KR20170051581A - Baked type cosmetic composition using volatile oils as solvent - Google Patents
Baked type cosmetic composition using volatile oils as solvent Download PDFInfo
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- KR20170051581A KR20170051581A KR1020150150879A KR20150150879A KR20170051581A KR 20170051581 A KR20170051581 A KR 20170051581A KR 1020150150879 A KR1020150150879 A KR 1020150150879A KR 20150150879 A KR20150150879 A KR 20150150879A KR 20170051581 A KR20170051581 A KR 20170051581A
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- cosmetic composition
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0245—Specific shapes or structures not provided for by any of the groups of A61K8/0241
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
Abstract
The present invention relates to a calcination type cosmetic composition comprising a volatile oil as a solvent and an aluminum soap and a modified clay mineral.
According to the present invention, the plastic type cosmetic composition of the present invention is capable of securing molding stability such as reduction in surface color elution, reduction in drying time, safety in preservation and dropping stability, and excellent feeling in use such as spreadability and adhesion.
Description
The present invention relates to a plasticized cosmetic composition comprising a volatile oil as a solvent and more particularly to a plasticized cosmetic composition comprising a volatile oil as a solvent and a plastic type cosmetic composition comprising an aluminum soap and a modified clay mineral .
Conventionally, a calcination type cosmetic composition which is formed by molding and drying a paste phase is formed by mixing a powder phase with an emulsion of an oil-in-water or water-in-oil type. However, these conventional methods are complicated due to the necessity of preparing an emulsion. Because of using water, there are restrictions on the coloring matters and the raw materials. Due to the problem of adjusting the pH depending on the problem and the problem of the emulsion stability in the bulk state There were difficulties in manufacturing.
A wet type cosmetic composition which contains a large amount of a volatile solvent and is formed by imparting flowability is generally subjected to suction molding by mixing a large amount of a volatile solvent in a powder composition containing or not containing an oil binder. However, this conventional method requires at least 50% of the solvent in comparison with the powder composition. In the suction molding, various components are lost together with the solvent, and some components such as pearl are poured into the suction part. . In particular, Korean Patent Publication No. 2012-0119330 discloses a wet molding cosmetic composition and a method for producing the same, which require a special equipment for removing a volatile solvent by 60% or more of the powder composition.
The cosmetic composition through the general production methods of the above two methods has been accompanied by problems such as dusting and lack of adhesion due to limitations in respective molding methods. Korean Patent No. 1439854 discloses a cosmetic composition and a method for producing a plasticized cosmetic composition having high skin adhesion and durability. In order to solve such drawbacks in feeling and difficulty in manufacturing in two ways, a volatile solvent dispersed in silicone- However, this volatile solvent has difficulties in using as well as equipment restrictions due to the use of isopropyl alcohol which is low in safety and heavy in use and handling as an alcohol system.
In addition, when a volatile solvent is used as the calcination type solvent, there arises a problem in the molding stability that the hardness becomes weak. In order to solve the above-mentioned problems, conventionally, modified clay minerals are contained. However, there is a limit to solving the above-mentioned problems by merely including the modified clay mineral in the calcined cosmetic composition containing a volatile solvent.
The inventors of the present invention have made intensive efforts to overcome the problems of the prior art. As a result, the inventors of the present invention have found that a calcined type cosmetic composition containing volatile oil as a solvent is characterized in that it comprises an aluminum soap and a modified clay mineral , It has been confirmed that the molded article is excellent in feeling and is also excellent in the hardness to ensure the molding stability and the stability of the product, thereby completing the present invention.
Accordingly, a main object of the present invention is to provide a plastic type cosmetic composition comprising aluminum soap not only excellent in usability but also excellent in hardness, molding stability and product stability.
According to one aspect of the present invention, there is provided a calcined cosmetic composition comprising a volatile oil as a solvent, wherein the calcined cosmetic composition comprises aluminum soap and modified clay mineral.
The term " calcined type " means a process of drying, and more particularly, a method of mixing a volatile solvent into a powder in a cosmetic composition and removing it through a drying process to complete a cosmetic composition. At this time, water or alcohol was used as a volatile solvent. However, in the present invention, volatile oil is used among non-volatile oils and hydrocarbon oils among volatile oils.
Conventionally, a powder phase is mixed with an emulsion of water-in-oil type or water-in-oil type to form a plastic type cosmetic. However, such a process is relatively complicated and has various manufacturing difficulties because it contains water as a solvent. In the case of plasticized cosmetics containing a volatile solvent as a solvent, since the volatile solvent is contained in an amount of 50% or more, there arises a problem of molding stability such that the hardness is weakened. In order to solve such a problem, There is a disadvantage that it occurs. In order to solve the above problems, the inventors of the present invention have found that a plasticized cosmetic composition using a volatile oil as a solvent contains 50% by weight or less of a volatile oil and the aluminum soap forms a gel at a specific temperature by an oil When the aluminum soap and modified clay minerals are contained by using the characteristics and the hardness formation property by the modified clay mineral, the molding stability such as reduction of the surface dye release, reduction of the drying time, stability of the anticorrosive and dropping stability can be ensured, It is possible to provide a superior plastic type cosmetic composition and complete the present invention.
The aluminum soap may be mixed first with the oil phase. However, if the gel is formed once by mixing the aluminum soap and the oil phase, the aluminum soap will not melt well. Further, since the high temperature process must be maintained continuously, So that a great deal of force is required for dispersion. Therefore, in the present invention, aluminum soap was linearly dispersed on a powder, and then mixed in an oil phase.
In the present invention, the aluminum soap may be a divalent or trivalent aluminum soap, and is preferably selected from the group consisting of Al-stearate, Al-palmitate, al-myristate, And at least one selected from the group consisting of al-laurate.
In the present invention, the modified clay minerals may include any modified clay minerals included in the conventional calcination type cosmetic composition. Preferably, the modified clay minerals include distearmonium hectorite, stearalkonium hectorite ), Quaternium-18 Hectorite, and Bentonite. ≪ Desc / Clms Page number 2 >
In the present invention, the calcined type cosmetic composition preferably comprises 40 to 75% by weight of powdery phase, 0.01 to 30% by weight of oil phase, 20 to 40% by weight of volatile solvent, 0.1 to 3.0 of aluminum soap and 0.1 to 3.0 of modified clay mineral By weight to 5.0% by weight. The ratio of powder phase, oil phase, and volatile solvent ultimately determines the flowability and aggregation of the whole bulk and determines the usability. Therefore, if the powder phase is too small, the extrusion process can not be performed because there is no lump, and if it is too much, the flowability becomes too high. Also, if the oil phase is too large, caking will occur when it is used, and if it is too small, it will not be used, and the powder will be blown out. The volatile solvent is limited to the amount of oil in accordance with the flow rate of the impregnation, so that the amount of the volatile solvent is limited. In the case of the aluminum soap, if it is less than 0.1% by weight, the formability is weakened, and the problem of stability of the formulation as well as the problems of dusting of the powder and the problem of flaking is problematic. When the content is more than 3% by weight, the feeling of use is caking (phenomenon in which the contents are not taken) A phenomenon may occur. In the case of the modified clay minerals, if it is less than 0.1% by weight, there is a problem of powderiness or lack of adhesion, and when it exceeds 5.0% by weight, the feeling of use is stiff and caking (phenomenon in which the contents are not taken) .
In the present invention, the powder phase may include all of the powders included in the calcination type cosmetic composition in the past, and preferably, talc, mica, synthetic mica, cericite, silica, titanium dioxide, silicone- Wherein the inorganic pigment is at least one selected from the group consisting of oxides, nylon powders, polymethacrylate powders, urethane powders, acrylate (co) polymers, polyethylene (co) polymers, organic dye pigments, inorganic dye pigments and pearl pigments. In addition, the powder phase may not be surface-treated, but may be surface-treated with silicone, metal salt, fatty acid, amino acid, lauroyl lysine or lecithin.
In the present invention, the oil phase may include all oils conventionally contained in the plastic type cosmetic composition, and preferably includes trihexylhexanone, diisostearylmaltite, triglyceride, dimethicone, phenyltrimethicone , Camphor wax, jojoba wax, olive oil, macadamia nut oil, sunflower oil, palm oil, palm oil, and camel vegetable liquid fats And the like.
In the present invention, the volatile solvent may include all the volatile solvents conventionally contained in the calcined type cosmetic composition, preferably the hydrocarbon volatile solvent, more preferably isododecane, iso Hexadecane, and isoparaffin.
In the present invention, the aluminum soap is dispersed on the powder, and the modified clay mineral is dispersed on the oil.
Specifically, the plastic type cosmetic composition of the present invention is provided through the following production method; 1) A composite powder composition is prepared by linearly dispersing aluminum soap on a powder in a machine such as Hensel or Atomizer, sprayed and mixed in an oil phase in which denatured clay mineral is linearly dispersed and then mixed with a ribbon mixer or an universal mixer 2) a composite powder composition prepared by linearly dispersing aluminum soap on a powder in a machine such as Hensel or Atomizer, a modified powder composition prepared by dispersing denatured clay mineral in oil in an azimixer or a dispersing mixer, A complex oil composition and a solvent, and then mixing and dispersing them in a ribbon mixer or a universal mixer to form a paste. Extruding and molding the paste phase formed in 1) and 2) above, and drying the molded product to remove the solvent. The drying may be performed in a drier at 60 to 90 ° C for 1 to 10 hours.
In the present invention, the cosmetic composition is characterized by being excellent in molding stability and hardness.
According to this experimental example, the aluminum soap is formed on the powder and the modified clay mineral is formed on the oil phase as described above by using the property that the aluminum soap forms a gel at a specific temperature by the oil and the hardness is formed by the modified clay mineral. , It was confirmed that the molding stability was excellent such as reduction of surface dye elution, reduction of drying time, safety of shelf stability and falling stability, and it was confirmed that the feeling of use was also excellent (see Experimental Examples 1 and 2).
In the present invention, the cosmetic composition is characterized by being at least one formulation selected from a formulation consisting of a fact, a blusher and an eye shadow.
As described above, in a calcined type cosmetic composition comprising a volatile oil as a solvent, in the case of a calcined type cosmetic composition containing not more than 50% by weight of volatile oil and containing aluminum soap and modified clay mineral, It is possible to secure molding stability such as reduction of drying time, safety of preservation and dropping stability, and it is possible to provide a uniform feel and feel as a good feeling of use.
Hereinafter, the present invention will be described in more detail with reference to Examples. These embodiments are only for illustrating the present invention, and thus the scope of the present invention is not construed as being limited by these embodiments.
The inventors of the present invention constructed the four groups as shown in Table 1 below. According to the following examples, it is also possible to use 40 to 80% by weight, 30 to 30% by weight of a volatile oil, 20 to 40% by weight of a solvent composed of a volatile oil, 0.1 to 3% by weight of an aluminum soap, 0.1 to 3% To 5% by weight.
The manufacturing method according to the embodiments of the present invention is possible by two methods. In the manufacturing method 1, the mixture of Group 1 and Group 2-1 is mixed with Group 2-2 and Group 3, and finally, Group 4 is dispersed to form a paste. Then, the mixture is extruded and shaped And in the production method 2, the powder composition containing Group 1 and Group 2-1 is dispersed in Group 2-2, Group 3 and Group 4 at the same time, and then the mixture is extruded, To form and dry the shape, and in each method, an additional pressing process can be added. In addition, at least one of the groups 2-1 and 2-2 should be included, and more preferably, the manufacturing method 1 is suitable. If group 3 is not included, group 1 and group 2-1 are mixed, and group 2-2 is completely dissolved in group 4 and mixed to form a paste.
The group 1 (on the powder) may be selected from the group consisting of talc, mica, synthetic mica, sericite, silica, titanium dioxide, silicone based powder, boron powder, zinc oxide, nylon powder, polymethacrylate powder, urethane powder, , A pigment such as a polyethylene (co) polymer, an organic coloring pigment, an inorganic coloring matter pigment, a pearl pigment, etc., and the powder may be surface treated with silicone, metal salt, fatty acid, amino acid, lauroyl lysine or lecithin .
The group 2-1 (aluminum soap) may be contained in an amount of 0.1 to 3% by weight, more preferably 0.3 to 2% by weight, depending on the constitution and content of the groups 1 and 3. If the amount is less than 0.1% by weight, the moldability is weakened, and the stability of the formulation is accompanied by a problem of flaking and problems. If the amount is more than 3% by weight, the feeling of use may cause caking (precipitation phenomenon) or precipitation. The aluminum soap may include at least one of Al-stearate, Al-palmitate, Al-myristate, and Al-laurate. More specifically, the present embodiment can include aluminum soap including disoap type Al-stearate
The amount of the group 2-2 (modified clay mineral) may be 0.1 to 5.0% by weight, more preferably 0.5 to 3.0% by weight, depending on the composition and content of the groups 1 and 3. If the amount is less than 0.5% by weight, there is a problem of powderiness or lack of adhesion. If the amount is more than 5.0% by weight, the feeling of use may be stiff and caking (phenomenon in which the contents are not taken) may occur. The modified clay minerals include those containing at least one of Distheardimonium Hectorite, Stearalkonium Hectorite, Quaternium-18 Hectorite and Bentonite. Modified clay minerals include hectorite gels dispersed in a solvent such as oil as well as raw materials in powder form, including in the examples.
The group 3 (oil phase) may include from about 30 wt% to about 30 wt%, and more preferably from about 5 wt% to about 25.0 wt%, depending on the spherical powder, the degree of powder absorption, and the content of pearl pigment. If it exceeds 30% by weight, caking (phenomenon in which the contents are not taken) may occur. Examples of the oil phase include esters such as triethyl hexanone, diisostearylmaltite, and triglyceride; Dimethicone, phenyl trimethicone, and vinyltimethicone copolymer; Hydrocarbons such as liquid paraffin, squalane, mineral oil and triglycerin; Waxes such as castor wax, carnauba wax and jojoba wax; Natural oils such as olive oil, macadamia nut oil, sunflower oil; Palm oil, palm oil, mayonnaise liquid vegetable oil, and the like, and mixtures thereof.
The group 4 (solvent) includes at least one non-polar or low-polar hydrocarbon-based volatile oil such as isotodecane, isohexadecane, isoparaffin and the like, which is capable of gelling the aluminum soap . More specifically, hydrocarbon-based volatile oil mixed with isododecane is used in this embodiment.
The powder cosmetic composition can be applied to a powder type product group including a fact, a blusher, an eyeshadow, etc., and the composition can be changed according to a desired color, pearl feeling, feeling of use.
Example 1 to 3 and Comparative Example 1 to 5: Cosmetics Composition manufacturing
The main production methods for the preparation of cosmetic compositions were based on the above preparation method 1 in the composition shown in the following Table 2, and Group 2-2 was emulsified in Group 3 and Group 4 only in Comparative Example 5 and used for sintering. Example 1 and Comparative Example 1 are examples with no pearlescent pigment, and Examples 2 to 3 and Comparative Examples 2 to 5 are examples with pearlescent pigment. Comparative Examples 1 and 2 were prepared by adding metal soap having no gelling ability to Group 4 (solvent) in place of aluminum soap for each Example. Comparative Example 3 was prepared by using isopropyl alcohol, which is alcohol, Comparative Example 4 is an example in which denatured clay minerals are removed, and Comparative Example 5 is an example in which water is used as a general firing type solvent and a water dispersing gelling agent or a thickening agent.
Group 1
Group 3
Group 4
The production methods of Examples 1 to 3 and Comparative Examples 1 to 4 are as follows.
1) The raw materials of Group 1 and Group 2-1 were weighed and pulverized and mixed with a Henschel mixer, an atomizer, etc. to prepare a mixture. At this time, some of the raw materials of Group 1 were coated with the raw materials. In addition, the organic coloring matter pigment which was eluted in water was used.
2) The raw materials of Group 2-2 and Group 3 are weighed and mixed by heating at 70 to 80 캜, and then mixed and dispersed in the mixture of 1) in a Henschel mixer to prepare a primary powder composition.
3) The primary powder composition of the above 2) and the raw material of the group 4 are added and kneaded evenly in a ribbon mixer or a universal mixer to prepare a paste-like secondary powder composition. At this time, the raw material of group 4 can be increased or decreased according to the kneading condition.
4) The secondary powder composition of 3) was extruded and molded into a desired shape, and dried at 75 to 85 ° C to prepare a final cosmetic composition.
The manufacturing method of Comparative Example 5 is as follows.
1) The raw materials of Group 1 and Group 2-1 were weighed and pulverized and mixed with a Henschel mixer, an atomizer, etc. to prepare a mixture. At this time, some of the raw materials of Group 1 were coated with the raw materials. In addition, the organic coloring matter pigment which was eluted in water was used.
2) Add the raw materials of group 2-2 to the raw materials of group 4, mix them with an agmixer at about 60 ° C until group 2-2 is completely dispersed, add group 3 heated to 80 ° C and emulsify with homomixer Thereby producing the emulsion base.
3) The mixture of 1) above and the emulsification base of 2) are put and kneaded evenly by a ribbon mixer or a universal mixer to prepare a paste-like powder composition. At this time, purified water (water) can be added according to the dough condition.
4) The powder composition 3) was extruded into a desired shape, dried at 75 to 85 ° C, and subjected to an expression process to prepare a final cosmetic composition.
Test Example 1: Measurement of molding stability
The molding stability of the cosmetic compositions prepared in Example 1 and Comparative Example 1, Examples 2 to 3 and Comparative Examples 2 to 5 was measured. The stability of the molding was confirmed by the stability of dropping, surface coloring, drying completion time and number of steps, and the preservation safety of bulk before molding.
The drop stability was measured by relative evaluation of the amount of vertical descent by 10 drops on the marble at a height of 30 cm. The above-mentioned surface dye elution was visually confirmed whether or not the surface or content of the dye was stained or touched after drying. The drying completion time and the process number were determined based on the time when the solvent remaining amount was less than 2% and the equipment replacement. The preservation safety was confirmed by the inoculation of bacteria, fungi and fungi into the bulk of the mixed raw materials before molding, respectively. The results are shown in Table 3 below.
As a result, as shown in Table 3, it can be seen that the embodiments are superior to the comparative examples in falling stability. In addition, it can be seen that Example 2 has less surface dye elution, simplification of production and higher preservation stability than Comparative Example 5.
Test Example 2: Usability evaluation (adhesion, durability, Feeling , No dusting )
Usability of the cosmetic compositions prepared in Example 1 and Comparative Example 1, Examples 2 to 3 and Comparative Examples 2 to 5 was evaluated. The evaluation was based on a score of 5 out of 30 panelists between 25 and 40 years of age. Usability was evaluated for adhesion, durability, feeling, and no dusting. The results are shown in Table 4 below.
As shown in Table 4, Example 1 showed higher evaluation than Comparative Example 1, and Example 2 showed higher evaluation than Comparative Examples 2 to 5. In addition, the evaluations of Examples 1 to 3 differed according to the composition of each prescription, but most of them showed a high score of 4 or more. From these results, it was confirmed that the cosmetic composition of the present invention showed excellent usability compared with the comparative example of similar composition in all items.
Claims (9)
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KR1020150150879A KR20170051581A (en) | 2015-10-29 | 2015-10-29 | Baked type cosmetic composition using volatile oils as solvent |
PCT/KR2016/009496 WO2017073898A1 (en) | 2015-10-29 | 2016-08-26 | Plasticization type cosmetic composition using volatile oil as solvent and preparation method therefor |
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KR1020150150879A KR20170051581A (en) | 2015-10-29 | 2015-10-29 | Baked type cosmetic composition using volatile oils as solvent |
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Cited By (1)
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KR20200085405A (en) | 2019-01-04 | 2020-07-15 | 코스맥스 주식회사 | A calcined cosmetic composition using clay gel as a solvent and method thereof |
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CN111494222A (en) * | 2020-05-28 | 2020-08-07 | 杭州心悦化妆品有限公司 | Mud-shaped eye shadow and preparation method thereof |
Family Cites Families (10)
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KR960016189B1 (en) * | 1993-05-18 | 1996-12-06 | 주식회사 태평양 | Cosmetics containing capsules comprising stabilized enzyme |
JP3767978B2 (en) * | 1997-06-26 | 2006-04-19 | 三菱鉛筆株式会社 | Stick cosmetic |
KR100405870B1 (en) * | 2000-10-27 | 2003-11-15 | 애경산업(주) | Oil-free and surfactant-free oil-powder disperse system and method for stabilizing thereof |
KR100789345B1 (en) * | 2006-08-21 | 2007-12-28 | 주식회사 엘지생활건강 | Solid stick cosmetics of water-in-oil emulsion |
KR101439854B1 (en) * | 2007-11-26 | 2014-09-17 | (주)아모레퍼시픽 | Baked makeup cosmetic composition having excellent adhesiveness and durability and the method for preparing thereof |
KR101017922B1 (en) * | 2008-11-26 | 2011-03-04 | (주)아모레퍼시픽 | Cosmetic composition containing licorice extract and natural thickeners for skin whitening |
KR101655346B1 (en) * | 2009-11-27 | 2016-09-08 | (주)아모레퍼시픽 | Cosmetic composition stabilized higher oily part |
JP2013147477A (en) * | 2012-01-23 | 2013-08-01 | Shiseido Co Ltd | Powder cosmetic |
KR101572218B1 (en) * | 2013-09-05 | 2015-11-26 | 주식회사 엘지생활건강 | Cosmetic composition of water in oil emulsion with high salts |
KR101587783B1 (en) * | 2014-02-21 | 2016-01-22 | 코스맥스 주식회사 | Make-up cosmetic composition containing volatile organic gel |
-
2015
- 2015-10-29 KR KR1020150150879A patent/KR20170051581A/en not_active Application Discontinuation
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2016
- 2016-08-26 WO PCT/KR2016/009496 patent/WO2017073898A1/en active Application Filing
Cited By (1)
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KR20200085405A (en) | 2019-01-04 | 2020-07-15 | 코스맥스 주식회사 | A calcined cosmetic composition using clay gel as a solvent and method thereof |
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