KR20170115433A - A dyeing and printing processing method for high shrinkable yarn fabric of imitation linen cotton - Google Patents

A dyeing and printing processing method for high shrinkable yarn fabric of imitation linen cotton Download PDF

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KR20170115433A
KR20170115433A KR1020167023839A KR20167023839A KR20170115433A KR 20170115433 A KR20170115433 A KR 20170115433A KR 1020167023839 A KR1020167023839 A KR 1020167023839A KR 20167023839 A KR20167023839 A KR 20167023839A KR 20170115433 A KR20170115433 A KR 20170115433A
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temperature
fabric
dyeing
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water
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웨이동 장
빙화 시
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지앙수 신카이성 엔터프라이즈 디벨롭먼트 컴퍼니 리미티드
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/10After-treatment with compounds containing metal
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20Physical treatments affecting dyeing, e.g. ultrasonic or electric

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

본 발명은 의마 면의 고수축사 원단의 염색 및 날염 가공 방법에 관한 것으로, 전처리 단계, 산세척 단계, 염색 단계 및 정형 단계를 포함하고, 원단이 충분히 수축함으로써 의마 면의 질감을 제공하는데 있다. 상기 방법에 의하여, 본 발명의 의마 면의 고수축사 원단의 염색 및 날염 가공 방법은, 전처리 및 산세척을 이용하여 원단에 염색을 진행하기 전에 세척 처리를 진행함으로써, 착색이 편리하고, 염색 후의 색깔 차이와 얼룩을 감소할 수 있으며, 염색 과정에서 원단 섬유의 풀림과 온도 하강 수축을 진행하여 독특한 제품 스타일을 얻을 수 있고, 원단의 감촉이 의마 면에 가까운 효과를 달성하며, 천이 오돌토돌한 느낌을 가지므로 완제품 원단이 우븐(woven) 원단에 더욱 가깝다.The present invention relates to a dyeing and printing processing method for a corn silk fabric, which comprises a pretreatment step, a pickling step, a dyeing step and a shaping step, wherein the fabric is sufficiently shrunk to provide a texture of the hemp surface. According to the above method, the dyeing and printing processing method of the corn silk fabric of the present invention can be easily colored by proceeding the washing process before the dyeing is performed on the fabric using the pretreatment and pickling, It is possible to reduce the difference and stain, and it is possible to obtain a unique product style by proceeding the loosening of the fabric and the lowering shrinkage of the fabric during the dyeing process, and the effect of the fabric is close to that of the hemp surface, So that the finished fabric is closer to the woven fabric.

Description

의마 면의 고수축사 원단의 염색 및 날염 가공 방법 {A DYEING AND PRINTING PROCESSING METHOD FOR HIGH SHRINKABLE YARN FABRIC OF IMITATION LINEN COTTON}TECHNICAL FIELD [0001] The present invention relates to a method for dyeing and printing a high-

본 발명은 고수축사 원단의 염색 및 날염 분야에 관한 것으로, 특히 의마 면의 고수축사 원단의 염색 및 날염 가공 방법에 관한 것이다.The present invention relates to the field of dyeing and printing of high-fiber barn fabrics and, more particularly, to dyeing and printing processing methods of high-barn fabrics of hemp yarns.

종래의 고수축사 원단의 생산공업은 아직 발전되지 않아, 원단 표면에 색깔 차이나 얼룩이 나타나기 쉽기에, 염색 공법을 개선할 필요가 있다.Conventionally, the production industry of high-fiber barn fabrics has not been developed yet, and it is necessary to improve the dyeing technique because color difference and unevenness easily appear on the surface of the fabric.

또한, 종래의 고수축사 원단은 감촉이 통상적으로 부드럽고 매끄러워 의마 면의 효과를 제공할 수 없고, 천에 오돌토돌한 느낌을 주지 못하므로 개선이 필요하다.In addition, conventional cored barn fabrics generally require a smooth, smooth, and smooth feel and can not provide a feeling of odor on the fabric.

본 발명이 주요하게 해결하고자 하는 기술적 과제는 의마 면의 질감을 제공하고 색깔 차이와 얼룩을 방지하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법을 제공하는 것이다.It is an object of the present invention to provide a method of dyeing and printing a cored barn of a corn surface to provide a texture of a corn surface and prevent color difference and stains.

의마 면의 고수축사 원단의 염색 및 날염 가공 방법에 있어서,In the method of dyeing and printing the corn fiber of the corn surface,

원단을 염색 항아리(dye vat) 내에 넣고 제1차 온도 상승 처리를 진행하되, 35℃까지 온도 상승되면 3 내지 5g/L의 탄산나트륨과 2 내지 5g/L의 유화 기름제거제를 첨가하고, 욕비(liquor ratio)를 1:8 내지 12로 제어한 다음 계속 제2차 온도 상승처리를 진행하되 온도는 100 내지 120℃로 제어하고, 보온시간은 30 내지 50분인 전처리 단계;The fabric was put in a dye vat and subjected to a first temperature raising treatment. When the temperature rose to 35 캜, 3 to 5 g / L of sodium carbonate and 2 to 5 g / L of an emulsifying oil remover were added, ratio is controlled to 1: 8 to 12, and then the second temperature raising treatment is continued but the temperature is controlled at 100 to 120 ° C and the keeping time is 30 to 50 minutes;

상기 전처리가 끝난 후 온도 하강 처리를 진행하되, 온도 하강 속도는 2 내지 3℃/분으로 제어하고, 50℃ 이하까지 온도 하강되면, 염색 항아리의 물을 모두 배출한 후 두 번 물 세척하고, 다시 급수하고 1 내지 3g/L의 빙초산을 첨가한 다음, 제3차 온도 상승 처리를 진행하고, 50℃까지 온도 상승되면 15 내지 30분동안 세척(cloth washing)을 진행하는 산세척 단계;After the pretreatment is completed, the temperature lowering treatment is performed, the temperature lowering rate is controlled at 2 to 3 ° C / min, and when the temperature is lowered to 50 ° C or lower, the water in the dyeing jar is drained, A pickling step in which glacial acetic acid is added in an amount of 1 to 3 g / L and then subjected to a third temperature raising treatment, and when the temperature is raised to 50 캜, washing is carried out for 15 to 30 minutes;

상온에서 염료액과 보조제를 첨가하고, 상기 보조제는 98% 농도의 빙초산1 내지 3g/L, 유화 기름제거제1 내지 3g/L, 균염제(leveling agent) 1.5 내지 5g/L와 안정제1 내지 4g/L를 포함하며, 욕비는 1:8 내지 12로 제어하고, 계속 온도 상승시키되, 온도 상승 속도는 2 내지 5℃/분으로 제어하고, 85℃까지 온도 상승되면 2 내지 5분 보온을 진행하고, 계속 1 내지 3℃/분의 속도로 110 내지 120℃까지 온도 상승시키고, 10 내지 15분 보온을 진행하며, 계속 1 내지 5℃/분의 속도로 130 내지 150℃까지 온도 상승시키고 30 내지 40분 보온을 진행하며, 보온이 끝난 후 1.5 내지 5℃/분의 속도로 80 내지 100℃까지 온도 하강시키고, 또 3 내지 5℃/분의 속도로 50 내지 70℃까지 온도 하강시킨 다음, 상온까지 가속 온도 하강시켜, 원단의 수축율을 증가시키며, 상기 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15 내지 30분 세척하며, 다시 급수하고 수산화나트륨(Caustic soda) 2 내지 5g/L와 티오황산나트륨(sodium hyposulfite) 1 내지 3g/L을 첨가하고, 수산화나트륨을 첨가하여 원단 섬유가 풀리게 하여 독특한 원단 스타일을 형성하고, 85 내지 100℃까지 온도 상승시키되, 온도 상승 속도는 2 내지 5℃/분이고, 후처리는 20 내지 30분 보온하여 천에 주름감이 생기게 하고 균염 효과를 달성하여 얼룩 및 색깔 차이가 나타나는 현상을 방지하고; 보온이 끝난 후 1 내지 3℃/분의 속도로 50 내지 70℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15 내지 20분 세척하며, 다시 급수하고, 98% 농도의 빙초산 0.8 내지 2g/L을 첨가하며, 60 내지 80℃까지 온도 상승시키되, 온도 상승 속도는 2 내지 5℃/분이고, 20 내지 30분 보온을 진행하고, 보온 과정에서의 시간이 천의 주름감이 충분한지의 여부를 결정하고; 보온이 끝난 후 3 내지 5℃/분의 속도로 50 내지 60℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15 내지 30분 세척하며, 다시 급수하고, 98% 농도의 빙초산 0.3 내지 1g/L을 첨가하며, 10 내지 15분 운행시킨 후 염색 항아리에서 물과 함께 꺼내는 염색 단계;The dye solution and the adjuvant are added at room temperature and the adjuvant is added at a concentration of 1 to 3 g / L of glacial acetic acid at a concentration of 98%, 1 to 3 g / L of an emulsifying oil remover, 1.5 to 5 g / L of a leveling agent and 1 to 4 g / And the bath temperature is controlled to 2 to 5 DEG C / min. When the temperature is raised to 85 DEG C, the heating is continued for 2 to 5 minutes, The temperature is raised to 110 to 120 ° C at a rate of 1 to 3 ° C / minute, the temperature is maintained at 10 to 15 minutes, the temperature is raised to 130 to 150 ° C at a rate of 1 to 5 ° C / The temperature is lowered to 80 to 100 DEG C at a rate of 1.5 to 5 DEG C / minute, the temperature is lowered to 50 to 70 DEG C at a rate of 3 to 5 DEG C / minute, To increase the contraction ratio of the fabric, and to remove all the water in the dyeing pot After draining, rinse twice with water each time for 15 to 30 minutes, re-water, add 2 to 5 g / L of Caustic soda and 1 to 3 g / L of sodium hyposulfite, add sodium hydroxide The fabric is loosened to form a unique fabric style, and the temperature is raised to 85 to 100 DEG C, the temperature rising speed is 2 to 5 DEG C / min, and the post-treatment is performed for 20 to 30 minutes, And achieving a leveling effect to prevent the appearance of stain and color difference; After the warming is completed, the temperature is lowered to 50 to 70 DEG C or less at a rate of 1 to 3 DEG C / minute, the water in the dyeing pot is drained, washed twice with water each time for 15 to 20 minutes, , 0.8 to 2 g / L of glacial acetic acid at a concentration of 98% is added and the temperature is raised to 60 to 80 DEG C, the temperature rising rate is 2 to 5 DEG C / min, the temperature is maintained for 20 to 30 minutes, Determining whether a wrinkle feeling of the cloth is sufficient; After the warming is completed, the temperature is lowered to 50 to 60 ° C or less at a rate of 3 to 5 ° C / minute, the water in the dyeing pot is drained and then washed twice, washed 15 to 30 minutes each time, , Adding 0.3 to 1 g / L of glacial acetic acid at a concentration of 98%, traveling for 10 to 15 minutes, and then taking out the water from the staining pot together with water;

정형 온도는 170 내지 190℃이고, 상기 정형 온도가 보통 원단보다 높은 목적은 원단 수축이 더욱 충분하게 하기 위한 것이며, 친수성 유연제 0.3 내지 1%를 첨가하고, 원단이 패더(padder)를 통과하여 정형 오븐 내에 진입하는 정형 단계를 포함하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법을 제공한다.The shaping temperature is in the range of 170 to 190 DEG C and the shaping temperature is higher than that of the normal fabric in order to more fully shrink the fabric. 0.3 to 1% of the hydrophilic softening agent is added, and the fabric is passed through a padder, The method comprising the steps of: (a) forming a stencil surface on the corn surface;

본 발명의 바람직한 실시예에 있어서, 상기 정형 단계에서 상기 패더의 속도는 21 내지 25m/분이다.In a preferred embodiment of the present invention, the speed of the fader in the shaping step is 21 to 25 m / min.

본 발명의 바람직한 실시예에 있어서, 상기 염색 단계에서 사용된 염료액 중의 염료는 각 색깔에 따라 그 사용량을 결정한다.In a preferred embodiment of the present invention, the dye in the dye liquid used in the dyeing step determines the amount of the dye to be used according to each color.

본 발명의 바람직한 실시예에 있어서, 상기 염색 단계에서 상온까지 가속 온도 하강시키는 과정에서 얼음을 포함한 냉각수를 이용하여 염색 항아리를 온도 하강시키는 것을 통해 상온까지 온도 하강시키는 속도를 가속화함으로써 원단 수축율을 증가시킨다.In a preferred embodiment of the present invention, in the process of lowering the acceleration temperature to room temperature in the dyeing step, the speed at which the dyeing pot is lowered to room temperature is accelerated by using the cooling water containing ice to increase the fabric shrinkage rate .

본 발명의 유리한 효과에 있어서, 본 발명이 제공하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법은, 전처리 및 산세척을 이용하여 원단에 염색을 진행하기 전에 세척 처리를 진행함으로써, 착색이 편리하고, 염색 후의 색깔 차이와 얼룩을 감소할 수 있으며, 염색 과정에서 원단 섬유의 풀림과 온도 하강 수축을 진행하여 독특한 제품 스타일을 얻을 수 있고, 원단의 감촉이 의마 면에 가까운 효과를 달성하며, 천이 오돌토돌한 느낌을 가지므로 완제품 원단이 우븐(woven) 원단에 더욱 가깝다.In the advantageous effect of the present invention, the dyeing and printing processing method of the corn silk fabric of the present invention provided with the present invention is advantageous in that it is convenient to perform the washing treatment before dyeing on the fabric using the pretreatment and pickling And the color difference and stain after dyeing can be reduced. In the dyeing process, the loosening of the fabric fibers and the lowering and shrinking of the fabric are promoted to obtain a unique product style. The fabric texture achieves the effect close to the hemp surface, The finished fabric is even closer to the woven fabric because it has an odorless texture.

이하, 본 발명의 실시예에 따른 기술적 해결수단에 대하여 더욱 명확하고 완전한 설명을 진행한다. 하기에서 설명된 실시예들은 단지 본 발명의 일부 실시예일 뿐 전부 실시예가 아니다. 본 발명의 실시예에 기반하여 본 기술분야의 통상의 기술자들이 진보성 창출에 힘쓸 필요가 없이 얻은 기타 모든 실시예들은 모두 본 발명의 보호 범위에 속해야 할 것이다.Hereinafter, the technical solution according to the embodiment of the present invention will be described more clearly and completely. The embodiments described below are merely some embodiments of the present invention and are not all embodiments. All other embodiments, which the ordinary artisan skilled in the art does not need to devote themselves to inventive steps based on the embodiments of the present invention, should be covered by the scope of the present invention.

본 발명의 실시예는 하기와 같다.An embodiment of the present invention is as follows.

실시예1Example 1

의마 면의 고수축사 원단의 염색 및 날염 가공 방법은The method of dyeing and printing of cornstarch fabrics

원단을 염색 항아리 내에 넣고 제1차 온도 상승 처리를 진행하되, 35℃까지 온도 상승되면 4g/L의 탄산나트륨과 3g/L의 유화 기름제거제를 첨가하고, 욕비를 1:8로 제어한 다음 계속 제2차 온도 상승 처리를 진행하되 온도는 100℃로 제어하고, 보온시간은 30분인 전처리 단계;When the temperature was raised to 35 ° C., 4 g / L of sodium carbonate and 3 g / L of emulsifying oil remover were added and the bath ratio was controlled to 1: 8. Then, A pretreatment step in which the temperature rise is controlled at 100 ° C and the keeping time is 30 minutes,

전처리가 끝난 후 온도 하강 처리를 진행하되, 온도 하강 속도는 2℃/분으로 제어하고, 45℃까지 온도 하강되면, 염색 항아리 중의 물을 모두 배출한 후 두 번 물 세척하고, 다시 급수하고 2g/L의 빙초산을 첨가한 다음, 제3차 온도 상승처리를 진행하고, 50℃까지 온도 상승되면 15분동안 세척(cloth washing)을 진행하는 산세척 단계;After the pretreatment is completed, the temperature is lowered, and the temperature lowering rate is controlled at 2 ° C / min. When the temperature is lowered to 45 ° C, the water in the dyeing jar is drained and washed twice, L of glacial acetic acid is added and then the third temperature raising treatment is carried out, and when the temperature is raised to 50 DEG C, washing is carried out for 15 minutes;

상온에서 염료액과 보조제를 첨가하고, 염료액 중의 염료는 각 색깔에 따라 그 사용량을 결정하며, 보조제는 98% 농도의 빙초산2g/L, 유화 기름제거제1g/L, 균염제 3g/L와 안정제2g/L를 포함하며, 욕비는 1:10으로 제어하고, 계속 온도 상승시키되, 온도 상승 속도는 3℃/분으로 제어하고, 85℃까지 온도 상승되면 4분 보온을 진행하고, 계속 2℃/분의 속도로 116℃까지 온도 상승시키고, 10분 보온을 진행하며, 계속 2℃/분의 속도로 140℃까지 온도 상승시키고 30분 보온을 진행하며, 보온이 끝난 후 3℃/분의 속도로 80℃까지 온도 하강시키고, 또 3℃/분의 속도로 60℃까지 온도 하강시킨 다음, 상온까지 가속 온도 하강시켜, 원단의 수축율을 증가시키며(상온까지 가속 온도 하강시키는 과정에서 얼음을 포함한 냉각수를 이용하여 염색 항아리를 온도 하강시키는 것을 통해 상온까지 온도 하강시키는 속도를 가속화함으로써 원단 수축율을 증가시킨다), 염색 항아리 중의 물을 모두 배출한 후, 두번 물 세척하되, 매번 18분 세척하며, 다시 급수하고 수산화나트륨 3g/L와 티오황산나트륨 2g/L을 첨가하고, 수산화나트륨을 첨가하여 원단 섬유가 풀리게 하여 독특한 원단 스타일을 형성하고, 85℃까지 온도 상승시키되, 온도 상승 속도는 3℃/분이고, 후처리는 20분 보온을 진행하여 천에 주름감이 생기게 하고 균염 효과를 달성하여 얼룩 및 색깔 차이가 나타나는 현상을 방지하고; 보온이 끝난 후 2℃/분의 속도로 55℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15분 세척하며, 다시 급수하고, 98% 농도의 빙초산 1g/L을 첨가하며, 65℃까지 온도 상승시키되, 온도 상승 속도는 3℃/분이고, 20분 보온을 진행하고, 보온 과정에서의 시간이 천의 주름감이 충분한지의 여부를 결정하며, 보온이 끝난 후 3℃/분의 속도로 50℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 20분 세척하며, 다시 급수하고, 98% 농도의 빙초산 0.5g/L을 첨가하며, 10분 운행시킨 후 염색 항아리에서 물과 함께 꺼내는 염색 단계;The dyestuffs and auxiliaries were added at room temperature, and the amounts of dyestuffs in the dye liquids were determined according to the respective colors. Adjuvants were 2 g / L of glacial acetic acid at a concentration of 98%, 1 g / L of an emulsifying oil remover, 3 g / L of a leveling agent, / L, and the bath ratio was controlled to 1:10, and the temperature was raised at a rate of 3 ° C / minute. When the temperature was raised to 85 ° C, , The temperature was raised to 116 DEG C at a rate of 10 DEG C / min, the temperature was increased to 140 DEG C at a rate of 2 DEG C / min and the temperature was maintained for 30 minutes. The temperature is lowered to 60 占 폚 at a rate of 3 占 폚 / minute and then the acceleration temperature is lowered to room temperature to increase the contraction ratio of the fabric (in the process of lowering the accelerating temperature to room temperature, To lower the temperature of the dyeing pot And the fabric shrinkage rate is accelerated by accelerating the temperature lowering rate to the solution temperature). After discharging all of the water in the dyeing jar, rinse twice with water each time for 18 minutes, again with water, add 3 g / L of sodium hydroxide and 2 g of sodium thiosulfate / L was added and sodium hydroxide was added to loosen the fabric to form a unique fabric style and the temperature was raised to 85 DEG C while the temperature rise rate was 3 DEG C per minute and the post- Preventing wrinkles and achieving a leveling effect so as to prevent appearance of stain and color difference; After warming, the temperature was lowered to 55 캜 or less at a rate of 2 캜 / minute. After discharging all of the water in the dyeing pot, it was washed twice with water each time for 15 minutes, again watered, 1 g / L was added and the temperature was raised to 65 ° C. The rate of temperature rise was 3 ° C / min. After 20 minutes of warming, the time during the warming process was determined. After completion, the temperature was lowered to 50 占 폚 or less at a rate of 3 占 폚 / min. After discharging all of the water in the dyeing jar, the water was washed twice, washed 20 minutes each time, / L for 10 minutes and then taken out of the staining jar together with water;

정형 온도는 170℃이고, 정형 온도가 보통 원단보다 높은 목적은 원단 수축이 더욱 충분하게 하기 위한 것이며, 친수성 유연제 0.5%를 첨가하고, 원단이 패더를 통과하여 정형 오븐 내에 진입하고, 패더의 속도는 22m/분인 정형 단계를 포함한다.The shaping temperature is 170 DEG C and the shaping temperature is higher than the normal fabric so that the fabric shrinkage is more sufficient. When 0.5% of the hydrophilic softening agent is added, the fabric enters the shaping oven through the fader, Min and a shaping step of 22 m / min.

실시예2:Example 2:

의마 면의 고수축사 원단의 염색 및 날염 가공 방법은,The method of dyeing and printing the corn fiber of the corn flour,

원단을 염색 항아리 내에 넣고 제1차 온도 상승 처리를 진행하되, 35℃까지 온도 상승되면 5g/L의 탄산나트륨과 4g/L의 유화 기름제거제를 첨가하고, 욕비를 1:12로 제어한 다음 계속 제2차 온도 상승처리를 진행하되 온도는 120℃로 제어하고, 보온시간은 50분인 전처리 단계;When the temperature was raised to 35 ° C, 5 g / L of sodium carbonate and 4 g / L of emulsifying oil remover were added, and the bath ratio was controlled to 1:12. Then, A pre-treatment step in which the secondary temperature raising treatment is carried out but the temperature is controlled to 120 ° C and the keeping time is 50 minutes;

전처리가 끝난 후 온도 하강 처리를 진행하되, 온도 하강 속도는 3℃/분으로 제어하고, 46℃까지 온도 하강되면, 염색 항아리 중의 물을 모두 배출한 후 두 번 물 세척하고, 다시 급수하고 3g/L의 빙초산을 첨가한 다음, 제3차 온도 상승처리를 진행하고, 50℃까지 온도 상승되면 30분 동안 세척(cloth washing)을 진행하는 산세척 단계;After the pretreatment is completed, the temperature is lowered, the temperature lowering rate is controlled at 3 ° C / min, and when the temperature is lowered to 46 ° C, the water in the dyeing jar is drained and washed twice, L of glacial acetic acid is added, and then the third temperature raising treatment is performed, and when the temperature is raised to 50 DEG C, washing is carried out for 30 minutes;

상온에서 염료액과 보조제를 첨가하고, 염료액 중의 염료는 각 색깔에 따라 그 사용량을 결정하며, 보조제는 98% 농도의 빙초산3g/L, 유화 기름제거제3g/L, 균염제 5g/L와 안정제4g/L를 포함하며, 욕비는 1:12으로 제어하고, 계속 온도 상승시키되, 온도 상승 속도는 5℃/분으로 제어하고, 85℃까지 온도 상승되면 5분 보온을 진행하고, 계속 3℃/분의 속도로 120℃까지 온도 상승시키고, 15분 보온을 진행하며, 계속 5℃/분의 속도로 150℃까지 온도 상승시키고 40분 보온을 진행하며, 보온이 끝난 후 4℃/분의 속도로 100℃까지 온도 하강시키고, 또 5℃/분의 속도로 70℃까지 온도 하강시킨 다음, 상온까지 최대속도로 온도 하강시켜, 원단의 수축율을 최대한도까지 향상시키며, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 30분 세척하며, 다시 급수하고 수산화나트륨 5g/L와 티오황산나트륨 3g/L을 첨가하고, 수산화나트륨을 첨가하여 원단 섬유가 풀리게 하여 독특한 원단 스타일을 형성하고, 100℃까지 온도 상승시키되, 온도 상승속도는 5℃/분이고, 후처리는 30분 보온을 진행하여 천에 주름감이 생기게 하고 균염 효과를 달성하여 얼룩 및 색깔 차이가 나타나는 현상을 방지하고; 보온이 끝난 후 3℃/분의 속도로 70℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두번 물 세척하되, 매번 20분 세척하며, 다시 급수하고, 98% 농도의 빙초산 2g/L을 첨가하며, 80℃까지 온도 상승시키되, 온도 상승 속도는 5℃/분이고, 30분 보온을 진행하고, 보온 과정에서의 시간이 천의 주름감이 충분한지의 여부를 결정하며, 보온이 끝난 후 5℃/분의 속도로 60℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 30분 세척하며, 다시 급수하고, 98% 농도의 빙초산 1g/L을 첨가하며, 15분 운행시킨 후 염색 항아리에서 물과 함께 꺼내는 염색 단계;The dyestuffs and auxiliaries were added at room temperature, and the amounts of dyestuffs in the dye liquids were determined according to each color. Adjuvants were 3 g / L of glacial acetic acid at a concentration of 98%, 3 g / L of an emulsifying oil remover, 5 g / / L, and the bath ratio was controlled to 1:12, and the temperature was raised to 5 ° C / min while the temperature was raised. When the temperature rose to 85 ° C, The temperature was raised to 120 DEG C at a rate of 5 DEG C / minute, the temperature was elevated to 150 DEG C at a rate of 5 DEG C / min and the temperature was maintained for 40 minutes. The temperature was lowered to 70 캜 at a rate of 5 캜 / minute, and then the temperature was lowered to the maximum temperature to the room temperature to improve the contraction ratio of the fabric to a maximum extent. After discharging all the water in the dyeing pot , Rinse twice, rinse for 30 minutes each time, 5 g / L of sodium hydroxide and 3 g / L of sodium thiosulfate were added and sodium hydroxide was added to loosen the fabric fibers to form a unique fabric style, and the temperature was raised to 100 캜 at a rate of 5 캜 / To prevent wrinkle feeling on the fabric and to achieve a leveling effect, thereby preventing occurrence of stain and color difference; After warming, the temperature was lowered to 70 캜 or less at a rate of 3 캜 / min. After discharging all of the water in the dyeing pot, it was washed twice with water for 20 minutes each time, again with water and 2 g of glacial acetic acid / L was added and the temperature was raised to 80 占 폚 while the rate of temperature rise was 5 占 폚 / min. After 30 minutes of warming, the time during the warming process was determined as to whether the wrinkle feeling of cloth was sufficient. Then, the temperature was lowered to 60 ° C or lower at a rate of 5 ° C / min. After discharging all of the water in the dyeing pot, it was washed with water twice, washed each time for 30 minutes, , Followed by running for 15 minutes and then taking out the dyed jar with water;

정형 온도는 190℃이고, 정형 온도가 보통 원단보다 높은 목적은 원단 수축이 더욱 충분하게 하기 위한 것이며, 친수성 유연제 1%를 첨가하고, 원단이 패더를 통과하여 정형 오븐 내에 진입하고, 패더의 속도는 25m/분인 정형 단계를 포함한다.The shaping temperature is 190 占 폚 and the shaping temperature is usually higher than that of the fabric so that the fabric shrinkage is more sufficient. When 1% of the hydrophilic softening agent is added, the fabric enters the shaping oven through the fader, Min and a shaping step of 25 m / min.

종합해보면, 본 발명이 제공하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법은, 염색시 수산화나트륨을 사용하여 원단의 섬유가 풀리게 하여 독특한 원단 스타일을 형성하고 원단 수축률이 높으며 천이 오돌토돌한 느낌을 가짐으로써, 의마 면 효과를 실현하고, 우븐 원단에 더욱 가깝기에 신규성을 구비한다.In summary, the dyeing and printing processing method of the corn silk fabric of the present invention provided with the present invention is characterized in that, in the dyeing process, sodium hydroxide is used to untie the fabric so that a unique fabric style is formed, the fabric shrinkage rate is high, Thereby realizing a hemming effect, and having novelty as it is closer to the woven fabric.

이상의 내용은 단지 본 발명의 실시예로서, 본 발명의 특허청구범위를 한정하기 위한 것이 아니며, 본 발명의 명세서의 내용에 이용하여 진행한 등가 구조 또는 등가 흐름 변경, 또는 직접적이나 간접적으로 기타 관련 기술분야의 지식을 응용한 것은 모두 본 발명의 특허보호범위에 속해야 할 것이다.The foregoing is merely illustrative of the present invention and is not to be construed as limiting the scope of the claims of the present invention. It will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention, Any application of knowledge in the field should fall within the scope of patent protection of the present invention.

Claims (4)

원단을 염색 항아리(dye vat) 내에 넣고 제1차 온도 상승 처리를 진행하되, 35℃까지 온도 상승되면 3 내지 5g/L의 탄산나트륨과 2 내지 5g/L의 유화 기름제거제를 첨가하고, 욕비(liquor ratio)를 1:8 내지 12로 제어한 다음 계속 제2차 온도 상승처리를 진행하되 온도는 100 내지 120℃로 제어하고, 보온시간은 30 내지 50분인 전처리 단계;
상기 전처리가 끝난 후 온도 하강 처리를 진행하되, 온도 하강 속도는 2 내지 3℃/분으로 제어하고, 50℃ 이하까지 온도 하강되면, 염색 항아리의 물을 모두 배출한 후 두 번 물 세척하고, 다시 급수하고 1 내지 3g/L의 빙초산을 첨가한 다음, 제3차 온도 상승 처리를 진행하고, 50℃까지 온도 상승되면 15 내지 30분동안 세척(cloth washing)을 진행하는 산세척 단계;
상온에서 염료액과 보조제를 첨가하고, 상기 보조제는 98% 농도의 빙초산1 내지 3g/L, 유화 기름제거제1 내지 3g/L, 균염제(leveling agent) 1.5 내지 5g/L와 안정제1 내지 4g/L를 포함하며, 욕비는 1:8 내지 12로 제어하고, 계속 온도 상승시키되, 온도 상승 속도는 2 내지 5℃/분으로 제어하고, 85℃까지 온도 상승되면 2 내지 5분 보온을 진행하고, 계속 1 내지 3℃/분의 속도로 110 내지 120℃까지 온도 상승시키고, 10 내지 15분 보온을 진행하며, 계속 1 내지 5℃/분의 속도로 130 내지 150℃까지 온도 상승시키고 30 내지 40분 보온을 진행하며, 보온이 끝난 후 1.5 내지 5℃/분의 속도로 80 내지 100℃까지 온도 하강시키고, 또 3 내지 5℃/분의 속도로 50 내지 70℃까지 온도 하강시킨 다음, 상온까지 가속 온도 하강시켜, 원단의 수축율을 증가시키며, 상기 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15 내지 30분 세척하며, 다시 급수하고 수산화나트륨(Caustic soda) 2 내지 5g/L와 티오황산나트륨(sodium hyposulfite) 1 내지 3g/L을 첨가하고, 수산화나트륨을 첨가하여 원단 섬유가 풀리게 하여 독특한 원단 스타일을 형성하고, 85 내지 100℃까지 온도 상승시키되, 온도 상승 속도는 2 내지 5℃/분이고, 후처리는 20 내지 30분 보온하여 천에 주름감이 생기게 하고 균염 효과를 달성하여 얼룩 및 색깔 차이가 나타나는 현상을 방지하고; 보온이 끝난 후 1 내지 3℃/분의 속도로 50 내지 70℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15 내지 20분 세척하며, 다시 급수하고, 98% 농도의 빙초산 0.8 내지 2g/L을 첨가하며, 60 내지 80℃까지 온도 상승시키되, 온도 상승 속도는 2 내지 5℃/분이고, 20 내지 30분 보온을 진행하고, 보온 과정에서의 시간이 천의 주름감이 충분한지의 여부를 결정하고; 보온이 끝난 후 3 내지 5℃/분의 속도로 50 내지 60℃ 이하까지 온도 하강시키고, 염색 항아리 중의 물을 모두 배출한 후, 두 번 물 세척하되, 매번 15 내지 30분 세척하며, 다시 급수하고, 98% 농도의 빙초산 0.3 내지 1g/L을 첨가하며, 10 내지 15분 운행시킨 후 염색 항아리에서 물과 함께 꺼내는 염색 단계;
정형 온도는 170 내지 190℃이고, 상기 정형 온도가 보통 원단보다 높은 목적은 원단 수축이 더욱 충분하게 하기 위한 것이며, 친수성 유연제 0.3 내지 1%를 첨가하고, 원단이 패더(padder)를 통과하여 정형 오븐 내에 진입하는 정형 단계를 포함하는 것을 특징으로 하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법.
The fabric was put in a dye vat and subjected to a first temperature raising treatment. When the temperature rose to 35 캜, 3 to 5 g / L of sodium carbonate and 2 to 5 g / L of an emulsifying oil remover were added, ratio is controlled to 1: 8 to 12, and then the second temperature raising treatment is continued but the temperature is controlled at 100 to 120 ° C and the keeping time is 30 to 50 minutes;
After the pretreatment is completed, the temperature lowering treatment is performed, the temperature lowering rate is controlled at 2 to 3 ° C / min, and when the temperature is lowered to 50 ° C or lower, the water in the dyeing jar is drained, A pickling step in which glacial acetic acid is added in an amount of 1 to 3 g / L and then subjected to a third temperature raising treatment, and when the temperature is raised to 50 캜, washing is carried out for 15 to 30 minutes;
The dye solution and the adjuvant are added at room temperature and the adjuvant is added at a concentration of 1 to 3 g / L of glacial acetic acid at a concentration of 98%, 1 to 3 g / L of an emulsifying oil remover, 1.5 to 5 g / L of a leveling agent and 1 to 4 g / And the bath temperature is controlled to 2 to 5 DEG C / min. When the temperature is raised to 85 DEG C, the heating is continued for 2 to 5 minutes, The temperature is raised to 110 to 120 ° C at a rate of 1 to 3 ° C / minute, the temperature is maintained at 10 to 15 minutes, the temperature is raised to 130 to 150 ° C at a rate of 1 to 5 ° C / The temperature is lowered to 80 to 100 DEG C at a rate of 1.5 to 5 DEG C / minute, the temperature is lowered to 50 to 70 DEG C at a rate of 3 to 5 DEG C / minute, To increase the contraction ratio of the fabric, and to remove all the water in the dyeing pot After draining, rinse twice with water each time for 15 to 30 minutes, re-water, add 2 to 5 g / L of Caustic soda and 1 to 3 g / L of sodium hyposulfite, add sodium hydroxide The fabric is loosened to form a unique fabric style, and the temperature is raised to 85 to 100 DEG C, the temperature rising speed is 2 to 5 DEG C / min, and the post-treatment is performed for 20 to 30 minutes, And achieving a leveling effect to prevent the appearance of stain and color difference; After the warming is completed, the temperature is lowered to 50 to 70 DEG C or less at a rate of 1 to 3 DEG C / minute, the water in the dyeing pot is drained, washed twice with water each time for 15 to 20 minutes, , 0.8 to 2 g / L of glacial acetic acid at a concentration of 98% is added and the temperature is raised to 60 to 80 DEG C, the temperature rising rate is 2 to 5 DEG C / min, the temperature is maintained for 20 to 30 minutes, Determining whether a wrinkle feeling of the cloth is sufficient; After the warming is completed, the temperature is lowered to 50 to 60 ° C or less at a rate of 3 to 5 ° C / minute, the water in the dyeing pot is drained and then washed twice, washed 15 to 30 minutes each time, , Adding 0.3 to 1 g / L of glacial acetic acid at a concentration of 98%, traveling for 10 to 15 minutes, and then taking out the water from the staining pot together with water;
The shaping temperature is in the range of 170 to 190 DEG C and the shaping temperature is higher than that of the normal fabric in order to more fully shrink the fabric. 0.3 to 1% of the hydrophilic softening agent is added, and the fabric is passed through a padder, And a shaping step of advancing the embroidery fabric into the embroidery fabric.
제 1항에 있어서,
상기 정형 단계에서 상기 패더의 속도가 21 내지 25m/분인 것을 특징으로 하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법.
The method according to claim 1,
Wherein the speed of the fader in the shaping step is 21 to 25 m / min.
제 1항에 있어서,
상기 염색 단계에서 사용된 염료액 중의 염료는 각 색깔에 따라 그 사용량을 결정하는 것을 특징으로 하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법.
The method according to claim 1,
Wherein the amount of the dye in the dye liquid used in the dyeing step is determined according to each color.
제 1항에 있어서,
상기 염색 단계에서 상온까지 가속 온도 하강시키는 과정에서 얼음을 포함한 냉각수를 이용하여 염색 항아리를 온도 하강시키는 것을 통해 상온까지 온도 하강시키는 속도를 가속화함으로써 원단 수축율을 증가시키는 것을 특징으로 하는 의마 면의 고수축사 원단의 염색 및 날염 가공 방법.
The method according to claim 1,
Wherein the dye shrinkage rate is increased by accelerating the temperature lowering temperature to room temperature by lowering the temperature of the dyeing jar using the cooling water containing ice in the process of lowering the acceleration temperature to room temperature in the dyeing step, Dyeing and printing process of fabrics.
KR1020167023839A 2016-03-10 2016-04-11 A dyeing and printing processing method for high shrinkable yarn fabric of imitation linen cotton KR20170115433A (en)

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