KR20160116112A - Copper-carbon composite powder and manufacturing method the same - Google Patents
Copper-carbon composite powder and manufacturing method the same Download PDFInfo
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- KR20160116112A KR20160116112A KR1020150041732A KR20150041732A KR20160116112A KR 20160116112 A KR20160116112 A KR 20160116112A KR 1020150041732 A KR1020150041732 A KR 1020150041732A KR 20150041732 A KR20150041732 A KR 20150041732A KR 20160116112 A KR20160116112 A KR 20160116112A
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Abstract
Description
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a copper (Cu) -carbon composite material, and more particularly, to a copper-carbon composite material that can be used as a heat dissipation material and a method of manufacturing the same.
2. Description of the Related Art Recently, electronic devices used in portable mobile devices, notebook computers, personal digital assistants (PDAs), electronic organizers, liquid crystal displays (LCDs), organic light emitting devices (OLEDs) and plasma display devices Together, they are being studied to speed up the signal transmission between electronic components.
As the microcircuitry of the printed circuit board (PCB) progresses, the damage due to the heat dissipation between adjacent circuits is increasing.
On the other hand, metals are materials having excellent heat and electric conductivity. Also, because of its ductility, it is easy to process compared to other materials and it is applied versatile throughout the industry.
In recent years, studies have been actively conducted to manufacture metal nano powder having a wide range of applications in industrial fields by incorporating nano technology into metal. In other words, in the study of metal nano-powders, besides the properties possessed by the metal itself, new mechanical and physical characteristics are attracting attention as the particle size of the metal becomes finer. Especially, surface effect, volume effect, The new properties caused by the action are expected to be applied to high temperature structural materials, tool materials, electromagnet materials, filters and sensors as advanced materials.
In such metal nano powders, studies have been made to improve the mechanical and electrical properties of existing metal powders by adding new functions while maintaining the properties of conventional metal powders. Particularly, There is a growing interest in composite powder materials that improve electrical properties.
The present invention provides a copper-carbon composite powder for coating a copper (Cu) particle with a carbon-based material to prepare a composite powder to replace the copper-based alloy material, and a method for producing the same.
In addition, the present invention provides a copper-carbon composite powder having improved heat dissipation properties and a method for producing the same.
The first embodiment of the present invention relates to a method of manufacturing a carbon nanotube, comprising: a dispersion step of dispersing a carbonaceous material selected from graphene oxide powder, mixed powder of graphene oxide and nano carbon into a solvent; Mixing the copper powder with a solvent in which the carbonaceous material is dispersed; A drying step of drying a solvent in which the copper powder is mixed and dispersed; A reducing step of reducing the oxide mixed with the copper powder through a heat treatment in a hydrogen atmosphere; And a sintering step of sintering the reduced carbon-based material and copper through a spark plasma. The present invention also provides a method for producing a copper-carbon composite material.
In the first embodiment, ultrasonic treatment can be performed in the dispersion step for 30 minutes to 90 minutes.
In the first embodiment, in the dispersing step, the solvent may include any one of ethanol, methanol, toluene, diethylene glycol, enemethylpyrrolidone, dimethylacetamide, dimethylformamide and methyl ethyl ketone.
In the first embodiment, in the mixing step, ultrasonic treatment may be performed at a temperature of 50 to 70 ° C for 10 to 14 hours.
In the first embodiment, the drying may be performed in a vacuum dry oven at a temperature of 60 to 90 ° C. for 4 to 6 hours.
In the first embodiment, the reducing step may be performed at a temperature of 500 to 900 DEG C for 4 to 6 hours.
In the first embodiment, in the sintering step, the sintering process can be performed by applying a pressure of 50 to 150 MPa in a temperature range of 500 ° C to 900 ° C.
The first embodiment may further include a ball milling step for increasing the degree of interface adhesion between the reducing step and the sintering step.
A second embodiment of the present invention is a method of manufacturing a carbon nanotube, comprising: a dispersion step of dispersing a carbonaceous material selected from the group consisting of a reduced-graphene oxide powder, a mixed powder of reduced-graphene oxide and nano-carbon into a solvent; Mixing the copper powder with a solvent in which the carbonaceous material is dispersed; A drying step of drying a solvent in which the copper powder is mixed and dispersed; And a sintering step of sintering the carbon-based material and copper through a spark plasma. The present invention also provides a method for producing a copper-carbon composite material.
In the second embodiment, ultrasonic treatment can be performed in the dispersion step for 30 minutes to 90 minutes.
In the second embodiment, in the dispersing step, the solvent may include any one of ethanol, methanol, toluene, diethylene glycol, enemethylpyrrolidone, dimethylacetamide, dimethylformamide, and methyl ethyl ketone.
In the second embodiment, in the mixing step, ultrasonic treatment may be performed at a temperature of 50 to 70 ° C for 10 to 14 hours.
In the second embodiment, the drying may be performed in a vacuum dry oven at a temperature of 60 to 90 ° C. for 4 to 6 hours.
In the second embodiment, in the sintering step, a sintering process may be performed by applying a pressure of 50 to 150 MPa in a temperature range of 500 to 900 ° C.
In the second embodiment, it is possible to further include a ball milling step for increasing the interface adhesion before the sintering step.
In a third embodiment of the present invention, there is provided a method of manufacturing a carbon nanotube, comprising: a dispersion step of dispersing a carbonaceous material selected from graphene oxide powder, mixed powder of graphene oxide and nanocarbon into a solvent; A mixing step of mixing a copper salt with the carbon-based material and ionizing the copper to mix the carbon-based material with the copper ion; A centrifugal step of centrifugally separating the carbon-based material and the copper to neutralize the acidic mixture; Drying the centrifuged carbonaceous material and copper; A reducing step of reducing the carbonaceous material and copper through heat treatment in a hydrogen atmosphere; And a sintering step of sintering the reduced carbon-based material and copper through a spark plasma. The present invention also provides a method for producing a copper-carbon composite material.
In the third embodiment, ultrasonic treatment can be performed in the dispersion step for 30 minutes to 90 minutes.
In the third embodiment, the mixing step may be conducted at a temperature of 80 to 100 ° C for 1 to 3 hours.
In the third embodiment, the drying step may be performed in a vacuum dry oven at a temperature of 60 to 90 ° C. for 4 to 6 hours.
In the third embodiment, the reducing step may be performed at a temperature of 500 to 900 DEG C for 4 to 6 hours.
In the third embodiment, in the sintering step, the sintering process can be performed by applying a pressure of 50 to 150 MPa in a temperature range of 500 to 900 ° C.
The third embodiment may further include a ball milling step for increasing the degree of interfacial adhesion between the reducing step and the sintering step.
In addition, embodiments of the present invention provide a heat-radiating material produced through hot extrusion or hot rolling using a copper-carbon composite material manufactured by any one of the above-described methods.
According to the embodiment of the present invention, the mechanical or electrical characteristics of the base metal can be improved by bonding the carbonaceous material of graphene and / or nano carbon with the metal particles of the base metal.
It should be understood that the effects of the present invention are not limited to the above effects and include all effects that can be deduced from the detailed description of the present invention or the configuration of the invention described in the claims.
FIG. 1 is a flowchart illustrating a physical manufacturing method of a copper-carbon composite material according to a first embodiment of the present invention.
2 is a Scanning Electron Microscope (SEM) image for explaining a copper-carbon composite material produced by the physical method of FIG.
FIG. 3 is a flowchart illustrating a physical manufacturing method of a copper-carbon composite material according to a second embodiment of the present invention.
4 is a Scanning Electron Microscope (SEM) image for explaining a copper-carbon composite material produced by the chemical method of FIG.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described with reference to the accompanying drawings. The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. In order to clearly illustrate the present invention, parts not related to the description are omitted, and similar parts are denoted by like reference characters throughout the specification.
Throughout the specification, when a part is referred to as being "connected" to another part, it includes not only "directly connected" but also "indirectly connected" . Also, when an element is referred to as "comprising ", it means that it can include other elements, not excluding other elements unless specifically stated otherwise.
The term "copper-graphene" composite powder as referred to in the specification means a powder in which copper or an alloy of copper is used as a base metal and graphene is dispersed and dispersed in a matrix metal. The term " base metal " is used to refer to various metals or alloys that function as a base for powders. Therefore, the term "copper-carbon composite material" as used in the specification means a composite material in which a base metal is an alloy of copper or copper, and a carbonaceous material including graphene is dispersed and dispersed in a base metal.
Meanwhile, in the embodiment of the present invention, the carbon-based material may be classified into graphene, reduced graphite and nano-carbon, and the nanocarbon may be carbon nanotube (CNT), carbon nanofiber (CNF) Carbon nanorods, and the like.
For example, the thermal conductivity of nano-carbon and graphene is about 3,000 W / mK or more, which is about 10 times higher than that of copper and aluminum. In addition, since nanocarbon and graphene have not only high thermal conductivity but also high heat emissivity, utilization of thermocouple adhesive / adhesive, coating agent, tape, pad, and composite exhibits excellent heat dissipation characteristics that conventional heat dissipation materials can not exhibit.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
The method for producing a copper-carbon composite material according to the present invention can be roughly divided into two methods, for example, a physical method and a chemical method.
Physical method
1 is a flow chart for explaining a physical manufacturing method of a copper-carbon composite material according to the first embodiment.
Referring to FIG. 1, the physical method for manufacturing the copper-carbon composite material according to the first embodiment includes a dispersion step of dispersing a carbonaceous material in a solvent; A mixing step of mixing the copper powder into the dispersion solution; A drying step of drying a dispersion solution in which copper powder is mixed; A reducing step of reducing the oxide through heat treatment in a hydrogen atmosphere; And a sintering step of sintering the reduced carbon-based material and copper through a spark plasma.
The carbonaceous material may be selected from the group consisting of graphene oxide (GO) powder, reduced graphene oxide (RGO) powder, and mixed powder of reduced-graphene oxide and nano-carbon.
In the dispersion step, any one of graphene oxide (GO) powder, reduced graphene oxide (RGO) powder, and mixed powder of reduced-graphene oxide and nano-carbon is dispersed in a solvent . Graphene oxide can be obtained by separating from the graphite structure through known processes. The graphen oxide can be a single sheet that is oxidized and separated from the carbon multi-layer structure of graphite.
The solvent may include at least one of pure water, ethanol, methanol, toluene, diethylene glycol, ethylmethylpyrrolidone, dimethylacetamide, dimethylformamide, methyl ethyl ketone, A wide variety of known solvents that can be uniformly dispersed can be applied.
According to one embodiment, in the dispersing step, the carbon-based material can be uniformly distributed in the solvent by performing dispersion treatment such as ultrasonic treatment.
In the mixing step, a copper salt is mixed with a solvent in which a carbonaceous material is dispersed. At this time, the amount of the copper salt can be controlled in comparison with the amount of the carbon-based material dispersed in the solvent. That is, the amount of the carbon-based material and the amount of the copper salt may be adjusted in order to prevent the graphene formed by reducing the carbon-based material from being coagulated in the subsequent process.
According to one embodiment, the amount of the carbon-based material and the amount of the copper salt may be adjusted so that the amount of the carbon-based material dispersed in the copper-carbon composite material as the final product has a volume ratio of 1 vol% to 15 vol%. When a carbonaceous material and a copper salt are provided so as to have a volume ratio of the carbonaceous material exceeding 15 vol%, structural deformation of the carbonaceous material may occur due to condensation of the reduced grains.
Examples of the structural modification of the carbonaceous material include structural transformation of graphene into graphite and the like. This is because the carbonaceous material which combines with the metal particles in the produced copper-carbon composite material and improves the mechanical properties of the base metal It interferes with the action of the substance.
According to one embodiment, in the mixing step, ultrasonic treatment or magnetic mixing treatment may be performed so that the carbon-based material and the copper salt can be uniformly mixed and dispersed in a solvent.
In the drying step, the copper-carbon composite material is heat-treated at 50 캜 to 90 캜 and dried. For example, the drying step may be carried out for 4 to 6 hours using a vacuum dry oven.
Before proceeding to the drying step, the obtained copper-carbon composite material may be washed with ethanol or water to remove impurities.
In the reducing step, the carbon-based material and the copper salt are reduced. According to one embodiment, a reducing process is performed in which a reducing agent is supplied to a solvent containing a carbonaceous material and a copper salt, and then the substrate is heat-treated. As the reducing agent, hydrazine (H 2 NH 2 ) may be applied.
On the other hand, the reducing step proceeds when any one of the graphene oxide powder and the mixed powder of graphene oxide and nano carbon is applied to the carbonaceous material, and the reduced-graphene oxide powder, the reduced- When a mixed powder of pin oxide and nano-carbon is applied, it is not necessary to carry out a separate reduction step since it is already in a reduced state.
According to one embodiment, the reducing step can be achieved by heat treating the solution containing graphene oxide, the copper salt and the reducing agent in a hydrogen atmosphere at a temperature of 600 ° C to 900 ° C for 4 to 6 hours. By the reduction step, a copper-carbon composite material in which copper is used as a base metal and a carbonaceous material is bonded to a base metal can be obtained.
Thus, impurities such as oxygen remaining in the copper-carbon composite material can be removed and the crystallinity of the carbon-based material can be improved. The hydrogen heat treatment can be carried out using, for example, a tube-type furnace, and using a gas containing hydrogen as a reaction gas.
In the sintering step, the produced carbon-based composite powder can be sintered to form a bulk material. According to the first embodiment, the sintering step can proceed while applying a high pressure at a temperature of 50% to 80% of the melting point of copper. For example, in the case of a copper-carbon composite material, a sintering process can be performed by applying a pressure of 50 to 150 MPa in a temperature range of 500 to 900 ° C.
According to an embodiment of the present invention, a ball milling step may be further included to uniformly disperse the copper-carbon composite material through the ball mill between the reducing step and the sintering step to increase the degree of interfacial adhesion.
Chemical method
3 is a flowchart illustrating a chemical manufacturing method of a copper-carbon composite material according to the second embodiment.
3, the chemical method for producing the copper-carbon based composite material according to the second embodiment includes a dispersion step of dispersing a carbonaceous material powder in a solvent, a mixing step of mixing a carbonaceous material solution and a copper solution , A centrifugation step of neutralizing the mixed solution in an acid state, a drying step of drying the centrifuged mixed solution, a reduction step of reducing the oxide by heat treatment in a hydrogen atmosphere, a step of sintering the reduced carbon material and copper through a spark plasma And a sintering step of treating the sintered body. And a ball milling step for increasing the interface adhesion between the reducing step and the sintering step.
As the carbonaceous material, any one of graphene oxide (GO) powder and mixed powder of graphene oxide and nano carbon may be applied.
In the dispersing step, the carbon-based material is dispersed in a solvent. For example, since the carbonaceous material itself is difficult to disperse, it is preferable that the carbonaceous material is contained in the form of a dispersion for dispersion in the heat radiation composition liquid.
The solvent may include, for example, pure water (DI water) or ethanol, but not limited thereto, and various kinds of known solvents capable of uniformly dispersing the carbonaceous material can be applied.
Among the carbon-based materials, graphene oxide can be obtained by separating from the graphite structure through a known process. The graphen oxide can be a single sheet that is oxidized and separated from the carbon multi-layer structure of graphite. Graphene oxide can be uniformly distributed in the solvent by performing a dispersion treatment such as ultrasonic treatment.
In the mixing step, a copper salt such as copper sulfate (CuSO 4 ) is mixed with a solvent in which a carbonaceous material is dispersed, and the copper ion is ionized to bond the carbonaceous substance and the copper ion. At this time, the amount of the copper salt can be controlled in comparison with the amount of the carbon-based material dispersed in the solvent. For example, 0.1 to 1 mol of the carbon-based material may be mixed with respect to 1 mol of the copper salt. When the amount of the carbonaceous material exceeds 1 mole per mole of the copper salt, the carbonaceous material formed by reducing the carbonaceous material in the subsequent step may coagulate with each other.
According to one embodiment, the amount of the carbon-based material and the amount of the copper salt may be adjusted so that the amount of the carbon-based material dispersed in the copper-carbon composite material as the final product has a volume ratio of 1 vol% to 15 vol%. When graphene oxide and a copper salt are provided so as to have a volume ratio of the carbonaceous material exceeding 15 vol%, structural transformation of the carbonaceous material may occur due to condensation between the reduced carbonaceous materials.
Examples of the structural modification of the carbonaceous material include structural transformation of graphene into graphite and the like. This is because the carbonaceous material which combines with the metal particles in the produced copper-carbon composite material and improves the mechanical properties of the base metal It interferes with the action of the substance.
According to one embodiment, in the mixing step, ultrasonic treatment or magnetic mixing treatment may be performed so that the carbon-based material and the copper salt can be uniformly mixed and dispersed in a solvent.
At this time, the copper salt in the solvent can be oxidized to form copper oxide. According to one embodiment, an oxidizing agent is provided to a solvent containing a carbon-based material and a copper salt, followed by heat treatment to form a copper oxide. The oxidizing agent can be, for example, sodium hydroxide (NaOH).
As an example, the oxidation process can be achieved by heat-treating a solution containing a carbonaceous material, a copper salt and an oxidizing agent at a temperature range of 40 to 100 占 폚. By the oxidation process, copper oxide is formed from the copper salt. Thereby forming a composite powder in which the carbon-based material and the copper oxide are combined. The term " bonding " is a concept encompassing physical or chemical bonding between a carbon-based material and a copper oxide.
In the centrifugal separation step, the composite powder of the carbon-based material and the copper oxide can be separated from the solvent by using a centrifugal separator. At this time, the composite powder from which the solvent has been removed is washed with water and ethanol so as to obtain a composite powder containing a carbon material and a copper oxide having higher purity, or the composite powder is vacuum- Filtering can proceed.
In the drying step, the copper-carbon composite material is heat-treated at 50 캜 to 90 캜 and dried. For example, the drying step may be carried out for 4 to 6 hours using a vacuum dry oven.
Before proceeding to the drying step, the obtained copper-carbon composite material may be washed with ethanol or water to remove impurities.
In the reducing step, the carbon-based material and the copper salt are reduced. According to one embodiment, a reducing process is performed in which a reducing agent is supplied to a solvent containing a carbonaceous material and a copper salt, and then the substrate is heat-treated. As the reducing agent, hydrazine (H 2 NH 2 ) may be applied.
According to one embodiment, the reducing step can be achieved by heat-treating the solution containing the carbon-based material, the copper salt and the reducing agent in a hydrogen atmosphere at a temperature of 600 ° C to 900 ° C for 4 to 6 hours. By the reduction step, a copper-carbon composite material in which copper is used as a base metal and a carbonaceous material is bonded to metal particles of a base metal can be obtained.
Thus, impurities such as oxygen remaining in the copper-carbon composite material can be removed and the crystallinity of the graphene can be improved. The hydrogen heat treatment can be carried out using, for example, a tube-type furnace, and using a gas containing hydrogen as a reaction gas.
In the sintering step, the produced composite powder can be sintered to form a bulk material. According to the second embodiment, the sintering step can proceed while applying a high pressure at a temperature of 50% to 80% of the melting point of copper. For example, in the case of a copper-carbon composite material, a sintering process can be performed by applying a pressure of 50 to 150 MPa in a temperature range of 500 to 900 ° C.
And a ball milling step for increasing the degree of interfacial adhesion between the copper-carbon composite material by uniformly distributing the copper-carbon composite material through the ball mill between the reducing step and the sintering step.
A copper-carbon composite material in which a carbonaceous material is coated on a copper particle as a base metal can be produced through the same processes as in the above-described embodiments.
The carbon-based material in the copper-carbon composite material can act as a reinforcing agent for improving the mechanical properties of the base metal by bonding with the copper particles as the base metal.
For example, graphene, which is a conductor, can improve the electrical characteristics of a copper-carbon composite material through bonding with a base metal. The graphene is known to have a high mobility on the surface of about 20,000 to 50,000 cm 2 / Vs, and thus the copper-carbon composite material produced by bonding with copper particles can be subjected to a process such as hot extrusion or hot rolling It can be manufactured from a heat-dissipating material.
FIG. 2 and FIG. 4 are scanning electron microscope photographs for explaining the copper-carbon composite material produced by the physical and chemical methods of the present invention, respectively.
The copper-carbon composite material produced by the embodiments of the present invention is formed by dispersing carbon-based materials such as graphene and / or nano-carbon in copper particles as a base metal. That is, the copper-carbon composite material has a structure in which copper particles and a carbonaceous material are mixed.
By bonding with grains of copper, graphene acts as an enhancer to improve mechanical properties such as the tensile strength of the copper base metal.
Nanocarbon is a typical nanomaterial, which is extremely stable physico-chemically and has excellent mechanical, electrical and thermal properties. In one embodiment, the nanocarbon may include carbon nanotubes (CNTs), carbon nanofibers (CNFs), graphite nanofibers, carbon nanorods, and the like.
Graphene is not only very stable and excellent in electrical, mechanical and chemical properties, it is also an excellent conductive material that can transport electrons much faster than silicon and can conduct much more current than copper, The method has been proved through experiments and many studies have been carried out to date.
Such graphene can be formed in a large area and has electrical, mechanical and chemical stability as well as excellent conductivity, and thus is attracting attention as a basic material for electronic circuits.
In addition, since graphenes generally have electrical characteristics that vary depending on the crystal orientation of graphene of a given thickness, the user can express the electrical characteristics in the selected direction and thus design the device easily. Therefore, graphene can be effectively used for carbon-based electric or electromagnetic devices.
Since the graphene has excellent thermal conductivity, the copper-carbon composite material produced in the embodiment of the present invention can be applied to heat-radiating materials such as a heat-radiating sheet and a heat-radiating film.
It will be understood by those skilled in the art that the foregoing description of the present invention is for illustrative purposes only and that those of ordinary skill in the art can readily understand that various changes and modifications may be made without departing from the spirit or essential characteristics of the present invention. will be. It is therefore to be understood that the above-described embodiments are illustrative in all aspects and not restrictive. For example, each component described as a single entity may be distributed and implemented, and components described as being distributed may also be implemented in a combined form.
The scope of the present invention is defined by the appended claims, and all changes or modifications derived from the meaning and scope of the claims and their equivalents should be construed as being included within the scope of the present invention.
Claims (23)
A dispersing step of dispersing a carbonaceous material selected from graphene oxide powder, mixed powder of graphene oxide and nano carbon into a solvent;
Mixing the copper powder with a solvent in which the carbonaceous material is dispersed;
A drying step of drying a solvent in which the copper powder is mixed and dispersed;
A reducing step of reducing the oxide mixed with the copper powder through a heat treatment in a hydrogen atmosphere;
A sintering step of sintering the reduced carbon-based material and copper through a spark plasma;
Based composite material.
And the ultrasonic treatment is performed for 30 minutes to 90 minutes in the dispersion step.
Wherein the solvent includes any one of ethanol, methanol, toluene, diethylene glycol, ethylmethylpyrrolidone, dimethylacetamide, dimethylformamide, and methylethylketone.
Wherein the ultrasonic treatment is performed at a temperature of 50 to 70 ° C for 10 to 14 hours in the mixing step.
Wherein the drying is performed in a vacuum dry oven at a temperature of 60 to 90 ° C for 4 to 6 hours.
Wherein the reducing step is performed at a temperature of 500 to 900 DEG C for 4 to 6 hours.
Wherein the sintering step is carried out by applying a pressure of 50 to 150 MPa in a temperature range of 500 ° C to 900 ° C to proceed the sintering step.
And a ball milling step of increasing the interface adhesion between the reducing step and the sintering step.
A dispersing step of dispersing one of carbonaceous materials selected from the group consisting of redisuded graphene oxide powder and redisuded graphene oxide and nano carbon into a solvent;
Mixing the copper powder with a solvent in which the carbonaceous material is dispersed;
A drying step of drying a solvent in which the copper powder is mixed and dispersed;
A sintering step of sintering the carbon-based material and copper through a spark plasma;
Based composite material.
And the ultrasonic treatment is performed for 30 minutes to 90 minutes in the dispersion step.
Wherein the solvent includes any one of ethanol, methanol, toluene, diethylene glycol, ethylmethylpyrrolidone, dimethylacetamide, dimethylformamide, and methylethylketone.
Wherein the ultrasonic treatment is performed at a temperature of 50 to 70 ° C for 10 to 14 hours in the mixing step.
Wherein the drying is performed in a vacuum dry oven at a temperature of 60 to 90 ° C for 4 to 6 hours.
Wherein the sintering step is carried out by applying a pressure of 50 to 150 MPa in a temperature range of 500 ° C to 900 ° C to proceed the sintering step.
And a ball milling step of increasing the interface adhesion before the sintering step.
A dispersing step of dispersing a carbonaceous material selected from graphene oxide powder, mixed powder of graphene oxide and nano carbon into a solvent;
A mixing step of mixing a copper salt with the carbon-based material and ionizing the copper to mix the carbon-based material with the copper ion;
A centrifugal step of centrifugally separating the carbon-based material and the copper to neutralize the acidic mixture;
Drying the centrifuged carbonaceous material and copper;
A reducing step of reducing the carbonaceous material and copper through heat treatment in a hydrogen atmosphere;
A sintering step of sintering the reduced carbon-based material and copper through a spark plasma;
Based composite material.
And the ultrasonic treatment is performed for 30 minutes to 90 minutes in the dispersion step.
Wherein the mixing step is performed at a temperature of 80 to 100 ° C for 1 to 3 hours.
Wherein the drying is performed in a vacuum dry oven at a temperature of 60 to 90 ° C for 4 to 6 hours.
Wherein the reducing step is performed at a temperature of 500 to 900 DEG C for 4 to 6 hours.
Wherein the sintering step is carried out by applying a pressure of 50 to 150 MPa in a temperature range of 500 ° C to 900 ° C to proceed the sintering step.
And a ball milling step of increasing the interface adhesion between the reducing step and the sintering step.
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| CN108220950A (en) * | 2018-03-07 | 2018-06-29 | 西迪技术股份有限公司 | A kind of face coat and preparation method for hydraulic motor |
| CN110828024A (en) * | 2019-11-20 | 2020-02-21 | 北京清大际光科技发展有限公司 | Conducting wire prepared from conductive graphene coated copper and preparation method and application thereof |
| KR102340386B1 (en) * | 2020-08-26 | 2021-12-17 | 주식회사 유디 | Manufacturing method of Hydrogen functionalized Graphene-Aluminum composite casting materials |
| WO2024060687A1 (en) * | 2022-09-20 | 2024-03-28 | 中国石油化工股份有限公司 | Copper-carbon composite material, preparation method therefor and use thereof |
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| KR20110093970A (en) | 2011-07-13 | 2011-08-19 | 이재환 | Composition of nano composite |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108220950A (en) * | 2018-03-07 | 2018-06-29 | 西迪技术股份有限公司 | A kind of face coat and preparation method for hydraulic motor |
| CN110828024A (en) * | 2019-11-20 | 2020-02-21 | 北京清大际光科技发展有限公司 | Conducting wire prepared from conductive graphene coated copper and preparation method and application thereof |
| KR102340386B1 (en) * | 2020-08-26 | 2021-12-17 | 주식회사 유디 | Manufacturing method of Hydrogen functionalized Graphene-Aluminum composite casting materials |
| WO2024060687A1 (en) * | 2022-09-20 | 2024-03-28 | 中国石油化工股份有限公司 | Copper-carbon composite material, preparation method therefor and use thereof |
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