KR20180015975A - Antimicrobial wet tissue using algae fabric and natural antibacterial agent - Google Patents

Abstract

The present invention relates to an antimicrobial wet tissue using a seaweed fabric and a natural antibacterial agent. The disclosed antimicrobial wet tissue using a seaweed fabric and a natural antibacterial agent according to the present invention is a wet tissue manufactured by impregnating a composite for wet tissue on a fabric material of wet tissue, wherein the composite for wet tissue includes: purified water; a moisturizing agent; a whitening component; essential oil; and a natural antibacterial agent, and the fabric material of wet tissue, which is a nonwoven fabric including one or more types of seaweed fabric selected from red and green algae. The composite for wet tissue includes: 1-3 parts by weight of the moisturizing agent, 0.5-5 parts by weight of the whitening component, 5-15 parts by weight of the essential oil, and 10-30 parts by weight of the natural antibacterial agent about 100 parts by weight of purified water.

Description

TECHNICAL FIELD [0001] The present invention relates to an antimicrobial wet tissue using a seaweed fiber and a natural antimicrobial agent,

The present invention relates to antibacterial wet tissue using seaweed fibers and natural antimicrobial agents. More particularly, the present invention relates to a wet tissue composition comprising a non-woven fabric containing seaweed fibers as an environment-friendly material and a wet tissue fabric, wherein the wet tissue fabric is impregnated with a composition for a wet tissue including a whitening component, an essential oil and natural antimicrobial agents derived from natural materials, The present invention relates to an antimicrobial wet tissue which can exhibit whitening effect, skin protection by essential oil, antibacterial effect by natural antibacterial agent, deodorant and preservative effect.

Conventional wet tissue products are mainly used for wiping the skin when the baby is discharged from the cow or stool. Since these products are applied directly to the skin of weak baby, they are excellent in safety to the skin, and are resistant to foreign substances and pathogenic microorganisms It has a drawback in that it can not effectively prevent rash, red spot, and skin inflammation due to secondary infection caused by a pathogenic microorganism.

In addition, since the wet tissue is mainly rubbed and rubbed in direct contact with the skin, it is required to have a high level of softness, stability to the skin, improved cleaning ability to remove foreign substances remaining on the skin, and strong antibacterial power against bacteria.

In addition, conventional wet tissue products have an advantage of being able to be stored for a long period of time and not be spoiled by adding a sterilizing disinfectant, a surfactant, a chemical preservative, and an alcohol, which are known to have skin irritation, , Rashes, etc., or harmful to the human body, it is a good condition to generate and reproduce. Therefore, there are problems such as secondary contamination due to residual microorganisms such as bacteria in the distribution process, so that antibacterial and cleaning functions are smoothly performed There is a problem that can not be done.

In recent years, as interest in environment and health has increased, products using natural materials have been developed. Accordingly, products containing natural materials have been developed for wet tissues. However, there is a growing demand for functional improvements.

As a prior art, Korean Patent Laid-Open No. 10-2007-0112497 discloses a cosmetic composition having antimicrobial and antiseptic activity using a natural extract of a cosmetic composition having an antiseptic activity with gold, persimmon, mugwort, and citron extract.

Also, Korean Patent Laid-Open No. 10-2010-0098308 discloses a skin remedial lotion having antimicrobial, whitening and antioxidative activity using garlic and mugwort, which comprises natural antimicrobial activity of garlic and mugwort, skin improvement A method of manufacturing a cosmetic lotion is disclosed.

Accordingly, in order to solve the above problems, the inventors of the present invention have found that an antimicrobial wet tissue using a natural material-derived material is prepared by impregnating a nonwoven fabric containing seaweed fibers into a composition for a wet tissue including a whitening component, an essential oil and a natural antimicrobial agent, Friendly antimicrobial wet tissue using a material derived from a natural material was produced and the present invention was completed.

Accordingly, it is a technical object of the present invention to provide an antibacterial wet tissue using seaweed fiber and natural antibacterial agent.

According to an aspect of the present invention,

A wet tissue produced by impregnating a wet tissue with a composition for a wet tissue,

The composition for a wet tissue includes purified water; Moisturizer; Whitening component; Essential oils and natural antimicrobial agents,

Wherein the wet tissue fabric is a nonwoven fabric containing at least one seaweed fiber selected from red algae and green algae,

Wherein the moisturizing agent is used in an amount of 1 to 3 parts by weight, the whitening component is used in an amount of 0.5 to 5 parts by weight, the essential oil is used in an amount of 5 to 15 parts by weight based on 100 parts by weight of the purified water, The present invention also provides antibacterial wet tissue using seaweed fiber and natural antimicrobial agent.

In the present invention, the nonwoven fabric may be prepared by mixing at least one selected from the group consisting of natural fibers and synthetic fibers with seaweed fibers and uniformly dispersing the fibers in water using an adhesive to prepare a mixed solution, then uniformly dispersing and laminating the mixed solution Forming a web, pressing it with a roller and drying it,

The seaweed fiber is contained in an amount of 1 to 80% by weight based on the dry weight of the nonwoven fabric.

In the present invention, the whitening component is at least one selected from the group consisting of arbutin, niacinamide, ascorbyl glucoside, ascorbyl tetraisopalmitate, alpha-bisabolol and licorice extract.

In addition, the natural antimicrobial agent according to the present invention may include a perennial herb extract, a sorghum extract, a green tea extract, a phytoncide extract and a propolis extract,

The extracts of the perennial herbs are prepared by mixing the dried leaves and roots of the perennial herb with the volume ratio of purified water to ethanol or methanol at a ratio of 1: 3 to 3: 1, taking 5 times the weight of the perennial herb, and extracting them at 75 to 80 ° C for 4 hours Filtered and concentrated,

The Sorghum extract was washed with shampoo and dried in the shade. The shampoo extract was divided into a ground part, which is a part except for roots, and a lower part, which is a root part. The extract was soaked in 80% (v / v) methanol for 3 days , And the extract was filtered with a membrane filter to separate solid matter, and the methanol extract was concentrated at 50 ° C using a rotary evaporator.

In the present invention, the humectant is at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol and propanediol.

In the present invention, the essential oil is preferably selected from the group consisting of 0.001 to 0.01 wt% of rosemary oil, 0.002 to 0.01 wt% of grapefruit oil, 0.002 to 0.01 wt% of bergamot oil, 0.001 to 0.01 wt% of black pepper oil, 0.001 to 0.01% by weight of cedar wood oil, 0.005 to 0.02% by weight of orange oil and 0.001 to 0.01% by weight of Clara sage oil.

According to the present invention having the above-described structure, the wet tissue fabric is impregnated with a composition for a wet tissue comprising a non-woven fabric containing seaweed fibers as eco-friendly materials as a wet tissue fabric and containing a whitening component, a natural antibacterial agent derived from an essential oil, By manufacturing, it is possible to exhibit whitening effect by whitening component, skin protection by essential oil, antibacterial effect by natural antibacterial agent, deodorant and preservative effect.

The wet tissue according to the present invention can also be used as a raw material for seaweeds when the seaweed fiber nonwoven fabric is used as a raw material to impregnate the composition for wet tissues with an excellent water content of seaweed fibers, a high formulation retention ability and an excellent harmful component adsorption effect, It is possible to maximize the effect by increasing the depth and greatly improving the feeling of use of the product.

The above and other objects, features and advantages of the present invention will be more apparent from the following detailed description taken in conjunction with the accompanying drawings, in which: FIG. BRIEF DESCRIPTION OF THE DRAWINGS The advantages and features of the present invention, and the manner of achieving them, will be apparent from and elucidated with reference to the embodiments described hereinafter in conjunction with the accompanying drawings.

As used herein, the term "extract" means an active ingredient isolated from a natural product, i.e., a substance exhibiting the desired activity. The extract can be obtained by an extraction process using water, an organic solvent, or a mixed solvent thereof, and includes all the forms that are formulated with the dry powder of the extract. In addition, the above-mentioned extract also includes a fraction obtained by fractionating the extract obtained through the above extraction process.

The present invention relates to a wet tissue produced by impregnating a wet tissue with a composition for a wet tissue, wherein the composition for wet tissue in the wet tissue comprises purified water; Moisturizer; Whitening component; Wherein the wet tissue fabric is a nonwoven fabric containing at least one seaweed fiber selected from red algae and green algae, wherein the composition for wet tissue comprises 1 to 100% by weight of the purified water, 3 to 5 parts by weight of a whitening component, 5 to 15 parts by weight of an essential oil, and 10 to 30 parts by weight of a natural antibacterial agent. Provide a wet tissue.

In one embodiment, the wet tissue fabric may be a nonwoven fabric containing at least one seaweed fiber selected from red algae and green algae. There are various methods for producing the nonwoven fabric. As a drying method, there are chemical bonding, thermal bonding, air-laid, and the like. Particularly, the chemical bonding method is a fiber bonding method in which a drying process is performed in which an adhesive is infiltrated or sprayed.

In the present invention, the seaweed fiber is selected from the group consisting of red algae such as Cymbidium sp., Cyclone, Spinos, Spinos, Stones, Kim, Seahorse, Phragmites, , Brown algae such as long-tailed gulls, long-tailed gulls, hearing gulls, and blue-green algae, seaweeds, kelp, mulberry leaves, Of seaweeds.

In addition, the algae fiber can be produced by a method known in the art. For example, the seaweed is immersed in an extraction solvent capable of dissolving the agar gel for a predetermined time to dissolve the agar gel with the extraction solvent, and then the remaining slurry is physically pulverized. If necessary, bleaching agents such as Cl2O or H2O2 are used to bleach , It can be obtained by extracting only seaweed fiber.

Alternatively, the seaweed may be dipped in an acidic solution such as acetic acid, washed with water and then dehydrated. The dewatered seaweed is immersed in an extraction solvent such as water for a certain period of time to extract the agar gel, Can be collected to produce seaweed fibers. The seaweed fiber does not require any detoxification process and does not require toxic chemicals and can maintain whiteness without mineral bleaching agents.

Seaweed fibers consist of fructose and cellulose as main components and are not melted by heat. Their thickness ranges from 1 to 10 μm and length ranges from several tens to several thousand μm. Filters can be used to easily obtain fibers of a desired size. Nonwoven fabrics can be produced by wet or spray bonding methods using a papermaking method, depending on the length and thickness.

More specifically, the nonwoven fabric containing seaweed fibers used as the wet tissue fabric used in the present invention is obtained by mixing the seaweed fibers with at least one selected from the group consisting of natural fibers and synthetic fibers and uniformly dispersing them in water using an adhesive And then forming a web by dispersing and laminating the mixed solution uniformly, pressing the mixed solution with a roller, and drying the resultant mixture.

In the present invention, the natural fiber or synthetic fiber is used to maintain the strength at the time of immersing the formulation. The natural fiber or synthetic fiber may be used in an amount of 1 to 80% by weight based on the dry weight of the finished nonwoven fabric, But is not limited thereto and is used in an amount of 1 to 80% by weight based on the dry weight of the finished nonwoven fabric. In the present invention, the adhesive used for the adhesion of the fibers is used in an amount of 5 to 60% by weight based on the dry weight of the finished nonwoven fabric in accordance with the desired properties of the nonwoven fabric, and the water- A natural substance may be used, and starch such as corn or potato may be used. It is also possible to use polyvinyl acetate, polyvinyl chloride, polyvinyl alcohol, polyvinyl acetate, isobutene, maleic anhydride copolymer, polyacrylamide, And the like can also be used as an adhesive.

Also, the formed web can be compressed by using a roller to have a shape stability and to ensure that the fiber aggregate is well entangled. In this case, the compression can be performed at a linear pressure of 10 to 50 kg / cmG, Lt; 0 > C.

When the seaweed fiber nonwoven fabric according to the present invention is impregnated into a composition for a wet tissue with an excellent water content of the seaweed fiber, a high formulation retention ability and an excellent harmful component adsorption efficiency, the absorption amount and the absorption depth of the active ingredient of the composition for a wet tissue are increased, It is possible to maximize the effect of the present invention.

In one embodiment, purified water refers to pure water from which various minerals and organic matters have been completely removed, and can be prepared by ion exchange, reverse osmosis, or the like.

Ion exchange is a method of separating water into positive and negative ions and then recombining them again. The ion exchange method is the most widely used method to obtain purified water with high purity. It is divided into a mixed-type method of separating positive and negative ions from one tank, and a replenishing method of separating positive and negative ions from two tanks.

In addition, the reverse osmosis method is a method of making purified water by reversely utilizing a phenomenon in which a solution having a low concentration moves upward. When a high permeability membrane is installed between the high concentration solution and the low concentration solution and a high pressure is applied to the high concentration solution side, the low concentration solution is not sucked into the high concentration solution and the purified water is permeated at low concentration. In order to obtain purified water of high purity, it is preferable to prepare purified water using ion exchange method.

In one embodiment, the moisturizing agent is at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol and propanediol. The glycerin is not stimulated, Is most preferable because it is excellent in compatibility. The amount of the moisturizing agent is preferably 1 to 3 parts by weight based on 100 parts by weight of purified water. When the amount is less than 1 part by weight, the moisturizing power is insufficient. When the amount is more than 3 parts by weight, the stability of the composition deteriorates.

In one embodiment, the whitening component is at least one selected from the group consisting of arbutin, niacinamide, ascorbyl glucoside, ascorbyl tetraisopalmitate, alpha-bisabolol and licorice extract. The amount of the whitening component is preferably 0.5 to 5 parts by weight based on 100 parts by weight of purified water. When the amount of the whitening component is less than 0.5 parts by weight, the whitening effect is insignificant. When the amount is more than 5 parts by weight, have.

In one embodiment, the essential oil comprises 0.001 to 0.01% by weight of rosemary oil, 0.002 to 0.01% by weight of grapefruit oil, 0.002 to 0.01% by weight of bergamot oil, 0.001 to 0.01% by weight of black pepper oil, %, 0.001 to 0.01 wt% of cedarwood oil, 0.005 to 0.02 wt% of orange oil, and 0.001 to 0.01 wt% of Clara sage oil. At this time, the method of extracting the oil is not particularly limited as far as it is known. For example, oil may be extracted from each natural plant and then blended with each natural plant oil. In addition, the above essential oils may contain rosemary, grapefruit, bergamot, black pepper, cedarwood, orange and clara sage oil in a weight ratio of 12: 15: 15: 10: 13: 25: 10.

In addition, when the essential oil is added, not only the flavor is excellent but also the antimicrobial effect of the antibacterial agent described later is enhanced, and the synergistic effects such as excellent moisturizing effect and skin barrier strengthening effect in the human body, anti- Can be obtained. In particular, the essential oil of the present invention can contain far superior synergistic effects than the case where each component is separately used, by containing the above-mentioned amounts of rosemary, grapefruit, bergamot, black pepper, cedarwood, orange and clara sage . The essential oil is preferably used in an amount of 5 to 15 parts by weight based on 100 parts by weight of the purified water. When the amount of the essential oil is less than 5 parts by weight, the antibacterial effect of the antibacterial agent and the moisture resistance of the antibacterial composition are insufficient. The viscosity of the composition of the present invention may increase, which may limit its use, and may cause skin troubles. The content of each ingredient of the essential oil can be adjusted according to the intended use within the range in which the total content of the essential oil does not deviate from the above range.

In addition, the natural antimicrobial agent according to the present invention may include a perennial herb extract, a Sorghum extract, a green tea extract, a Phytoncide extract, and a propolis extract.

In one embodiment, the extract of Rhododendron sulphate is obtained by drying leaves and roots of Rhododendron sulphate and then extracting them through a solvent. Houttuyniae herba (Scientific name: Houttuynia cordata) is a perennial plant with Saururaceae. It is the perennial plant of medicinal herb (Houttuynia cordata Thumb) in Korea and is a perennial herbaceous plant. Hwasungcho is rich in components such as flavonoids, quercitrin, myrcens, and lauric aldehyde, and can exert excellent antibacterial action. Especially, Escherichia coli, typhoid bacteria, Staphylococcus aureus, and Streptococcus pneumoniae are definitely inhibited. It is also effective against skin fungi, and it is a natural antibiotic that can suppress inflammation and regenerate tissues.

For example, the leaves and roots of the dried perlite are mixed with the volume ratio of purified water to ethanol or methanol at a ratio of 1: 3 to 3: 1, and the weight of the perlite weight 5 times, and extracted at 75 to 80 ° C for 4 hours, filtered and concentrated to be used as an extract.

In one embodiment, the extract of Rumex crispus is a genus Rumex spp. It is a perennial herb that grows well in moist places of various places. It uses the lysoon as a food in the private sector. In the oriental medicine, it is called a yosei, and it is categorized into various diseases including cystitis, gallbladder disease, bile secretion disorder, spleen disease, It is used as an adjuvant treatment for tumors and cancer. In addition, it has an antimicrobial and antioxidant effect against various microorganisms, and when it is mixed with a small amount of sulfur, it has an excellent effect on skin itching. It has been reported that saponins, tannins, flavonoids, essential oils and chrysophanol, and anthraquinone derivatives such as emodin, are known to be useful components of the present invention.

As an example of the method of extracting the Sorghum extract, the Sorghum is washed well, dried in the shade, and divided into the ground part (excluding the root) and the root part (root part). After immersing in 80% (v / v) methanol for 3 days as an extraction solvent, the extract was filtered with a membrane filter (pore size 0.5 mu m) to separate solids, and the methanol extract was concentrated at 50 DEG C using a rotary evaporator . After concentration, store in a suitable container and store at 4 ℃.

In one embodiment, commercially available products such as green tea extract, phytoncide extract and propolis extract contained as natural antimicrobial agents can be used.

The green tea has excellent antiseptic activity and deodorization efficiency due to the antioxidative action and active oxygen scavenging action of the cadenine component, and is a natural compound extracted from the leaves of green tea. Especially, the green tea polyphenol is an epigallocatechin gallate, It consists of five main components: epigallocatechin, epicatechin gallate, epicatechin and catechin. It contains antioxidant, ultraviolet absorbing, antihistaminic action, elimination of harmful oxygen, Anti-aging, anticancer effect, and so on.

Phytoncide is a substance that plants excrete or secretes to resist pathogens, insects and fungi. It is known to have a forest effect, a deodorizing effect, a insecticidal effect, a sterilization and an antibacterial effect and a side effect. Phenolic compounds including interferon, alkaloid components, glycosides, and the like.

Among the phytoncide components, terpenes act as a bactericide and preservative to kill bacteria, fungi, parasites and insects and inhibit growth and proliferation. They can be volatile and liquefied, so they can be inhaled deep into the body, There is no side effect because it is small, and it is excellent value.

The Phytoncide extract is a functional active active ingredient which is called a forest bath material in the present invention and has a sterilizing effect, antimicrobial effect and insecticidal effect. (Phytoncide) extracts selected from the group consisting of a mixture of phytoncide extract and phytoncide extract, or extracts of commercially available phytoncide extracts.

The propolis, also known as a sticky material used to build the honeycomb, contains 50-55% rosin and syrup (resin), 25-35% wax, 10% purified volatile oil, 5% , And 5% organic minerals. It is known to be completely harmless to human body. FLAVONOID, which is the main component of PROPOLIS, has antibacterial, anti-inflammatory, antioxidant, antibiotic, It also has immune and resistance-enhancing effects and cell regeneration.

In the present invention, the natural extract is a natural extract which does not cause toxicity or irritation in the human body. The extracts of Hwasungsuschae, Soraxiae extract, Green tea extract, Phytoncide extract and Propolis extract are each a mixture of single components having various actions, The pharmacological action of the liver is compounded and synergized. At this time, the natural antibacterial agent of the present invention containing the natural extract is preferably 10 to 30 parts by weight based on 100 parts by weight of purified water. When the natural antibacterial agent is less than 10 parts by weight, If the amount is more than 30 parts by weight, the degree of improvement of the antibacterial effect is insignificant and uneconomical.

As described above, the antimicrobial wet tissue of the present invention has excellent antimicrobial effect, direction effect, and deodorizing effect by replacing the existing chemical preservative with a natural substance extract (antibacterial agent) and an essential oil.

In the present invention, it is preferable to further include a surfactant and a pH adjusting agent. The surfactant may be sorbitan oleate or the like, but it is not limited thereto, and known surfactants may be used, except for those which are harmful to the human body and prohibited. The amount of the surfactant is preferably 0.1 to 0.3 parts by weight based on 100 parts by weight of the purified water. When the amount of the surfactant is less than 0.1 part by weight, the purified water and each component are not smoothly mixed. There is a disadvantage that the stability of the composition is poor.

In addition, the pH adjusting agent is added to inhibit oxidation. For example, sodium citrate, citric acid and the like may be used, but the present invention is not limited thereto. Except for being harmful to the human body and prohibited A known one can be used. The pH adjusting agent is preferably 0.1 to 0.3 parts by weight based on 100 parts by weight of purified water. When the pH is less than 0.1 part by weight, the pH of the composition is not smoothly controlled. When the amount is more than 0.3 part by weight,

Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.

<Examples>

First, a seaweed fiber nonwoven fabric was prepared by a chemical bonding method. Specifically, in order to form a web, cotton fibers, algae fibers and starch were blended with water and then pulverized as needed to form fluffs. The pulverization and mixing process includes a step of keeping the fiber length constant, and the blending ratio is 70% cotton, 10% seaweed fiber, 10% starch, and 10% polyvinyl acetate resin. Polyvinyl acetate resin was applied onto the web by spraying method to bond the webs when the web was formed by tangling the fiberstructure well. The nonwoven fabric was produced by pressing and drying at 120 ° C at 30 kg / cmG.

Next, an eco-friendly composition for wet tissue containing 100 parts by weight of purified water, 2 parts by weight of glycerin as a moisturizing agent, 0.2 parts by weight of sodium citrate as a pH adjusting agent, 1 part by weight of whitening component, 10 parts by weight of essential oil, and 20 parts by weight of natural antibacterial agent .

The prepared seaweed fiber nonwoven fabric was impregnated with the prepared composition for a wet tissue to prepare a wet tissue.

As described above, it is to be understood that the technical structure of the present invention can be embodied in other specific forms without departing from the spirit and essential characteristics of the present invention.

Claims (6)

A wet tissue produced by impregnating a wet tissue with a composition for a wet tissue,
The composition for a wet tissue includes purified water; Moisturizer; Whitening component; Essential oils and natural antimicrobial agents,
Wherein the wet tissue fabric is a nonwoven fabric containing at least one seaweed fiber selected from red algae and green algae,
Wherein the moisturizing agent is used in an amount of 1 to 3 parts by weight, the whitening component is used in an amount of 0.5 to 5 parts by weight, the essential oil is used in an amount of 5 to 15 parts by weight based on 100 parts by weight of the purified water, Wherein the antimicrobial wet tissue is made of algae fiber and natural antimicrobial agent. The method according to claim 1,
The nonwoven fabric may be prepared by mixing at least one selected from the group consisting of natural fibers and synthetic fibers with seaweed fibers and uniformly dispersing the fibers in water using an adhesive to prepare a mixed solution and then uniformly dispersing and laminating the mixed solution to form a web , Pressing it with a roller and drying it,
Wherein the algae fiber is contained in an amount of 1 to 80 wt% based on the dry weight of the nonwoven fabric. The method according to claim 1,
Wherein the whitening component is at least one selected from the group consisting of arbutin, niacinamide, ascorbyl glucoside, ascorbyl tetraisopalmitate, alpha-bisabolol and licorice extract. . The method according to claim 1,
Wherein the natural antimicrobial agent comprises a perennial herb extract, a sorghum extract, a green tea extract, a phytoncide extract and a propolis extract,
The extracts of the perennial herbs are prepared by mixing the dried leaves and roots of the perennial herb with the volume ratio of purified water to ethanol or methanol at a ratio of 1: 3 to 3: 1, Filtered and concentrated,
The Sorghum extract was washed with shampoo and dried in the shade. The shampoo extract was divided into a ground part, which is a part except for roots, and a lower part, which is a root part. The extract was soaked in 80% (v / v) methanol for 3 days , And the extract is filtered with a membrane filter to separate solid matter, and the methanol extract is concentrated at 50 캜 using a rotary evaporator. The antimicrobial wet tissue using the seaweed fiber and the natural antimicrobial agent. The method according to claim 1,
Wherein the humectant is at least one selected from the group consisting of glycerin, butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol and propanediol. The method according to claim 1,
Wherein the essential oil is selected from the group consisting of 0.001 to 0.01 wt% of rosemary oil, 0.002 to 0.01 wt% of grapefruit oil, 0.002 to 0.01 wt% of bergamot oil, 0.001 to 0.01 wt% of black pepper oil, 0.001 to 0.01 wt% of cedarwood oil, To 0.01% by weight of an orange oil, 0.005% to 0.02% by weight of an orange oil and 0.001% to 0.01% by weight of Clara sage oil.