide having a purity of at least 95% by weight in 3 ml of triglyceride was dispersed at 2-5% by weight of copolymer polyethylene glycol (PEG) and 5-10% by weight of ethyl alcohol during the saponification process to give a surface tension of 40 dyne / cm < 2 > (20 < 0 > C) or less.
50.0-60.0 wt% of the crude calcined calcium carbonate solution prepared in claim 1, 9.5-10.0 wt% of caustic soda,
A natural soap composition comprising 27.0-32.0 wt% of purified water, 1.0-2.0 wt% of polyethylene glycol, 1.0-2.0 wt% of ethyl alcohol, 0.5-1.0 wt% of calcined calcium oxide, and 1.0-3.0 wt% of various additives.
15.0-30.0 wt% of the crude calcined calcium carbonate solution prepared in claim 1, 0.05-0.25 wt% of calcined calcium oxide cluster, 15.0-25.0 wt% of ethyl alcohol, 0.0001-2.0 wt% of polyethylene glycol (PEG), 0.0001-10.0 wt %, A moisturizer of 0.0001-0.5 wt%, and a fragrance of 0.0001-0.5 wt%, the balance being water.