KR20170021523A - Method and apparatus of pipe cleaning by electrolysis - Google Patents

Method and apparatus of pipe cleaning by electrolysis Download PDF

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Publication number
KR20170021523A
KR20170021523A KR1020150116011A KR20150116011A KR20170021523A KR 20170021523 A KR20170021523 A KR 20170021523A KR 1020150116011 A KR1020150116011 A KR 1020150116011A KR 20150116011 A KR20150116011 A KR 20150116011A KR 20170021523 A KR20170021523 A KR 20170021523A
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South Korea
Prior art keywords
cleaning
water
washing water
piping
electrolysis
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KR1020150116011A
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Korean (ko)
Inventor
황덕흥
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황덕흥
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Publication of KR20170021523A publication Critical patent/KR20170021523A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/02Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027Cleaning the internal surfaces; Removal of blockages
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4616Power supply

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The present invention provides an electrolytic reaction in cleansing water containing chlorine ions of a predetermined concentration or more by using hydrochloric acid and salt, so that micro-gaseous by-products containing chlorine gas as an oxidizing germicide form minute bubbles, It increases the solubility of the scale and the like immersed by the fluid flow of the turbulent flow and weakens the binding force of the scale and the like by the action of cleaning the flow friction of minute bubbles and oxidizing and sterilizing by chlorine having the oxidative sterilizing power, And then discharged out of the pipe to be cleaned. The present invention relates to a pipe cleaning apparatus and a pipe cleaning method using the electrolysis method.
In order to accomplish the above object, the present invention provides a piping cleaning apparatus comprising cleaning water producing means, cleaning water supplying means, electrolytic reaction generating means, and a control panel, A washing water producing means for preparing and supplying washing water using hydrochloric acid and salt so as to contain the washing water; A rinsing water storage tank, a rinsing water supply pump, rinsing water supply means comprising a rinsing water direction switching valve and an injector for adjusting rinsing water supply direction; A DC power supply for supplying DC power, an electrolytic reaction generating means equipped with an electrode tube module configured to alternately maintain a constant interval between a net type anode tube and a cathode tube; And a control panel for allowing the electrolysis reaction to be automatically operated on and off periodically, thereby effectively achieving pipeline cleaning.

Figure pat00001

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a pipe cleaning apparatus,

The present invention relates to a piping cleaning apparatus and a piping cleaning method using an electrolysis method, and more particularly, to a piping cleaning apparatus and piping cleaning method using an electrolysis method, and more particularly to a piping cleaning apparatus and a piping cleaning method using chlorine Ionic cleansing water is passed through the electrolytic device to generate microbubbles of chlorine gas and hydrogen gas, which are electrolysis byproducts in the anode and the cathode, and are supplied to the cleaning pipe, whereby the dissolving action and oxidizing action of the cleansing water, The apparatus and the method are configured so as to obtain an efficient cleaning effect by the action of the flow friction by the electrolytic apparatus, thereby achieving the optimized piping cleaning method and effect by having the light weight, In a pipe cleaning apparatus and a pipe cleaning method using an electrolysis method One will.

Generally, pipes used for heat exchangers such as water supply, drainage, or boiler in houses and various industrial facilities and factories are used for long time, and due to the interaction with hardness components and microorganisms included in the piping water, Impurities such as corrosion, scale and slime are accumulated. When the impurities are deposited on the inner wall of the pipe, the flow of the fluid in the pipe is disturbed, and metal oxides such as rust and harmful impurities such as bacteria are accumulated, thereby causing odor, water taste, suspended substances and chromaticity. Will influence. In addition, in the piping of a heat exchanger such as a boiler, efficiency of heat transfer due to scale and the like is lowered, and efficiency of cooling and heating is lowered, thereby causing energy loss to increase. Also, since it is left to stand for a long time, In order to solve these problems, it is necessary to periodically clean and manage an effective piping cleaning device because time and cost are required.

In the case of the Korean Patent No. 10-0821715, it is assumed that the auxiliary equipment such as a compressor, a pressurizing pump, and an air tank, which pressurizes the air, In the case of the Korean Patent No. 10-1261316, there is a limit to the complexity of the apparatus and the practicality of the operation due to the complicated piping structure such as apparatus for generating fine bubbles, air piping, washing water piping, detergent supply tank and piping There is a limit to cleaning piping that is difficult to access.

The present invention has been developed in order to solve all of the above problems, and it is an object of the present invention to provide an electrolytic reaction in cleansing water containing chlorine ions of a predetermined concentration or more using hydrochloric acid and salt, Byproducts of fine bubbles form fine bubbles, thereby increasing the solubility of scales and the like deposited by the fluid flow of the turbulent flow in the cleaning piping, and by performing the friction rinsing cleaning of fine bubbles and the oxidizing and sterilizing cleaning by the chlorine having the oxidizing sterilizing power, And effectively removing contaminants such as bacteria from the microbial layer and discharging the contaminants to the outside of the pipe to clean the pipe cleaning apparatus and the pipe cleaning method using the electrolysis method.

To achieve the above object, the present invention provides a piping cleaning apparatus comprising cleaning water producing means, cleaning water supplying means, electrolytic reaction generating means, and a control panel. A washing water producing means for preparing and supplying washing water using hydrochloric acid and salt; A rinsing water storage tank, a rinsing water supply pump, rinsing water supply means comprising a rinsing water direction switching valve and an injector for adjusting rinsing water supply direction; A DC power supply for supplying DC power, an electrolytic reaction generating means equipped with an electrode tube module configured to alternately maintain a constant interval between a net type anode tube and a cathode tube; And an electrolytic reaction in the electrode tube module is constituted by a control panel that can be automatically operated on and off periodically, thereby effectively achieving pipeline cleaning.

According to the present invention, cleansing water prepared for effective piping cleaning is prepared by using hydrochloric acid to make cleansing water containing acid concentration of about 2 ~ 3 and salt concentration of 5,000 ~ 10000 ppm .

In the present invention, in order to supply the washing water to the electrolytic apparatus, when the self water pressure of the water in the pipe is large, the washing water is naturally supplied by the pressure difference formed in the injector and supplied. The washing water is directly supplied to the electrolytic apparatus by using the washing water supply pump. In each case, the direction of supplying the washing water is changed through the switching valve in the washing water direction and the washing water is supplied to the electrolytic apparatus So that it can be supplied.

According to the present invention, there is provided a method for simultaneously forming a dissolution action by cleansing water, an oxidizing sterilizing agent and fine bubbles, and supplying the same to a cleaning pipe, The electrolytic reaction stopper is provided with the step of dissolving and cleaning by the washing water and the step of operating the electrolytic water stopper and the actuator by supplying the oxidizing sterilizing agent in the electrolytic water and the fine And a step of oxidizing and desorbing due to the flow friction of the bubbles.

In addition, in the electrode plate module of the present invention, the base materials of the net-type anode and cathode tubes are made of titanium material, the surface of the titanium tube is coated with iridium dioxide and ruthenium, and a cross-shaped insulator is used between the alternate anode- And the upper portion of each of the net-like electrode tubes connected to the power source of the anode and the cathode is configured to be able to be welded together by separating the anode-cathode tube and the cathode-cathode tube, .

The electrochemical reactions that show the cleaning effect by electrolysis are summarized as follows.

When an electrolysis reaction occurs in water containing chlorine ions, a chlorine gas acts as a powerful oxidizing and disinfecting agent in the anode, and hydrogen gas which is not soluble in the cathode is generated in the cathode.

The gases produced in the anode and cathode through the electrochemical reaction are as follows.

2Cl - → Cl 2 (chlorine gas) + 2e - (electrolysis at anode)

H 2 O + 2e - → H 2 (hydrogen gas) + 2OH - (electrolysis at the cathode)

The chlorine gas generated through the electrolysis reaction is dissolved in water because of its high solubility in water and forms an oxidizing bactericide. The chemical reaction formula is as follows.

Cl 2 (gas) + H 2 O → HOCl (oxidizing fungicide) + H + + Cl - (oxidation fungicide production reaction)

The oxidizing agent and the fine bubbles generated through the electrolysis reaction penetrate into the gap of the scale layer of the pipe due to the dissolution and oxidization by the turbulent fluid flow, and the flow friction of these minute bubbles and oxidizer And dissolves through reaction with the microbial layer to weaken the bonding force in the pipe, thereby detoxifying and sterilizing contaminants in the pipe and removing it from the pipe.

According to the present invention, it is possible to simplify and lighten the piping cleaning apparatus by supplying the oxidizing agent and the fine bubbles through the electrolytic reaction of the pipeline cleaning water, thereby providing the economical efficiency, the convenience of the cleaning operation, the mobility and the efficiency There is an effect that can be increased.

The effective cleaning effect of the piping is the electrochemical by-product of the electrolysis reaction, which forms chlorine gas and micro-bubbles with oxidative sterilizing power at the anode and cathode, and thus the flow friction of the micro bubbles due to the fluid flow in the pipe water, The cleaning effect of the chlorine gas with the chlorine gas is dissolved, washed, desorbed, and sterilized by the contaminants such as scales deposited on the wall surface of the pipe and the microorganism layer.

1 is a flow chart for explaining a pipe cleaning apparatus using an electrolysis method according to the present invention.
2 is a schematic view showing an electrode tube module.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.

As shown in FIG. 1, the present invention comprises a washing water producing means, a washing water supplying means, an electrolysis reaction generating means, and a control panel. The washing water is produced by using hydrochloric acid in an acidic condition of about 2 to 3 A washing water reservoir 101 and a washing water feed pump 103, and a washing water supply unit 104 for supplying washing water to the cleaning water supply unit 103 A washing water supply means composed of a water direction switching valve 104 and an injector 105 and a DC power supply 108 for supplying a DC power source and a net cathode tube 201 and a cathode tube 202 alternately Up-type electrolytic unit 107 equipped with an electrode tube module 200 which is vertically supported by a cruciform insulator 203 and is held at a constant interval, and a standing-up type electrolytic unit 107 107) was subjected to an electrolysis reaction And a control panel 109 for enabling the on and off operations to be performed automatically. By controlling the control panel 109, chlorine gas generated through the electrolysis reaction in the standing upflow electrolytic apparatus 107 and fine gas Is connected to the inlet of the cleaning pipe 111 through the electrolytic water supply pipe 110 in the form of minute bubbles so as to be supplied into the cleaning pipe 111 so that the inside of the contaminated pipe can be effectively cleaned.

Since the scale components immersed in the piping or the microbial layer are generated by the simultaneous action of the dissolution and oxidation by the washing water passing through the stocking upflow electrolytic apparatus 107 and the flow friction by the microbubbles and the cleaning action, Characterized by dissolving, oxidizing and desorbing components or microbial layers. Particularly, micro-bubbles penetrate into the gaps formed in the dissolution and oxidation process of the existing gaps and the scale layer or the microbial layer to weaken the binding force of the scale components or the microbial layer to improve the dissolution and desorption effect, And collected in the storage tank 112 to be removed.

In the present invention, the degree of microbubbles to be cleaned and the cleaning time for cleaning the polluted cleaning pipe 111 are different depending on the characteristics of the scale layer and the microbial layer formed in the piping. However, The control unit 109 controls the amount of current supplied from the DC power supply 108 so that the amount of the oxidizing agent and the amount of microbubbles can be controlled And the electrolysis reaction is performed at a constant electrolysis reaction time interval according to the state of the washing pipe 111. In the electrolysis reaction stopper, dissolution and oxidation of the deposits by the washing water and oxidation reaction occur in the electrolysis reaction reactor It is possible to effectively combine the oxidative sterilization action of the chlorine oxide and the minute bubbles with the flow cleaning action, thereby effectively removing the scale.

Therefore, according to the present invention, it is possible to optimize the operation convenience and the mobility of the apparatus by simplifying the construction of the washing water and the electrolytic device and reducing the weight, and also it is possible to improve the cleaning efficiency and economical efficiency.

While the present invention has been described in connection with what is presently considered to be practical exemplary embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but, on the contrary, It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the appended claims.

100. Piping water supply piping 101 Rinse water reservoir 102. Rinse water supply piping
103. Rinse water supply pump 104. Rinse water direction switching valve 105. Injector
106. Wash water valve 107. Standing upflow type electrolysis device
108. DC power supply 109. Control panel 110. Electrolysis water supply piping
111. Cleaning piping 112. Cleaning waste liquid storage tank
200. Electrode tube module 201. Mesh type anode tube 202. Mesh type cathode tube
203. Cross-shaped insulator

Claims (3)

A cleaning water producing means for supplying and supplying cleaning water by using hydrochloric acid and salt so as to contain an appropriate acid state and a chloride ion concentration for cleaning the piping;
The washing water reservoir, the washing water supply pump, the number of the piping water itself is weak, and the washing water which adjusts the direction of the washing water supply pipe is supplied when the washing water is supplied by the self- A rinse water supply means composed of an orientation switching valve and an injector for supplying rinse water with a pressure difference of negative pressure formed in the injector by the self water pressure of the piping water supplied without the need for the rinse water supply pump;
A direct current power supply for supplying direct current power, a standing up type electrolytic device equipped with an electrode tube module made by alternately arranging a net type anode tube and a cathode tube;
And a control panel for automatically activating and deactivating the electrolysis reaction of the standing type upflow electrolytic apparatus periodically,
Through the adjustment of the control panel, the chlorine gas and the fine gas generated through the electrolysis reaction in the standing upflow type electrolytic apparatus are connected to the inlet of the cleaning pipe through the electrolysis water supply pipe in the form of minute bubbles, So that the cleaning is carried out.
In the production of the washing water, a certain amount of hydrochloric acid and salt are injected to make an acidic condition of about 2 to 3 and a chlorine ion concentration of about 5000 to 8000 ppm so that the washing water can effectively wash the washing water, A piping cleaning apparatus and piping cleaning method using an electrolysis method In the electrode tube module, both the base material of the meshed anode tube and the cathode tube are made of titanium, and the surface of the titanium tube of the anode and the cathode is coated with iridium dioxide and ruthenium to provide an effective electrolysis reaction. Anodic and cathodic tubes are mounted alternately and cross-shaped insulators support the top and bottom to form a constant electrode gap. The tops of the electrode tubes, which are connected to the power supply of each anode and cathode, are welded to facilitate electrical contact, Pipe cleaning apparatus and piping cleaning method using an electrolysis method for causing a decomposition reaction
KR1020150116011A 2015-08-18 2015-08-18 Method and apparatus of pipe cleaning by electrolysis KR20170021523A (en)

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KR1020150116011A KR20170021523A (en) 2015-08-18 2015-08-18 Method and apparatus of pipe cleaning by electrolysis

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109340076A (en) * 2018-11-02 2019-02-15 东莞市末客信息科技有限公司 A kind of double-pump type unidirectionally single main pipeline anti-clogging pumping method and system
KR102147188B1 (en) * 2020-03-13 2020-08-25 미령환경개발(주) Scrubber with depression of microorganism using sterilization water based on tap water
CN116422108A (en) * 2023-03-23 2023-07-14 滕州祥润化工有限公司 Ammonia recoverer during ammonia loading and unloading

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109340076A (en) * 2018-11-02 2019-02-15 东莞市末客信息科技有限公司 A kind of double-pump type unidirectionally single main pipeline anti-clogging pumping method and system
KR102147188B1 (en) * 2020-03-13 2020-08-25 미령환경개발(주) Scrubber with depression of microorganism using sterilization water based on tap water
CN116422108A (en) * 2023-03-23 2023-07-14 滕州祥润化工有限公司 Ammonia recoverer during ammonia loading and unloading
CN116422108B (en) * 2023-03-23 2023-09-15 滕州祥润化工有限公司 Ammonia recoverer during ammonia loading and unloading

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