KR20180013343A - Agricultural Chemicals Composition for Prevention and Extermination of Anthracnose and Virosis - Google Patents

Abstract

The present invention provides a pesticide composition for preventing and treating anthracnose and viral diseases, which contains, as active ingredients: a) 20-23 liters of water; b) 400-440 g of diamino diphenyl sulfone as a sulfone agent; c) 160-175 g of sulfamethoxazole as a sulfa agent; d) 720-800 g of trimethoprim as a sulfa agent; e) 5-5.5 g of streptomycin sulfate as an antibiotic agent; f) 2.5-3 g of Pai Nong San from the ancient prescriptions by Zhang Zhongjing; and g) 2.5-3 g of Shi Wei Bai Du San from the ancient prescriptions by Zhang Zhongjing, wherein preferably, the diamino diphenyl sulfone is contained in a quantity of 400-410 g, the sulfamethoxazole in a quantity of 160-164 g, and the trimethoprim in a quantity of 780-800 g.

Description

[0001] The present invention relates to an agricultural chemical composition for preventing and treating anthrax and viral diseases,

TECHNICAL FIELD The present invention relates to an agricultural chemical composition for preventing and treating anthrax and viral diseases, and more particularly to an agricultural chemical composition excellent in the prevention and treatment of anthrax and viral diseases (also called agoraphobia) which often occur in crops.

Anthrax is tomato, sweet potato, apple, peach. Strawberry, melon, red pepper, etc. It is a disease that rotten with dark brown or yellowish brown spots. It is usually sprayed with bordeaux solution to take precautions, but it has not seen any effect, and once it is known it is not cured .

On the other hand, viral diseases such as fruit trees, vegetables, tobacco, etc. are black rotted, stem and leaf are wilted, and after growing, leaves are severely shattered. If such a disease occurs, it is highly contagious, .

Therefore, farmers are spraying various pesticides to prepare for such diseases. However, it is known that no anthracnose and viral diseases are present in the anthrax and viral diseases at present.

[0004] Known therapeutic agents for anthrax include a copper sulfate basic salivating agent (trade name: Neo Bordeaux / Youngil Chemical), an oxy-pro wetting agent (trade name: Sando Fang Ai / Dongbang Hanong) Are known. Korean Patent Registration No. 10-0346313 discloses a red pepper anthracnose control agent based on rosin, and Korean Patent Registration No. 10-0669085 discloses a method for preventing and inhibiting anthrax anthracnose by using sodium hydroxide and sodium isocyanuric acid And Korean Patent Registration No. 10-0809797 discloses an anthrax control composition for plants containing a root extract of a strawberry root and a compound isolated therefrom. However, these components are slow in treatment and difficult to be completely treated. In addition, there is no cure for viral diseases, and fruit trees and crops have been protected for prevention.

The present applicant has invented a pesticidal composition having an excellent effect for the prevention / treatment of anthrax and viral diseases.

For example, the pesticide composition for preventing and treating anthrax and viral diseases of Patent Application No. 10-2000-0038293 was filed by the present applicant, and it is known that a mixture of a sulfone agent containing Diamino diphenyl sulfone as an active ingredient, a mixture of Sulfamethoxazole and Trimethoprim, or Norfloxacin is effective (W / w%) of 23-27: 36-47: 28: 36 or an antimicrobial agent comprising Diamino diphenyl sulfone as an active ingredient Or a mixture of sulfamethoxazole and trimethoprim or an antibiotic comprising a sulfa agent and sulphate streptomycin or kanamycin sulfate as an active ingredient in a ratio by weight of 23-27: 36-47: 28: 36 (w / w%) .

In order to solve the problem, the composition of the present invention has a problem in that its efficacy is reduced when it is applied outdoors, as compared with an excellent efficacy in a room. Therefore, in Korean Patent No. 10-0771530 (pesticide composition for the prevention and treatment of anthrax and viral diseases), Diamino diphenyl sulfone , A mixture of sulfamethoxazole and trimethoprim, or a mixture of sulfasulfate containing Norfloxacin as an active ingredient, antibiotics containing streptomycin sulfate or kanamycin sulfate, (W / w%) of 41-49: 21-27: 4-6: 4-6: 0.5-1, and has developed an excellent pesticidal composition for preventing and treating anthrax and viral diseases even outdoors .

However, even when the above composition is treated on crops, there is a problem in that vinegars or spore tinctures are found on trees, stems and the like, and they are not completely treated in a short time. Particularly, in case of pepper tree, the speed of the disease progresses rapidly, and even when the composition for treatment is sprayed, the treatment rate is slow depending on the progress of the disease, and the spore stain and the sperm remain in many cases.

Accordingly, the inventors of the present invention have been studying a substance capable of solving the above problems. When the herbal medicines of the rhubarb mordanti and the herb medicine are treated on the crops together with the components in the conventional composition, the spores produced in the crops due to anthrax and viral diseases The present inventors have completed the present invention by confirming that the viscous substance and the dirt phenomenon are suppressed and the treatment speed is fast.

That is, according to one aspect of the present invention, there is provided a pesticide composition for preventing and treating anthrax and viral diseases according to Patent Application No. 10-2012-0099688 filed by the present applicant, wherein a) a diamino diphenyl sulfone is used as an active ingredient A sulphonic agent; b) a mixture of Sulfamethoxazole and Trimethoprim or a sulfa agent containing Norfloxacin as an active ingredient; c) streptomycin sulfate or kanamycin sulfate; d) small diameter bowls; e) Pear; f) rhubarb mordanti tang; g) Cretaceous Paddox; And h) a pesticidal composition for preventing and treating anthrax and viral diseases comprising diatomaceous earth as an active ingredient.

The components a) to h) in the above-mentioned second conventional invention are in the order of 19 to 22:41 to 49:21 to 27: 4 to 6: 4 to 6:25 to 35:25 to 35: 0.5 to 1 It can be included.

However, the above-mentioned invention has a good effect, but it is difficult to purchase raw materials with high purity, and it is expensive and difficult to mass-produce and apply them.

Here, the term "ancient" refers to Chinese medicine, which refers to the prescriptions contained in the "upper limit" and "the golden rule" made by Zhang Zhongqing during the Chinese reign, and refers to a good pharmacy which has been passed down from ancient times in Oriental medicine.

In addition, although there are some effects which are caused by the above-mentioned medicines, there is a problem in economical efficiency due to a decrease in the effect or an increase in the unit price due to redundant over-prescription, and the effect is only good when the other pesticides are used. Therefore, it was necessary to select and test a herb medicine which can be applied at the least while giving the same effect as an environmentally friendly pesticide which has a function of eliminating toxicity due to the combination of herbs and herbs.

It is an object of the present invention to provide a method for preventing anthrax and anthrax caused by anthrax and viral diseases so that a certain anthrax anthrax can be eradicated even if the ratio of general medicines is slightly increased, The present invention provides a pesticide composition which completely inhibits spore tincture and genital formation and shows a high rate of disease treatment. Further, even if an environmentally friendly pesticide is produced by using a herb medicine which can exert a more pharmacological effect, Is an eco-friendly pesticide that has the effect of disappearing toxicity. It has a purpose of selecting and applying a herb medicine which can be applied at least with minimum effect while giving the same effect. To find and apply herbal medicine that can supply It is an object.

The present invention relates to a process for the preparation of a mixture of a) 20-23 liters of water; b) 400 g to 440 g of Diamino diphenyl sulfone as a sulfonic agent; c) 160-175 g of sulfamethoxazole as a sulfazine; d) 720-800 g of Trimethoprim as a sulfazine; e) 5 to 5.5 g of streptomycin sulfate as an antibiotic; f) 2.5 to 3 g of abalone as a herb; g) 2.5 to 3 g of Tryptic Paddan as a herb; As an active ingredient, for preventing and treating anthrax and viral diseases.

The present invention also provides an agricultural chemical composition for preventing and treating anthrax and viral diseases, wherein Diamino diphenyl sulfone is 400-410 g, Sulfamethoxazole is 160-164 g, and Trimethoprim is 780-800 g.

The CAS No. of Diamino diphenyl sulfone is 80-08-0, the molecular structure is C12H12N202S, the CAS No. of Sulfamethoxazole is 723-46-6, the molecular structure is C1OH11N303S, and the CAS No. of Trimethoprim is 738-70-5, the molecular structure is C14H18N403, the CAS No. of the streptomycin sulfate is 3810-74-0, and the molecular structure is C21H39N7012-1.5H2SO4, and a pesticidal composition for preventing and treating anthrax and viral diseases .

The pesticidal composition according to the present invention has the advantage of completely and rapidly suppressing the formation of spore glandular and algae of crops caused by anthrax and viral diseases, and the treatment rate of disease is greatly improved.

As a result of the application of the conventional antibiotics using high-dose antibiotics, the effect of small amounts of antibiotics has been obtained. Even if the antibiotics are used, the antibiotics of easy-to- have.

In addition, the composition is excellent in both indoors and outdoors crops, and has an economical merit because it exhibits sufficient control effect even with only a single spray.

Furthermore, since the composition of the present invention is made of a medicament containing no heavy metals, it is possible to avoid pesticide pollution and its effect is remarkable, so that it will be possible to drastically relieve the pests and diseases of farming.

Figure 1 is a photograph of an early detection of anthrax as an experimental scene in the Hadong area of Gyeongnam.
FIG. 2 is a photograph of the state after the first and second spraying of an anthrax medicine as an experimental scene in the Hadong area,
Fig. 3 shows the results of the experiment
Fig. 4 is a photograph showing the initial state of anthrax disease as an experiment scene in Daegu area, Gyeongbuk province.
FIG. 5 is a photograph showing the state after the first and second spraying of anthrax remedy,
FIG. 6 is a photograph of an early detection of anthrax as an experimental scene in the Chuncheon area of Gangwon Province.
FIG. 7 is a photograph of the state after the first and second spraying of an anthrax medicine as an experimental scene in the Chuncheon area of Gangwon Province

Hereinafter, the configuration of the present invention will be described in more detail.

The pesticidal composition of the present invention comprises: a) 20 to 23 liters of water; b) 400 g to 440 g of Diamino diphenyl sulfone as a sulfonic agent; c) 160-175 g of sulfamethoxazole as a sulfazine; d) 720-800 g of Trimethoprim as a sulfazine; e) 5 to 5.5 g of streptomycin sulfate as an antibiotic; f) 2.5 to 3 g of abalone as a herb; g) 2.5 to 3 g of Tryptic Paddan as a herb; Wherein the diamino diphenyl sulfone is 400-410 g, the sulfamethoxazole is 160-464 g, and the trimethoprim is 780-800 g. The present invention also provides a pesticide composition for preventing and treating anthrax and viral diseases, And a pesticide composition for preventing and treating viral diseases.

The medicament used in the composition of the present invention is a general medicine to be taken by humans, and contains no heavy metals, unlike ordinary pesticides (containing heavy metals), and is almost harmless to the human body.

The pesticidal composition according to the present invention is based on a sulfone agent containing diamino diphenyl sulfone (dapsone) as an active ingredient, and a sulfa agent and an aminoglycoside antibiotic are mixed therewith.

Diamino diphenyl sulfone used in the pesticidal composition of the present invention is often called DDS and is effective for microorganisms such as streptococcus and pneumococcus, and has a bactericidal action against Mycobacterium tuberculosis and nematodes.

The sulfa agent used in the pesticidal composition of the present invention is a co-operative mixed agent comprising Sulfamethoxazole and Trimethoprim as an active ingredient or a pharmaceutical agent containing Norfloxacin as an active ingredient. The former exhibits a synergistic effect with respect to a bacterium, Laryngitis, urethritis and enteritis, and the latter is known to be effective against Staphylococcus, Streptococcus, Enterococcus, Streptococcus pneumonia, and Escherichia coli.

Aminoglycoside antibiotics are antibiotics containing Streptomycin sulfate or Ganamycin sulfate belonging to the group of Streptomycin as an active ingredient and have antimicrobial effect against Mycobacterium tuberculosis , And the present invention has adopted the above-mentioned streptomycin sulfate.

In addition, the herbal medicine used in the pesticidal composition of the present invention, which is a herbal medicine, is effective for muscular pain, back pain, arthralgia and neuralgia, and its main ingredients are antioxidant, , Ganghwal (羌 活), 天 궁 (风), wind (风)), 白 朮, Yongdam Yongdam, 茯 笭 笭, ginger (生薑), doin , Peony (藥 药), blank paper (白 紙), 牛 (牛膝), licorice (甘草) and so on.

Here, the present inventor found baejungsan and tenyum paddoxan, which are effective in the treatment of anthrax, with the above-mentioned medicines, and succeeded in the experiment.

Bacillus is a herbal medicine used for acute inflammation. Its main ingredients are licorice, gigyeong, ginger, jujube, peony, and zilch. It has the effect of drainage by using it in a state of edema which has not yet developed agitation due to pus, exudate, acne, subcutaneous abscess, purulent lymphadenitis, tonsillitis, sinusitis, gingivitis, , The present invention serves to kill insects parasitic on crops.

Tryptic Paddox is used as a herbal medicine for the improvement of allergic constitution. Its main ingredients are Seoh, Gyungyang, Windblown, Tunggung, Aspie, Bokryeong, Health, Easybye, Chrysanthemum, Licorice and Ankong. The efficacy of the allergic constitution due to dermatitis and rhinitis, eczema (leprosy), lymphadenitis (lonorrhea), maxillary sinusitis (maxillary sinusitis), otitis (otitis media) and 癰 절 (癰 癤) It is used to treat neuropsychiatric, chest and lobular redness and swelling and swelling of the boil.

The crops to which the pesticidal composition of the present invention can be applied are not particularly limited as long as they are crops capable of causing anthrax and viral diseases. For example, rice, beans and peas are used as food crops, Spinach, Sagittarius, Tomatoes are possible, and the persimmon is persimmon, vine, plum tree, peach tree, citrus tree, chestnut. Apple trees and so on.

The pesticidal composition of the present invention further increases the rate of treatment of anthrax and viral diseases within the range of the weight ratio, and suppresses the generation of sludge and spore tangles in the crops, thereby enabling complete treatment.

Further, the composition of the composition CAS No. And CAS No. of the diamino diphenyl sulfone are 80-08-0, the molecular structure is C12H12N202S, the CAS No. of Sulfamethoxazole is 723-46-6, the molecular structure is C1OH11N303S, and the CAS No. of Trimethoprim is CAS No. 738-70-5, the molecular structure is C14H18N403, the CAS No. of the streptomycin sulfate is 3810-74-0, and the molecular structure is C21H39N7012-1.5H2SO4.

The pesticidal composition of the present invention may further include known antibacterial and antiviral substances in addition to the above components. In addition, the composition may further comprise pharmaceutical ingredients commonly used in pesticides, such as solvents, coagulants, dispersants, surfactants, binders, flow aids, and the like.

The pesticidal composition of the present invention can be prepared into a suitable formulation according to the application method. For example, formulations such as concentrates, dispersants, wettable powders, soluble powders, tablets, water-dispersible granules and the like, which can be immediately and diluted with water, preferably, but not exclusively, wettable agents.

When the composition of the present invention is a wetting agent, 10-20 g of water may be added per 20 liters of water. It is expected that sufficient anthrax and viral disease prevention and treatment effects can be expected while minimizing drug loss in the above range of usage.

The pesticidal composition of the present invention can be treated with crops in a conventional manner to control crop anthrax. For example, the composition may be treated before or after the onset of anthrax and viral diseases, and may be sprayed on the soil at an appropriate concentration, or sprayed once or several times with the leaf, stem, flower or fruit of the crop.

The number of administration, the interval of administration, and the concentration of administration can be controlled according to the degree of growth of anthrax bacteria and environmental conditions such as climate, but it is possible to obtain sufficient preventive and therapeutic effect even by one time spraying. For example, when the pesticide formulation of the wettable powder formulation is mixed with water, the pesticide sprayer can be used to spray the plantlets and vegetables evenly.

 The pesticidal composition of the present invention is safe because it does not cause toxicity to ecosystems such as crops, livestock, and humans, and is environmentally friendly because it does not contain heavy metals.

The present inventors have examined the synergistic action of the drug efficacy due to the selection of various medicines, the composition of the compounding ratio, and the combination thereof. As a result, it has been found that the pesticidal composition according to the present invention is effective for anthrax and viral diseases Is not clear, but it is presumed that the synergistic effect is due to the interaction of the constituents.

Hereinafter, the configuration and operation of the present invention will be described in more detail with reference to preferred embodiments of the present invention. However, the following examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited to the following examples. The contents not described here are sufficiently technically inferior to those skilled in the art, and a description thereof will be omitted.

Examples and test examples of the present invention were conducted on outdoor crops.

Example 1 . Pesticide composition manufacturing

Each of the pesticidal compositions was prepared with the compositions described below.

a) 20 to 21 liters of water; b) 400-410 g of Diamino diphenyl sulfone as a sulfonic agent; c) 160 to 164 g of sulfamethoxazole as a sulfazine; d) 780-800 g of Trimethoprim as a sulfazine; e) 5 to 5.1 g of streptomycin sulfate as an antibiotic; f) 2.5 to 2.7 g of crude oil per day; g) 2.5 to 2.7 g of cedar Paddan as a herb; And spray it evenly over the whole pepper tree with an atomizer.

CAS No. < / RTI > And CAS No. of the diamino diphenyl sulfone are 80-08-0, the molecular structure is C12H12N202S, the CAS No. of Sulfamethoxazole is 723-46-6, the molecular structure is C1OH11N303S, and the CAS No. of Trimethoprim is CAS No. 738-70-5, the molecular structure is C14H18N403, the CAS No. of the streptomycin sulfate is 3810-74-0, and the molecular structure is C21H39N7012-1.5H2SO4.

At this time, it is found that anthrax is transferred from moist soil, and it is useful to spray down the leaves of pepper tree.

Since the formulation of the composition herein may be somewhat different depending on the degree of skill of the person who prepared it, the standardized amount within the above range was used as the standard.

Test Example  1. Control and prevention of pepper anthracnose (Hadong area)

FIG. 1 is a photograph of an actual anthrax of anthrax in the Hadong area of Gyeongnam, FIG. 2 is a photograph of a real situation after the first and second application of an anthrax healing agent as an experimental scene of the Hadong area of Gyeongnam, This is the personal information of the experimenter in Hadong area.

As shown in the photograph of the above drawing, it was found that the initial occurrence of anthrax can be visually judged at the time when the red pepper starts to bear fruit.

≪ 1 >

Picture 1  : Anthrax outbreak (taken on October 10, 2013)

The composition solution of Example 1 was sprayed once in an amount of 200 cc per square and observed visually after 10 days.

It was sprayed once again on the 10th day, and the appearance of spore glue and spermatogenesis was evaluated by looking at the appearance of the pepper tree.

The result was a normal red pepper state as shown in Fig.

2,

Picture 2  : Anthrax Cure 1, 2nd After spraying (Photographed on March 10, 2013)

As shown in the photograph of FIG. 2, when the composition solution of Example 1 was sprayed on the red pepper, it regenerated at a rapid rate in the initial state.

Test Example  2. Control and prevention of pepper anthracnose (Daegu area)

FIG. 4 is an actual photograph of an anthrax disease discovery state in an experimental site in Daegu, Kyungbuk Province, and FIG. 5 is an actual photograph of a state after an anthrax disease agent is applied as an experimental scene in Daegu, Kyungbuk Province.

As can be seen from the above photographs, it was found that the initial occurrence of anthrax can be visually judged at the time when the red pepper is cooked.

<Fig. 4>

Picture 3  : When anthrax occurs

The composition solution of Example 1 was sprayed once in an amount of 200 cc per square and observed visually after 10 days.

It was sprayed once again on the 10th day, and the appearance of spore glue and spermatogenesis was evaluated by looking at the appearance of the pepper tree.

The result was a normal pepper state as shown in Fig.

5,

Picture 4  : Anthrax Cure 1, 2nd After spraying

As shown in the photograph of FIG. 5, when the composition solution of Example 1 was treated with pepper, it regenerated at a rapid rate in the initial state.

Test Example  3. Control and prevention of pepper anthracnose (Chuncheon area)

FIG. 6 is an actual photograph of an anthrax disease discovery state as an experimental scene in the Chuncheon area of Gangwon Province and FIG. 7 is an actual photograph of a state after the first and second spraying of an anthrax remedy as an experimental scene in Chuncheon area, Kangwon Province.

As shown in the photograph of the above drawing, when pepper fruit was produced and an anthrax bottle was caught, a part of the pepper body was found to be plastered or scratched.

6,

Picture 5  : When anthrax occurs

The composition solution of Example 1 was sprayed once in an amount of 200 cc per square and observed visually after 10 days.

It was sprayed once again on the 10th day, and the appearance of spore glue and spermatogenesis was evaluated by looking at the appearance of the pepper tree.

The result was as shown in Fig. 7, but leaves were not treated with anthracnose of pepper.

7,

Picture 6  : Anthrax Cure 1, 2nd After spraying

As shown in the photograph of FIG. 7, when the composition solution of Example 1 was treated with pepper, it was found that the red pepper would not be treated if an anthrax disease occurred and the red pepper body was scratched. Therefore, It is through this that it is necessary to treat it.

In addition to the above, the inventor of the present invention found that the tobacco leaves were shrunk and dried due to the development of tobacco disease in the growing period of the tobacco tobacco, and as a result of the experiments, it was confirmed that these were treated, and the roots of the ginger were rotten, They came to the dry field and confirmed that they were cured.

Claims (3)

a) 20-23 liters of water;
b) 400 g to 440 g of Diamino diphenyl sulfone as a sulfonic agent;
c) 160-175 g of sulfamethoxazole as a sulfazine;
d) 720-800 g of Trimethoprim as a sulfazine;
e) 5 to 5.5 g of streptomycin sulfate as an antibiotic;
f) 2.5 to 3 g of abalone as a herb;
g) 2.5 to 3 g of Tryptic Paddan as a herb;
As an active ingredient, for the prevention and treatment of anthrax and viral diseases. The method according to claim 1,
Wherein the Diamino diphenyl sulfone is 400-410 g, Sulfamethoxazole is 160-164 g, and Trimethoprim is 780-800 g. 3. The method according to claim 1 or 2,
The CAS No. of Diamino diphenyl sulfone is 80-08-0, the molecular structure is C12H12N202S, the CAS No. of Sulfamethoxazole is 723-46-6, the molecular structure is C1OH11N303S, and the CAS No. of Trimethoprim is 738-70-5 , The molecular structure is C14H18N403, the CAS No. of the streptomycin sulfate is 3810-74-0, and the molecular structure is C21H39N7012-1.5H2SO4.

Images