KR100929118B1 - Electrolysis solution producing device - Google Patents
Electrolysis solution producing device Download PDFInfo
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- KR100929118B1 KR100929118B1 KR1020080057631A KR20080057631A KR100929118B1 KR 100929118 B1 KR100929118 B1 KR 100929118B1 KR 1020080057631 A KR1020080057631 A KR 1020080057631A KR 20080057631 A KR20080057631 A KR 20080057631A KR 100929118 B1 KR100929118 B1 KR 100929118B1
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- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
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Abstract
Description
본 발명은 물을 전기 분해하여 pH 13.0 이상 강 알칼리수와 pH 2.0 이하의 강 산성수를 제조할 수 있는 전해수 생성장치에 관한 것으로서, 더 상세하게는 강 알칼리수 및 강 산성수를 생산하기 위한 에너지 소비량을 최소화시킬 수 있고(1 kw 미만), 단시간에 대량의 강 알칼리수 및 강 산성수를 생산할 수 있도록 구성되는 전해수 생성장치이다.The present invention relates to an electrolytic water generating device capable of producing strong alkaline water of pH 13.0 or higher and strong acidic water of pH 2.0 or lower by electrolyzing water, and more particularly, energy consumption for producing strong alkaline water and strong acidic water. It is an electrolytic water generating device that can be minimized (less than 1 kw) and configured to produce a large amount of strong alkaline water and strong acidic water in a short time.
강 알칼리수는 특정 유해 물질(TCE, CFC, HCFC류)로 규정된 산업용 세정제를 대체할 수 있으며 가정용 다목적 세정제로도 탁월한 효능을 발휘하고 있는 물질이며, 강 산성수는 식품 첨가물인 차아염소산수로서 식기나 식재료의 살균 소독뿐만 아니라 의료용 내시경 세정 등에도 널리 이용되는 물질이다.
대한민국 등록특허 10-0439998호에는 유입된 원수를 각각 음극쉘과 양극쉘로 인입 되게 하여 다단으로 전해하여 양극과 음극의 pH차를 증대시키는 "다단식 유격막 전해수 생성장치"가 제시되어 있고, WO 2005/105678호에는 중공의 다각주상에 외측 전극과 격막 지지체와 내측 전극이 동축상에 위치하게 하여 다각주상의 양측면 및 제4면에서 전해가 되는 장치가 제시되어 있다. 또한, 대한민국 등록특허 10-0533710호에는 인라인상에 3개의 전극과 3실을 구비한 전해조가 제시되어 있으며, 대한민국 공개특허 제 10-0433856호, 제10-0506767호, 대한민국 등록실용신안 제20-0339730호에도 전해수 생성장치들이 개시되어 있다.Strong alkaline water can replace the industrial cleaning agents specified by certain harmful substances (TCE, CFC, HCFCs), and it is a material that shows excellent efficacy as a multipurpose cleaner for home use. Strong acidic water is a hypochlorous acid water as a food additive. B. It is a material widely used for sterilization and disinfection of food ingredients, as well as for cleaning medical endoscopes.
Korean Patent No. 10-0439998 discloses a "multistage diaphragm electrolyzed water generating device" which increases the pH difference between the positive electrode and the negative electrode by introducing the raw water into the negative electrode shell and the positive electrode shell, respectively, to increase the pH difference between the positive electrode and the negative electrode, WO 2005. / 105678 discloses an apparatus in which the outer electrode, the diaphragm support, and the inner electrode are coaxially positioned on a hollow polygonal column so as to be electrolyzed on both sides and the fourth side of the polygonal column. In addition, Korean Patent Registration No. 10-0533710 discloses an electrolytic cell having three electrodes and three chambers on an inline. 0339730 also discloses electrolytic water generating devices.
종래의 유수식 전해수 제조장치로는 저전압 저전류의 전해 조건으로 소정의 pH를 갖는 전해수를 대량으로 생산하기가 용이하지않고, 특히 전해수는 미분해 식염 농도가 상당(600~1200ppm)하여 세정 대상물, 예를 들어 내시경이나 의료 용구, 금속 제품 등이 부식하여 그 용도가 제한되고 있다.Conventional flow-type electrolytic water production apparatus is not easy to produce a large amount of electrolytic water having a predetermined pH under the electrolytic conditions of low voltage, low current, in particular, the electrolytic water has a considerable undecomposed salt concentration (600 ~ 1200ppm) to be cleaned, eg For example, endoscopes, medical equipment, and metal products are corroded, and their use is limited.
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WO 2005/105678호에 개시된 전해장치는, 외측 전극과 격막 지지체와 내측 전극이 동축상에 배치되므로, 전극용적을 크게 하고자 할 경우 전해조의 크기가 비례하여 커져야 하고 따라서 전해질의 공급용적이 필요 이상 커져야 하며 전체적인 장치의 사이즈가 비대해지는 단점이 있다.In the electrolytic apparatus disclosed in WO 2005/105678, since the outer electrode, the diaphragm support, and the inner electrode are disposed coaxially, in order to increase the electrode volume, the size of the electrolytic cell must be increased proportionally, and thus the supply volume of the electrolyte must be larger than necessary. And there is a disadvantage that the size of the overall device is enlarged.
본 발명은 상기와 같은 문제점을 해결하기 위해 안출된 것으로, 강 알칼리수의 생산에 전해질로 탄산칼륨 수용액을 사용하여 미분해 식염농도를 전혀 포함하지 않는 pH 13.0 이상의 강력한 세정제를 제조할 수 있고, 미분해 식염 농도가 100ppm(0.1%)이하의 강산성 전해수(pH 2.3 이하)를 생성할 수 있으며, 저전압 저전류 대용량 전해수 제조장치를 구현하여 에너지 절감은 물론, 전해수 생산 비용을 저렴화하여 친환경 세정제 및 의료용 무자극성 소독제, 광범위한 살균제를 생산할 수 있는 전해수 제조장치를 제공하는데 목적이 있다.The present invention has been made to solve the above problems, using a potassium carbonate aqueous solution as an electrolyte in the production of strong alkaline water can be prepared a powerful detergent of pH 13.0 or more that does not contain any undecomposed salt concentration, undecomposed It can produce strong acid electrolytic water (pH 2.3 or less) with a salt concentration of 100ppm (0.1% or less), and implements a low-voltage low-current large-capacity electrolytic water manufacturing device to save energy and lower the cost of producing electrolytic water, making it an eco-friendly cleaner and medical non-irritant. An object of the present invention is to provide an electrolytic water production apparatus capable of producing a disinfectant and a wide range of disinfectants.
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본 발명에 의한 전해수 생성장치는 유수식 유격막 전해수 생성장치로서,
중공의 4각형 한 면에 전해질과 전해수 생성 수로를 분리하는 이온 격막이 부착된 다수(2~6조)의 이온 격막 지지체(30,31)가 설치되고, 상기 이온 격막 지지체(30,31) 내, 외측에 서로 다른 극성(+,-)의 전극 판이 다단계(4~12단)로 설치되는 전해조와;
상기 이온 격막 지지체(30,31)가 부착된 면에 장착되며, 상하로 구분되어 하부로는 적정 농도의 전해질 공급로가, 상부에는 농도가 약해진 전해질의 배수로가 구비되는 전해질 공급 장치와;
외측 전극 판과 상기 이온 격막을 3㎜ 이격시킴으로써 마련된 생성수 수로에 물을 공급하도록 구성되며, 유량 조절 밸브를 갖춘 물공급 장치와;
전해수의 토출구 관로에 플로우스위치(FLOW SWITCH)를 설치하여 전해조 내부에 물의 공급 여부를 감지함으로써, 시스템의 비정상 가동을 방지하는 장치;
를 구비한다.Electrolyzed water generating device according to the present invention is a flow type diaphragm electrolyzed water generating device,
A plurality of (2 to 6 sets) ion diaphragm supports 30 and 31 are provided on one side of the hollow quadrilateral with an ion diaphragm separating the electrolyte and the electrolytic water generating channel, and inside the ion diaphragm supports 30 and 31. An electrolytic cell in which electrode plates of different polarities (+,-) are installed in multiple stages (4-12 stages);
An electrolyte supply apparatus mounted on a surface to which the ion diaphragm supports 30 and 31 are attached, and divided into upper and lower portions, and having an electrolyte supply path having an appropriate concentration at a lower portion thereof, and a drain passage of an electrolyte whose concentration is weakened at an upper portion thereof;
A water supply device configured to supply water to a product water channel provided by separating the outer electrode plate and the ion diaphragm 3 mm, the water supply device having a flow control valve;
An apparatus for preventing abnormal operation of the system by installing a flow switch on a discharge pipe of the electrolyzed water and detecting whether water is supplied into the electrolyzer;
It is provided.
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본 발명에 의한 전해수 생성장치는, 간단하면서도 고효율의 전기 분해가 가능하여 장비 제작의 저비용을 실현할 수 있고, 저전압 저전류의 에너지 소비량을 최소화하여 고기능성 다목적 세정제, 농업 축산 분야의 무자극성 살균 소독제, 특정 유해 물질(TCE, CFC, HCFC류)로 지정된 산업용 세정제를 대체할 수 있는 양질의 친환경 전해수를 저렴하게 공급할 수 있다는 효과가 있다.The electrolytic water generating device according to the present invention is simple and highly efficient electrolysis can realize a low cost of equipment production, high-functional multi-purpose cleaner by minimizing the energy consumption of low voltage, low current, non-irritating disinfectant in the field of agricultural livestock, It has the effect of being able to supply high quality eco-friendly electrolytic water at low cost, which can replace the industrial cleaner designated as a specific harmful substance (TCE, CFC, HCFC).
제 1 실시 내용 - 전해조의 구성
도 1은 본 발명에 의한 전해수 생성장치의 분해사시도이다.
본 발명에 의한 전해수 생성장치는 도 1에 도시된 바와 같이, 절연체인 PVC로 구성된 외부 케이스(10)와, 상기 외부 케이스(10) 내부 중 원수 공급 측과 전해수 배수 측 및 중심부에 설치되는 외측 전극 판(20,21,22)과, 측방향 4면 중 3면에 이온 격막이 부착되고 이온 격막이 미부착된 나머지 1면에는 전해질 공급 및 배수 구멍이 마련되어 상기 외부 케이스(10) 내벽에 설치되는 이온 격막 지지체(30,31)와, 상기 이온 격막 지지체(30,31) 내부에 설치되는 내측 전극(40,41,42,43)을 포함하여 구성된다.
상기 격막 지지체(30,31)의 내외부가 밀폐되도록, 케이스 커버(50)를 상기 격막 지지체(30,31) 상측에 가스켓을 삽입하여 조립한다. 1st implementation contents-composition of electrolyzer
1 is an exploded perspective view of an electrolytic water generating device according to the present invention.
As shown in FIG. 1, the electrolytic water generating device according to the present invention includes an
The
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제 2 실시 내용 - 전해수 생성장치의 시스템 구성
도 2는 본 발명에 의한 전해수 생성장치의 시스템 및 작동 개념도이다 Second Embodiment-System Configuration of Electrolyzed Water Generator
2 is a conceptual diagram of the system and operation of the electrolytic water generating device according to the present invention.
통상적인 전해수(pH 10.5~12.0, ORP -700~-900mV인 알칼리수 및 pH 2.5~3.1, ORP 1100mV 이상인 산성수)의 생성에는, 도2에 도시된 바와 같이 생성수 공급관 (28)에 원수를 직접 공급하고, 유량 조절 밸브(23)를 설치하여 원수의 유입량을 가감함으로써 전해조 내에서의 전해 시간과 전해수의 생산량을 조절하며(전해수 배수관(29)으로 생성되는 전해수의 pH농도는 생산량이 적을수록 높아지게 된다), 전해조 배수관 연결부에는 플로우 스위치(유량감지 센서,37)를 설치하여 전해조 내부에 원수의 공급 여부를 감지하여 시스템의 비정상 가동을 방지한다. 전해질 공급 장치 (33)는 전해질 공급관(33b)을 통해 이온 격막 지지체(30,31)와 연결된 전해질 급/배수기(34) 하부에 알칼리수 생성시에는 탄산칼륨 수용액을 산성수 생성시에는 식염수를 공급하여 이온 격막 지지체(30,31) 내부에 전해질을 공급한다.For the production of conventional electrolytic water (pH 10.5-12.0, alkaline water at ORP -700 to -900 mV and acidic water at pH 2.5-3.1, ORP 1100 mV or more), as shown in FIG. The raw water is directly supplied to the production water supply pipe 28, and the flow rate control valve 23 is installed to adjust the electrolysis time and the production amount of the electrolytic water in the electrolytic cell by adjusting the inflow of the raw water (generated by the electrolytic water drain pipe 29 The pH concentration of the electrolyzed water becomes higher as the production volume decreases, and a flow switch (flow sensor 37) is installed at the connection of the electrolyzer drain pipe to detect the supply of raw water into the electrolyzer to prevent abnormal operation of the system. The electrolyte supply device 33 supplies an aqueous potassium carbonate solution during the generation of alkaline water to the lower portion of the electrolyte supply / drainer 34 connected to the ion diaphragm supports 30 and 31 through the electrolyte supply pipe 33b, and saline solution when the acidic water is generated. The electrolyte is supplied into the ion diaphragm supports 30 and 31.
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이온 격막 지지체 내부에 전해질 충전을 완료하고 플로우 스위치를 통해 원수의 공급이 확인되면, 전원 공급 장치 및 콘트롤 시스템(70)으로부터 내측 전극(40,41,42,43) 및 외측 전극(20,21,22)에 각각 양극과 음극의 전원을 공급함으로써 전해수를 생성한다. When the electrolyte filling is completed inside the ion diaphragm support and the supply of raw water is confirmed through the flow switch, the
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더 나아가 산업상 이용가능성이 있는 강 알칼리수를 생성하기 위해서는, 생성수 공급관(28)과 전해수 배수관(29) 사이에 생성수의 잔량 및 기준수 투입량, 원수 공급량을 일정하게 관리할 수 있는 3세트의 수위 레벨 센서(63,64,65)를 구비한 생성 탱크(60)를 설치하여, 특수하게 고안된 다단계의 전해장치를 통해 생성된 고농도(pH 13.5 이상, ORP -985mV 이하)의 전해수를 촉매용 기준수로 사용하여 생성코자 하는 전해수 농도에 따라 적당량(5~10%)을 생성 탱크(60)에 투입하여 순환 펌프(24), 타이머를 설치하여 설정된 농도의 전해수를 자동으로 반복 생성한다(도 2 참조).Furthermore, in order to generate industrially available strong alkaline water, three sets of constant water can be managed between the production water supply pipe 28 and the electrolytic water drainage pipe 29, the standard water input amount, and the raw water supply amount. A production tank 60 with
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본 전해수 생성장치에서 생산된 pH 13.0이상, ORP -930mV 이하의 강알칼리 전해수는 화학 성분이 포함되지 않은 인체에 무해한 무자극성 친환경 세정제로서 특정 유해 물질(TCE, CFC, HCFC류)로 지정된 산업용 세정제를 대체 할 수 있으며, 수용성 절삭유를 대체 할 경우 방청 효과가 있어 피 세정물의 부식을 방지하여 추가 방청 작업을 하지 않아도 되며, 전해질로 탄산칼륨을 사용하므로 종래의 전해수에 남아있는 미분해 식염이 전혀 없어 염해 걱정 없이 산성 토양의 회복 및 식물의 성장 발육에 도움을 준다.
pH 2.0 이하, ORP +1150mV 이상, 유효 염소농도 30~60ppm의 강산성수는 식약청 고시 식품 첨가물인 차아염소산수로서 식기 및 식자재의 살균 소독제로 사용되며(도마, 부엌칼등의 조리 기구나 식기류의 제균세정), O157균이나 살모네라균(SE)등의 식중독균으로부터 MRSA 등의 내성균까지 제균하며 소독약과 같은 잔류성이 없어서 손이 거칠어지지 않고 인체에 해가 없는 환경에도 친화적이며 염소계 소독제, 알코올 등의 대체물로 사용될 수 있다. Strong alkaline electrolytic water with pH above 13.0 and below ORP -930mV produced by this electrolytic water generator is a non-irritating eco-friendly cleaner that is harmless to human body and replaces industrial cleaners designated as specific hazardous substances (TCE, CFC, HCFC). If the water-soluble cutting oil is replaced, it has an rust prevention effect, which prevents corrosion of the cleansing material and does not require additional rust prevention work, and since potassium carbonate is used as electrolyte, there is no unresolved salt remaining in the conventional electrolytic water, so there is no worry about salt. Without acidic soil recovery and plant growth development.
Strong acidic water with pH below 2.0, ORP + 1150mV and effective chlorine concentration of 30 ~ 60ppm is hypochlorite water, a food additive admitted by KFDA.It is used as a disinfectant for tableware and food materials. It sterilizes from food poisoning bacteria such as O157, Salmonella (SE) to resistant bacteria such as MRSA, and has no residue such as disinfectant, so it is friendly to the environment without rough hands and harmless to the human body. Can be.
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도 1)은 본 발명의 실시 형태의 전해수 제조장치의 전해조 구성을 나타내고 있는 분해 개념도 이다1) is an exploded conceptual diagram showing the electrolytic cell configuration of the electrolytic water production apparatus according to the embodiment of the present invention.
도 2)는 본 발명의 실시 형태의 기준수 투입, 순환식 전해수 생성장치의 시스템 및 작동 개념도 이다2) is a system and operation conceptual diagram of the reference water input, circulating electrolytic water generating device of the embodiment of the present invention.
도 3)은 이온 격막 지지체 2조, 4단 전해 전극 전해조의 내부 구성 개념도 이다3) is a schematic diagram illustrating the internal structure of two sets of ion diaphragm supports and a four-stage electrolytic electrode electrolyzer.
도 4)는 이온 격막 지지체 4조, 8단 전해 전극 전해조의 내부 구성 개념도 이다4) is a conceptual diagram of the internal configuration of four pairs of ion diaphragm supports and an eight-stage electrolytic electrode electrolyzer.
도 5)는 이온 격막 지지체 3조, 6단 전해 전극 전해조의 내부 구성 개념도 이다FIG. 5 is a conceptual diagram illustrating the internal structure of three sets of ion diaphragm supports and a six-stage electrolytic electrode electrolyzer. FIG.
도 6)은 이온 격막 지지체 6조, 12단 전해 전극 전해조의 내부 구성 개념도 이다6) is a schematic diagram of the internal structure of the 6-thickness diaphragm support and the 12-stage electrolytic electrode electrolyzer.
도면 부호의 설명Explanation of Reference Numbers
*10,13. 전해조 외부 PVC CASE* 10,13. Electrolyzer Outer PVC CASE
20,21,21a,22. 외측 전극20,21,21a, 22. Outer electrode
30,31,32. 격막이 부착된 격막 지지체30,31,32. Diaphragm Support with Diaphragm
40,41,42,43,44,45. 내측 전극40,41,42,43,44,45. Inner electrode
50. 전해조 외부 CASE COVER50. Outer case cover
70. SMPC(POWER SUPPLY)를 장착한 콘트롤시스템 장치70. Control system device equipped with SMPC (POWER SUPPLY)
71,72. 전원 CABLE71,72. Power CABLE
23. 촉매용 기준수 공급 펌프23. Reference Water Supply Pump for Catalyst
24. 생성수(원수) 순환 펌프24. Generated water (raw water) circulation pump
25. 생산 완료된 전해수 토출 펌프25. Completed electrolytic water discharge pump
26. 원수 공급용 전자(SOLENOID) 밸브26. Solenoid Valve for Raw Water Supply
27. 생성수(원수) 공급 유량 조절 밸브27. Produced water (raw water) supply flow control valve
28. 생성수(원수) 공급관28. Produced water (raw water) supply pipe
29. 전해수 배수관29. Electrolyzed water drain pipe
33. 전해질 공급 장치33. Electrolyte Supply Unit
33a. 전해질 배수관33a. Electrolyte drain pipe
33b. 전해질 공급관33b. Electrolyte supply pipe
34. 전해질 급/배수기34. Electrolyte Feed / Drainer
35. 전해질 공급 펌프35. Electrolyte Feed Pump
36. 유량 제어 밸브36. Flow Control Valve
60. 순환식 생성 탱크60. Circulating production tank
61.62. 촉매용 기준수 저장 탱크 및 공급관61.62. Reference Water Storage Tanks and Supply Lines for Catalysts
63,64,65. 수위 레벨 감지 센서63,64,65. Water level sensor
Claims (10)
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WO2016153145A1 (en) * | 2015-03-26 | 2016-09-29 | 주식회사 블루텍 | Device for preparing sterilized water for livestock |
KR102062810B1 (en) | 2019-02-18 | 2020-02-03 | 주식회사 타운에스앤지 | Cooling-type barrel structure diaphragm electro-analysised water producing device |
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KR20050020298A (en) * | 2003-08-21 | 2005-03-04 | 바이오닉스(주) | making apparatus of electrolysis water |
JP2007252963A (en) * | 2004-04-30 | 2007-10-04 | Jws Tecnica Kk | Electrolytic water producer |
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KR20050020298A (en) * | 2003-08-21 | 2005-03-04 | 바이오닉스(주) | making apparatus of electrolysis water |
JP2007252963A (en) * | 2004-04-30 | 2007-10-04 | Jws Tecnica Kk | Electrolytic water producer |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2016153145A1 (en) * | 2015-03-26 | 2016-09-29 | 주식회사 블루텍 | Device for preparing sterilized water for livestock |
KR102062810B1 (en) | 2019-02-18 | 2020-02-03 | 주식회사 타운에스앤지 | Cooling-type barrel structure diaphragm electro-analysised water producing device |
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