KR20160140094A - Composition for inner face printing of balloon - Google Patents

Composition for inner face printing of balloon Download PDF

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Publication number
KR20160140094A
KR20160140094A KR1020150076236A KR20150076236A KR20160140094A KR 20160140094 A KR20160140094 A KR 20160140094A KR 1020150076236 A KR1020150076236 A KR 1020150076236A KR 20150076236 A KR20150076236 A KR 20150076236A KR 20160140094 A KR20160140094 A KR 20160140094A
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KR
South Korea
Prior art keywords
balloon
vinyl
composition
printing
weight
Prior art date
Application number
KR1020150076236A
Other languages
Korean (ko)
Inventor
종열 서
Original Assignee
종열 서
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 종열 서 filed Critical 종열 서
Priority to KR1020150076236A priority Critical patent/KR20160140094A/en
Publication of KR20160140094A publication Critical patent/KR20160140094A/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toys (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention relates to a composition for printing the inside of a balloon. More particularly, the composition comprises a solvent, a pigment, and a vinyl-based copolymer binder. The composition for printing the inside of a balloon is capable of embodying various colors, and exhibits excellent adhesion properties and tightness with the inside of a balloon, thereby providing a printing layer which does not generate delamination.

Description

TECHNICAL FIELD [0001] The present invention relates to a composition for inner printing of a balloon,

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition for printing on an inner surface of a balloon, and more particularly, to a composition for printing on an inner surface of a balloon which not only can realize various colors but also exhibits excellent adhesiveness and adhesion with the inner surface of the balloon, To a printing composition.

Balloons are inflated with gases such as helium, hydrogen, and nitrous oxide in a bag made of paper, vinyl, and rubber. They are mostly played with toys like children, It is also used as a means of transportation by using features.

In the case of a vinyl balloon, in the case of a vinyl balloon, various printed layers are formed on the outer surfaces of the front and back balloon sheets according to the design, and then the edges of the balloon sheets on both sides are bonded together.

When the balloon touches the mouth of the baby or infant as the printed layer is formed on the outer surface of the vinyl balloon, the harmful components contained in the print layer can be introduced into the body through the mouth, The printed layer is easily damaged and the commerciality of the balloon is deteriorated.

In addition, conventionally, a composition applied to a printed layer of a vinyl balloon has a problem that adhesion and adhesion to an inflatable balloon made of a synthetic resin such as vinyl are low, so that the printed layer easily peels off during use.

Korean Patent Registration No. 10-1325123 (Oct. 29, 2013). Korean Patent Publication No. 10-2014-0021993 (Feb.

It is an object of the present invention to provide a composition for printing on an inner surface of a balloon that not only can realize various colors but also exhibits excellent adhesion and adhesion with the inner surface of a balloon, thereby providing a printing layer free from peeling.

An object of the present invention is attained by providing a composition for printing on an inner surface of a balloon, which is characterized by comprising a solvent, a pigment, and a vinyl-based copolymer binder.

According to a preferred aspect of the present invention, the composition for printing on the inner surface of the balloon is composed of 100 parts by weight of solvent, 30 to 35 parts by weight of pigment, and 40 to 50 parts by weight of a vinyl copolymer binder.

According to a further preferred feature of the present invention, the solvent is composed of ethyl acetate and methyl ethyl ketone.

According to a further preferred feature of the present invention, the solvent is a mixture of ethyl acetate and methyl ethyl ketone in a weight ratio of 1: 1.

According to a further preferred feature of the present invention, the vinyl-based copolymer binder is made of a copolymer of vinyl acetic acid, vinyl alcohol and vinyl chloride.

The composition for inner surface printing of the balloon according to the present invention exhibits an excellent effect of providing a printing layer which can realize various colors and exhibits excellent adhesion and adhesion with the inner surface of the balloon and does not cause peeling.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a perspective view showing a balloon to which a printing layer made of a composition for printing an inner surface of a balloon according to the present invention is applied. FIG.

Hereinafter, preferred embodiments of the present invention and physical properties of the respective components will be described in detail with reference to the accompanying drawings. However, the present invention is not limited thereto, And this does not mean that the technical idea and scope of the present invention are limited.

The composition for inner surface printing of balloons according to the present invention is composed of a solvent, a pigment and a vinyl copolymer binder, and is preferably composed of 100 parts by weight of a solvent, 30 to 35 parts by weight of a pigment and 40 to 50 parts by weight of a vinyl copolymer binder.

An inner printed balloon in which a printed layer 20 is formed on the inner surface includes a balloon sheet member 10, a printing layer 20 formed on the inner surface of the balloon sheet member 10, The balloon sheet member 10 serves to form the overall outer shape of the balloon printed on the inner surface and includes a front sheet 10a and a rear sheet 10b Is divided.

The balloon sheet member 10 divided into the front sheet 10a and the back sheet 10b may be formed in various designs such as a character or animal shape and may be formed on the inner surface of the balloon sheet member 10, It is preferable to use a nylon resin having excellent transparency so as not to deteriorate the visibility of the photoconductor 20.

Accordingly, the composition for inner surface printing of the balloon according to the present invention is a material constituting the printing layer 20 formed on the inner surface of the balloon sheet member 10. In the related art, the printing layer 20 is formed on the outer surface of the balloon sheet member, , When the infant takes the balloon to the mouth, the problem that the harmful component constituting the print layer 20 can flow into the body can be solved, and the print layer 20 can be prevented from being damaged by the external force.

The solvent serves to uniformly mix the pigment and the vinyl-based copolymer binder constituting the composition for printing on the inner surface of the balloon according to the present invention. The solvent is composed of ethyl acetate and methyl ethyl ketone, and ethyl acetate and methyl ethyl ketone are contained in 1 : 1 part by weight.

The ethyl acetate has the formula CH 3 COOC 2 H 5 , and has a molecular weight of 88.11, a melting point of -83.67 ° C, a boiling point of 77.15 ° C and a specific gravity of 0.9005.

In nature, it is present in fruits such as pineapples and acts as a component of its aroma. It is a colorless liquid and has good compatibility with almost all organic solvents such as ethanol, ether and benzene.

The methyl ethyl ketone has the formula CH 3 COC 2 H 5 , the molecular weight is 72.11, the boiling point is 79.6 ° C, the freezing point is -86 ° C, and the specific gravity is 0.805.

At room temperature, it can be mixed with about four times the amount of water, but when it is high, the solubility in water is lowered and it is well mixed with organic solvents such as ether, benzene and ethanol.

The solvent composed of 1: 1 parts by weight of ethyl acetate and methyl ethyl ketone exhibiting excellent physical properties exhibits excellent mixing properties with respect to the pigment and the vinyl-based copolymer binder. Thus, the pigment and the vinyl- And serves to provide a balloon-like inner surface printing composition which is uniformly mixed with the copolymer binder component and exhibits uniform physical properties.

The pigment is contained in an amount of 30 to 35 parts by weight, and serves to impart various colors to the composition for printing an inner surface of a balloon according to the present invention. In the present invention, both an inorganic pigment and an organic pigment can be used. It is preferable to use a pigment.

The inorganic pigment is a pigment in which a coloring component is an inorganic substance and has high hiding power and high heat resistance and light fastness, so that even when the balloon is exposed to ultraviolet rays for a long period of time, damage to the print layer 20 is suppressed.

When the content of the pigment is less than 30 parts by weight, the color clarity of the printed layer 20 is lowered. When the content of the pigment exceeds 35 parts by weight, the content of the solvent and the vinyl copolymer binder is relatively decreased, The homogeneity and adhesiveness of the printing composition may deteriorate and the physical properties of the printing layer 20 formed on the inner surface of the balloon may be deteriorated.

At this time, the inorganic pigment may be at least one selected from the group consisting of titanium dioxide, mercury sulfide, copper sulfate, copper carbonate, copper hydroxide, arsenic sulfide, lead oxide, lead carbonate and zinc oxide.

The vinyl-based copolymer binder is contained in an amount of 40 to 50 parts by weight, binds the pigment component, and provides adhesion to the balloon inner-printing composition according to the present invention. The content of the vinyl- If the content of the vinyl copolymer binder is less than 40 parts by weight, the adhesion of the composition for inner surface printing of the balloon according to the present invention may deteriorate and peel off from the inner surface of the balloon. If the content of the vinyl copolymer binder exceeds 50 parts by weight, The viscosity of the composition for inner printing of the balloon is excessively increased and the efficiency of the process of applying the composition to the surface of the balloon may be decreased.

At this time, it is preferable that the vinyl-based copolymer binder is composed of a copolymer of vinyl acetic acid, vinyl alcohol and vinyl chloride. The vinyl-based copolymer binder composed of the above-mentioned components has excellent compatibility with ethylene vinyl acetate or polyurethane resin And exhibits excellent mixing properties with the pigment to provide a printing layer 20 having excellent physical properties and excellent adhesive properties.

The composition for inner surface printing of the balloon comprising the above components was prepared by charging 50 parts by weight of ethyl acetate into a reactor equipped with a stirrer, adding 40 to 50 wt% of a copolymer of vinyl acetate, vinyl alcohol and vinyl chloride to a reactor charged with ethyl acetate 50 parts by weight of methyl ethyl ketone and 30 to 35 parts by weight of a pigment were further mixed with stirring at a speed of 30 to 50 rpm using a stirrer provided in the reactor and the mixture was stirred at a temperature of 60 to 70 캜 at a speed of 100 to 150 rpm ≪ / RTI > for 30 to 90 minutes.

The inner surface printing composition of the balloon manufactured through the above process is printed on the inner surface of the balloon sheet member with a thickness of 0.1 to 1.5 탆 through the gravure printing method. After printing on the inner surface of the balloon sheet member, the drying process is performed for 20 to 30 hours And the solvent component contained in the composition for printing on the inner surface of the balloon is removed through the above drying process.

Accordingly, the composition for inner surface printing of the balloon manufactured through the above-described components and processes exhibits various colors, and exhibits excellent adhesion and adhesion with the inner surface of the balloon, thereby providing a printing layer 20 free from peeling do.

10; Balloon sheet member
10a; Front sheet
10b; Rear Sheet
20; Printing layer
30; Coating layer

Claims (5)

A solvent, a pigment, and a vinyl-based copolymer binder.
The method according to claim 1,
Wherein the composition for inner surface printing of the balloon is composed of 100 parts by weight of a solvent, 30 to 35 parts by weight of a pigment, and 40 to 50 parts by weight of a vinyl copolymer binder.
The method according to claim 1 or 2,
Wherein the solvent is ethyl acetate and methyl ethyl ketone.
The method of claim 3,
Wherein the solvent is a mixture of ethyl acetate and methyl ethyl ketone in a weight ratio of 1: 1.
The method according to claim 1 or 2,
Wherein the vinyl-based copolymer binder is a copolymer of vinyl acetic acid, vinyl alcohol and vinyl chloride.

KR1020150076236A 2015-05-29 2015-05-29 Composition for inner face printing of balloon KR20160140094A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020150076236A KR20160140094A (en) 2015-05-29 2015-05-29 Composition for inner face printing of balloon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020150076236A KR20160140094A (en) 2015-05-29 2015-05-29 Composition for inner face printing of balloon

Publications (1)

Publication Number Publication Date
KR20160140094A true KR20160140094A (en) 2016-12-07

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KR1020150076236A KR20160140094A (en) 2015-05-29 2015-05-29 Composition for inner face printing of balloon

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101325123B1 (en) 2010-09-10 2013-11-06 종열 서 Inner face printing balloon
KR20140021993A (en) 2010-12-21 2014-02-21 후지필름 이미징 컬러런츠 아이엔씨. Ink & printing process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101325123B1 (en) 2010-09-10 2013-11-06 종열 서 Inner face printing balloon
KR20140021993A (en) 2010-12-21 2014-02-21 후지필름 이미징 컬러런츠 아이엔씨. Ink & printing process

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