KR101891953B1 - Color cosmetic composition having excellent adhesiveness, moisturizing property and spreadability and method for manufacturing the same - Google Patents

Abstract

The present invention provides a color cosmetic composition having excellent adhesion, moisturizing properties, and spreadability, and a production method thereof. The color cosmetic composition comprises: a pulverized material which is obtained by coating, drying, and pulverizing a first mixture with a compound represented by chemical formula 1; and a water-in-oil emulsion. With respect to 100 parts by weight of the pulverized material, components including 5-15 parts by weight of the water-in-oil emulsion are mixed, dispersed, and molded.

Description

[0001] The present invention relates to a color cosmetic composition having excellent adhesiveness, moisturizing property and spreadability and a method for producing the same,

The present invention relates to a color cosmetic composition having excellent adhesion, moisturizing properties and spreadability, and a process for producing the same.

Emulsion is a dispersion system in which energy is added to a system that does not mix with each other spontaneously like water and oil, and it is a thermodynamically unstable state that will eventually separate and release energy to the outer environment and return to a stable layer separation state. Emulsions can be classified into water-in-oil type and water-in-oil type. When silicone oil is used as oil, it is classified as silicone oil water, but silicon oil water is basically a kind of water-in-oil type.

The emulsion can be prepared by adding a disperse phase to a continuous phase containing a surfactant and using a direct emulsification method using a simple crushing power by an emulsifier, dissolving the surfactant in a dispersed phase, A phase inversion emulsification method for forming an emulsion, a liquid crystal emulsification method in which a liquid crystal is formed using a surfactant having a high phase transition temperature and a fatty acid alcohol, a nonionic ionic liquid A phase inversion temperature emulsification method in which fine emulsion particles are formed and cooled at the phase transition temperature of the surfactant, a method in which a gel in which an aqueous phase is dispersed in a lipophilic surfactant is dispersed in an oil phase or an organic degeneration containing a surfactant and an oil Gel emulsification method in which an oil gel containing clay minerals is dispersed in an aqueous phase ( gel emulsification method, and a membrane emulsification method in which uniform particles are formed using a Shiraz porous glass (SPG) membrane.

Emulsion type color cosmetics include foundation, makeup base, bib cream, skin cover, concealer, primer, makeup chest, sun cream and various products.

Emulsion-type color cosmetics mainly include inorganic pigments, and can be classified into extender pigments, color pigments, white pigments, pearlescent pigments, and special functional pigments. Among them, iron oxide is generally used as a color pigment, and a color pigment in which iron oxide is coated with silicon or silane is mainly used.

When a pigment is put in an emulsion type color cosmetic, it is put in a color base type in which color is base to enhance convenience and reproducibility. Generally, a compression grinding method and a mixed grinding method are mainly used as a method of base coloring pigment.

Compression milling is a method of dispersing colored pigments in a viscous oil phase followed by compression-milling with a three-step roller and then dissolving in oil phase in the production of foundation. It is very excellent in pigment dispersibility and reproducibility. But there is a disadvantage in that a large amount of raw material is lost and labor and time are required in the manufacturing process.

The mixed pulverization method is a method in which the coloring pigment and the excipient are uniformly mixed and then pulverized by a pulverizer and then dispersed in an oil phase or an aqueous phase by stirring to thereby reduce the loss of the raw material and reduce labor and time. However, It is difficult to use it because it does not have excellent color dispersibility and it can not be used commonly for various products.

Therefore, in the field of color cosmetics, it is required to solve the above-mentioned disadvantages.

Korean Patent Publication No. 10-2017-0124320

SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned disadvantages of the prior art,

It is an object of the present invention to provide a color cosmetic composition excellent in adhesion, moisturizing and spreading properties by using a surface modified color pigment and an excipient and using a specific water-in-oil emulsion, and a process for producing the same.

According to the present invention,

(a) 5 to 15 parts by weight of titanium dioxide, 10 to 20 parts by weight of talc, 3 to 7 parts by weight of silica, 30 to 60 parts by weight of mica, 10 to 20 parts by weight of sericite, 5 to 10 parts by weight of iron oxide, To 0.5 parts by weight of a compound represented by the following formula (1), dried and pulverized;

(b) 2 to 5 parts by weight of methoxypigi-114 / polyepsilon caprolactone, 1 to 5 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 1 to 5 parts by weight of wax, glyceryl stearate / 2 to 6 parts by weight of Pigment-100 stearate, 3 to 6 parts by weight of butylene glycolylacodipyrate / dicaprate, 1 to 4 parts by weight of quaternary 18-hectorite, 1 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, 2 to 6 parts by weight of dicaprylyl carbonate, 1 to 5 parts by weight of caprylic / capric triglyceride, 1 to 5 parts by weight of triethylhexanoin, 1 to 5 parts by weight of ethylhexyl palmitate, 1 to 3 parts by weight of polysorbate 80, 2 to 6 parts by weight of sodium polyacrylate / ethylhexyl stearate / trideceth-6, 15 to 40 parts by weight of glycerin, 15 to 40 parts by weight of lenglycol, and 2 to 7 parts by weight of a compound represented by the following formula (1)

Water was added in an amount of 20 to 40 parts by weight based on 100 parts by weight of the mixture, followed by mixing and emulsification using a mixer, and sodium acrylate / sodium acryloyldimethyltaurate copolymer / isohexadecane / polysorbate 80 0.5 to 3 parts by weight based on 100 parts by weight of the emulsion;

(c) 5 to 15 parts by weight of the water-in-oil emulsion of (b) based on 100 parts by weight of the pulverized product of (a) are mixed, dispersed and molded.

[Chemical Formula 1]

In this formula,

n is a natural number of 2 to 10,

a and b are molar fractions, a is 0.5 and b is 0.5;

c and d are mole fractions, c is 0.05 to 0.2, d is 0.8 to 0.95, and c + d is 1.

In one embodiment of the present invention, the formulation of the color cosmetic composition may be selected from the group comprising a two-way cake, a fact, a powder foundation, an eye shadow and a blusher.

The present invention also relates to

(a) 5 to 15 parts by weight of titanium dioxide, 10 to 20 parts by weight of talc, 3 to 7 parts by weight of silica, 30 to 60 parts by weight of mica, 10 to 20 parts by weight of sericite, 5 to 10 parts by weight of iron oxide, ~ 0.5 part by weight of the compound of formula (I), drying and pulverizing the pulverized product;

(b) 2 to 5 parts by weight of methoxypigi-114 / polyepsilon caprolactone, 1 to 5 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 1 to 5 parts by weight of wax, glyceryl stearate / 2 to 6 parts by weight of Pigment-100 stearate, 3 to 6 parts by weight of butylene glycolylacodipyrate / dicaprate, 1 to 4 parts by weight of quaternary 18-hectorite, 1 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, 2 to 6 parts by weight of dicaprylyl carbonate, 1 to 5 parts by weight of caprylic / capric triglyceride, 1 to 5 parts by weight of triethylhexanoin, 1 to 5 parts by weight of ethylhexyl palmitate, 1 to 3 parts by weight of polysorbate 80, 2 to 6 parts by weight of sodium polyacrylate / ethylhexyl stearate / trideceth-6, 15 to 40 parts by weight of glycerin, 15 to 40 parts by weight of a vulcanizing agent and 2 to 7 parts by weight of a compound represented by the following general formula (1) are heated to 50 to 90 占 폚, dissolved and mixed,

Water was added in an amount of 20 to 40 parts by weight based on 100 parts by weight of the mixture, and the mixture was mixed and emulsified using a mixer. The mixture was gradually cooled to 20 to 40 ° C, cooled and then sodium acrylate / sodium acryloyldimethyltaurate copolymer / Adding isohexadecane / polysorbate 80 in an amount of 0.5 to 3 parts by weight based on 100 parts by weight of the emulsion, and then mixing to prepare a water-in-oil type emulsion; And

(c) mixing and dispersing components including 5 to 15 parts by weight of the water-in-oil emulsion of step (b) based on 100 parts by weight of the pulverized product of step (a), and molding the composition. ≪ / RTI >

The color cosmetic composition of the present invention uses a surface-modified coloring pigment and an excipient, and by using a specific water-in-oil type emulsion, it provides excellent adhesion, moisturizing and wettability.

Hereinafter, the present invention will be described in detail.

The present invention relates to a method for producing an iron oxide nanoparticle comprising (a) 5-15 parts by weight of titanium dioxide, 10-20 parts by weight of talc, 3-7 parts by weight of silica, 30-60 parts by weight of mica, 10-20 parts by weight of cericite, 5-10 parts by weight of iron oxide, And 0.1 to 0.5 parts by weight of an antiseptic is coated with a compound represented by the following formula (1), dried and pulverized;

(b) 2 to 5 parts by weight of methoxypigi-114 / polyepsilon caprolactone, 1 to 5 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 1 to 5 parts by weight of wax, glyceryl stearate / 2 to 6 parts by weight of Pigment-100 stearate, 3 to 6 parts by weight of butylene glycolylacodipyrate / dicaprate, 1 to 4 parts by weight of quaternary 18-hectorite, 1 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, 2 to 6 parts by weight of dicaprylyl carbonate, 1 to 5 parts by weight of caprylic / capric triglyceride, 1 to 5 parts by weight of triethylhexanoin, 1 to 5 parts by weight of ethylhexyl palmitate, 1 to 3 parts by weight of polysorbate 80, 2 to 6 parts by weight of sodium polyacrylate / ethylhexyl stearate / trideceth-6, 15 to 40 parts by weight of glycerin, 15 to 40 parts by weight of lenglycol, and 2 to 7 parts by weight of a compound represented by the following formula (1)

Water was added in an amount of 20 to 40 parts by weight based on 100 parts by weight of the mixture, followed by mixing and emulsification using a mixer, and sodium acrylate / sodium acryloyldimethyltaurate copolymer / isohexadecane / polysorbate 80 0.5 to 3 parts by weight based on 100 parts by weight of the emulsion;

(c) 5 to 15 parts by weight of the water-in-oil emulsion of (b) based on 100 parts by weight of the pulverized product of (a) are mixed, dispersed and molded.

[Chemical Formula 1]

In this formula,

n is a natural number of 2 to 10,

a and b are molar fractions, a is 0.5 and b is 0.5;

c and d are mole fractions, c is 0.05 to 0.2, d is 0.8 to 0.95, and c + d is 1.

In one embodiment of the present invention, the pulverized product of (a) may further comprise at least one selected from cellulose and boron nitride.

In one embodiment of the present invention, the formulation of the color cosmetic composition may be selected from the group including, but not limited to, two-way cakes, facts, powder foundation, eye shadow and blusher.

The pulverized product of (a) may have a particle size of usually 1 mm or less, but is not limited to this range. The pulverized material which can be used in the color cosmetic composition of the present invention may further contain at least one selected from the group consisting of extender pigments, coloring pigments and white pigments, which are conventionally used in cosmetics, in addition to the above-mentioned ingredients .

In the color cosmetic composition of the present invention, the compound of Chemical Formula 1 used for the surface modification of solid pigment and excipient may be a block copolymer of polyacrylic acid substituted with poly-D, L-lactic acid-co-glycolic acid and diisocyanate compound It is united.

In the block copolymer of poly-D, L-lactic acid-co-glycolic acid and polyacrylic acid substituted with a diisocyanate compound, poly-D, L-lactic acid-co- glycolic acid is included as a hydrophobic part, The substituted polyacrylic acid is included as a hydrophilic moiety.

The weight average molecular weight of the block copolymer of poly-D, L-lactic acid-co-glycolic acid and polyacrylic acid substituted with a diisocyanate compound as the emulsifying aid may be 50,000 to 200,000, more preferably 70,000 to 100,000 .

In the above, polyacrylic acid substituted by poly-D, L-lactic acid-co-glycolic acid (Formula 2) and diisocyanate compound (Formula 3 below) can be produced by the combination of an isocyanate group and a hydroxyl group of a carboxyl group. a block copolymer of polyacrylic acid substituted with -co-glycolic acid and diisocyanate compound is formed.

(2)

(3)

The weight average molecular weight of the poly-D, L-lactic acid-co-glycolic acid may be 1,000 to 150,000, and the weight average molecular weight of the copolymer of polyacrylic acid substituted with the diisocyanate compound may be 1,000 to 50,000 .

The average particle diameter of the copolymer is preferably from 10 to 100 nm. When such a particle size is used, penetration into the skin and collection of the active ingredient are excellent. The thus obtained copolymer is remarkably stable in an aqueous solution as compared with a low molecular weight micelle.

The color cosmetic composition of the present invention may further contain at least one selected from the group consisting of fragrances, coloring agents, preservatives, oxidation stabilizers, ultraviolet screening agents and pearlescent agents within the range not lowering the effect of the composition other than the above components .

The present invention also relates to

(a) 5 to 15 parts by weight of titanium dioxide, 10 to 20 parts by weight of talc, 3 to 7 parts by weight of silica, 30 to 60 parts by weight of mica, 10 to 20 parts by weight of sericite, 5 to 10 parts by weight of iron oxide, To 0.5 part by weight of a compound represented by the following formula (1); drying and pulverizing the pulverized product;

(b) 2 to 5 parts by weight of methoxypigi-114 / polyepsilon caprolactone, 1 to 5 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 1 to 5 parts by weight of wax, glyceryl stearate / 2 to 6 parts by weight of Pigment-100 stearate, 3 to 6 parts by weight of butylene glycolylacodipyrate / dicaprate, 1 to 4 parts by weight of quaternary 18-hectorite, 1 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, 2 to 6 parts by weight of dicaprylyl carbonate, 1 to 5 parts by weight of caprylic / capric triglyceride, 1 to 5 parts by weight of triethylhexanoin, 1 to 5 parts by weight of ethylhexyl palmitate, 1 to 3 parts by weight of polysorbate 80, 2 to 6 parts by weight of sodium polyacrylate / ethylhexyl stearate / trideceth-6, 15 to 40 parts by weight of glycerin, 15 to 40 parts by weight of a vulcanizing agent and 2 to 7 parts by weight of a compound represented by the following general formula (1) are heated to 50 to 90 占 폚, dissolved and mixed,

Water was added in an amount of 20 to 40 parts by weight based on 100 parts by weight of the mixture, and the mixture was mixed and emulsified using a mixer. The mixture was gradually cooled to 20 to 40 ° C, cooled and then sodium acrylate / sodium acryloyldimethyltaurate copolymer / Adding isohexadecane / polysorbate 80 in an amount of 0.5 to 3 parts by weight based on 100 parts by weight of the emulsion, and then mixing to prepare a water-in-oil type emulsion; And

(c) mixing and dispersing components including 5 to 15 parts by weight of the water-in-oil emulsion of step (b) based on 100 parts by weight of the pulverized product of step (a), and molding the composition. The method provides:

[Chemical Formula 1]

In this formula,

n is a natural number of 2 to 10,

a and b are molar fractions, a is 0.5 and b is 0.5;

c and d are mole fractions, c is 0.05 to 0.2, d is 0.8 to 0.95, and c + d is 1.

The above-mentioned contents of the color cosmetic composition may be applied as it is to the above-mentioned production method.

In addition, methods generally used in this field can be employed without limitation, except for those specifically defined in the above-mentioned manufacturing method.

Hereinafter, the present invention will be described in more detail by way of examples. However, the following examples are intended to further illustrate the present invention, and the scope of the present invention is not limited by the following examples. The following examples can be appropriately modified and changed by those skilled in the art within the scope of the present invention.

Production Example 1: Preparation of block copolymer (compound of formula (1)) of polyacrylic acid substituted with poly-D, L-lactic acid-co-glycolic acid and diisocyanate compound

(1) Preparation of polyacrylic acid substituted with diisocyanate compound

40 parts by weight of acrylic acid was added to a 1 L reactor equipped with a cooling device so that nitrogen gas was refluxed and the temperature thereof was easily controlled. 60 parts by weight of ethyl acetate (EAc; ethyl acetate) was poured into the solvent, and nitrogen gas was purged for 30 minutes. The temperature was maintained at 60 占 폚 and 0.1 part by weight of AIBN (azobisisobutyronitrile) as a reaction initiator was added and reacted for 3 hours to prepare an acrylic acid polymer having a weight average molecular weight of 1,500.

100 parts by weight of ethyl acetate (EAc; ethyl aceate) was added to a 1 L reactor equipped with a cooling device to easily regulate the temperature of the reflux of the nitrogen gas. 100 parts by weight of the acrylic acid polymer solid component prepared above and 100 parts by weight of hexamethylene di 10 parts by weight of isocyanate, 54 mg of magnesium trifluorosulfonate, 0.5 part by weight of lonol and 0.15 part by weight of Tinuvin were added. And heated to 110 deg. Heating was carried out for 15 hours to prepare acrylic acid substituted with hexamethylene diisocyanate.

(2) Preparation of block copolymer of poly-D, L-lactic acid-co-glycolic acid and polyacrylic acid substituted with diisocyanate compound

100 ml of dimethylformamide and 290 mg of N, N-carbonyldiimidazole (CDI) were added to the reaction vessel and stirred. To this was added 20 g of poly-D, L-lactic acid-co-glycolic acid (RG502, Boehringer Ingelheim, Germany) having a number average molecular weight of 11,000 to obtain a hydroxyaldehyde group of poly-D, L-lactic acid- Lt; / RTI > 0.5 mg of lonol, 0.15 mg of Tinuvin and 25 g of polyacrylic acid having a number average molecular weight of 2,000 prepared above were added to the solution and heated to 110 캜. After heating for 15 hours, the mixture was filtered through a nylon filter having a pore size of 0.45 micrometer, dispersed in tertiary distilled water, and then unreacted and reaction reagent were removed by dialysis to obtain a block copolymer having a weight average molecular weight of 82,000 .

Preparation Example 2: Preparation of a pulverized product obtained by coating titanium dioxide, talc, silica, mica, sericite, iron oxide, and preservative mixture with the compound of Chemical Formula 1 of Production Example 1, drying and pulverizing

A mixture of 10 parts by weight of titanium dioxide, 15 parts by weight of talc, 5 parts by weight of silica, 46.8 parts by weight of mica, 15 parts by weight of sericite, 8 parts by weight of iron oxide and 0.2 parts by weight of preservative was dissolved in an aqueous solution of the compound of Formula 1 Solid content: 30% by weight), followed by drying and pulverization.

Production Example 3: Preparation of water-in-oil type emulsion

4 parts by weight of methoxypyridyl-114 / polyepsilon caprolactone, 3 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 3 parts by weight of beeswax, 5 parts by weight of glyceryl stearate / 5 parts by weight of butyleneglycol dicaprylate / dicaprate, 2 parts by weight of Quaterium 18-Hectorite, 3 parts by weight of dimethicone / dimethicone / vinyl dimethicone crosspolymer, 4 parts by weight of carbonate, 3 parts by weight of caprylic / capric triglyceride, 3 parts by weight of triethylhexanoin, 2 parts by weight of ethylhexyl palmitate, 2 parts by weight of polysorbate 80, 4 parts by weight of hexyl stearate / trideceth-6, 26 parts by weight of glycerin, 26 parts by weight of butylene glycol, and 5 parts by weight of a compound of the following formula 1 were mixed and 30 parts by weight of water, Mixed and emulsified.

One part by weight of sodium acrylate / sodium acryloyldimethyltaurate copolymer / isohexadecane / polysorbate 80 was added to the emulsion, followed by mixing to prepare a water-in-oil type emulsion.

Preparation Comparative Example 1: Preparation of a mixture of titanium dioxide, talc, silica, mica, cericite, iron oxide, and preservative (coating by the compound of formula (1)

10 parts by weight of titanium dioxide, 15 parts by weight of talc, 5 parts by weight of silica, 46.8 parts by weight of mica, 15 parts by weight of sericite, 8 parts by weight of iron oxide and 0.2 part by weight of preservative.

Examples 1 and 2 and Comparative Examples 1 and 2: Preparation of a color cosmetic composition

The water-in-oil type emulsion (the component described in Table 1 in the case of Comparative Example 1) prepared in Production Example 3 was heated to 80 DEG C, and then the pulverized product prepared in Production Example 2 or the pulverized product The water was dispersed and then pulverized twice using an atomizer.

The pulverized powder was filtered once using a 60 mesh filter net, filled with a predetermined amount on a molding plate, and then pressed with a forming cloth at a pressure of 100 psi for 3 seconds to prepare a color cosmetic composition comprising the water-in-oil type emulsion binder of the present invention.

Example 1 Example 2 Comparative Example 1 Comparative Example 2 The pulverized product of Production Example 2 90 92 - - The water-in-oil emulsion of Preparation Example 3 10 8 - 10 Preparation The pulverized product of Comparative Example 1 - - 90 90 glycerin - - 3 - Butylene glycol - - 3 - Diisostearyl malate - - 0.5 - Ethylhexyl palmitate - - 1.5 - Butyleneglycol dicaprylate / dicaprate - - 0.5 - Hydrogenated polydecene - - 1.5 -

(Unit: parts by weight) Test Example 1: evaluation of feeling of color cosmetic composition

The feeling of use of the color cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2 was evaluated.

Ten women in their thirties were selected as experiential groups, and after using the color cosmetic compositions of Examples 1 and 2 and Comparative Examples 1 and 2, the skin cosmetics composition was applied to each of 1 to 10 points of adhesion, moisturizing, .

The values given by each experiential group are averaged and shown in Table 2 below.

Production Example 1 Production Example 2 Example 1 Example 2 A sense of closeness 5.3 6.7 9.5 9.3 Moisturizing 4.3 4.8 8.7 8.5 Brittle 5.1 7.3 9.5 9.4 Sum 4.9 6.3 9.2 9.1

As can be seen from the above Table 2, in the case of the color cosmetics of Examples 1 and 2 prepared using the colored pigment and the excipient solid particles and the water-in-oil type emulsion coated with the compound of Formula 1 of the present invention, 1 (uncoated solid particles used and water-in-oil type emulsion unknown) and Comparative Example 2 (using uncoated solid particles and water-in-oil emulsion), it showed a remarkable effect in terms of adhesion, moisturizing and wetting .

Claims (4)

(a) 5 to 15 parts by weight of titanium dioxide, 10 to 20 parts by weight of talc, 3 to 7 parts by weight of silica, 30 to 60 parts by weight of mica, 10 to 20 parts by weight of sericite, 5 to 10 parts by weight of iron oxide, To 0.5 part by weight of a compound represented by the following general formula (1); drying and grinding the first mixture;
(b) 2 to 5 parts by weight of methoxypigi-114 / polyepsilon caprolactone, 1 to 5 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 1 to 5 parts by weight of wax, glyceryl stearate / 2 to 6 parts by weight of Pigment-100 stearate, 3 to 6 parts by weight of butylene glycolylacodipyrate / dicaprate, 1 to 4 parts by weight of quaternary 18-hectorite, 1 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, 2 to 6 parts by weight of dicaprylyl carbonate, 1 to 5 parts by weight of caprylic / capric triglyceride, 1 to 5 parts by weight of triethylhexanoin, 1 to 5 parts by weight of ethylhexyl palmitate, 1 to 3 parts by weight of polysorbate 80, 2 to 6 parts by weight of sodium polyacrylate / ethylhexyl stearate / trideceth-6, 15 to 40 parts by weight of glycerin, 15 to 40 parts by weight of lenglycol, and 2 to 7 parts by weight of a compound represented by the following formula (1) are mixed to obtain a second mixture,
Water is added in an amount of 20 to 40 parts by weight based on 100 parts by weight of the second mixture, followed by mixing and emulsification using a mixer to obtain an emulsion. Then, sodium acrylate / sodium acryloyldimethyltaurate copolymer / isohexadecane / 0.5 to 3 parts by weight of sorbate 80 based on 100 parts by weight of the emulsion;
(c) 5 to 15 parts by weight of the water-in-oil emulsion of (b) based on 100 parts by weight of the pulverized product of (a) are mixed and dispersed and molded.
[Chemical Formula 1]

In this formula,
n is a natural number of 2 to 10,
a and b are the respective mole fractions for a and b as a whole, wherein a is 0.5 and b is 0.5;
c and d are the respective mole fractions of c and d as a whole, c is 0.05 to 0.2, d is 0.8 to 0.95, and c + d is 1. delete ◈ Claim 3 is abandoned due to the registration fee. The method according to claim 1,
Wherein the formulation of the color cosmetic composition is selected from the group consisting of two-way cakes, facts, powder foundations, eye shadows, and blushers. (a) 5 to 15 parts by weight of titanium dioxide, 10 to 20 parts by weight of talc, 3 to 7 parts by weight of silica, 30 to 60 parts by weight of mica, 10 to 20 parts by weight of sericite, 5 to 10 parts by weight of iron oxide, To 0.5 part by weight of a compound represented by the following formula (1); drying and pulverizing the pulverized product;
(b) 2 to 5 parts by weight of methoxypigi-114 / polyepsilon caprolactone, 1 to 5 parts by weight of cetylpyridine / piperidine-10/1 dimethicone, 1 to 5 parts by weight of wax, glyceryl stearate / 2 to 6 parts by weight of Pigment-100 stearate, 3 to 6 parts by weight of butylene glycolylacodipyrate / dicaprate, 1 to 4 parts by weight of quaternary 18-hectorite, 1 to 5 parts by weight of dimethicone / vinyl dimethicone crosspolymer, 2 to 6 parts by weight of dicaprylyl carbonate, 1 to 5 parts by weight of caprylic / capric triglyceride, 1 to 5 parts by weight of triethylhexanoin, 1 to 5 parts by weight of ethylhexyl palmitate, 1 to 3 parts by weight of polysorbate 80, 2 to 6 parts by weight of sodium polyacrylate / ethylhexyl stearate / trideceth-6, 15 to 40 parts by weight of glycerin, 15 to 40 parts by weight of a crosslinking agent and 2 to 7 parts by weight of a compound represented by the following general formula (1) are heated to 50 to 90 DEG C and dissolved, Obtaining,
Water was added in an amount of 20 to 40 parts by weight based on 100 parts by weight of the mixture, followed by mixing and emulsification using a mixer to obtain an emulsion. The mixture was gradually cooled to 20 to 40 캜 and then cooled with sodium acrylate / sodium acryloyldimethyltaurate Adding a copolymer / isohexadecane / polysorbate 80 in an amount of 0.5 to 3 parts by weight based on 100 parts by weight of the emulsion, and then mixing to prepare a water-in-oil type emulsion; And
(c) mixing and dispersing components including 5 to 15 parts by weight of the water-in-oil emulsion of step (b) based on 100 parts by weight of the pulverized product of step (a), and molding the composition. Way:
[Chemical Formula 1]

In this formula,
n is a natural number of 2 to 10,
a and b are the respective mole fractions for a and b as a whole, wherein a is 0.5 and b is 0.5;
c and d are the respective mole fractions of c and d as a whole, c is 0.05 to 0.2, d is 0.8 to 0.95, and c + d is 1.