KR20170021930A - Coating method of woven paper or textile fabrics, the woven paper or textile fabrics coated by the method, and articles using the coated woven paper or textile fabrics - Google Patents

Coating method of woven paper or textile fabrics, the woven paper or textile fabrics coated by the method, and articles using the coated woven paper or textile fabrics Download PDF

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Publication number
KR20170021930A
KR20170021930A KR1020150115766A KR20150115766A KR20170021930A KR 20170021930 A KR20170021930 A KR 20170021930A KR 1020150115766 A KR1020150115766 A KR 1020150115766A KR 20150115766 A KR20150115766 A KR 20150115766A KR 20170021930 A KR20170021930 A KR 20170021930A
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South Korea
Prior art keywords
weight
coated
fabric
powder
mixture
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KR1020150115766A
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Korean (ko)
Inventor
임봉학
안종희
임보라
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임봉학
임보라
안종희
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Priority to KR1020150115766A priority Critical patent/KR20170021930A/en
Priority to CN201580081868.1A priority patent/CN107847972A/en
Priority to PCT/KR2015/013197 priority patent/WO2017030246A1/en
Publication of KR20170021930A publication Critical patent/KR20170021930A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/64Inorganic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00Other substrates
    • B05D2203/22Paper or cardboard

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Paints Or Removers (AREA)
  • Paper (AREA)

Abstract

The present invention provides a method of coating fabrics, which comprises: a first step of preparing a mixture by mixing at least one between zeolite powder and diatomaceous earth powder with a fluidity enhancer; a second step of mixing 50-64 wt% of water, 6-10 wt% of an environmentally friendly adhesive, and 26-44 wt% of the mixture to prepare a coating agent; a third step of coating a paper fabric, a fiber fabric, or a non-woven fabric with the coating agent; and a fourth step of drying the fabrics coated with the coating agent. Furthermore, the present invention provides coated fabrics coated by the method, and articles using the coated fabrics.

Description

[0001] The present invention relates to a method of coating a fabric, a coated fabric coated by the method, and a method of using the coated fabric to provide a coating method of woven paper or textile fabrics, the woven paper or textile fabrics coated by the method, }

The present invention relates to a method of coating an inorganic material capable of adsorbing gas and moisture on a paper fabric, a textile fabric or a nonwoven fabric fabric, a coating fabric coated by the method, and an article using the fabric.

Conventionally, a method of coating an inorganic material capable of adsorbing gaseous gas and moisture on a paper fabric, a textile fabric, or a nonwoven fabric fabric is disclosed in Korean Patent Registration No. 10-0788874. This technique is to produce a packaging material for applying a coating agent containing zeolite and bentonite to a nonwoven fabric or paper to adsorb the gas possessed by the zeolite and bentonite and to retain the vegetables and fruits for a long time by the water absorption function.

In the above-mentioned technique, the fluidity of the coating agent is low, so that a relatively high weight of zeolite and bentonite powder is submerged in the reservoir. To solve this problem, the reservoir is continuously stirred to cause the zeolite and bentonite powder to sink However, there was a problem that the zeolite and the bentonite powder settled during the movement from the reservoir to the nozzle such as the nozzle through the pipe.

Due to such a problem, Korean Patent No. 10-0788874 has a problem that it has a great obstacle to the mass production of the packaging material despite the superiority of the technology.

Korean Patent No. 10-0788874

SUMMARY OF THE INVENTION The present invention has been made in order to solve the above-mentioned problems, and it is an object of the present invention to solve the problem that the inorganic powder capable of adsorbing gas and moisture quickly sinks in the reservoir, A method of coating a paper or a fiber or a nonwoven fabric so that it is easy to mass-produce a fabric coated with a coating agent containing zeolite powder and / or diatomaceous earth powder by solving the problem of sinking on the way to the jetting port, And to provide an article using the coated fabric and the coated fabric.

In order to accomplish the above object, the present invention provides a method for coating a fabric, comprising the steps of: preparing a mixture by mixing at least one of zeolite powder and diatomite powder with a fluidity increasing agent; A second step of preparing a coating agent by mixing 50 to 64% by weight of water, 6 to 10% by weight of an environmentally friendly adhesive, and 26 to 44% by weight of the mixture; A third step of coating the paper fabric or the textile fabric or the nonwoven fabric fabric with the coating agent; And a fourth step of drying the coated cloth with the coating agent.

In the first step, 88 to 92% by weight of zeolite powder and 8 to 12% by weight of calcium carbonate are mixed to prepare a mixture, or 88 to 92% by weight of diatomaceous earth powder and calcium carbonate 8 Or 12 wt.% Of the zeolite powder is mixed to prepare a mixture, or a mixture is prepared by mixing 76 to 84 wt.% Of zeolite powder, 8 to 12 wt.% Of diatomaceous earth powder and 8 to 12 wt. %, Diatomaceous earth powder of 76 to 84% by weight and calcium carbonate of 8 to 12% by weight.

In the third step, the fabric is uniformly coated with the coating agent in an amount of 5 to 300 g per minute per square meter of the fabric at a rate of 80 to 500 m per minute. In the fourth step, the coating agent is preferably dried at a temperature of 60 to 350 ° C.

Meanwhile, the coated fabric of the present invention is characterized in that it is coated by the above-described fabric coating method.

Meanwhile, the article using the coated fabric of the present invention is formed by using the fabric coated by the above-described fabric coating method.

Herein, the above items are used for agricultural product packaging boxes, air purification filters, house curtains, exhaust chimneys for houses, polluted water purification sheets, agricultural padding pads, agricultural padding pads, agricultural padding pads, .

According to the present invention, the inorganic powder capable of adsorbing gas and moisture quickly sinks in the reservoir, and the inorganic powder sinks on the way from the reservoir to the nozzle such as the nozzle through the pipe It is easy to mass-produce a fabric coated with a coating agent containing zeolite powder and / or diatomaceous earth powder.

In addition, according to the present invention constructed as described above, the adsorbability and hygroscopicity of the zeolite powder and the diatomaceous earth powder are excellent, and the adsorbability of the zeolite powder and the diatomaceous earth powder is excellent.

According to the present invention having the above-described structure, the adsorbability of zeolite powder and diatomaceous earth powder makes it possible to adsorb gases such as ammonia gas, carbon dioxide gas, and hydrogen sulfide gas and heavy metals, , The purification ability can be improved when applied to a soot purifying device and a facility.

1 is a process flow diagram schematically showing a fabric coating method according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, with reference to the accompanying drawings, a description will be given in detail of a method of coating a fabric according to the present invention, a coated fabric coated by the method, and articles using the coated fabric.

1 is a process flow diagram schematically showing a fabric coating method according to the present invention.

As shown in the figure, the raw material coating method of the present invention comprises a first step (10) of preparing a mixture by mixing at least one of zeolite powder and diatomaceous earth powder with a fluidity-increasing agent, A second step (20) of preparing a coating agent by mixing, a third step (30) of coating a coating agent on the raw fabric, and a fourth step (40) of drying the coated raw material coated with the coating agent.

In zeolite, zeolite, like feldspar, is a three-dimensional skeleton structure of (Si, Al) O 4 tetrahedrons by apical oxygen, but it has voids and contains water molecules and exchangeable cations. The water molecules are easily removed by heating at a relatively low temperature, but since the framework of the structure is not changed, the water molecules are absorbed in the air to fill the water. The chemical composition can be expressed as [Wy (Si, Al) (O 2 xnH 2 O)]. W is known to be Na and Ca, and K, Mg, Ba and Li.

The diatomaceous earth is mainly made of silicic acid (SiO 2 ), and since it is very porous, it is highly absorbent and is known to be used as an adsorbent, a filter material, a high-temperature material, an abrasive and the like.

The zeolite powder and the diatomaceous earth powder have excellent adsorbability and hygroscopicity, and have excellent water adsorbability, excellent gas binding property, and excellent adsorption ability of gases such as ammonia gas, carbon dioxide gas, hydrogen sulfide gas and heavy metals.

The zeolite powder and the diatomaceous earth powder preferably have a particle size of 200 to 500 mesh.

Meanwhile, in the first step (10), it is preferable to use calcium carbonate as the fluidity increasing agent, and the calcium carbonate improves fluidity while preserving solidification of the material. Here, the calcium carbonate preferably has a particle size of 200 to 500 mesh.

In the first step 10, a mixture may be prepared by mixing 88 to 92% by weight of zeolite powder and 8 to 12% by weight of calcium carbonate. In the first step 10, 88 to 92% by weight of the diatomite powder and 8 to 12% by weight of calcium carbonate may be mixed to prepare a mixture. In the first step 10, a mixture may be prepared by mixing 76 to 84% by weight of zeolite powder, 8 to 12% by weight of diatomaceous earth powder and 8 to 12% by weight of calcium carbonate. In the first step 10, 8 to 12 wt% of zeolite powder, 76 to 84 wt% of diatomaceous earth powder, and 8 to 12 wt% of calcium carbonate may be mixed to prepare a mixture.

Meanwhile, in the second step, it is preferable to prepare a coating agent by mixing 50 to 64% by weight of water, 6 to 10% by weight of an environmentally friendly adhesive, and 26 to 44% by weight of the mixture. As the environmentally friendly adhesive, Is preferably used. The high-weight zeolite powder or diatomaceous earth powder contained in the coating material thus prepared is improved in fluidity by the calcium carbonate, so that the sinking is significantly reduced in the reservoir and on the way from the reservoir to the nozzle such as the nozzle through the tube .

In the third step, the fabric may be any one of a paper fabric, a fiber fabric, and a nonwoven fabric. In the third step, about 5 to 300 g of coating agent per square meter of fabric, preferably about 20 to 60 g, Coating. Further, it is preferable to coat the fabric at a rate of about 80 to 500 m per minute.

In addition, in the fourth step, it is preferable to dry at a temperature of 60 ° C to 350 ° C, and it is preferable that the raw material after the coating process is coated at a temperature of 60 ° C to 350 ° C for about 80 to 500m per minute.

Next, the present invention will be described in more detail with reference to examples and comparative examples.

≪ Example 1 >

90% by weight of zeolite powder and 10% by weight of calcium carbonate were mixed to prepare a mixture, and 58% by weight of water, 8% by weight of environmentally friendly adhesive, and 34% by weight of the mixture were mixed to prepare a coating agent.

≪ Example 2 >

90 wt% of diatomaceous earth powder and 10 wt% of calcium carbonate were mixed to prepare a mixture, and 58 wt% of water, 8 wt% of environmentally friendly adhesive, and 34 wt% of the mixture were mixed to prepare a coating agent.

≪ Example 3 >

A mixture was prepared by mixing 80% by weight of zeolite powder, 10% by weight of diatomaceous earth powder and 10% by weight of calcium carbonate, and mixing the mixture with 58% by weight of water, 8% by weight of environmentally friendly adhesive, and 34% by weight of the mixture.

<Example 4>

A mixture was prepared by mixing 10% by weight of zeolite powder, 80% by weight of diatomaceous earth powder and 10% by weight of calcium carbonate, and a coating agent was prepared by mixing 58% by weight of water, 8% by weight of environmentally friendly adhesive, and 34% by weight of the mixture.

&Lt; Comparative Example 1 &

95% by weight of zeolite powder and 5% by weight of calcium carbonate were mixed to prepare a mixture, and 58% by weight of water, 8% by weight of eco-friendly adhesive and 34% by weight of the mixture were mixed to prepare a coating agent.

&Lt; Comparative Example 2 &

95% by weight of diatomaceous earth powder and 5% by weight of calcium carbonate were mixed to prepare a mixture, and 58% by weight of water, 8% by weight of eco-friendly adhesive and 34% by weight of the mixture were mixed to prepare a coating agent.

&Lt; Comparative Example 3 &

A mixture was prepared by mixing 85% by weight of zeolite powder, 10% by weight of diatomaceous earth powder and 5% by weight of calcium carbonate. A coating agent was prepared by mixing 58% by weight of water, 8% by weight of environmentally friendly adhesive, and 34% by weight of the mixture.

&Lt; Comparative Example 4 &

10% by weight of zeolite powder, 85% by weight of diatomaceous earth powder and 5% by weight of calcium carbonate were mixed to prepare a coating material. 58% by weight of water, 8% by weight of environmentally friendly adhesive and 34% by weight of the mixture were mixed.

&Lt; Comparative Example 5 &

58% by weight of water, 8% by weight of an eco-friendly adhesive, and 34% by weight of zeolite powder were mixed to prepare a coating agent.

&Lt; Comparative Example 6 >

58% by weight of water, 8% by weight of eco-friendly adhesive, and 34% by weight of diatomaceous earth powder were mixed to prepare a coating agent.

&Lt; Comparative Example 7 &

90% by weight of zeolite powder and 10% by weight of diatomaceous earth powder were mixed to prepare a mixture. 58% by weight of water, 8% by weight of eco-friendly adhesive and 34% by weight of the mixture were mixed to prepare a coating agent.

&Lt; Comparative Example 8 >

10% by weight of zeolite powder and 90% by weight of diatomaceous earth powder were mixed to prepare a mixture, and 58% by weight of water, 8% by weight of environmentally friendly adhesive and 34% by weight of the mixture were mixed to prepare a coating agent.

<Experiment>

The coating agent prepared in Examples 1 to 4 and the comparative coating agents prepared in Comparative Examples 1 to 8 were stirred in a stirrer at 30 rpm for 2 minutes, stirring was stopped, and the degree of sinking of the powder was observed.

Approximately 5 minutes and 30 seconds in the case of Embodiment 1, approximately 5 minutes and 24 seconds in Embodiment 2, approximately 5 minutes and 35 seconds in Embodiment 3, and approximately 5 minutes and 18 seconds in Embodiment 4 At one point, the powder was observed to sink. In the case of Comparative Example 1, about 4 minutes and 20 seconds, about 4 minutes and 16 seconds for Comparative Example 2, about 4 minutes and 26 seconds for Comparative Example 3, and about 4 minutes and 22 seconds for Comparative Example 4 It was observed that the powder settled down from the time when it passed. In the case of Comparative Example 5, the time was about 3 minutes and 45 seconds. In Comparative Example 6, about 3 minutes and 48 seconds. In Comparative Example 7, about 3 minutes and 42 seconds. In Comparative Example 8, It was observed that the powder settled down from the point of time when the seconds passed.

As can be seen from this experiment, it was confirmed that the flowability of the zeolite powder and diatomite powder contained in the coating agent was remarkably increased due to the addition of calcium carbonate.

As described above, according to the present invention, it is possible to solve the problem that the inorganic powder capable of adsorbing gas and moisture quickly sinks in the reservoir, and furthermore, it is possible to solve the problem that the inorganic powder sinks while moving from the reservoir to the injection port It is easy to mass-produce a fabric coated with a coating agent containing zeolite powder and / or diatomaceous earth powder.

In addition, according to the present invention constructed as described above, the adsorbability and hygroscopicity of the zeolite powder and the diatomaceous earth powder are excellent, and the adsorbability of the zeolite powder and the diatomaceous earth powder is excellent.

According to the present invention having the above-described structure, the adsorbability of zeolite powder and diatomaceous earth powder makes it possible to adsorb gases such as ammonia gas, carbon dioxide gas, and hydrogen sulfide gas and heavy metals, , The purification ability can be improved when applied to a soot purifying device and a facility.

The present invention is not limited to the above-described specific embodiments, and various modifications and changes may be made without departing from the gist of the present invention. It will be obvious that such modifications and variations are included in the appended claims.

10 to 40: Manufacturing process steps

Claims (7)

A first step of preparing a mixture by mixing at least one of zeolite powder and diatomaceous earth powder with a fluidity increasing agent;
A second step of preparing a coating agent by mixing 50 to 64% by weight of water, 6 to 10% by weight of an environmentally friendly adhesive, and 26 to 44% by weight of the mixture;
A third step of coating the paper fabric or the textile fabric or the nonwoven fabric fabric with the coating agent; And a fourth step of drying the coated cloth with the coating agent.
The method according to claim 1,
Wherein the fluidity-increasing agent is calcium carbonate.
3. The method of claim 2,
In the first step, 88 to 92% by weight of zeolite powder and 8 to 12% by weight of calcium carbonate are mixed to prepare a mixture, 88 to 92% by weight of diatomite powder and 8 to 12% by weight of calcium carbonate are mixed to prepare a mixture By weight of zeolite powder, 76 to 84% by weight of zeolite powder, 8 to 12% by weight of diatomaceous earth powder and 8 to 12% by weight of calcium carbonate, And 8 to 12 wt% of calcium are mixed to prepare a mixture.
The method of claim 3,
Wherein the fabric is uniformly coated with the coating agent in an amount of 5 to 300 g per minute per square meter of the fabric in an amount of 80 to 500 m per minute and the fourth step is dried at a temperature of 60 to 350 ° C.
A coated coated fabric characterized by being coated by the method according to any one of claims 1 to 4. Characterized in that it is made using a coated fabric coated by the method according to any one of claims 1 to 4 above. The method according to claim 6,
Products made from the above coated fabrics include agricultural packaging boxes, air purifying filters, barn curtains, exhaust chimneys for housing, polluted water purification sheets, hardwood pads for agricultural product packaging boxes, cubicle pads for agricultural product packaging boxes, agricultural product packaging boxes &Lt; RTI ID = 0.0 &gt; and / or &lt; / RTI &gt;
KR1020150115766A 2015-08-18 2015-08-18 Coating method of woven paper or textile fabrics, the woven paper or textile fabrics coated by the method, and articles using the coated woven paper or textile fabrics KR20170021930A (en)

Priority Applications (3)

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KR1020150115766A KR20170021930A (en) 2015-08-18 2015-08-18 Coating method of woven paper or textile fabrics, the woven paper or textile fabrics coated by the method, and articles using the coated woven paper or textile fabrics
CN201580081868.1A CN107847972A (en) 2015-08-18 2015-12-04 The preparation method of packaging material for food and the packaging material for food being prepared by this method
PCT/KR2015/013197 WO2017030246A1 (en) 2015-08-18 2015-12-04 Food wrapping manufacturing method and food wrapping manufactured using same

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KR102030318B1 (en) * 2019-05-10 2019-10-10 임봉학 Manufacturing method of pulp molded article and the pulp molded article by the same

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ES2685994B1 (en) * 2017-03-30 2019-05-03 Smurfit Kappa Espana Sa Procedure for obtaining an ethylene absorber paper and product obtained
CN108894058B (en) * 2018-06-11 2021-04-13 浙江上峰包装新材料有限公司 Water-based back coating liquid, cigarette packaging paper and preparation method of cigarette packaging paper
CN114517006B (en) * 2022-02-23 2024-01-02 佛山市湘聚新材料有限公司 Bio-based degradable plastic and preparation method thereof
CN114572558B (en) * 2022-03-22 2023-06-16 衢州学院 Novel edible preservative paper and preparation process thereof

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